Total Phosphorus Input Research Articles

Analysis of the Physical and Morphological Aspects of a Hydrographic Watershed with Critical Areas for the use of Water Resources, Brazil

Objective: Map the excavated ponds, hydrology, relief, slope and soil types in the Jesuítas river micro-watershed. Estimate the input of Total Nitrogen and Total Phosphorus due to fish production in excavated ponds. Theoretical Framework: Georeferencing is one of the technologies applied in geoscience. It encompasses the collection, storage, processing, analysis and representation of data from a given geographical space, using computer systems. Method: Open access geo-technological tools such as QGIS and Google Earth to create maps, morphometric indicators and estimate nutrient inputs from fish farming in excavated ponds in the Jesuítas Creek watershed. Qualitative and quantitative exploratory research on fish production in the municipalities that share the Jesuítas Creek watershed. Results and Discussion: The Jesuítas Creek watershed has a favorable geomorphometry and road network for aquaculture production in excavated ponds. Fish production in the municipalities in 2023 reached 35,112 tons, especially in Nova Aurora, with Tilapia accounting for 99.6% of this production. Large excavated ponds, those larger than 6,000 m², are the most abundant in the watershed and are estimated to contribute the most nitrogen and phosphorus to the watershed hydrology. Research Implications: Planning the orderly and environmental use of water resources for fish farming in the region. The maps and indices provided important data for the sustainable and economic expansion of fish farming. Originality/Value: The mapping of ponds and physical resources, such as land use and occupation, is important information for analyzing the direction of the expansion of activities, as well as pointing out, on maps and data, the suitable locations and the actions needed for the sustainable planning of fish farming in the micro-watershed of the Jesuítas stream.

Spatiotemporal Changes in the Quantity and Quality of Water in the Xiao Bei Mainstream of the Yellow River and Characteristics of Pollutant Fluxes

The Xiao Bei mainstream, located in the middle reaches of the Yellow River, plays a vital role in regulating the quality of river water. Our study leveraged 73 years of hydrological data (1951–2023) to investigate long-term runoff trends and seasonal variations in the Xiao Bei mainstream and its two key tributaries, the Wei and Fen Rivers. The results indicated a significant decline in runoff over time, with notable interannual fluctuations and an uneven distribution of runoff within the year. The Wei and Fen Rivers contributed 19.75% and 3.59% of the total runoff to the mainstream, respectively. Field monitoring was conducted at 11 locations along the investigated reach of Xiao Bei, assessing eight water quality parameters (temperature, pH, dissolved oxygen (DO), chemical oxygen demand (COD), ammonia nitrogen (NH3-N), total phosphorus (TP), permanganate index (CODMn), and 5-day biochemical oxygen demand (BOD5)). Our long-term results showed that the water quality of the Xiao Bei mainstream during the monitoring period was generally classified as Class III. Water quality parameters at the confluence points of the Wei and Fen Rivers with the Yellow River were higher compared with the mainstream. After these tributaries merged into the mainstream, local sections show increased concentrations, with the water quality parameters exhibiting spatial fluctuations. Considering the mass flux process of transmission of the quantity and quality of water, the annual NH3-N inputs from the Fen and Wei Rivers to the Yellow River accounted for 11.5% and 67.1%, respectively, and TP inputs accounted for 6.8% and 66.18%. These findings underscore the critical pollutant load from tributaries, highlighting the urgent need for effective pollution management strategies targeting these tributaries to improve the overall water quality of the Yellow River. This study sheds light on the spatiotemporal changes in runoff, water quality, and pollutant flux in the Xiao Bei mainstream and its tributaries, providing valuable insights to enhance the protection and management of the Yellow River’s water environment.

