Interim Sediment Quality Guidelines Research Articles

Assessment of potentially toxic element contamination in wetland sediments of Boracay Island, Philippines

Boracay Island, Philippines, famous for its white sand beaches, has wetlands increasingly threatened by human activities. This study evaluated the ecological state of Boracay Island's wetlands and assessed the consequences of anthropogenic activities on sediment quality. Results showed that sediments from Wetland Nos. 3 and 4 have higher concentrations of potentially toxic elements (PTEs) than Wetland No. 1. Comparative analysis with other Southeast Asian wetlands revealed that Boracay's sediments contain the highest average values of As, Cd, Cu, Ni, Zn. Enrichment factor values suggest that the moderate enrichment of Cd, Cr, Cu, Mo, Pb, and Zn in the wetland sediments can be attributed to anthropogenic activities on the island. Elevated concentrations of Cr, Cu, and Zn above interim sediment quality guidelines indicate occasional adverse biological effects on aquatic biota. These findings provide a crucial baseline for future pollution monitoring and highlight the need for ongoing conservation efforts in Boracay's wetlands.

Polychlorinated biphenyls (PCBs) in the Persian Gulf and Gulf of Oman: baseline report on occurrence, distribution, and ecological risk assessment.

In the present study, 18 polychlorinated biphenyl (PCB) compounds were measured in marine sediments collected from 49 offshore stations in the Persian Gulf and the Gulf of Oman in 2019. After the last oceanographic cruise in 2006, no study has been performed on the offshore sediments of this region, and this is the first study on the PCBs in this area. The total amount of PCB compounds in the sediment samples ranged from 74.38ngkg-1 (near Abu Musa Island) to 1212.98ngkg-1 (near Siri and Kish Island). The maximum and minimum values of the individual detected PCB compounds were 175.88ngkg-1 (PCB52) and 2.09ngkg-1 (PCB156), respectively. The levels of total PCBs detected in sediments were lower than the Canadian interim sediment quality guideline value of 21500ngkg-1 for marine sediments. The sedimentary mass inventories for Σ18PCBs were 0.6 and 0.2 mt for the Persian Gulf and Gulf of Oman, respectively.

Trends in sedimentary Cladocera and metal(loid)s from Williams Lake (Washington, USA) track ∼125 years of trans-boundary contamination from smelter emissions in the upper Columbia River valley

The lead‑zinc smelter at Trail (British Columbia, Canada) has operated continuously for ∼125 years, with long-standing concerns that transboundary metal(loid) and sulphur emissions have contaminated water bodies in both western Canada and Washington (WA), USA. To assess aquatic ecosystems affected by over a century of industrial contamination requires an understanding of pre-smelting conditions. Here, we use a dated sediment core from Williams Lake (WA), downwind of both the Trail and the short-lived LeRoi (Northport, WA) smelters, to track regional contaminant history and other environmental stressors. Specifically, we examine a selection of chemical elements, cladoceran assemblages, visible range spectroscopy-inferred chlorophyll a (VRS-Chl a) and visible near-infrared spectroscopy-inferred lake-water total organic carbon (VNIRS-TOC). Sedimentary proxies recorded the onset of smelting in 1896 CE, peak periods of aerial emissions in the early to mid-20th century, and the history of emission controls. With a few exceptions, sedimentary metal(loid)s exceeded Canadian Interim Sediment Quality Guidelines during the height of the smelting era and have declined substantially since ca. 2000 CE. The loss of metal-sensitive Cladocera and declines in primary production (VRS-Chl a) at the onset of the regional smelting era indicate a strong biological response to airborne industrial contamination. The largest cladoceran change in the sediment record was concurrent with accelerated mitigation efforts at the Trail facilities following the 1960s; however, this compositional shift was between ecologically similar daphniid taxa. Steep declines in VNIRS-TOC concentrations during the period of peak emissions at Trail suggested an increase in sulphur deposition on the landscape that reduced terrestrial carbon supply. However, the persistence of calcium-sensitive daphniids throughout the record indicates that alkaline Williams Lake had not acidified. Current cladoceran assemblages remain substantially distinct from pre-industrial communities, demonstrating how paleoecotoxicological approaches can be used to track the effects of multiple stressors in a temporally appropriate context.

