Interior Dust Research Articles

Ecological and health risk assessment of heavy metals in interior dust from college campus.

Contamination of college campus dust with heavy metals and the calculation of their ecological and health risks to the students and staff did not receive much attention except in recent years. This study aims to assess the ecological and human health risks of Cd, Cr, Cu, Pb, and Zn in interior dust of College of Science/University campus. An atomic absorption spectrophotometer was utilized to estimate the samples that were collected from 46 locations of the college campus including: classrooms, offices, and laboratories. The Pb, Cu, Cr and Zn metals in the interior dust of the College of Science pose low potential ecological risk, whereas Cd generates medium potential ecological risk. The gained results showed that the student and staff of the College are exposed to low non-cancerous health risks (HI < 1) caused by Cd, Cr, Cu, Pb, and Zn in interior dust. The total lifetime carcinogenic risks (TLCR) of Cd, Cr, and Pb are within the acceptable safe limit (10-6-10-4). The low non-carcinogenic health risks of Cd, Cr, Cu, Pb, and Zn and that the carcinogenic health risks of Cd, Cr and Pb fall within acceptable safe limits, measured in the interior dust of the campus of the College of Science, does not mean neglecting the continuous assessment of those risks.

Tetrabromobisphenol A and hexabromocyclododecanes from interior and surface dust of personal computers: implications for sources and human exposure.

Tetrabromobisphenol A (TBBPA) and hexabromocyclododecane isomers (HBCDs) are widely detected in indoor environments, but the research on the accumulation, contamination, and human exposure of TBBPA and HBCDs in electronic products dust is still limited. It is unclear whether electronic products might pose human health risk via dust ingestion and dermal absorption. In this study, the levels and distributions of TBBPA and HBCDs were investigated in the personal computer (PC) interior dust and PC surface (upper and bottom) wipes. The median concentrations of TBBPA in PC interior dust, upper, and bottom surface wipes were 168.1ng/g, 13.2ng/m2, and 15.2ng/m2, respectively. These levels were generally higher than those of HBCDs, which were 95.2ng/g, 11.7ng/m2, and 12.3ng/m2, respectively. No significant correlations were found among the PC upper and bottom surface wipes, and interior dust, indicating different sources of TBBPA and HBCDs in PC interior and surface dust. The TBBPA and HBCDs in the PC interior dust were mainly released from inner PC materials, while the sources of target compounds on the surface wipes were likely from external environments. The exposure values of two occupational populations (including PC owners and PC repair workers) to TBBPA and HBCDs were measured by PC interior dust and upper surface wipes. The results imply dust ingestion (including hand-to-mouth uptake) is the main contributor of the exposure route to TBBPA and HBCDs for both PC owners and repair workers. Compared to PC owners, PC repair workers showed the greater risk in exposure assessment, which should be paid more attention.

Validity of a portable X-ray fluorescence device for analyzing field dust wipe samples for lead

Interior dust lead loadings on floors and windowsills are reliable predictors of a child’s blood lead level and an important predictor in “clearance testing” of residences. The portable X-ray fluorescence device is an alternate technique that can provide fast, accurate, and precise results regarding the presence of dust lead hazards in residences. In this paper, we tested the comparability of the portable X-ray fluorescence device against Inductively Coupled Plasma Mass Spectrometry, using the newer lead hazard standards for dust wipe samples. Dust wipe samples (n = 109) collected from floors and interior windowsills of 13 homes were tested by means of a portable X-ray fluorescence device and subsequently analyzed for lead using Inductively Coupled Plasma Mass Spectrometry. Considering Inductively Coupled Plasma Mass Spectrometry as the “gold standard,” the portable X-ray fluorescence device produced an average false negative rate of 27.3% at the new dust lead hazard standards of 10 μg/ft2 for floors, and 100 μg/ft2 for windowsills. There were no false positive results from the portable X-ray fluorescence device at the new dust lead hazard standards. A Bland Altman analysis showed that 96.3% of the data points were within the lower and upper acceptable limits of agreement. The results of the study suggested that the portable X-ray fluorescence device has a good agreement with the Inductively Coupled Plasma Mass Spectrometry method at lower lead concentrations and is appropriate for measuring lead concentrations in field dust wipe samples from homes where lead concentrations are in a lower range.