Land management policy shift influenced seasonal variation of erosion-induced nitrogen and phosphorus outputs from intensive agricultural catchment

A shift in policy to intensive agricultural production and land management often leads to excessive fertilizer application and accelerated erosion with consequent detrimental effects to water bodies. We investigated the impact of that shift by quantifying the spatial and temporal change in sediment sources and associated total nitrogen (TN) and total phosphorus (TP) pollutants output loads in an intensive agricultural catchment in North China across one year (November 2021–November 2022). We describe the implications of this work for intensive agriculture elsewhere in China and other countries. Seasonal sediment source apportionment was estimated at the catchment outlet using Berillium-7 (7Be) combined with compound-specific stable isotope (CSSI) signatures from sources and sediments. Diagnostic ‘fingerprints’ in MixSIAR were used to discriminate sediment sources between forest and crop farmland converted from forest (F + C(F)), crop farmland (C), and vegetable farmland (V). Our study identified F + C(F) as the dominant sediment source (mean 55.24 ± 2.91 %), intermediate on V (mean 30.06 ± 2.20 %), and least on C (mean 14.70 ± 2.13 %). Sedimentation ranged from 37.98 ± 3.02 to 89.60 ± 12.68 t·ha−1·event−1 and coincided with shifted land use policy and rainfall distribution. The TN and TP in sediment were both mainly derived from F + C(F) (averaged 22.27 ± 4.26 t·event−1 and 11.62 ± 2.28 t·event−1) and least from V (averaged 1.63 ± 0.29 and 2.09 ± 0.33 t·event−1). Despite being a significant sediment source, V contributed little sediment TN and TP input for eutrophication. Our findings imply that F + C(F) are diffuse sources of catchment pollution over the short term. These results describe the successful use of CSSI and 7Be to cost-effectively quantify the seasonal variation of sediment TN and TP loads from land-use-specific sources in the catchment under shifting land management policy in China with potential for use elsewhere. These findings enable soil conservation strategies and land management practices optimized for implementing targeted pollutant abatement initiatives in intensive agriculture in China and elsewhere.

Efficacy of point source legislation quantified for a 64-year river water quality trajectory of phosphorus loading

Changes in river water quality often follow typical trajectories characterized by sequential phases of degradation and recovery induced by management measures, typically achieved with combinations of legislative and technological interventions. However, the key question about the effectiveness of the different types of legal interventions – source control, use-related, and end-of-pipe – remains poorly understood. With the case of phosphorus (P), which is a valuable indicator of surface water quality and a widespread target of legislation at various governance levels in order to control eutrophication of water bodies, we quantified the relation between point source loading of P and resulting river water quality for a multidecadal trajectory of the river Ruhr (Germany). In particular, we analysed P-related legislation targeting point source pollution enforced at EU, national, state, and local level and linked their development with measured total phosphorus (TP) concentrations in the river Ruhr (Germany). To this end, we combined archival data with information in the literature and conducted interviews with contemporary witnesses to describe and quantify the efficacy of each legislative approach. Although not specifically targeted at P reduction, end-of-pipe measures (sewer systems and wastewater treatment plants (WWTP)) reduced TP inputs to surface waters already in the 1960s and 1970s, curbing TP inputs to the Ruhr by 38% in 1980. The first targeted source control legislation – the banning of phosphates in textile detergents in 1981 – effectively reduced TP concentrations in WWTP influents by 36% since 1990. In combination with stronger end-of-pipe legislation focusing on P elimination in WWTP since the 1990s, TP concentrations in WWTP effluents were reduced by 86% at the end of the 1990s and by 92% in 2021. Complete and successful source control for textile detergents made use-related legislation redundant. Our study demonstrates that source control measures should be prioritized, because they are the fastest way to curb emissions. These findings provide insights that can inform efficient decision-making regarding water quality in a trajectory perspective of hierarchical governance and technological needs, as well as effective policy-making and management for other pollutants requiring control from point sources.

Current assessment of nitrogen and phosphorus content in the river water and snow cover of the Southern Baikal basin

The paper presents the results of long-term studies of chemical composition of water of tributaries and snow cover of the south-eastern and south-western coasts of Lake Baikal. The content of different forms of nitrogen and phosphorus in river water and snow cover was analyzed. A quantitative assessment of total nitrogen and phosphorus input from the atmosphere to the Southern Baikal catchment area for 2019-2023 is given. The south-western coast of the lake experiences a great load in terms of the content of various forms of nitrogen and phosphorus in the snow cover and water of tributaries. Nitrogen in the snow cover and tributaries of Southern Baikal is represented mainly by its mineral form. The rivers of the south-eastern coast, which are exclusively atmosphere-fed, are generally not subjected to anthropogenic impact. In contrast, the minor watercourses of the south-western coast of the lake (Listvyanka settlement) are significantly influenced by economic activities. The organic form of phosphorus predominates in the snow cover of Southern Baikal and in river waters of the south-eastern coast. In the water of tributaries of the south-west coast phosphorus is found in its mineral form. A comparison of current data with the results of previous years was carried out.