Accumulation of Cd and Pb in sediments and Asian swamp eels (Monopterus albus) from downstream area of Cisadane River, Indonesia.

This study examined the presence of two heavy metals (Cd and Pb) in the sediments and Asian swamp eels (Monopterus albus) in the downstream area of Cisadane River. The average concentrations of Cd and Pb in the sediments from all sampling locations were 0.594 ± 0.230mg/kg and 34.677 ± 24.406mg/kg, respectively. These concentrations were above the natural background concentration and the recommended value of interim sediment quality guidelines (ISQG), suggesting an enrichment process and potential ecological risk of studied metals to the ecosystem of Cisadane River. The increase in contamination within this region may be attributed to point sources such as landfill areas, as well as the industrial and agricultural land activities in surrounding area, and experienced an increasing level leading towards the estuary of Cisadane River. Meanwhile, the average concentrations of Cd and Pb in the eels from all sampling locations were 0.775 ± 0.528μg/g and 28.940 ± 12.921μg/g, respectively. This study also discovered that gill tissues contained higher levels of Cd and Pb than the digestive organ and flesh of Asian swamp eels. These concentrations were higher than Indonesian and international standards, suggesting a potential human health risk and therefore the needs of limitations in the consumption of the eels. Based on the human health risk assessment, the eels from the downstream of Cisadane River are still considered safe to be consumed as long as they comply with the specified maximum consumption limits.

Identifying the key sources of metal (loid) deposition to remote Tasmanian lakes: is legacy mining a problem?

Reports have shown that even remote lakes have been negatively affected by anthropogenic activities. This study used metal concentrations and enrichment factors to comprehensively determine key metal sources and identify potential impacts of recent anthropogenic activity in remote Central Highland Tasmanian (Australia) lakes. Metal concentrations (Al, As, Cd, Cu, Fe, Pb, and Zn) in these lakes remain below Australian interim sediment quality guidelines but have been slowly increasing since the start of the twentieth century. This increase is likely related to increasing organic matter content, rather than any direct, increased input of metals. The largest anthropogenic impact to these systems was damming, which typically led to an increase in organic matter content either directly, by the trapping of particles and nutrients, or indirectly, by stimulating primary production in the lake. This increased organic matter content, in turn, increased the retention of metals, manifesting as an increase to measured metal concentrations. Minor impacts are the historical use of lead shot, leaded petrol, and industrial processes, which may have contributed to the higher Pb enrichment, compared to the other studied metals, in these lakes. Despite recent concerns of metal contamination in the Tasmanian Wilderness World Heritage Area from distant mining activities, there is no strong evidence in this study indicating that lakes in the Central Highlands (a similar distance away) have been impacted by long-distance atmospheric deposition. This is likely related to the decreased rainfall, and thus decreased rates of wet deposition of aerosols in the east of Tasmania, compared to that of the west and in the Tasmanian Wilderness World Heritage Area.

Potential ecological risk from heavy metals in surface sediment of lotic systems in central region Peru

High Andean rivers are fragile ecosystems in the face of various threats, including heavy metal contamination. The objective of this study was to evaluate the potential ecological risk of heavy metals in surface sediment of lotic systems in the central region of Peru. Composite samples of surface sediments were collected from the Chía and Miraflores rivers and the concentrations of heavy metals were determined. The ecological risk analysis was carried out based on the contamination indexes and confirmed by the modified degree of contamination (mCd). The concentration of heavy metals in the sediment of the Chía river was in the following descending order: Fe > Mn > Zn > V > Pb > Cr > Ni > Cu > Mo > Hg, y en el río Miraflores fue: Fe > Mn > Zn > Ni > V > Cr > Cu > Pb > Hg > Mo. The mean concentration of Cu, Cr, Fe, Mn, Mo, Ni, Pb, and V in the sediment samples in both rivers did not exceed the threshold values of the continental crust concentration, nor the interim sediment quality guidelines of the Canadian Council of Ministers of the Environment. However, the mean concentration of Hg exceeded the guideline values in the Miraflores river and the likely effect (0.7 mg.kg−1) adverse effects. The values of the enrichment factor (EF), contamination factor (CF), geoaccumulation index (Igeo), and pollution load index (PLI) indicated low contamination in the sediments of the rivers studied, being confirmed by the modified degree of contamination (mCd). Finally, the risk assessment showed that heavy metals in the sediments presented a low potential ecological risk.