Partial dust removal in vehicles does not mitigate human exposure to organophosphate esters

Organophosphate esters (OPEs) have been detected within car interior dust, suggesting that the indoor microenvironment of vehicles may represent a potential route of human exposure to OPEs. We recently showed that people with longer commutes are exposed to higher concentrations of tris(1,3-dichloro-2-isopropyl)phosphate (TDCIPP) – a widely used OPE – and other studies have suggested that dust removal may lead to lower exposure to chemicals. Therefore, the overall objective of this study was to determine if a decrease in interior car dust results in mitigation of personal OPE exposure. Participants (N = 49) were asked to wear silicone wristbands, and a subset of them wiped interior parts at the front of their vehicles prior to one study week (N = 25) or both study weeks (N = 11). There were no significant differences in total OPE concentrations (77.79–13,660 ng/g) nor individual OPE concentrations (0.04–4852.81 ng/g) across the different wiping groups nor in relation to participant residence ZIP codes and AC/Heater usage. These findings suggest that higher exposure to TDCIPP for participants with longer commutes may be independent of dust located on interior parts at the front of the vehicle. Therefore, our study demonstrates that there is a need for research on the potential contribution of other sources of TDCIPP exposure within car interiors.

Environmental assessment of pediatric Lead exposure in Tehran; a prospective cross-sectional study

BackgroundIngestion and inhalation are common routes of exposure for lead in humans. Developing countries still have unacceptably high rates of lead toxicity, especially in children. Studies on probable risk factors of lead poisoning in Iranian children are insufficient. In this study, we aimed to evaluate possible environmental factors in children with high blood lead concentrations living in Tehran and neighboring cities.MethodsIn a prospective cross-sectional study between March 2018 and March 2019 we followed all children referred from two pediatric gastrointestinal clinics with blood lead level (BLL) > 5 μg/dL in metropolitan Tehran to investigate possible environmental risk factors in their home. Household specimens including scratched wall paint, house floor dust, windowsill dust, tap water, and consumed spice were evaluated using atomic absorption method to detect lead concentrations. Epidemiological and environmental data collected through in-depth interviews with parents/guardians. Industrial areas were defined based on municipality maps on industrial places.ResultsThirty of 56 parents/guardians with BLL > 5 μg/dL agreed to be followed through environmental investigation. The only categorical statistically significant risk factor was a history of lead poisoning in the family and living in an industrial zone. There was a positive correlation between BLL and interior windowsills dust lead level, r = 0.46, p = 0.01. Scratched paint lead level and BLL showed a significant positive correlation, r = 0.50, p = 0.005. House floor dust lead level (median = 77.4, p < 0.001) and interior windowsill dust lead level (median = 291, p = 0.011) were both significantly higher than the environmental protection agency (EPA) standards of 40 μg/ft2, 250 μg/ft2. Interior windowsill dust lead concentrations were significantly higher in industrial areas (p = 0.026).ConclusionChildren’s playing environment should be cleaned more often to reduce dust. Moreover, specific rules may need to be implemented for paint lead concentrations and air pollution, especially in industrial areas.

