Frictional Interaction Research Articles

Increasing the Wear and Corrosion Resistance of a CP-Ti Surface by Plasma Electrolytic Borocarburizing and Polishing

The paper examines the possibility of increasing the wear and corrosion resistance of a CP-Ti surface by duplex plasma electrolytic treatment (borocarburizing and polishing). The structure and composition of diffusion layers, their microhardness, surface morphology and roughness, wear resistance during dry friction and corrosion resistance in Ringer’s solution were studied. The formation of a surface-hardened layer up to 200 μm thick with a microhardness of up to 950 HV, including carbides and a solid solution of boron and carbon, is shown. Subsequent polishing makes it possible to reduce surface roughness and remove weak areas of the porous oxide layer, which are formed during high-temperature oxidation in aqueous electrolyte vapor during borocarburizing. Changing the morphology and structural-phase composition of the CP-Ti surface helps reduce weight wear by a factor of three (the mode of frictional interaction changes from microcutting to oxidative wear) and corrosion current density by a factor of four after borocarburizing in a solution of boric acid, glycerin and ammonium chloride at 950 °C for 5 min and subsequent polishing in an ammonium fluoride solution at a voltage of 250 V for 3 min.

Surface-engineered caterpillar-like silica nanocomposites for enhanced interparticle friction and interlock in shear thickening suspension

This study presents a novel method for fabricating surface-engineered caterpillar-like silica nanocomposites by combining rod-like nanorods with spherical nanoparticles to control aspect ratios and surface functionalization. This unique design facilitates functional assembly at the nanoscale. Additionally, we developed an innovative composite by encapsulating polyurethane elastomers within shear thickening fluid (STF)-impregnated Kevlar, significantly enhancing the flexibility and durability of the resulting STF/Kevlar/PU composite. Microstructural and chemical modifications were characterized, and detailed rheological analysis revealed a 165 % increase in viscosity and a substantial rise in storage modulus from 91.56 to 18,640 Pa, indicating improved surface morphology and roughness. These enhancements promoted stronger interparticle friction and rotational motion during flow. Impact resistance tests further demonstrated a 314 % increase in peak impact force, driven by frictional interactions between the dispersed caterpillar-like particles. The results confirmed that surface roughness and adhesive forces play a critical role in activating stress-dependent frictional contacts, a key mechanism behind the improved performance. These findings highlight the potential of these composites for mitigating penetration injuries and offer precise control over the shear-thickening transition in engineering applications, making them promising candidates for lightweight protective materials.

Analyzing multicomponent permeation and coupling effects in pervaporation of Acetone-Butanol-Ethanol solutions using Maxwell-Stefan based modeling

The state-of-the-art research in pervaporation lacks a comprehensive understanding of the selective membrane permeation in real and multicomponent mixtures, a factor critical for its widespread commercial adoption. This work elucidates the contribution of various interaction effects, known as coupling phenomena, on the pervaporation of multicomponent Acetone-Butanol-Ethanol (ABE) solutions through a commercial PDMS membrane. Maxwell-Stefan (MS) diffusion formulations, combined with the UNIQUAC thermodynamic model, mostly restricted in literature to binary solutions permeating through a polymer membrane, are extended to multicomponent feed solutions. The thermodynamic correction factor [Γ] and correlation [B]−1 matrices are analyzed to resolve coupling into its thermodynamic and kinetic (diffusive) constituents.A generalized and explicit analytical derivation for calculation of [Γ] by UNIQUAC model is proposed, allowing estimation for any number of permeants. Subsequently, a significant inhibitory coupling of the component fluxes to the driving forces of its accompanying penetrants is revealed. In addition to the non-ideality arising from diagonal elements Γii, the substantial negative off-diagonal elements Γij in the thermodynamic correction matrices anticipate a decline in effective driving forces, butanol fluxes and permeation selectivity as we transition from binary butanol-water to multicomponent ABE mixtures.Following this, a detailed hit-and-trial based strategy is implemented to evaluate the relevance of membrane plasticization, cluster formation and interspecies frictional interactions towards the MS self and cross diffusivities within the [B]−1 matrix. Existing semi-empirical expressions for self-diffusivities in binary alcohol-water systems incorporating plasticization and clustering constants are reformulated and compared for their ability to accurately describe fluxes in binary and ternary ABE solutions. Furthermore, the optimal model fit was found to be insensitive to variation in MS cross-diffusivities. This suggests that the contribution of correlation effects may be neglected altogether, provided the expressions for self-diffusivities are adequately tailored for membrane plasticization and clustering. Notably, while only butanol clustering suffices for binary mixtures, additional aggregates involving butanol-water, water-water, and butanol-acetone/ethanol are suggested to play a crucial role in steering diffusivities in ternary solutions.Consequently, the proposed models exhibit exceptional agreement with experimental data, achieving R2 values of approximately 0.96, 0.95, and 0.98 for butanol flux in binary butanol-water and ternary solutions containing acetone and ethanol, respectively. Besides providing a more cohesive fit to the overall experimental permeation data, the usefulness of this approach lies in significantly simplifying model computations, thus easing the potential modeling of even more complex mixtures.

