Instantaneous Volume Fraction Research Articles

Co-production of hydrogen and carbon nanotubes by catalytic cracking of waste cooking oil model compound over Ni-Cu/Al-KCC-1

ABSTRACT Ni-Cu/Al-KCC-1 catalysts with different metal contents were prepared using fibrous nano-silica (Al-KCC-1) as a support. Field emission scanning electron microscopy observations showed that the spherical particle morphology and fibrous structure of the Al-KCC-1 were not changed after metal loading. Transmission electron microscopy images demonstrated that the introduction of copper improved the dispersion of the nickel, while X-ray diffraction and hydrogen temperature-programmed reduction confirmed the formation of a Ni-Cu alloy. The N2-Brunauer–Emmett–Teller specific surface areas of the catalysts were in the range of 269–378 m2/g and the average pore diameters were 7.988–12.078 nm. These Ni-Cu/Al-KCC-1 catalysts were used to promote the cracking of waste cooking oil model compound (WCOMC) to produce H2 and carbon nanotubes (CNTs), and the 10 wt% Ni-5 wt% Cu/Al-KCC-1 exhibited the highest catalytic activity. At a WCOMC flow rate of 0.04 mL/min and 750 °C, the instantaneous volume fraction of H2 reached 49.8 vol% and the content of H2 in the gaseous product was close to 71.4 vol%.

Effect of time dependent morphological parameters of nanoclusters on perikinetic heat conduction and induced micro-convection mechanisms of oxide based nanofluids

ABSTRACTThe article represents an experimentally supported quantitative analysis to observe the effect of time, temperature, nanoclusters’ morphology, and instantaneous volume fractions on perikinetic heat conduction and Brownian motion-based induced convection mechanisms of oxide (Al2O3 and TiO2, size 25–30 nm) based nanofluids. The appropriate models of thermal conductivity have been introduced to study the effect of various parameters such as; varying volume fractions, suspensions’ stabilities, nanoclusters’ growth, temperature, and the liquid layering. The developed model could predict the thermal conductivity enhancements of nanofluids within the accuracy of ± 0.5% to ± 4.5.0% in the temperature range from 20°C to 50°C.Abbreviations: DI: De-ionized water; DLS: Dynamic light scattering; XRD: X-rays diffraction; TEM: Transmission electronic microscope; SDBS:Sodium dodecyl benzene sulphonate.Figure Effect of temperature on the Brownian Reynold number for Al2O3-H2O and TiO2-H2O nanofluids.

Indirect measurement of $$\mu (I)$$ μ ( I ) relation from finite granular avalanche down an inclined narrow reservoir of smooth bed

This work examines the algebraic \(\mu -I\) relation proposed for steady uniform dry granular flows via unsteady granular avalanche experiments of finite nearly identical dry glass spheres down an inclined narrow reservoir of smooth bed. Lateral high-speed digital imaging permits particle tracking velocimetry with which we can evaluate bulk local instantaneous volume fraction and velocity components to conduct a quasi-two-dimensional control volume analysis of streamwise momentum assuming an internal shear stress based on the \(\mu -I\) rheology, a hydrostatic normal stress and a Coulomb yielding condition at lateral walls. Hence, the desired \(\mu \) is a function of flow dynamics and a wall friction coefficient \(\mu _w\). Complementary sliding table experiments were conducted to estimate an upper bound of \(\mu _w=0.17\) which was used with a chosen nonzero lower bound \(\mu _w=0.05\) to extract possible range of \(\mu \) at a local instantaneous inertial number I. The so-obtained local instantaneous \(\mu -I\) data conform to the non-linear monotonically increasing trend proposed for steady inertial flows above a crossover value \(I_c\approx 0.03\). Below \(I_c\), a peculiar segment of decaying \(\mu \) with I was revealed agreeing to the rheology tests in quasi-static regime.