Inhalation of two Prop 65-listed chemicals within vehicles may be associated with increased cancer risk

Chemicals are listed on California’s Proposition 65 (Prop 65) for their potential to cause cancer, birth defects or other reproductive harm, and certain chemicals from this list are often detected within interior vehicle dust and air. Therefore, this study examined the potential risk associated with five Prop 65-listed chemicals detected within vehicle interiors: benzene, formaldehyde, di (2-ethylhexyl) phthalate (DEHP), dibutyl phthalate (DBP), and tris(1,3-dichloro-2-propyl)phosphate (TDCIPP). Exposure estimates based on time spent within a vehicle were derived from a meta-analysis of estimated concentrations from the literature. Regulatory levels established by the California Office of Environmental Health Hazard Assessment (OEHHA) were then used to generate percent reference doses (%RfDs) for chemical-specific daily doses as well as determine the probability of risk (exceedance probability) as a function of %RfD for each chemical-specific daily dose. Based on our meta-analysis, benzene and formaldehyde were detected in vehicle interior air whereas DEHP, DBP and TDCIPP were detected in vehicle interior dust. Benzene and formaldehyde were the only two chemicals with an estimated %RfD > 100 across any of the commute times. For commute times of 20 min or longer, the %RfD was > 100 for maximum exposures based on the “maximum allowable daily level” for benzene, and for 95th-percentile exposures based on the “no significant risk level” for benzene and formaldehyde. Furthermore, the probability of exceeding 100% RfD was highest for cancer risks associated with benzene, followed by cancer risks associated with formaldehyde and the risk of reproductive and developmental toxicity associated with benzene. Lastly, within the entire state of California, the percent of commuters with a 10% probability of exceeding cancer risk associated with benzene or formaldehyde exposure was 78% and 63%, respectively. Overall, our study raises concerns about the potential risk associated with inhalation of benzene and formaldehyde for people who spend a significant amount of time in their vehicles, an issue that is especially pertinent to traffic-congested areas where people have longer commutes.

Brominated and phosphate flame retardants from interior and surface dust of personal computers: insights into sources for human dermal exposure.

It remains unclear whether internal or external sources play the more significant role in flame retardant (FR) contamination of surface dust from personal computers (PCs), which may lead to bias on dermal exposure assessment of FRs. In the present study, the occurrence and profiles of several brominated and phosphate FRs were measured in the interior dust, and the upper surface (keyboard) and bottom surface (bottom cover) wipes of PCs. BDE 209 (639 ng/g), decabromodiphenyl ethane (DBDPE, 885 ng/g), and triphenyl phosphate (TPHP, 1880 ng/g) were the most abundant chemicals in interior PC dust, while tris(2-chloroisopropyl) phosphate (TCIPP), TPHP, and DBDPE were dominant on both surfaces of PCs. No significant correlation between interior dust and both PC surfaces was observed for concentrations of most FRs except BDE 183. Different sources of FRs for interior and surface dust of PCs were further revealed by principal component analysis (PCA). FRs from external sources, rather than emission from inner PC components, are likely the main contributor for FR profiles on PC surfaces. Exposure assessment results demonstrated a minor contribution from PC dermal contact, compared with hand-to-mouth uptake, to total exposure. The applicability of surface wipes to assess dermal exposure to FR-treated products needs to be further investigated.

Lead exposure in young children over a 5-year period from urban environments using alternative exposure measures with the US EPA IEUBK model – A trial