Validation of finite-element-simulated orthodontic forces produced by thermoplastic aligners: Effect of aligner geometry and creep

PurposeFinite element (FE) models for determining the orthodontic forces delivered by clear aligners often lack validation. The aim of this study was to develop and validate accurate FE models for clear aligners, considering the small but important geometrical variations from the thermoforming process and the creep behavior of the aligner material. Methods and materialsThe tooth misalignment considered was a 2.4° torque aberration (rotation about the mesial-distal axis at the level of the center of resistance) of the maxillary left central incisor. FE models were created from Micro-CT scans of a model dental arch and five nominally identical aligners with the aforementioned misfit. Fitting of the aligners onto the dental arch was simulated using Abaqus's Interference Fit function, followed by surface-to-surface frictional interaction. Stress relaxation of the aligner material was measured using double-cantilever beam bending and modeled with a Prony series. The assembled FE models were validated by comparing the predicted forces and moments delivered to the maxillary left central incisor with experimental data, obtained with a custom-built but fully calibrated apparatus. ResultsGood agreement between prediction and measurement was obtained for both the short- and long-term forces and moments. In the short-term, i.e., after 30 s, the dominant force in the labial-lingual direction had a maximum difference of 2.9% between experiment and simulation, and the dominant moment about the mesial-distal axis had a maximum difference of 8.3%. In the long-term, i.e., after 4 h, the experimental and numerical forces had a maximum difference of 8.4%. There were statistically significant differences in the forces delivered among the nominally identical aligners, which were predicted by the geometrically accurate FE models and attributed to the variations in the points of contact between the aligners and the dental arch. The decay in force applied was affected by both the viscoelastic material behavior and friction between the aligner and arch. ConclusionFor accurate prediction of the forces and moments delivered by thermoplastic aligners, FE models that can accurately capture the point contacts between the aligners and the underlying teeth are essential. Stress relaxation of the aligners could be adequately modeled using the Prony series to represent the temporal changes of their elastic modulus.

Discrete and continuum modelling of rock-ice avalanches: vertical segregation and its feedback on flow mobility

Rock-ice avalanches are rapid, catastrophic mass flows consisting of massive rock and ice particles in alpine regions. Varying material properties of rock and ice particles cause them to spontaneously mix and segregate during the flow. However, the impacts of segregation on the mobility remain poorly understood and are overlooked in current rock-ice avalanche models. Here, we address modeling of segregation and its mobility feedback from both discrete and continuum points of view. Using the discrete element method, we simulate rock-ice avalanches, and the segregation that occur therein, as steady gravity-driven flows of particles different in size, density, and surface friction. Segregation results in sharp particle concentration gradients which, when coupled with the large surface friction difference between rocks and ice, lead to transitions in the flow kinematic profiles. We reveal that rocks and ice contact probabilities are key to modelling the effective friction and volume fraction of the mixture flows. Continuum equations are proposed to model the concentration dependence of the pressure, while segregation-induced flow velocity profiles are modelled using the non-local granular fluidity framework that accounts for microscopic frictional interactions. The findings are expected to promote more sophisticated modeling of rock-ice avalanches necessary for hazard risk reduction and mitigation.