CFD investigation of the cold hydrodynamics of a laboratory scale CFB furnace

This investigation presents a computational and experimental study of the flow characteristics of a laboratory scale CFB cold model riser. i) The first part of the work deals with 2D, CFD validation of a literature based CFB riser of circular cross section of 1m height. Simulation results showed good agreement with experimental literature data for radial profiles of volume fraction and particle velocity. ii) The second part is a work on simulation and experimental verification of a CFB riser flow characteristics of a CFB riser of rectangular cross section (400mm x 550mm x2000mm). An experimental run on the test rig was conducted for sand of 300 micron size at a fluidization velocity of 4 m/s and the fluidization behavior was captured on a high speed camera. For simulation, 3D, transient, Euler-ian approach combined with the Kinetic theory of Granular flow and Gidaspow drag model was used to describe the gas–particle behavior. A frame by frame visual comparison of instantaneous volume fraction distribution was made between camera images and 3D simulated profiles. A further graphical comparison between experimental literature data and simulated 3D profiles of volume fraction and particle velocity profiles yielded fairly good results. It was observed that, in spite of non inclusion of turbulence factor in the current 3D simulation, no significant influence was observed in the results

The effect of global mixing on soot volume fraction: measurements in simple jet, precessing jet, and bluff body flames

Measurements of soot volume fraction were performed in three different turbulent diffusion flames using laser-induced incandescence (LII) to provide insight into the effect of global mixing rate on the instantaneous local and the average soot volume fraction. The three flames, produced by simple jet, precessing jet, and bluff-body jet burners, are chosen because they span a wide range of different global mixing rates for the same fuel, nozzle diameter, and flow rate, and because global measurements of their radiation, NO x emissions, and residence times are available. The measurements reveal an inverse relationship between global mixing rate and both the total amount of soot in the flame and local instantaneous soot volume fractions, broadly consistent with trends in laminar flames. However, probability density functions reveal that the relationship between local instantaneous and time-averaged soot volume fraction is different in the lower and upper regions of each flame. In the lower regions, the instantaneous and average volume fractions increase together with distance from the burner. However, the upper regions exhibit a bi-modal distribution in local, instantaneous volume fraction. This suggests that burnout in the tip region occurs predominantly by reducing the proportion of the flame being occupied by the sheets of soot, rather than by reducing the instantaneous volume fraction within the sheets. In addition, the shape of the pdf is different for each flame, showing a dependence on the turbulent characteristics, and that care must be taken in applying measurements obtained from one class of burner to another.

X-ray measurements within unsteady cavitation

The purpose of this work is to describe the two-phase flow structure of cloud cavitation. The experimental study is performed in a cavitation tunnel equipped with a Venturi-type test section. The geometry studied is characterized by a convergent angle of 18° and a divergent angle of 8°. It leads to regular large vapour cloud shedding. The flow is investigated by means of an X-ray attenuation device. Twenty-four collimated detectors enable the instantaneous volume fraction of the vapour phase to be measured at different locations of the two-phase flow. The X-ray intensity measurement mode enables fast data acquisition (1,000 Hz). The results are compared with double optical probe measurements. The influences of the velocity and the size of the cavitation area on the time–space distribution of the vapour fraction are studied. The convection velocity of the vapour structures is estimated. The mean distribution of the volume fraction of the vapour phase during the shedding cycle is computed using the phase- averaging method.

Microvessel hematocrit: measurement and implications for capillary oxygen transport.

Microvascular preparations of the hamster cheek pouch and cremaster muscle were used to establish the relationship among three measures of red cell distribution: 1) the systemic hematocrit defined as the volume percentage of red cells sampled from a toe clip; 2) the tube hematocrit defined as the instantaneous volume fraction of red cells in a microvessel segment of measured length and diameter; and 3) the discharge hematocrit defined as the volume percentage of red cells that flowed into micropipettes inserted into microvessels. The results show the tube hematocrit is low and highly variable in the presence of a nearly constant systemic hematocrit. The discharge hematocrit, in contrast, consistently approximated systemic values in blood taken from arterioles or venules with diameters of 6-98 micron. Indeed, the mean ratio of the discharge to the systemic hematocrit did not differ from unity (P greater than 0.25). The observed similarity between the discharge and systemic hematocrit indicates that red cells are distributed uniformly across capillary networks. Differences between the absolute value and variance of the tube hematocrit compared with the discharge hematocrit imply that the anatomical volume of a microvessel can differ from the volume available to cells and plasma within a microvessel. Thus moment-to-moment variation in the tube hematocrit or capillary red cell spacing may be indicative of a change in the effective capillary flow cross section and not solely on the inflow hematocrit.