The US Environmental Protection Agency (EPA) Integrated Exposure Uptake Biokinetic (IEUBK) model has been widely used to predict blood lead (PbB) levels in children especially around industrial sites. Exposure variables have strongly focussed on the major contribution of lead (Pb) in soil and interior dust to total intake and, in many studies, site-specific data for air, water, diet and measured PbB were not available. We have applied the IEUBK model to a comprehensive data set, including measured PbB, for 108 children monitored over a 5-year period in Sydney, New South Wales, Australia. To use this data set, we have substituted available data (with or without modification) for standard inputs as needed. For example, as an alternative measure for soil Pb concentration (μg/g), we have substituted exterior dust sweepings Pb concentration (μg/g). As alternative measures for interior dust Pb concentration (μg/g) we have used 1) 30-day cumulative petri dish deposition data (PDD) (as µg Pb/m2/30days), or 2) hand wipe data (as μg Pb/hand). For comparison, simulations were also undertaken with estimates of dust Pb concentration derived from a prior regression of dust Pb concentration (μg/g) on dust Pb loading (μg/ft2) as concentration is the unit specified for the Model. Simulations for each subject using observed data aggregated over the 5-year interval of the study, the most usual application of the IEUBK model, showed using Wilcoxon tests that there was a significant difference between the observed values and the values predicted by the Model containing soil with hand wipes (p < 0.001), and soil and PDD (p = 0.026) but not those for the other two sets of predictors, based on sweepings and PDD or sweepings and wipes. Overall, simulations of the Model using alternative exposure measures of petri dish dust (and possibly hand wipes) instead of vacuum cleaner dust and dust sweepings instead of soil provide predicted PbB which are generally consistent with each other and observed values. The predicted geometric mean PbBs were 2.17 ( ± 1.24) μg/dL for soil with PDD, 1.95 ( ± 1.17) μg/dL for soil with hand wipes, 2.36 ( ± 1.75) μg/dL for sweepings with PDD, and 2.15 ( ± 1.69) for sweepings with hand wipes. These results are in good agreement with the observed geometric mean PbB of 2.46 ( ± 0.99) μg/dL. In contrast to all other IEUBK model studies to our knowledge, we have stratified the data over the age ranges from 1 to 5 years. The median of the predicted values was lower than that for the observed values for every combination of age and set of measures; in some cases, the difference was statistically significant. The differences between observed and predicted PbB tended to be greatest for the soil plus wipes measure and for the oldest age group. Use of ‘default dust’ values calculated from the site-specific soil values, a common application of the IEUBK model, results in predicted PbB about 22% (range 0 to 52%) higher than those from soil with PDD data sets. Geometric mean contributions estimated from the Model to total Pb intake for a child aged 1–2 years was 0.09% for air, 42% for diet, 5.3% for water and 42% for soil and dust. Our results indicate that it is feasible to use alternative measures of soil and dust exposure to provide reliable predictions of PbB in urban environments.

Vibro-acoustic model of an active aircraft cabin window

This paper presents modeling and design of an active structural acoustic control (ASAC) system for controlling the low frequency sound field transmitted through an aircraft cabin window. The system uses stacked piezoelectric elements arranged in a manner to generate out-of-plane actuation point forces acting on the window panel boundaries. A theoretical vibro-acoustic model for an active quadruple-panel system is developed to characterize the dynamic behavior of the system and achieve a good understanding of the active control performance and the physical phenomena of the sound transmission loss (STL) characteristics. The quadruple-panel system represents the passenger window design used in some classes of modern aircraft with an exterior double pane of Plexiglas, an interior dust cover pane and a glazed dimmable pane, all separated by thin air cavities. The STL characteristics of identical pane window configurations with different piezoelectric actuator sets are analyzed. A parametric study describes the influence of important active parameters, such as the input voltage, number and location of the actuator elements, on the STL is investigated. In addition, a mathematical model for obtaining the optimal input voltage is developed to improve the acoustic attenuation capability of the control system. In general, the achieved results indicate that the proposed ASAC design offers a considerable improvement in the passive sound loss performance of cabin window design without significant effects, such as weight increase, on the original design. Also, the results show that the acoustic control of the active model with piezoelectric actuators bonded to the dust cover pane generates high structural vibrations in the radiating panel (dust cover) and an increase in sound power radiation. High active acoustic attenuation can be achieved by designing the ASAC system to apply active control forces on the inner Plexiglas panel or dimmable panel by installing the actuators on the boundaries of one of the two panels. In some cases, increasing the actuator numbers in the structure advances the active control performance by controlling more structural modes; however, this decreases the STL of the passive control system because of the increase in structure-borne sound transmission paths of the stiffer piezoelectric actuators.