Effects of adhesive and frictional contacts on the nanoindentation of two-dimensional material drumheads

Nanoindentation of suspended circular thin films, dubbed drumhead nanoindentation, is a widely adopted technique for characterizing the mechanical properties of micro- or nano-membranes, including atomically thin two-dimensional (2D) materials. This method involves suspending an ultrathin specimen over a circular microhole and applying a precise indenting force at the center using an atomic force microscope (AFM) probe. Classical solutions assuming a point load and a fixed edge, which are referred to as Schwerin-type solutions, are commonly used to estimate Young’s modulus of the membrane material out of load–deflection measurements. However, given the widespread experimental evidence for adhesive and frictional contacts between the probe tip and the membrane, as well as sliding between the membrane and its supporting substrate, quantitative investigations of the effects of these interactions are required. In this paper, we formulate a boundary value problem to rigorously model such effects, ensuring relevance to experimental operations. Our numerical analyses reveal that the adhesive effect at the tip-membrane interface diminishes as the indentation depth increases or the tip size decreases. Furthermore, frictional interactions at this interface shift the maximum membrane stress from the center to the tip-membrane contact line with increasing indentation depth and interfacial shear stress. At large indentation depths, the size of the indenter tip and the sliding of the membrane-substrate are found to have a large effect on the indentation load–deflection relationship. Thus, we propose a new approximate formula for this relationship assuming a non-adhesive and frictionless spherical tip of a finite radius and a slippery contact with the supporting substrate. This formula is more accurate than the widely used Schwerin-type solution. It can be used to simultaneously extract the in-plane stiffness of the membrane and the shear strength at the membrane-substrate interface.

Electromagnetic wave absorption performance of porous geopolymer: Dual effects of fly ash on alkali activation and microwave dissipation

The simultaneous occurrence of aggregation reactions in fly ash (FA) facilitates the uniform dispersion of internal ferrite into the geopolymer. Considering the excellent impedance matching and multiple reflection effects of foam concrete, this paper develops a ‘zero-absorber’ foam geopolymer-based electromagnetic absorbing material. The effects of different densities (400, 600, 800, 1000, 1200 kg/m3) and FA contents (40 %, 50 %, 60 %, 70 %, 80 %) on the electromagnetic absorption performance of foam geopolymer are investigated, respectively. Combined with the iron element distribution and 3D pore structure by SEM and X-CT analysis, the dissipation mechanism of electromagnetic energy by FA and pore structure in foam geopolymer are further explored. Experimental results show that FA can uniformly disperse inherent ferric ions from the matrix into the geopolymer during the polymerization reaction, leading to excellent magnetic losses through magnetic moment orientation adjustment and intermolecular friction interactions without adding external absorber. Additionally, the uniformly dispersed porous structure consumes incident electromagnetic energy through reflection, scattering, coherent attenuation, and interference resonance loss effects. It shows multi-scale electromagnetic absorption effects in the ‘zero-absorber’ foam geopolymer-based electromagnetic absorbing material, including pore structure multiple reflections (millimeter scale), inter-pore wall interference resonance (micrometer scale), and ferric ion magnetic loss (nanometer scale). For the foam geopolymer with 1000 kg/m3 density and 50 % FA, it achieves the optimal electromagnetic absorbing performance with the minimum reflection loss (RL) of −34.9 dB and the effective absorption bandwidth of 14.1 GHz (RL below −10 dB) in 2–18 GHz range.