A mass-balance approach for predicting lake phosphorus concentrations as a function of external phosphorus loading: Application to the Lake St. Clair – Lake Erie System (Canada – USA)

Abstract A mass balance model is presented that links the total phosphorus concentration in lakes to the water residence time, Rw (lake volume divided by the annual water inflow) and the total phosphorus residence time, Rp (average standing stock of lake total phosphorous divided by the external annual total phosphorus input). Following a change in the external load, the lake total phosphorus concentration asymptotically approaches a new value that depends on the Rp:Rw ratio, with the rate of approach controlled by Rp. We applied this approach to a recent reanalysis of the water and total phosphorus budgets of the Lake Erie system of the Laurentian Great Lakes for the 2003-2016 period. We generated load–response relationships and response matrices that relate the steady state total phosphorus concentrations to external total phosphorus loads, for the whole Lake Erie system and for the individual basins (Lake St. Clair, western basin, central basin, eastern basin) and connecting channels (St. Clair River, Detroit River). These relationships and matrices provide a simple but robust framework to gauge the potential response of total phosphorus concentrations to total phosphorus load reductions, such as the 40% reduction proposed for Lake Erie under the Canada-United States Great Lakes Water Quality Agreement. The mass balance analysis further highlights the importance of inter-basin total phosphorus transfers. For example, around 70% of the total phosphorus concentration in the eastern basin is contributed by inflow from the central basin. Consequently, total phosphorus load abatements in watersheds upstream of the eastern basin, rather than in the direct watershed itself, will have the greatest impact on the eastern basin's concentration. Overall, our results illustrate how simple mass balance calculations can provide useful guidance to efforts to manage phosphorus enrichment of lakes.

The effects of nutrient loading from different sources on eutrophication in a large shallow lake in Southeast China.

Lake water eutrophication has become one of the leading obstacles to sustainable economic development in China. Research on the effects of mainstream currents on reservoirs has been relatively underdeveloped compared with research on tributaries, though changes in the water-sediment transport regime in a downstream river may affect nutrient transport behavior in a lake connected to that river. This is particularly problematic because certain wastewater sources, including runoff from agricultural wastes and industrial discharges, adversely affect lake water. Our study focused on Sanshiliujiao Lake, a significant drinking water source in Fujian, Southeast China, that has suffered considerably from eutrophication over the past few decades. This study aimed to estimate the phosphorus and nitrogen loads to the lake, exploring their sources and their ecologic effects using in situ observation and the export coefficient model. Our results showed that the pollution loads of total phosphorus (TP) and total nitrogen (TN) were 2.390 and 46.040 t/year, respectively, most of which were derived from the water diversion (TP 45.7%, TN 29.2%) and non-point source (TP 30.2%, TN 41.6%). The TN input was the highest in East river (3.557kg/d), followed by Red river (2.524kg/d). During the wet season, the input of TP and TN increased by 14.6 and 18.7 times, respectively, but produced only slight variations in concentration. Water diversion enriched the nutrients inputs and altered the structure and abundance of phytoplankton communities. In addition, when water flows from the main river directly to Sanshiliujiao Lake, algal blooms in river-connected lakes are significantly exacerbated, so our study may also serve as a theoretical basis to regulate eutrophication in Sanshiliujiao Lake.

