In this work, the concept of plasma–metal junction (pm-junction) is presented, in addition to well established physics of pn-junction, metal–semiconductor junction, semiconductor–insulator junction, etc. We demonstrate experimentally the dependence of I-V characteristics on work function of the metal for a pm-junction. The experiment is done using tungsten (W) and stainless steel (SS) having different work functions (Φm) of 4.55 eV and 4.30 eV, respectively. The W and SS planar metal probes of identical geometry were exposed to plasma simultaneously, making two distinct pm-junctions. The plasma exposed is identical for both the metals, and therefore, the difference observed in the I-V characteristics of these two pm-junctions is attributed only to the difference in an energy-band diagram of these junctions, owing to respective work function. The proposed concept of the pm-junction may simplify the complex plasma–material interactions in all laboratory plasmas, including cold glow discharges to hot fusion plasmas.