(Invited) Triboelectric Identification of Amino Acids

Triboelectrification necessitates a frictional interaction between two dissimilar materials, and their contact electrification is characteristically based on the polarity variance in the triboelectric series. Utilizing this fundamental advantage of the triboelectric phenomenon, different materials can be identified according to their contact electrification capability. Herein, we perform an in-depth analysis of the amino acids present in the stratum corneum of human skin, and we quantify them regarding triboelectric polarization. The principal focus of this study lies in analyzing and identifying the amino acids present in copious amounts in the stratum corneum to explain their positive behavior during the contact electrification process. Thus, we present an augmented triboelectric series of amino acids with quantified triboelectric charging polarity by scrutinizing the transfer charge, work function, and atomic percentage. Furthermore, we detect the chirality of aspartic acid as it is most susceptible to racemization with clear consequences on the human skin. We expect this study to accelerate research exploiting triboelectrification and provide valuable information on the surface properties and biological activities of these important biomolecules.

Cellulose binary coatings with spherical envelope structure via structure rearrangement in ball milling for integrated radiative cooling-electricity generation

Passive daytime radiative cooling is a zero-energy consumption cooling technology, which can dissipate heat to outer space via infrared radiation. Recently, coupling radiative cooling technology and thermoelectric devices to generate electricity has attracted much attention. However, existing radiative cooling integrated thermoelectric devices still suffer from low-temperature gradient and output voltage. Here, based on the Mie scattering and internal reflection enhancing principle, an impact-inducing geometry reconstruction approach was proposed to fabricate hierarchical nanostructured cellulosic coatings with good daytime cooling performance to achieve stable electricity generation function, which can be realized by using a scalable and facile wet ball milling technology. Guided by the theoretical simulations of the finite difference time domain method (FDTD), the cellulose and TiO2 nanoparticles can assemble into spherical envelope structured coatings drying by the shear, impact, and friction interaction in the ball milling process, dramatically enhancing the Mie scattering and internal reflection of coatings. The cellulosic coatings exhibit sunlight reflectivity of 0.962 and infrared emissivity of 0.94, resulting in a daytime radiative cooling efficiency of 5.9 °C under direct sunlight. Energy Plus stimulation demonstrated 35 % cooling energy and 468.9 kWh of cooling energy can be saved annually in China. Meanwhile, this cellulosic coating-based thermoelectric device can deliver a high voltage output of 150 mV under 1 Sun due to the strong bonding and high-temperature gradient formation (30 °C), which is higher than previous reports. This study will facilitate the development of sustainable power generation device for the goal of green future.

Tuning Surface Adhesion Using Grayscale Electron-beam Lithography.

Surface texturing of manufactured products tailors their properties, such as friction, adhesion, biocompatibility, or fluid interactions. However, advancements in this area are largely the result of trial-and-effort testing and generally lack a science-guided framework for determining the surface topography that will optimize performance. The present investigation explores grayscale electron-beam lithography as a means to create multiscale surface patterns to control surface performance. Here, we created and characterized a set of surface textures on a silicon wafer; the textures were superpositions of sine waves of varying wavelengths and amplitudes. First, the multiscale topography of the patterned surface was characterized, using profilometry and atomic force microscopy, to understand its fidelity to the designed-in pattern. The results of this analysis demonstrated how grayscale lithography accurately controlled the lateral size of features but was less precise on the vertical height of the surface, and also introduced inherent roughness below the scale of patterning. Second, a micromechanical tester was used to characterize the adhesion of the surfaces with large-scale polished silicon spheres. The results showed that adhesion could be tailored, with significant contribution from all of the designed-in length scales of topography. The strength of adhesion did not correlate with conventional roughness parameters but could be accurately modeled using simple numerical integration. Taken together, this investigation demonstrates the promise and challenges of grayscale e-beam lithography with multiscale patterns as a method for the tailoring of surface performance.