Large-scale sediment and phosphorus transport in the Three Gorges Reservoir based on a new reservoir operation method

Change of hydrodynamic conditions is a key factor inducing sedimentation, water eutrophication and algal blooms in the Three Gorges Reservoir (TGR). How to mitigate sedimentation and phosphorus (P) retention by improving hydrodynamic conditions in the Three Gorges Reservoir area (TGRA) is an urgent issue in the study of sediment and water environment. In this study, a Hydrodynamic-Sediment-Water quality model for the whole TGRA is proposed considering sediment and P inputs from numerous tributaries, and a new reservoir operation method namely the tide-type operation method (TTOM) is used to investigate the large-scale sediment and P transport in the TGR based on the model. Results indicate that the TTOM can reduce sedimentation and total phosphorus (TP) retention in the TGR. Compared with the actual operation method (AOM), sediment outflow and sediment export ratio (Eratio) of the TGR increased about 17.13% and 1%–3% in 2015–2017, and sedimentation decreased about 3% under the TTOM. TP retention flux and retention rate (RE) decreased about 13.77% and 2%–4%. The flow velocity (V) and sediment carrying capacity (S*) increased about 40% in the local reach. Larger daily water level fluctuation at dam site is more conducive to reducing sedimentation and TP retention in the TGR. Sediment inputs from the Yangtze River, Jialing River, Wu River and other tributaries account for 59.27%, 11.21%, 3.81% and 25.70% of the total sediment inflow during 2015–2017, and TP inputs were 65.96%, 10.01%, 17.40% and 6.63%. In the paper, an innovative method is proposed to reduce sedimentation and P retention in the TGR under the given hydrodynamic conditions and related quantitative contribution driven by the proposed method is analyzed. The work is favorable for expanding the understanding of the hydrodynamic and nutrition flux changes in the TGR, and provides a new perspective for water environment protection and reasonable operation of large reservoirs.

Study on total phosphorus pollution load estimation and prevention and control countermeasures in Dongting Lake

In order to fight the battle for reducing total phosphorus (TP) in Dongting Lake and continuously improve the water ecological environment of the Yangtze River, this study accounts for the TP pollution load in Dongting Lake. To this end, the sources of the pollutants are analyzed and corresponding prevention and control measures are proposed by comprehensive use of field research and historical data analysis. The obtained results reveal that the annual TP input to the Dongting Lake was 23287 t in 2017, among which the input from four rivers and three lake entrances represent the main source with an annual TP input of 14033 t (including 3681 t from sediment input), accounting for 60.26%. Agricultural pollution is the second largest source of TP input, accounting for 32.69%, while domestic pollution only accounts for 5.93%. Additionally, the contributions of atmospheric deposition and industrial pollution in order are 0.69% and 0.4%. The TP input from moving sources such as birds and waterway shipping is very small, only accounting for 0.03%. Based on the achieved results, this study aims to propose corresponding prevention and control measures in four aspects: interception of river and lake pollution, control of agricultural pollution sources, enhancement of sewage treatment and industrial pollution prevention.

Output characteristics and driving factors of non-point source nitrogen (N) and phosphorus (P) in the Three Gorges reservoir area (TGRA) based on migration process: 1995–2020

Although physical models at present have made important achievements in the assessment of non-point source pollution (NPSP), the requirement for large volumes of data and their accuracy limit their application. Therefore, constructing a scientific evaluation model of NPS nitrogen (N) and phosphorus (P) output is of great significance for the identification of N and P sources as well as pollution prevention and control in the basin. We considered runoff, leaching and landscape interception conditions, and constructed an input-migration-output (IMO) model based on the classic export coefficient model (ECM), and identified the main driving factors of NPSP using geographical detector (GD) in Three Gorges Reservoir area (TGRA). The results showed that, compared with the traditional export coefficient model, the prediction accuracy of the improved model for total nitrogen (TN) and total phosphorus (TP) increased by 15.46 % and 20.17 % respectively, and the error rates with the measured data were 9.43 % and 10.62 %. It was found that the total input volume of TN in the TGRA had declined from 58.16 × 104 t to 48.37 × 104 t, while the TP input volume increased from 2.76 × 104 t to 4.11 × 104 t, and then decreased to 4.01 × 104 t. In addition Pengxi River, Huangjin River and the northern part of Qi River were high value areas of NPSP input and output, but the range of high value areas of migration factors has narrowed. Pig breeding, rural population and dry land area were the main driving factors of N and P export. The IMO model can effectively improve prediction accuracy, and has significant implications for the prevention and control of NPSP.