Legacy lead arsenate soil contamination at childcare centers in the Yakima Valley, Central Washington, USA

BackgroundFrom the early 1900s to the 1950s, Yakima Valley orchards were commonly treated with lead arsenate (LA) insecticides. Lead (Pb) and arsenic (As) soil contamination has been identified on former orchard lands throughout Central Washington and pose a threat to human health and the environment. ObjectivesThe levels of Pb and As in soil and interior dust at participating childcare centers in the Upper Yakima Valley (Yakima County), Washington were sampled to explore exposure potential for young children. MethodsChildcare center soils were collected from two soil depths, homogenized, and analyzed in bulk by a field-portable X-ray fluorescence spectrometer (XRF). Interior dust wipes samples were collected from at least two locations in each facility. All soil samples >250 mg/kg Pb and/or >20 As mg/kg were sieved to 250 μm, tested by XRF a second time, and analyzed via acid digestion and inductively coupled plasma mass spectrometry (ICP-MS) analysis. ResultsBulk and sieved XRF results, as well as ICP-MS to XRF results were strongly correlated. Maximum Pb and As XRF results indicated that 4 (21%) and 8 (42%) of the 19 childcare centers surveyed exceeded the regulatory standard for Pb and As, respectively. Historic land use was significantly associated with elevated Pb and As levels. Interior dust loadings were below United States Environmental Protection Agency (EPA) guidelines. ConclusionsChildcare centers are areas of intensive use for children and when coupled with potential residential exposure in their homes, the total daily exposure is a potential hazard to children.

The Remnant of Supernova 1987A

Although it has faded by a factor of ∼107, SN 1987A is still bright enough to be observed in almost every band of the electromagnetic spectrum. Today, the bolometric luminosity of the debris is dominated by a far-infrared (∼200μm) continuum from ∼0.5 M⊙ of dust grains in the interior debris. The dust is heated by UV, optical, and near-infrared (NIR) emission resulting from radioactive energy deposition by 44Ti. The optical light of the supernova debris is now dominated by illumination of the debris by X-rays resulting from the impact of the outer supernova envelope with an equatorial ring (ER) of gas that was expelled some 20,000 years before the supernova explosion. X-ray and optical observations trace a complex system of shocks resulting from this impact, whereas radio observations trace synchrotron radiation from relativistic electrons accelerated by these shocks. The luminosity of the remnant is dominated by an NIR (∼20μm) continuum from dust grains in the ER heated by collisions with ions in the X-ray emitting gas. With the Atacama Large Millimeter Array (ALMA), we can observe the interior debris at millimeter/submillimeter wavelengths, which are not absorbed by the interior dust. The ALMA observations reveal bright emission lines from rotational transitions of CO and SiO lines that provide a new window into the interior structure of the supernova debris. Optical, NIR, and ALMA observations all indicate strongly asymmetric ejecta. Intensive searches have failed to yield any evidence for the compact object expected to reside at the center of the remnant. The current upper limit to the luminosity of such an object is a few tens of solar luminosities.

Polybrominated diphenyl ethers in indoor air during waste TV recycling process

Recycling process for waste TV sets mainly consists of dismantling, printed wiring board (PWB) heating, PWB recycling, and plastic crushing in formal recycling plant. Polybrominated diphenyl ethers (PBDEs) contained in waste TV sets are released to indoor air. Air samples at 4 different workshops were collected to measure the PBDEs concentrations in both gaseous and particulate phases. The mean concentrations of ∑PBDEs in indoor air were in the range of 6780–2,280,000pg/m3. The highest concentration in gaseous phase (291,000pg/m3) was detected in the PWB heating workshop. The ∑12PBDEs concentrations in PM2.5 and PM10 at the 4 workshops ranged in 6.8–6670μg/g and 32.6–6790μg/g, respectively. The gas-particle partitioning of PBDEs was disrupted as PBDEs were continuously released during the recycling processes. Occupational exposure assessment showed that only the exposure concentration of BDE-47 (0.118μg/kg/day) through inhalation in the PWB heating workshop for workers without facemask exceeded the reference dose (0.1μg/kg/day), posing a health hazard to workers. All the results demonstrated that recycling of TV sets was an important source of PBDEs emission, and PBDEs emission pollution was related to the composition of TV sets, interior dust, and recycling process.