Designing tribotechnical epoxy composite materials reinforced with chopped fibers and modified with silicon organic varnish

The object of research is modified epoxy composite materials containing fibrous fillers treated in physical fields. The technological features of the development of tribotechnical epoxy composites, which must withstand the effects of elevated temperatures, have been considered. In this case, it is necessary to modify the structure of the epoxy polymer matrix, which is achieved as a result of the introduction of heat-resistant organosilicon varnish. Organosilicon varnishes and chopped fibers contain technological additives, which complicates the process of structuring epoxy composites and leads to the appearance of structural defects. Removal of technological additives and cleaning the surface of the aramid and glass fibers from lubricants is possible as a result of processing the components of the composition in physical fields. There is a need to study the influence of physical fields on the structuring processes of the epoxy system and the formation of the structure of epoxy composites with specified properties. Modified epoxy composites contain chopped aramid and glass fibers treated with ultrasound. The tribotechnical characteristics of epoxy composites were studied at a sliding speed of V=1.0 m/s with a change in specific load from 0.5 MPa to 1.5 MPa. The temperature in the tribocontact zone during frictional interaction rises to 100 °C with an increase in the specific load. An increase in the density of the surface layer of tribocontact of epoxy composites with fillers treated in physical fields was revealed. The practical recommendations have been compiled for the implementation of the treatment technology of components in physical fields, which ensures structuring of epoxy composites with high tribotechnical characteristics

Emergence of critical state in granular materials using a variationally‐based damage‐elasto‐plastic micromechanical continuum model

AbstractThe mechanical response of granular materials, exemplified by frictional grain interactions, is characterized by a critical state in which deformation occurs without change of material volume or stresses when subjected to large shear deformation. In this work, a granular micromechanics approach (GMA) based continuum model is used to investigate the emergence of such a critical state. The continuum description is constructed through mechanical concepts based upon elastic and dissipation energies defined for a generic grain‐pair interaction. A hemivariational principle provides the basis for considering the evolution of damage and plasticity phenomena comprising grain‐pair contact loss and irreversible deformation. As a consequence, the Karush–Kuhn–Tucker (KKT)‐type conditions are derived, which give the evolution equations for the irreversible phenomena. Notably, in this derivation there is no invocation of flow rules and other similar assumptions of classical phenomenological continuum damage and plasticity. Further, Piola's ansatz is elaborated to kinematically connect granular micromechanics of grain‐pair to the continuum description. While the concept of critical state analysis has been handled with either phenomenological approaches or discrete numerical frameworks, in the present paper this concept is examined within a micromechanics‐based continuum description. The constitutive model is established and the coupled damage and plastic irreversible quantities are assessed. The critical state is shown to emerge as grain‐pair related damage and plastic evolution in a competitive/collaborative manner during the imposed loading path.

Characterisation of process-induced variability in wrinkle defects during double diaphragm forming of non-crimp fabric

Experiments and numerical simulations are employed to determine the critical process variables that affect the quality of a two-layer biaxial non-crimp fabric (NCF) preformed using the double diaphragm forming (DDF) process. To prevent wrinkling defects, the process variables must be controlled, including the vacuum pressure, diaphragm tension, and ply-tool alignment. Inter-ply friction plays a critical role in the deformation mechanism, while the frictional interaction between the diaphragm and tool has a limited impact. The study also reveals that geometrical features have an impact on the variability induced by the forming process. Preforms deformed to tools with geometrical features of higher asymmetry or Gaussian curvatures reduce the uncertainty of the forming process by maintaining the same preform quality despite changes in forming variables.