Historical gold mining increased metal(loid) concentrations in lake sediments from Nova Scotia, Canada

Historical gold mining operations between the 1860s and 1940s have left substantial quantities of arsenic- and mercury-rich tailings near abandoned mines in remote and urban areas of Nova Scotia, Canada. Large amounts of materials from the tailings have entered the surface waters of downstream aquatic ecosystems at concentrations that present a risk to benthos. We used paleolimnological approaches to examine long-term trends in sedimentary metal(loid) concentrations, assess potential sediment toxicity, and determine if geochemical recovery has occurred at four lakes located downstream of three productive gold-mining districts. During the historical mining era, sedimentary total arsenic and mercury concentrations and enrichment factors increased substantially at all downstream lakes that received inputs from tailings. Similarly, chromium, lead, and zinc concentrations increased in the sediments after mining activities began and the urbanization that followed. The calculated probable effects of concentration quotients (PEC-Qs) for sediments exceeded the probable biological effects threshold (PEC-Q > 2) during the mining era. Although sedimentary metal(loid) concentrations have decreased for most elements in recent sediments, relatively higher PEC-Q and continued exceedance of Canadian Interim Sediment Quality Guidelines suggest that complete geochemical recovery has not occurred. It is likely that surface runoff from tailing fields, urbanization, and climate-mediated changes are impacting geochemical recovery trajectories.

Mercury deposition to lake sediments near historic gold mines in northern Canada

Mercury (Hg) contamination in aquatic systems can lead to adverse human and environmental health outcomes. Yellowknife, a city in Canada’s Northwest Territories, is a historic mining community, with two large gold mines (Giant Mine and Con Mine) that used Hg amalgamation methods to extract gold between ∼1938 and 1960. We analyzed dated sediment cores from 20 small lakes to investigate the spatial and temporal Hg deposition patterns within 50 km of Giant Mine. Breakpoint analysis of the within-lake z-score normalized anthropogenic Hg flux indicates two significant time periods of changing emission rates. The first is a significant increase in Hg deposition rate (∼1925) during the time of gold exploration in the region and onset of Hg amalgamation (1938) and the second is a significant decrease in deposition rate that begins around the time of the cessation of Hg amalgamation at Giant Mine (∼1959). Sediment Hg concentrations exceeded the Canadian Council for Ministers of the Environment Interim Sediment Quality Guideline (ISQG) for Hg (0.17 mg/kg dw) in 55% of the lakes (n = 11) during mining (1948–1999). All lakes within 5 km of the Giant Mine roaster stack exceeded CCME ISQG during mining (n = 8), with a 4-fold increase in total Hg concentration observed during mining at these near-field (<5 km from stack) sites. We observed evidence of enriched Hg in near-field, mid-field, and far-field sites. The elevated sedimentary Hg concentrations during mining in near-field sites would have posed a hazard to human and wildlife health during the height of emissions, however the significant decrease in Hg concentrations since the closure of mines in the region demonstrate the potential for recovery in these aquatic ecosystems.

Spatial distribution and seasonal variation of pesticide residues in the sediment, seawater, and edible seaweeds: Environmental and human health risk assessment

This study evaluates the distribution of pesticide residues (PRs) and assesses the ecological and human health risks posed by them from seawater, sediment and edible seaweeds in the Gulf of Mannar. Results showed that hexachlorocyclohexane, heptachlor, aldrin, endrin and endosulfan were the predominant PRs. The maximum concentration of PRs was observed in the monsoon and post-monsoon seasons. Their concentrations in sediment exceeded interim sediment quality guidelines, indicating significant risks to benthic organisms. Except for endrin, the presence of other organochlorine pesticides (OCPs) was below the maximum residual limit. Human health risk assessment revealed that the estimated daily intake of PRs through seaweeds was below the acceptable daily intake. The hazard quotient and hazard ratio were <1, implying that the study seaweeds do not pose significant health risks. The presence of endrin in edible seaweeds, however, indicates safety concerns for consumers and the continued use of banned OCPs in agriculture.