Evaluation of Biogeochemical Changes in Channelized and Restored Portions of a Subtropical Floodplain

Floodplains are critically important ecosystems that provide a whole suite of ecosystem services, including nutrient and carbon sequestration, flood mitigation, water storage, and critical wildlife habitat. However, human modification of rivers and floodplains through channelization, artificial levee construction, reductions in the active floodplain area, and water management can significantly reduce the ecosystem function of river–floodplain systems. In this study, we evaluated the changes in the nutrient loading of the Kissimmee River floodplain during the restoration of the river–floodplain system. In addition to time-series loading analysis, we also evaluated soil nutrient concentrations across the lower portion of the Kissimmee River floodplain. During the 44-year nutrient loading time-series, the floodplain remained a nutrient exporter with changes in nutrient loading generally corresponding to both water quality (i.e., point source reductions) and hydrologic restoration activities in the watershed and Kissimmee River floodplain. During the study period, inputs of total phosphorus and total nitrogen loads from upstream either significantly increased or remained the same. In addition to external sources of nutrients, internal sources of nutrients from floodplain soils can also contribute to the total nutrient export from the system. These internal sources could be organic via the decomposition of organic matter or geologic from the original excavation of the canal and/or restoration backfilling. Soil nutrient concentrations vary between vegetative communities and landscape position and could be a significant source of phosphorus to the downstream system, which is plagued by eutrophic conditions. Therefore, as floodplain function in the Kissimmee River continues to be restored and managed, additional effort may be needed to address nutrient inputs and internal legacy nutrients.

Hail-caused greenfall leaves, litterfall, nutrients, and leaf decomposition in tropical cloud forest and a restoration planting

Abstract Greenfall leaves caused by hailstorms may represent a resource pulse of nutrients. We determined the contribution of greenfall versus senescent leaves to total litterfall production, carbon, nitrogen and phosphorus input to the system, and leaf decomposition rate. Litterfall was collected monthly for three years in two cloud forests (F1, F2) and a restoration planting area (R) in Veracruz, Mexico. Two fortuitous hailstorms occurred in the second year. Leaf decomposition rate was determined in all three sites but did not differ across them. Total annual litterfall, excluding greenfall, was 10.0, 10.1, and 7.7 Mg ha−1 y−1 for F1, F2, and R, respectively. Senescent leaves represented 65% of the litterfall, while greenfall leaves increased the annual leaf biomass component of the litterfall by 12%. Concentrations of carbon, nitrogen, and phosphorus were 2.3, 5.7, and 18.1% higher, respectively, in greenfall than in senescent leaves. Greenfall increased the annual input of C, N, and P by 12, 13, and 14%, respectively. Despite their short duration (approximately 70 minutes), the hailstorm events generated a substantial contribution of greenfall leaves and a source of extra C, N, and P, since these leaves decompose and are incorporated into the cloud forest system.

Threshold indicators of primary production in the north-east Atlantic for assessing environmental disturbances using 21 years of satellite ocean colour

Primary production (PP) is highly sensitive to changes in the ecosystem and can be used as an early warning indicator for disturbance in the marine environment. Historic indicators of good environmental status of the north-east (NE) Atlantic and north-west (NW) European Seas suggested that daily PP should not exceed 2–3 g C m−2 d−1 during phytoplankton blooms and that annual rates should be <300 g C m−2 yr−1. We use 21 years of Copernicus Marine Service (CMEMS) Ocean Colour data from September 1997 to December 2018 to assess areas in the NE Atlantic with similar peak, climatology, phenology and annual PP values. Daily and annual thresholds of the 90th percentile (P90) of PP are defined for these areas and PP values above these thresholds indicate disturbances, both natural and anthropogenic, in the marine environment. Two case studies are used to test the validity and accuracy of these thresholds. The first is the eruption of the volcano Eyjafjallajökull, which deposited large volumes of volcanic dust (and therefore iron) into the NE Atlantic during April and May 2010. A clear signature in both PP and chlorophyll-a (Chl a) was evident from 28th April to 6th May and from 18th to 27th May 2010, when PP exceeded the PP P90 threshold for the region, which was comparatively more sensitive than Chl a P90 as an indicator of this disturbance. The second case study was for the riverine input of total nitrogen and phosphorus, along the Wadden Sea coast in the North Sea. During years when total nitrogen and phosphorus were above the climatology maximum, there was a lag signature in both PP and Chl a when PP exceeded the PP P90 threshold defined for the study area which was slightly more sensitive than Chl a P90. This technique represents an accurate means of determining disturbances in the environment both in the coastal and offshore waters in the NE Atlantic using remotely sensed ocean colour data.