Entangled metallic porous material–silicone rubber interpenetrating phase composites with simultaneous high specific stiffness and energy consumption

High stiffness and superior energy consumption have consistently been primary research focuses in the field of damping materials. Hence, this work presented an innovative interpenetrating phase composite (IPC) crafted from wound elastic entangled metallic porous material and silicone rubber. The proposed composite effectively integrates the unique properties of the original materials, showcasing a seamless blend. Dynamic experimental tests were conducted to analyze the dynamic compression mechanical behavior of the composites, revealing that the composites exhibit excellent energy consumption capabilities and elevated stiffness characteristics. The improvement in both stiffness and damping characteristics is attributed to the addition of silicone rubber, which solidifies the structure of the composites. The introduction of interfacial friction results from maintaining compression, sliding, and other frictional interactions among the original spiral coils. Notably, the composites also display exceptional fatigue resistance. Overall, this work demonstrates the potential to concurrently achieve enhanced stiffness and superior energy consumption through the use of entangled metallic porous material and silicone rubber.

Normal Contact Model of Fractal Surfaces Considering Friction and Asperity Interactions

Friction as well as asperity interactions have significant influence on the contact area and force of rough surfaces. In this work, a single-asperity, elastoplastic contact model, considering friction, is established by means of continuum mechanics and power-exponential functions. Then, the deformation of the asperity interactions is modeled by the displacement of the average line for asperity height. Using fractal theory, the actual deformation and contact stiffness of an asperity are derived, which take the friction and asperity interactions into account. Furthermore, the actual contact area and normal stiffness models for fractal surfaces are developed, accounting for friction and asperity interactions. The accuracy of the developed models is confirmed by using published experimental results. The developed models are closer to experimental results than the reported fractal contact models. Finally, the effects of the friction coefficient and surface morphology parameters on contact characteristics are discussed.

Combined application of CDWs as precursors and aggregates in geopolymer composites: A comprehensive rheological analysis

The study of rheological characterization of construction and demolition waste (CDW)-based geopolymeric materials has gained interest due to digital innovation in construction and the increased focus on sustainable materials. Understanding the rheological behavior of these materials is essential due to their rapid geopolymeric reaction kinetics and viscosity behavior. This study investigated the impact of various CDW-based fine recycled aggregates, including crushed concrete aggregates (CRC), crushed ceramic-tile aggregates (CTA), and crushed brick aggregates (CBA), on the rheological behavior of geopolymer mortars (GPMs). Natural sand (NSA) was utilized as a reference for comparison purposes. In addition to CDW-aggregates, the GPMs were also made from optimized CDW-based precursors of brick waste powder (BP), ceramic-tile waste powder (TP), or concrete waste powder (CP). As a result, twelve different GPMs were considered, each containing 100 % individual CRC, CTA, and CBA fine aggregates, blended with BP, TP, and CP precursors. The study evaluated the relationship between the design variable of SiO2/Al2O3 molar ratio as well as the packing densities (PD) of GPM systems and their rheological characteristics, such as flow, apparent and plastic viscosity, yield and shear stresses, thixotropy and shear strains employing the compressible packing method. The results indicate that all GPMs possess shear-thinning or pseudoplastic characteristics. Enhanced SiO2/Al2O3 molar ratio generally resulted in increased rheological parameters. However, using TP as a precursor and CBA as fine aggregates in GPM matrices led to significant enhancement in rheological parameters due to the higher specific surface area of TP and the greater irregularity, convexity, and absorption capacity of CBA particles. Notably, although the enhanced non-colloidal frictional interactions and colloidal flocculation of CRC, CTA, and CBA resulted in reduced flow tendency of GPMs, they have been found to improve the thixotropy during the initial geopolymeric gelation stage.