Temporal and Spatial Trends in Benthic Infauna and Potential Drivers, in a Highly Tidal Estuary in Atlantic Canada

Infaunal invertebrate communities of coastal marine sediments are often impacted by human activities, particularly in harbours and estuaries. However, while many studies have attempted to identify the key factors affecting benthic infauna, few have done so for highly energetic tidal estuaries. Samples were collected over a decade (2011–2020) from a series of reference sites in Saint John Harbour (45.25° N, 66.05° W), a highly tidal estuary in the Bay of Fundy, Canada. These data were used to examine spatial and temporal trends in infaunal invertebrate communities and sediment properties and to determine the extent to which the biological patterns were driven by measured physical and chemical variables. There were substantial differences among sites in infaunal invertebrate abundance (median ranging from 688 to 13,700 individuals per square meter), infaunal species richness (median ranging from 8 to 22), and Shannon diversity (median ranging from 1.26 to 2.34); multivariate analysis also revealed variation in species composition among sites. Sediment contaminant concentrations also varied among sites, but differences tended to be smaller (e.g. median chromium concentrations ranging from 21.6 to 27.6 mg/kg). Sample contaminant concentrations were all below probable effect levels, and almost all below threshold effect levels (Canadian interim sediment quality guidelines), but relationships with biological data were still detectable. However, physical variables (depth, sediment characteristics) were better predictors of biological variables and community composition. These results confirm the importance of physical factors in shaping infaunal communities in soft-sediment habitats in tidally influenced coastal waters.

RISK ASSESSMENT, LEVELS, SPECIATION AND SEASONAL VARIATION OF HEAVY METALS (Cd and Cu) IN WATER AND PARTICLE SIZES OF SEDIMENTS FROM HUNKI OX-BOW LAKE, AWE LGA, NASARAWA STATE-NIGERIA

This research aimed at assessment of the levels, speciation, risk assessment indices and seasonal variation of heavy metals (Cd and Cu) in water and sediments from Hunki Ox-bow Lake in Awe L.G.A of Nasarawa State, using Atomic Absorption Spectrophotometer (AAS), during the dry and wet seasons. The mean concentration of Cd in water samples of both dry and wet seasons was higher than that of Cu, but Cu was higher than Cd on the whole (raw) sediment samples. The baseline levels of Cd and Cu in water samples (mg/L) were as follows: Cd (0.354) and Cu (0.014), which revealed that Cd level in water was higher than the WHO Guidelines for Drinking Water Quality. The baseline levels of Cd and Cu in sediment samples (mg/kg) were as follows: Cd (7.149) and Cu (8.363) which showed that Cd and Cu were lower than Interim Sediment Quality Guidelines – High of (Cd: 10 and Cu: 270 mg/kg). However, Cd level from sediment was higher than Interim Sediment Quality Guidelines – Low of 1.5 mg/kg but that of Cu was lower (65 mg/kg). Results of the Tessier five-step sequential extraction procedure indicated that Cd was more in the first four steps of the sequential extraction (non-residual) which accounted for 84.64 - 94.52 % in both seasons. Copper dominated more of the organic matter fraction of the sediments (48.17 – 85.54 %) for both dry and wet seasons. The mean of Bioavailability Index (BI) for wet season was relatively higher than that of dry season. The mean values of Mobility Factor (MF) revealed that Cd had higher values than Cu irrespective of seasons. This indicated that Cd was more mobilizable and bioavailable to this aquatic ecosystem compared to Cu. The geo-accumulation Index (I-geo) values of Cd showed practically unpolluted (sites 1, 2 and 5 of dry season), moderately polluted (sites 3 and 4 of dry season), heavily polluted (sites 1, 2, 4 and 5 of wet season) to very heavily polluted (site 3of wet season). The I-geo values of Cu indicated practically unpolluted. In dry season generally, Contamination Factor (Cf) values for Cd were all moderate in dry season. The Cf values of Cd indicated very high contamination factor for wet season, while that of Cu was low in both seasons. In both seasons, the ecological risk index (Er) of Cd in dry season had low to moderate ecological risk, and high to serious ecological risk in wet season. The Er values of Cu were low. This study revealed that: sediments and water samples of the dry season had lower concentration of Cd and Cu than in wet season; concentrations of Cd and Cu from sediments were more of manmade sources rather than natural sources and most ecological risk indices evaluated revealed that Cd had greater ecological risk.&#x0D;