Identification of lead sources in residential environments: Sydney Australia

Interior and exterior dust, soil and paint were analysed at five brick urban Sydney homes over 15 months to evaluate temporal variations and discriminate sources of lead (Pb) exposure. Exterior dust gauge Pb loading rates (μg/m2/28 days), interior vacuum dust Pb concentrations (mg/kg) and interior petri-dish Pb loading rates (μg/m2/28 days), were correlated positively with soil Pb concentrations. Exterior dust gauge Pb loading rates and interior vacuum dust Pb concentrations peaked in the summer. Lead isotope and Pb speciation (XAS) were analysed in soil and vacuum dust samples from three of the five houses that had elevated Pb concentrations. Results show that the source of interior dust lead was primarily from soil in two of the three houses and from soil and Pb paint in the third home. IEUBK child blood Pb modelling predicts that children's blood Pb levels could exceed 5 μg/dL in two of the five houses.

Particle size fractionation and human exposure of polybrominated diphenyl ethers in indoor dust from Chicago

The objective of this study was to investigate the concentration level, the mass distribution based on dust particle size, and the associated human exposure of polybrominated diphenyl ethers (PBDEs) in indoor dust. The total concentration of 13 PBDEs Σ13(BDEs) was found to be 500–6,944 ng/g in indoor dusts, 4,000 ng/g in car interior dust, 260–300 ng/g in outdoor ambient air particles, 30 ng/g in carpet fibers, and as high as 0.5% in carpet padding. Selected dust samples were fractionated based on particle size, and over 80% of the Σ13BDEs were associated with particles < 150 μm in diameter. Mass ratios of BDE206/BDE209 are higher in both indoor and outdoor samples than in commercial deca products; and mass ratio BDE47/BDEs(85+99+100) was much higher in outdoor than in indoor samples. Using EPA software ProUCL, the exposure of Americans to PBDEs via hand-to-mouth transfer of house dust was estimated under the central tendency exposure and reasonable maximum exposure scenarios. The results suggest that ingestion of PBDE-laden house dust via hand-to-mouth contact is likely a significant exposure pathway, especially for children.

Simulation of flow-field interior dust removal system at a transit point and the overall technology of dust removal

In order to make a reasonable dry-type dust removal plan of the coal transit spot in a coal washery, it is essential to install the dust removal fan and guide chute. By means of the numerical simulation, the pollution mechanism at a transit point and the flow-field interior dust removal system had been analyzed. The result shows that the dust pollution at transit spot is mainly cased by the joint effort of induced airflow and shock-wave. With the appropriate dust removal fan and the guide chute, will effectively eliminate the positive pressure by gave rise to by the impact of falling coal, also avoid the secondary pollution.

Selecting a Lead Hazard Control Strategy Based on Dust Lead Loading and Housing Condition: I. Methods and Results