The Role of Friction in Athletic Performance: A Descriptive Analysis

Friction is a fundamental force that has a substantial impact on athletic performance across all sports disciplines. This descriptive research investigates the varied impact of friction in building athletic skill. This study looks at how friction affects running, jumping, throwing, and other sports activities by examining static and kinetic frictional forces, as well as elements that influence frictional interactions. The research examines the interaction of athletes, footwear, surfaces, and equipment to explain how friction governs propulsion, stability, and efficiency in sports activity. The findings of this study have important significance for players, coaches, and sports scientists, as they provide avenues for optimizing training techniques, equipment design, and performance tactics for increased athletic achievement. Keywords Friction , Athletic Performance , Role , Descriptive Analysis , Surface Friction , Footwear Friction , Sports Science , Biomechanics , Performance Optimization , Surface Interaction , Traction , Stability , Movement Efficiency , Injury Prevention ,Training Strategies

A general kinematic model for lubricated ball bearings based on the minimum energy hypothesis

Accurately predicting the performance of lubricated rolling elements is critical for certain key bearing applications. A widely employed simulation technique is quasi-static models, which although computationally efficient to implement, lack accuracy in predicting the kinematics of bearing components. This problem arises from their construction under kinematic assumptions, instead of solving the kinematic based on real frictional interactions. This paper presents a quasi-static model based on the minimum energy hypothesis for lubricated contacts, which determines the kinematic of the ball considering the effects of the frictional interactions governed by the elastohydrodynamic lubrication mechanism. The influence of kinematic variables on the sliding patterns and power loss distribution of the contact are analysed. The results are compared with other published quasi-static models, revealing substantial differences. The influence of the kinematic hypotheses on power losses are also studied at a bearing component scale. Finally, the effect of the governing lubrication mechanism of the contact is discussed, concluding that the limiting shear stress of the lubricant and the centrifugal forces have a significant effect on the kinematic of the ball.

The solution-diffusion model for water transport in reverse osmosis: What went wrong?

Reverse osmosis (RO) stands as the state-of-the-art desalination technology, owing to its high energy efficiency and low cost. Further improvements in the performance of this technology require a fundamental understanding of transport mechanisms in RO membranes. For decades, the solution-diffusion model has been the prevalent approach to describe water transport mechanism in RO membranes. In this model, water first partitions into the membrane and then diffuses down a concentration gradient of water within the RO membrane. However, recent experimental and theoretical findings pose serious challenges to the fundamental assumptions of this theory. In this perspective, we discuss seven critical flaws in the solution-diffusion model and explain why the model fails to describe water transport in RO membranes. Instead, through our careful analyses, we determine that the pore-flow model, in which a pressure gradient drives water flow through membrane pores or interconnected free volumes, represents the true mechanism for water transport. We conclude by highlighting the need for research efforts to better understand the frictional interactions between water, salt, and membrane and their impact on water transport. Overall, a fundamental understanding of the water transport mechanism will inform the development of next-generation RO desalination membranes.

Producing Cellulose Microfibrils at a High Solid Content with and without Mechanical or Enzymatic Pretreatment.

This study conducted a detailed evaluation of the feasibility of producing cellulose microfibrils (CMF) from a kraft-bleached hardwood pulp at high solid contents with and without pretreatments. CMFs produced by planetary ball milling at solid contents 17 and 28% were compared with those from 1 to 5% under the same milling conditions. Fiber pretreatments using a commercial endoglucanase and mechanical refining using a laboratory PFI mill were also applied before ball milling at a solid content of 28%. Two mechanisms of fiber fibrillation were identified from the results obtained: (i) ball and fiber/fibril interactions─the primary mechanism and (ii) interfiber/fibril frictional and tensional interactions─the secondary mechanism. The secondary mechanism plays an important role only in early-stage fibrillation and became less important as fibrillation proceeded in the later stage toward nanofibrillation. Improving fiber dispersion at lower solid content facilitated fibrillation. Endoglucanase pretreatment substantially shortened fibers to result in a "pulverized-like" CMF with short fibrils at an extended milling time. Mechanical refining of fibers facilitated fibrillation to result in CMFs with a morphology similar to that from runs without any fiber pretreatment but for a much shorter milling time. Both CMF water retention value (WRV) measurements and CMF suspension sedimentation experiments showed results consistent with imaging observations. The insights gained through this study provide relevant information with commercial significance regarding CMF production at high solids, which is not currently available in the literature.