Occurrence and Source Identification of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans and Polychlorinated Biphenyls in Surface Sediments from Liangshui River in Beijing, China

Polychlorinated dibenzo-p-dioxins and dibenzofurans and polychlorinated biphenyls were measured in the surface sediments of Liangshui River, the second largest drainage river in Beijing, China. The sum concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans and polychlorinated biphenyls ranged from 3.5 to 3019 (mean value: 184) pg g-1 dry weight and from 319 to 5949 (mean value: 1958) pg g-1 dry weight, and the corresponding World Health Organization toxic equivalent quantity values were 0.0011-5.1 pg TEQ g-1 dry weight and 0.0074-1.4 pg TEQ g-1 dry weight, respectively. The spatial distributions of polychlorinated dibenzo-p-dioxins and dibenzofurans and polychlorinated biphenyls showed increasing trends from urban area and development area to suburb. Principal component analysis revealed that polychlorinated dibenzo-p-dioxins and dibenzofurans contamination in the sediments may originate from pentachlorophenol and sodium pentachlorophenate and municipal solid waste incineration. Regarding polychlorinated biphenyls, the steel industry, combustion processes and usage of some commercial polychlorinated biphenyl products were identified as the major sources. The emission from a former steel plant could be the main contributor to polychlorinated biphenyls in urban areas. The mean value of the total toxic equivalent quantities in the sediment samples exceeded the Canadian interim sediment quality guidelines. Long-term wastewater irrigation increases the load of sediment-bound pollutants in agricultural soil and may pose potential ecological risks to crops and human health.

Baseline levels and characterization of hydrocarbons in surface marine sediments along the transportation corridor in Hudson Bay: A multivariate analysis of n-alkanes, PAHs and biomarkers

Hudson Bay is a small arctic inland shelf sea which receives large amounts of freshwater from riverine discharges, with marine flow from the north and the Atlantic. A warming climate has resulted in an expanded open water season which will result in an increase in shipping of fuel oil and petroleum to communities and mines on the western shore, increasing the risk of hydrocarbon releases. To evaluate the status of hydrocarbons, surface sediments were collected at 34 locations in the transportation route and offshore and analysed for several types of hydrocarbons. Total hydrocarbons varied by over 25 times between sites, reaching a maximum of 1116 μg/g OC (organic carbon basis) in Hudson Strait due to low molecular weight n-alkanes from marine primary production. The gross mean for all sites was 344 μg/g OC (GSD = 173–682), roughly equivalent to other remote sites in the Canadian Arctic with no known local hydrocarbon source. n-alkanes accounted for >90 % of residues. Diagnostic ratios (e.g., Carbon Preference Index (CPI), Odd-Even Predominance (OEP)) indicated mixed sources of n-alkanes, likely due to the input from vascular plants and ombrotrophic peat in northern and western watersheds, and primary production within the Bay. The elevated proportion of high molecular weight n-alkanes at deep water sites is consistent with lotic particulate organic matter deposited in the nearshore environment and redeposited offshore. Ʃ36PAHs were a small fraction (1.9 %) of hydrocarbons, with a gross mean of 5.68 μg/g OC (GSD = 3.30–9.79). PCA separated deep water sediments from nearshore and community samples due to 4 alkylated naphthalenes which usually indicate a petrogenic source but probably indicates a natural source due to the lack of other petrogenic markers. Priority PAHs (i.e., Ʃ16PAH) varied from 31.5 % to 56.6 % of the Ʃ36PAH residues. The concentrations of individual PAHs were well below the Interim Sediment Quality Guidelines recommended by the Canadian Council of Ministers of the Environment.

Bioavailability of chromium, nickel, iron and manganese in relation to their speciation in coastal sediments downstream of ultramafic catchments: A case study in New Caledonia.