A methodology was developed to classify housing conditions and interior dust lead loadings, using them to predict the relative effectiveness of different lead-based paint hazard control interventions. A companion article in this issue describes how the methodology can be applied. Data from the National Evaluation of the HUD Lead Hazard Control Grant Program, which covered more than 2800 homes in 11 U.S. states, were used. Half these homes (1417) met the study's inclusion criteria. Interior interventions ranged from professional cleaning with spot painting to lead abatement on windows, and enclosure, encapsulation, or removal of other leaded building components. Modeling was used to develop a visual Housing Assessment Tool (HAT), which was then used to predict relative intervention effectiveness for a range of intervention intensities and baseline floor and windowsill dust lead loadings in occupied dwellings. More than 117,000 potential HATs were considered. To be deemed successful, potential HATs were required to meet these criteria: (1) the effect of interior strategy had to differ for HAT ratings of good vs. poor building condition and/or baseline dust lead loadings; (2) the HAT rating had to be a predictor of one year post-intervention loadings; (3) interior intervention strategy had to be a predictor of one-year loadings; (4) higher baseline loadings could not be associated with lower one-year loadings; and (5) neither exterior work nor site/soil work could result in higher predicted one-year loadings for either HAT rating. Of the 1299 HATs that met these criteria, one was selected because it had the most significant differences between strategy intensities when floors and sills were considered together. For the selected HAT, site/soil work was a predictor of one-year loadings for floors (p = 0.009) but not for sills (p = 0.424). Hazard control work on the building exterior was a predictor of both sill and floor one-year loadings (p = 0.004 and p < 0.001, respectively). Regardless of the type of interior intervention strategy, interior work was a predictor of both floor and sill one-year loadings (each p ≤ 0.001).

Quantification of the risk associated with high levels of mercury pollution at Temirtau, Kazakhstan

This research aims to establish the risks of human exposure to high environmental mercury levels, based on a quantitative risk modelling approach. The study site was located on the River Nura in central Kazakhstan. From the 1950s until its closure in the mid 1990s, an acetaldehyde production plant located in the industrial city of Temirtau released Hg-containing wastewater into the river. River sediments are highly contaminated with Hg up to a distance of 25 km and beyond. In additon, a local power station released an estimated 6 million tonnes of fly-ash into the water and the Hg has become quite tightly associated with the ash deposits. River water, fish and agricultural land in the floodplain are also contaminated with mercury, yet the risks posed to the local population have not been evaluated to date. In June and July 2005, we took samples of soil, interior and exterior dust, drinking water, and food from individual households, communal areas and markets. Additionally, water and sediment samples and fish were taken from the river. Interviews were conducted with householders to establish their age and body weight, general living conditions and sources of irrigation and drinking water. A food frequency questionnaire (FFQ) was designed to investigate the frequencies of consumption of several common regional food items, including fish from the river and/or local market. Human hair samples were also collected to estimate the Hg bioburden and to enable the validity of the modelling approach to be established. The paper expands on the main pathways of contamination and looks at linkages between exposure pathways and Hg concentrations found in peoples’ hair. Uncertainties inherent in risk analysis as well as their influence on the relative importance of different exposure routes are also discussed. The analysis showed that the risk was less than originally expected, the most likely cause being the ability of the fly-ash to reduce the bioavailability of the mercury.

A survey of spatially distributed exterior dust lead loadings in New York City

This work documents ambient lead dust deposition values (lead loading) for the boroughs of New York City in 2003–2004. Currently, no regulatory standards exist for exterior concentrations of lead in settled dust. This is in contrast to the clearance and risk assessment standards that exist for interior residential dust. The reported potential for neurobehavioral toxicity and adverse cognitive development in children due to lead exposure prompts public health concerns about undocumented lead sources. Such sources may include settled dust of outdoor origin. Dust sampling throughout the five boroughs of NYC was done from the top horizontal portion of pedestrian traffic control signals (PTCS) at selected street intersections along main thoroughfares. The data ( n = 214 samples) show that lead in dust varies within each borough with Brooklyn having the highest median concentration (730 μg/ft 2), followed in descending order by Staten Island (452 μg/ft 2), the Bronx (382 μg/ft 2), Queens (198 μg/ft 2) and finally, Manhattan (175 μg/ft 2). When compared to the HUD/EPA indoor lead in dust standard of 40 μg/ft 2, our data show that this value is exceeded in 86% of the samples taken. An effort was made to determine the source of the lead in the dust atop of the PTCS. The lead in the dust and the yellow signage paint (which contains lead) were compared using isotopic ratio analysis. Results showed that the lead-based paint chip samples from intact signage did not isotopically match the dust wipe samples taken from the same surface. We know that exterior dust containing lead contributes to interior dust lead loading. Therefore, settled leaded dust in the outdoor environment poses a risk for lead exposure to children living in urban areas, namely, areas with elevated childhood blood lead levels and background lead dust levels from a variety of unidentified sources.

