AbstractThis work aims to develop and apply an algorithm for solving space‐time fractional reaction‐advection diffusion (STFRAD) nonlinear coupled equations with specified initial and boundary conditions by employing a Shifted Legendre Gauss‐Lobatto collocation (SLGLC) scheme. The fractional derivatives of time and space are defined in Caputo sense. The approximate solutions have been constructed with the help of shifted Legendre polynomials. The proposed numerical scheme reduces the coupled fractional order differential equations into a system of algebraic equations which can then be easily solved. The error analysis through the two test problems is carried out to validate the efficiency and efficacy of the method. The effect of advection and reaction terms, and various space‐time fractional order derivatives on the solution profiles have been studied and are shown graphically for different particular cases. It has been observed that the species whose transport is simulated using STFRADE shows higher concentration at a specific distance in porous media in case of integer order differential equations as compared to fractional order equations demonstrating overestimation of its impact in case of integer order differential equation. This is extremely important observation with respect to applications in the field of groundwater pollution management. The salient feature of the article is the stability and convergence analyses of the proposed scheme on the concerned model, which demonstrates the effectiveness and capabilities of the developed method.