Coastal sediments downstream of ultramafic catchments can show Ni and Cr concentration well above sediment quality guidelines. Despite their potential ecological impact, the bioavailability of these trace metals in such sedimentary settings has been poorly investigated. In this study, we tried to fill this gap by performing kinetic EDTA-extractions across a shore-to-reef gradient in lagoon sediments downstream of an ultramafic catchment in New Caledonia and interpreting the results in regard of synchrotron-derived speciation. Measured bioavailability ranged from very low for Cr (below 1% of total Cr) to medium for Ni (below 5% of total Ni). Both trace metals showed a decreasing shore-to-reef bioavailability gradient reflecting the larger deposition of ultramafic sediments close to the shore. According to synchrotron-derived speciation data, the very low bioavailability of Cr is attributed to its major occurrence as Cr(III)-bearing Fe-(oxyhydr)oxides and phyllosilicates, with no evidence of Cr(VI). Considering the low occurrence of Fe-sulfides, the medium bioavailability of Ni is considered to arise mainly from the reductive dissolution of Ni-bearing Fe-(oxyhydr)oxides during early diagenesis. This reaction also explains the medium bioavailability of Fe (up to 15% of total Fe) and the positive correlation observed with Total Organic Carbon (TOC). In this regard, this latter parameter appears as a major driver of Ni and Fe bioavailability in coastal sediments downstream of ultramafic catchments. On the opposite, in the absence of Mn-oxides, TOC has no influence on Mn bioavailability (up to 30% of total Mn) that appears more likely driven by sediment sources. From an ecological point of view, considering the Australian and New-Zealand High Interim Sediment Quality Guidelines (ANZ-ISQG-H), Cr should not represent a significant risk towards benthic communities in coastal sediments downstream of ultramafic catchments. On the opposite, Ni, Fe and Mn might represent an ecological risk that should be further investigated in such sedimentary settings.

Assessment of mercury enrichment in lake sediment records from Alberta Oil Sands development via fluvial and atmospheric pathways

Exploitation of bitumen-rich deposits in the Alberta Oil Sands Region (AOSR) by large-scale mining and processing activities has generated widespread concern about the potential for dispersal of harmful contaminants to aquatic ecosystems via fluvial and atmospheric pathways. The release of mercury has received attention because it is a potent neurotoxin for wildlife and humans. However, knowledge of baseline mercury concentration prior to disturbance is required to evaluate the extent to which oil sands development has contributed mercury to aquatic ecosystems. Here, we use stratigraphic analysis of total mercury concentration ([THg]) in radiometrically dated sediment cores from nine floodplain lakes in the AOSR and downstream Peace-Athabasca Delta (PAD) and two upland lakes in the PAD region to establish pre-1900 baseline [THg] and evaluate if [THg] has become enriched via fluvial and atmospheric pathways since oil sands mining and processing began in 1967. Concentrations of THg in sediment cores from the study lakes range from 0.022–0.096 mg/kg (dry wt.) and are below the Canadian interim sediment quality guidelines for freshwater (0.17 mg/kg). Results demonstrate no enrichment of [THg] above pre-1900 baseline via fluvial pathways at floodplain lakes in the AOSR or PAD. Enrichment of [THg] was detected via atmospheric pathways at upland lakes in the PAD region, but this occurred prior to oil sands development and aligns with long-range transport of emissions from coal combustion and other anthropogenic sources across the northern hemisphere recognized in many other lake sediment records. The inventory of anthropogenic [THg] in the upland lakes in the AOSR is less than at the Experimental Lakes Area of northwestern Ontario (Canada), widely regarded as a “pristine” area. The absence of enrichment of [THg] in lake sediment via fluvial pathways is a critical finding for stakeholders, and we recommend that monitoring at the floodplain lakes be used to inform stewardship as oil sands operators prepare to discharge treated oil sands process waters directly into the Athabasca River upstream of the PAD.