Residential Dust Lead Loading Immediately After Intervention in the HUD Lead Hazard Control Grant Program

At the conclusion of most lead hazard control interventions in federally assisted housing built before 1978, a certified clearance examiner must verify that the lead hazard control work was completed as specified and that the area is safe for residents, a process referred to as clearance. This study explores the experience of 14 grantees participating in the Evaluation of the HUD Lead-Based Paint Hazard Control Grant Program in passing clearance. The study also considers how preintervention lead levels (interior dust and paint), building condition/characteristics, and the scope of work influenced initial clearance dust lead loadings and clearance rates. At the initial clearance inspection, 80% of the 2682 dwellings achieved grantee-specific clearance standards on windowsills, window troughs (500 μ g/ft 2 and 800 μ g/ft 2 , respectively), and floors (80, 100, or 200 μ g/ft 2 depending on state/local regulations at the dates of clearance in the mid-1990s), with individual grantee success rates ranging from 63 to 100%. Dwellings that failed initial clearance required an average of 1.13 retests to clear. The high level of success at clearance demonstrates that following methods for work site containment, lead hazard control, and cleaning similar to those recommended in the HUD Guidelines for the Evaluation and Control of Lead-Based Paint in Housing is effective. The most common lead hazard control intervention was window abatement accompanied by the repair or abatement of all other deteriorated lead-based paint (56% of dwellings). An additional 5% of dwellings were fully abated, 29% had lower intensity interventions. Interventions including window replacement are recommended to reduce dust lead loading on windowsills and troughs at clearance, but lower level interventions such as full paint stabilization are just as good at reducing floor dust lead loadings. Whatever lead hazard control activities are selected, the condition of the surfaces of interest should be in good condition at clearance.

Imputation of Data Values That are Less Than a Detection Limit

Results of the analyses of occupational and environmental samples are frequently reported as “less than a specified value,” a practice followed by many analytical laboratories. A left-censored distribution occurs when analytical laboratories do not report results that fall below their limits of detection or quantification. Approximately 37% of the household interior dust lead loadings collected in a large-scale, multisite, longitudinal study of lead-based paint hazard controls were reported to be below the “method detection limit.” These unreported values are unusable in any statistical analysis of the data and must be replaced by a valid dust lead loading estimate, a process called data imputation. This investigation tested how well data imputed using a newly formulated procedure for estimating the data below the method detection limit were correlated with dust lead loadings reported by the participating laboratories after special request. These results were also compared with those obtained by imputing the minimum detectable level by the square root of 2. Imputation of the low lead loadings was accomplished by substituting the value associated with the median percentile below each laboratory's method detection limit. A correlation of r = 0.50 was calculated between the predicted and reported dust lead loadings, with only slight bias (2.9%) in the predicted values. An alternative imputation procedure that used the predicted value from structural equation models fit to the noncensored dust lead loadings performed about as well, although the predictions had to be “centered” to correspond to the censored data. An estimator that combined both of these imputation procedures only slightly improved the correlation between the predicted and laboratory values (r = 0.51). These results support the use of the new procedure rather than the commonly used imputed values of the method detection limit divided by 2 or by the square root of 2. Imputing values based on either of these common approaches may result in much more biased predictions for the censored data; in the case of these data, the dust lead loadings were overestimated by 348%. The results also suggest that analytical laboratories should provide a numerical result for all analyzed samples, with a “flag” of those values below their detection limit, since these results may be more accurate than any imputed value, particularly those provided by the commonly used method of dividing the minimum detection limit by the square root of 2.