This paper uses experimental analysis to understand the freezing law of water to determine the freezing damage mechanism of Glazed Hollow Bead Insulation Concrete (GIC). The critical saturations of GIC with different Glazed Hollow Beads (GHBs) contents were obtained by the relative moving modulus after testing seven saturations of the concrete (70% to 100%, 5% interval). The critical saturation of GIC-0 (i.e., 0% GHBs content) occurred at ∼ 76–78%. GIC-50 occurred at about 86–88%. GIC-100 occurred at about 89–91%. GIC-0, GIC-50, and GIC-100 were then saturated to S60, Scr, and S100 based on their respective critical saturation. Low-field nuclear magnetic resonance (NMR) was used to study the freezing process of different water types in GIC. The results showed that: 1) The water inside GIC was composed of adsorb water, pore water, and free water; 2) The whole freezing process could be roughly divided into four stages: subcooling stage, rapid freezing stage, stable freezing stage, and the end of the freezing phase; 3) During the freezing and thawing process, the change in unfrozen water content of GIC specimens had a hysteresis curve, while the specimens less than the critical saturation had almost no hysteresis curve. Moreover, the saturation significantly influenced the freezing process of different water types, which determined the proportion of them. This study also determined the evolution of the pore size of GIC, which provides a new idea for analyzing the freezing damage mechanism of porous GIC.
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