Distribution and ecological risk of heavy metal(loid)s in surface sediments of the Hai Phong coastal area, North Vietnam

ABSTRACT Surface sediment samples were collected from the Hai Phong coastal area, and grain size and heavy metal content were analyzed to estimate the effects of natural and anthropogenic activities. The area comprised five sediment types: fine sand, very fine sand, very coarse silt, coarse silt, and medium silt. Ten heavy metal(loid)s (Fe, Cu, Pb, Zn, Cd, As, Cr, Co, Mn, Mo) were assessed. The average concentration of followed the order of Fe > Mn > Zn > Pb > Cu > Cr > As > Co > Mo > Cd. Cu, Pb, and As were over Interim Sediment Quality Guideline (ISQGs), while Cr, Zn, and Cd were below ISQG levels. Three sediment groups with three levels of heavy metal(loid)s were identified: group 1 was distributed in the river and nearshore, with coarse silt and the highest heavy metal(loid) concentration; group 2 was distributed in the river, nearshore, and offshore, with very coarse silt and high heavy metal concentrations; and group 3 was distributed in the river and offshore, with very fine sand and the lowest heavy metal concentrations. Runoff from the mainland had a significant effect with a high contamination of As, Cu, and Pb in Hai Phong coastal area.

Risk assessment of potentially toxic elements in stream sediments around granite quarries, barite mines, and cultivation areas, Southeastern Nigeria.

This study assessed the contamination of streams with potentially toxic elements (PTEs) in sediments around mining, quarrying, and cultivation areas in Akamkpa and environs Southeastern Nigeria. Analysis done using ICP MS technique shows that barium (Ba) and lead (Pb) recorded mean concentrations above their average shale content (ASC) in stream sediments. Chromium (Cr) exceeded Canadian Interim Sediment Quality Guideline (ISQG) and US Environmental Protection Agency (USEPA) screening benchmark value. Pb exceeded Canadian ISQG value but tallies with USEPA benchmark value. Pearson's correlation exhibited significant correlation (p < 0.01) of molybdenum (Mo) with copper (Cu) and Pb; Cu with Pb, vanadium (V), and Ba; V with Cu, Pb, iron (Fe), Ba, and beryllium (Be); and Fe with Be and V. Principal component (PC 1) consists of Pb, Mo, cobalt (Co), Cu, arsenic (As), Cr, V, and nickel (Ni) and showed significant correlation. Geo accumulation index (I-geo) values for Mo, Cu, V, Pb, Zn, Ni, Co, Mn, and Ba fall under unpolluted (0) to moderately polluted (1-2) classes. Maximum enrichment factor (EF) values show extremely high and significant enrichment of Ba and Pb in few locations. Co, Cr, Cu, Mn, and Zn possess maximum EF values classified as moderate enrichment. Ni, Mo, As, and V obtained maximum EF values classified as depleted to minimal enrichment. Modified pollution index (MPI) values showed high PTEs contamination in mostly cultivation locations. Single element potential ecological risk (EiR) mean values trend EiR (As) > EiR (Pb) > EiR (Co) > EiR (Cr) > EiR (Cu) > EiR (V) > EiR (Ni) > EiR (Zn). Comprehensive potential ecological risk (RI) shows medium risk "B" and strong risk "C" levels in few locations. The use of multiple pollution indices such as I-geo, EF, EiR, and RI in pollution assessment indicated similar trend of PTEs contamination of stream sediments. Levels of PTEs contamination are elevated in cultivation areas more than in granite quarrying and mining areas. This study serves as a benchmark for conducting suitable environmental management strategies to scientists in Nigeria and other parts of the world.

Uptake of copper and chromium by Avicennia marina and Avicennia alba at Wonorejo Estuary, East-coastal area of Surabaya, Indonesia

