In order to improve the quality of distance education and solve the problem of slow data processing of the teaching system, an intelligent distance education assistance system based on WEB is developed in this paper. After verification, students, teachers and administrators log into the distance intelligent teaching assistance system and transmit various information to the interface of the teaching and administration subsystems. The submitted information is merged using the Bayesian model for integrating educational resources in the digital cloud to create a distance education database that supports the system with data. At the same time, the evaluation of the business logic of the data is performed. After the data is converted to other formats in the subsequent convertible database, it returns to the user interface to provide browsing and consulting functions for users. The experimental results show that the designed system can realize the remote auxiliary function of intelligent education and effectively improve the quality of teaching. The real-time data acquisition rate of the system in this paper is always equal to the set value. The average acceleration of the system in this paper is 5.5 and the data processing efficiency is higher. The minimum safety factor of the system is between 7.8 and 8.5, and the system has high stability. The user satisfaction of the system is over 93%, and the accuracy of the collected data is relatively high. The auxiliary system designed in this paper can provide a stable and efficient application environment for distance education.