Potential to Reduce Chemical Fertilizer Application in Tea Plantations at Various Spatial Scales.

Tea is the main commercial crop grown in China, and excessive application of chemical fertilizers in tea plantations is common. However, the potential to reduce chemical fertilizer use in tea plantations is unclear. In this study, Zhejiang Province was selected as the research object to systematically analyze the potential for tea plantation chemical-fertilizer reduction at different spatial scales. The geographic information system-based analytic hierarchy process method and Soil and Water Assessment Tool model were used to determine the chemical fertilizer reduction potential at the province scale and watershed scale, respectively. At the field scale, two consecutive years of field experiments were conducted on a tea plantation. Province-level analysis showed that 51.7% of the area had an average total fertilization intensity greater than 350 kg/hm2 and a high reduction potential. Watershed analysis revealed that chemical fertilizer reduction had better potential in reducing total nitrogen and total phosphorus inputs to runoff in the short term, whereas 50% organic fertilizer substitution was the best strategy to achieve long-term effects. The field experiments further proved that organic fertilizer substitution balanced tea growth and environmental protection. This study provides a useful method to investigate strategies to reduce chemical fertilizer use in tea-growing areas.

Nutrient levels, trophic status and land-use influences on streams, rivers and lakes in a protected floodplain of Uruguay

Land-use intensification impacts freshwater ecosystems in many agricultural landscapes, including the Rio de la Plata grasslands in Southeastern South America. We evaluated water chemistry of rivers, streams and lakes associated with a protected river-floodplain in the Queguay River basin in Uruguay. From 2019–2021, we measured phosphorus (P) and nitrogen (N) forms, dissolved oxygen (DO), turbidity and other chemical parameters; basin-scale land-use via Sentinel satellite imagery; and trophic status based on nutrient concentrations and Principal Components Analysis (PCA). Results highlighted low nutrient concentrations in the Queguay rivers, indicating this watershed as a national reference for evaluating eutrophication in Uruguay. Levels of total nitrogen (TN) in rivers averaged 430–510 µg/L and total phosphorus (TP) averaged 44–51 µg/L, classifying them as oligotrophic-mesotrophic systems. Streams ranged in TP from 51 to 97 µg/L and in TN from 545 to 701 µg/L, suggesting meso- to eutrophic states according to TP levels, and potential anthropogenic eutrophication in smaller basins with crop cover > 25%. Floodplain lakes are a conservation target within the protected area and had TP averaging 74–109 µg/L, suggesting eutrophic-hypereutrophic states based on TP and potential external nutrient inputs. The positive correlation between basin-scale crop cover and mean TP and soluble reactive phosphorus (SRP) concentrations suggested that land-cover plays a role in nutrient levels of fluvial and lotic systems. This study establishes a baseline for water chemistry in lakes and fluvial ecosystems in the Queguay River basin within an extensive agricultural region of the La Plata River Grasslands. By providing the first time series dataset of water chemistry for this area, we fill a major geographical gap regarding the limnological attributes of freshwater ecosystems in northwestern Uruguay. Results highlight the value of the Queguay basin for freshwater habitat conservation, and the vulnerability of these systems to land cover changes and nutrient loading from external sources.

Seasonal Dynamics of Algal Net Primary Production in Response to Phosphorus Input in a Mesotrophic Subtropical Plateau Lake, Southwestern China

A comprehensive 3-dimensional hydrodynamic and eutrophication model, the environmental fluid dynamics code model (EFDC) with three functional phytoplankton groups, was applied to simulate the algal dynamics in a mesotrophic P-limited subtropical plateau lake, Lake Erhai, Southwestern China. Field investigations revealed the seasonal patterns in external total phosphorus (TP) input and TP concentration, as well as the composition of the phytoplankton community. The model was calibrated to reproduce qualitative features and the succession of phytoplankton communities, and the net primary production was calculated. The modeled daily net primary production (NPP) ranged between −16.89 and 15.12 mg C/m2/d and exhibited significant seasonal variation. The competition for phosphorus and temperature was identified as the primary governing factor of NPP by analyzing the parameter sensitivity and limitation factors of the lake. The simulation of four nutrient loading reduction scenarios suggested high phytoplankton biomass and NPP sensitivity to the external TP reduction. A significant positive correlation was found among NPP, total phytoplankton biomass and TP concentration. Overall, this work offers an alternative approach to estimating lake NPP, which has the potential to improve sustainable lake management.