Wonorejo River is one of the rivers that discharge into the East Coast area in Surabaya, Indonesia. This river also contains wastewater from industry and households and can be polluted at the estuary area in Surabaya. Avicennia marina and Avicennia alba are mangrove species that have a high population at the Wonorejo Coastal area. This area was planted with mangroves 10 years ago. The aims of this research were to determine the concentration of Cu and Cr in sediment and the roots of A. marina and A. alba at the Wonorejo Coastal area, to determine the value of Bioconcentration Factor (BFC) of Cu and Cr by A. marina and A. alba and to determine the distribution of Cu and Cr concentration in sediment. Sampling activities were conducted using a Transect quadrat sampling method with a 10 x 10 m dimension. Sediment and mangrove root samples were extracted before being analysed using an atomic absorption spectrophotometer (AAS). Based on Interim sediment quality guidelines (ISQGs), the average concentrations of Cu and Cr at some sampling points were above the standard, i.e Cu reached 94.0 ± 79.2 mg/kg and Cr was 70.8 ± 20.2 mg/kg. A. marina could uptake metals and the accumulations of Cu and Cr were 110 ± 10.4 mg/kg and 83.8 ± 10.6 mg/kg, respectively. However, the highest accumulation by A. alba reached 90.8 ± 24.7 mg/kg for Cu and 55.3 ± 1.1 mg/kg for Cr. Based on the BCF value, A. marina was a hyperaccumulator species for the heavy metals Cu and Cr. However, A. alba showed potential as a hyperaccumulator for Cu and as an accumulator for Cr. In conclusion, both mangroves A. marina and A. alba can be considered for use in Cu and Cr phytoremediation in coastal areas.

Speciation and partitioning of uranium in waterbodies near Ranger Uranium Mine

Environmental contextAs a part of the rehabilitation of Ranger Uranium Mine, Northern Australia, closure criteria for water concentrations of uranium and other contaminants in local waterbodies have been developed. Increased concentrations of uranium in the water column can result in an accumulation of uranium in the sediment and be hazardous to benthic organisms. A uranium partitioning relationship was derived to predict sediment uranium concentrations from water column concentrations. AbstractAfter almost four decades of mineral processing, the Ranger Uranium Mine (RUM) is set to cease operations in 2021. Beyond this period, rehabilitation of the Ranger Project Area (RPA) will continue into 2026. As part of the rehabilitation of RUM, water quality guideline values (WQGVs) for U and other metals in local waterbodies have been developed to protect aquatic organisms from the effects of metal toxicity. However, benthic organisms will also be exposed to U as it partitions from the water column to the sediments. This important component of the ecosystem may then be exposed to increased U concentrations through ingestion and adsorption of U from sediments. As increased concentrations of U in the water column can result in an accumulation of U in sediment, a U partitioning relationship was derived to enable prediction of sediment U concentrations when water column concentrations were at the WQGV. In this work, the effect of U counter ions and dissolved organic carbon on uranium speciation was modelled and demonstrated a high affinity for the formation of uranyl-organic complexes. Uranium partitioning was studied using experimental U-spiked sediment data as well as water/sediment data collected from multiple sites on and adjacent to the RPA. Using a Freundlich isotherm, and a water-column U concentration of 2.8µg L−1 (representing the WQGV), the acid-extractable U in sediment was calculated to be 48mg kg−1, i.e. lower than the interim sediment quality guideline value (SQGV) of 94mg kg−1. This offers assurance that a WQGV implementation of 2.8µg L−1 U will not lead to a level of U accumulation in sediment that will impact benthic communities.

Geoaccumulation Index and Enrichment Factor of Arsenic in Surface Sediment of Bukit Merah Reservoir, Malaysia.

An investigation study was conducted in Bukit Merah Reservoir (BMR) for the assessment of arsenic concentration in the surface sediment in 23 sampling stations. The sediment samples were digested and analysed for arsenic using Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES). Sediment parameters such as pH (4.42 ± 0.71), redox potential (121.77 ± 42.45 mV), conductivity (205.7 ± 64.07 μS cm−1) and organic matter (25.35 ± 9.34%) were also examined. The main objectives of this study are to determine the arsenic distribution and concentration and at the same time to assess the enrichment of arsenic using the geoaccumulation index (Igeo) and enrichment factor (EF). This study shows the total arsenic concentration in the surface sediment of BMR is 4.302 ± 2.43 mg kg−1 and found to be below the threshold value of Canadian Interim Sediment Quality Guidelines (ISQG). High arsenic concentration is recorded near the southern part of the lake where anthropogenic activities are prevalent. Based on Igeo, 13% of sampling stations are categorised as moderately polluted, 52.2% as unpolluted to moderately polluted and the rest is categorised as unpolluted. EF shows 78.3% stations are classified as extremely high enrichment and the rest as very high enrichment. This finding provides important information on the status of arsenic contamination in BMR and creating awareness concerning the conservation and management of the reservoir in the future.