Assessment of Phosphorus Input from Urban Areas in the Passaúna River and Reservoir

Elevated phosphorus loads play an important role in the deterioration of water quality and can subsequently pose a threat to the aquatic organisms in a river or a standing water body. The accurate assessment of total phosphorus (TP) fluxes from a catchment is of high importance to the well-being of the entire river ecosystem. In this study, we assessed the yearly input of TP from the urban areas of the Passaúna catchment in southern Brazil. The catchment drains into the eponymous reservoir, which provides drinking water for more than 800,000 inhabitants of the Curitiba Metropolitan region. The protection of the water quality in the river as well as in the reservoir is of paramount importance, yet high phosphorous inputs have been detected. For adequate protection, the catchment emissions need to be accurately assessed. Initially, the TP concentration in the river sediment was determined in order to assess the relationship between the TP export of the urban areas and the TP stock of the river. It was found that in areas with a higher share of urban land cover and especially in areas with a lack of sewage treatment, the TP concentration in the sediment reached up to 6700 mg/kg. The assessment of the overall TP input from urban areas was based on a regionalized emission-modeling approach, combined with data from long-term water quality monitoring of the river. The monitoring station established upstream of the Passaúna Reservoir inflow provided an initial assessment and the necessary output for the validation and calibration of the model. From the drainage basin of the monitoring station, an overall TP input of 2501 kg/a (0.31 kg/(ha a)) was measured between 1 May 2018 and 1 May 2019 (3508 kg TP/a or 0.23 kg/(ha a) when extrapolating the overall catchment of the Passaúna Reservoir). The monitoring data indicated that the TP input increases during the wet months of the year. The sediment stock of the river also plays an important role in the interannual budget of TP. During the timespan of one year, many deposition–resuspension events happen. The resuspended material is included in the baseflow and hinders the differentiation between urban and nonurban input. After calibration, the model was able to predict the yearly input of TP from the urban areas of the Passaúna catchment. In addition, the share of inhabitants who are not connected to the sewer system was assessed. Overall, the combination of monitoring and modeling in this study offers a valuable overview of the TP dynamics of the system, while the model ensures reproducibility with high accuracy at the same time.

Spatial characteristics of nutrient budget on town scale in the Three Gorges Reservoir area, China

Accurately quantifying nutrient budget is an essential step toward sustainable nutrient management in large watersheds increasingly disturbed by human activity. A town-scale nutrient budget framework based on the Soil and Water Assessment Tool was developed for 2010–2012 in the Three Gorges Reservoir area in China (TGRA). Moran's I spatial correlation test and Geodetector spatial heterogeneity test were employed to systematically analyze the spatial characteristics of the resulting nutrient budget. The Moran's I value of total nitrogen (TN) and total phosphorus (TP) gradually increased from input to output in the range of 0.091–0.232 and 0.102–0.484, respectively. Towns with higher TN and TP inputs were largely concentrated in the main urban area of Chongqing because of its high population density. By contrast, towns with higher TN and TP outputs were concentrated in the head of the TGRA. The Moran's I values of the TN and TP retention coefficients (R) were 0.433 and 0.524, respectively, demonstrating clear spatial consistency. Towns with a “High-high” spatial consistency pattern and positive R value were concentrated in the tail and hinterland, while those with a “Low-low” spatial consistency pattern and negative coefficient value were located mainly in the head of the TGRA. This phenomenon was mostly caused by differences in regional elevation, the normalized difference vegetation index, and soil erosion factor. The interaction effect between any two of these three factors on nutrient retention (Geodetector q-value) was greater than 60%. Therefore, future nutrient management should be based on a full understanding of regional biophysical conditions, especially in large areas. These findings provide a new perspective on fine nutrient management.

Modeling and assessing water and nutrient balances in a tile-drained agricultural watershed in the U.S. Corn Belt

Identifying the key processes and primary sources of water and nutrient losses is essential for water quantity and quality management in watersheds. This is especially true in the U.S. Corn Belt, which has been recognized as the primary region contributing nutrient loads to the Great Lakes and the Gulf of Mexico. A SWAT (Soil and Water Assessment Tool) model simulation was set up in an agricultural watershed with about 50% tile drainage area in the U.S. Corn Belt to study the water and nutrient balance components for the whole watershed and the corn-soybean rotation system. The SWAT model was improved to consider additional nitrogen and phosphorus loss paths from the soil. The model was comprehensively calibrated and validated for simulating monthly stream flow, total suspended solids (TSS), nutrient loads (including total Kjeldahl nitrogen (TKN), nitrate and nitrite nitrogen (NOx-N), total phosphorus (TP) and orthophosphate phosphorus (orthoP)), actual evapotranspiration (ETa), leaf area index (LAI) and annual crop yields in the watershed from 2011 to 2019. Results showed the model performance was very good for simulating the stream flow, TSS and ETa, and acceptable for nutrient loads, LAI and crop yields. ETa, surface runoff, lateral soil flow, tile drainage and percolation respectively accounted for 65%, 15%, 2%, 8% and 9% of the precipitation. Fertilizer was the main source of nitrogen and phosphorus input to the watershed, and harvested crops were the main paths removing nutrients. Surface runoff, tile drainage and percolation each contributed about 30% of total nitrogen losses to water, with surface runoff being dominated by organic nitrogen while tile drainage and percolation were dominated by nitrate nitrogen. Phosphorus losses were mainly through surface runoff, which resulted in 66% of the total losses and was dominated by organic phosphorus and soluble phosphorus. Representing about 49% of the watershed area, the corn-soybean rotation system contributed 83% and 88% of the total nitrogen and phosphorus inputs, respectively, to the watershed, as well as 64% and 46% of the nitrogen and phosphorus losses to the water system, respectively. The non-growing season (October to the next April) was identified as the critical period resulting in water and nutrient losses due to low evapotranspiration and plant uptake. Targeted management strategies for reducing nutrient loads in key hydrological paths were suggested.

Hortonian Scaling of Coupled Hydrological and Biogeochemical Responses Across an Intensively Managed River Basin

Structural and functional attributes across fractal river networks have been characterized by well-established and consistent hierarchical, Hortonian scaling patterns. In most of the global river basins, spatial patterns of human settlements also conform to similar hierarchical scaling. However, emergent spatial hierarchical patterns and scaling of heterogeneous anthropogenic nutrient loads over a river basin are less known. As a case study, we examined here a large intensely managed river basin in Germany (Weser River; 46K km2; 8M population). Archived data for point-/diffuse-sources of total Phosphorus (Ptot) input loads were combined with numerical and analytical model simulations of coupled hydrological and biogeochemical processes for in-stream Ptot removal at the network scale. We find that Ptot input loads scale exponentially over stream-orders, with the larger scaling constant for point-source loads from urban agglomerations compared to those for diffuse-source contributions from agricultural and forested areas. These differences in scaling patterns result from hierarchical self-organization of human settlements, and the associated clustering of large-scale, altered land-cover. Fraction of Ptot loads removed through in-stream biogeochemical processes also manifests Hortonian scaling, consistent with predictions of an analytical model. Our analyses show that while smaller streams are more efficient in Ptot removal, in larger streams the magnitude of Ptot loads removed is higher. These trends are consistent with inverse scaling of nutrient removal rate constant with mean discharge, and downstream clustering of larger cumulative input loads. Analyses of six nested sub-basins within the Weser River Basin also reveal similar scaling patterns. Our findings are useful for projecting likely water-quality spatial patterns in similar river basins in Germany, and Central Europe. Extensions and generalizations require further examination of diverse basins with archetype spatial heterogeneities in anthropogenic pressures and hydroclimatic settings.