Soil Input Research Articles

Quantification of the Effect of Soil and Biophysical Parameters on Water Balance Modelling Using SWAT+ in Forested Catchments

ABSTRACTAccurate simulation of water balance components is crucial for effective water and land management practices. The performance of process‐based hydrological models relies on the accurate determination of input variables. The objective of this study is to quantify the magnitude of the effect of soil properties (depth and texture) and biophysical parameters on water balance simulation for a forested catchment using the Soil and Water Assessment Tool (SWAT+). Simulations were carried out for a baseline scenario using the default soil inputs, followed by extending the soil profile depth up to 15 m under three different rainfall scenarios. Sensitivity analysis of model outputs was performed using the SENSitivity ANalysis (SENSAN) programme of the Parameter ESTimation (PEST) suite, coupled with SWAT+. The results showed that increasing soil profile depth to 15 m led to around 50% increase in water yield, and around 20% reduction in percolation with slight variations across the three rainfall scenarios. Evapotranspiration rates were slightly increased in deeper soil profiles. The sensitivity of evapotranspiration, surface runoff, and percolation to LAI‐related biophysical parameters was pronounced, highlighting the need to include such parameters in SWAT+ model calibration. The water uptake from deeper soil layers by deep roots, even in rocky substrates, as documented in the literature, is not adequately captured by the SWAT+ model. Our work showed that in general, developing local soil databases with detailed information on deeper layers is needed, to improve the accuracy and reliability of hydrological models in predicting water fluxes, thereby supporting informed water resources management decisions.

Carbon and Nitrogen Allocation and Input in Soil with Grain Crops Post-Harvest Residues: East-European Plain Case Study

Carbon and Nitrogen Allocation and Input in Soil with Grain Crops Post-Harvest Residues: East-European Plain Case Study

Nitrogen Transport Pathways and Source Contributions in a Typical Agricultural Watershed Using Stable Isotopes and Hydrochemistry

The increasing global nitrogen input poses a significant threat to aquatic environments, particularly in agricultural watersheds, where intensive human activities and insufficient water protection infrastructure exacerbate the risk of nitrogen pollution. Accurate identification of nitrogen pollution sources and the associated transformation processes is essential for protecting watershed ecosystems. In this study, a combination of hydrochemical analysis, correlation and principal component analysis, and stable nitrate isotopes (δ15N-NO3− and δ18O-NO3−) were employed to trace nitrogen transport pathways and source contributions in both surface water and groundwater within a typical agricultural watershed. The results revealed the presence of nitrogen pollution, including total nitrogen (TN), ammonia nitrogen (NH3-N), and nitrate nitrogen (NO3−-N), with significant spatial and seasonal variations in both surface water and groundwater. The spatiotemporal evolution of hydrochemical indicators and nitrate isotope compositions highlighted multiple potential sources of nitrogen, including soil input, agricultural input, and manure and sewage input. The results from stable isotope analysis in an R (SIAR) model indicated that ammonium fertilizers (7.1~78.4%) and manure and sewage (2.6~69.7%) were the primary sources of nitrates in surface water, while manure and sewage were the main sources in groundwater (67.9~73.7%). This research demonstrated that nitrification, seasonal variations, and human activities significantly impact nitrogen migration and transformation in agricultural watersheds. However, the issue of groundwater severely polluted by manure and sewage has received insufficient attention. To effectively control nitrogen pollution in agricultural watersheds, it is necessary to improve septic tanks and sewage networks, as well as implement scientific fertilization practices.

Cd mobilization in mining-impacted soils with different bedrock lithology: Insights from stable Cd isotopes

The environmental risk of Cd in soils strongly depends on the mobilization of Cd in soils. However, limited knowledge exists on the redistribution of exogenic Cd inputs in soils, especially across diverse lithological regions. Herein, we aimed to investigate the fate of Cd in soils from two mining areas with contrasting lithologies (siliceous and calcareous) using stable Cd isotopes. The isotope tracing results confirm that mining activities are the main Cd source in both areas. The positive correlation between δ114/110Cd values and goethite/dolomite content indicates the release of heavy Cd isotopes during the dissolution of exogenetic minerals. Additionally, high contents of exchangeable Cd (11 % to 36 %) and Fe oxide-bound Cd (29 % to 42 %) drive plant pumps to transport heavy Cd isotopes from the deeper to upper horizons of the soils from the siliceous area. In the calcareous area, the total organic carbon content is positively correlated with the Cd concentration and δ114/110Cd value, suggesting potential complexation of Cd with organic matter due to the stabilizing effect of carbonate minerals on soil organic matter. This study highlights the different redistributions of exogenous Cd in soils from diverse lithological regions, emphasizing the need to consider regional lithology when developing soil quality standards for Cd.

Changing the Sugarcane N Credit and C Fluxes in Soil by the Application of N-Enhanced Efficiency Fertilizers

The accumulation of sugarcane residues (ASR) on the soil surface in areas with mechanized harvest increases the soil quality with a direct effect on crop production. However, the ASR presents a high C:N (carbon: nitrogen) which promotes N immobilization. The application of N enhanced efficiency fertilizers (EFF) could be an alternative to increase the sugarcane N credit and C in the soil due to inputs in soil. Our goal here was to monitor the additions of EFF in soil and the influence in routes of C stabilization and N credit. A laboratory study was run with the association of urea/U, urea + sulfur/U + S, urea + copper + boron/U + CuB, or urea-kimcoat/U + Kc with sugarcane residue in the soil. Soil C (total organic carbon/TOC, humin/HU, humic acid/HA, and fulvic acid/FA), N (soil and residues) and CO2 emissions were monitored. Results showed that the application of U and U + CuB presented a higher CO2 emission, which created a negative balance in TOC and FA. The routes of C were increased in HA, while there was a decrease in FA. The credit N of fertilizers and sugarcane residue were positive, with an average of 90% and 86%, respectively. Using machine learning, the U + S and U + Kc presented a lower CO2 emission, if compared with the performance of U and U + CuB. Based on these results we conclude that the U and U + CuB presents a lower performance with higher C losses with reduction of carbon in soil.

Clay soil amendment suppressed microbial enzymatic activities while increasing nitrogen availability in sandy soils

AbstractConservation management practices often produced positive but limited desirable outcomes in US Southeast sandy soils, likely due to their intrinsically low clay contents that constrain the soil's capacity to preserve organic carbon (C) and nutrients. In the field, we tested the effectiveness of a novel approach, that is, clay soil amendment, to improve sandy soils. In October 2017, clay‐rich soils (25% clay) were spread at 25 metric tons ha−1 and tilled onto a sandy soil (1.9% clay) in the field, which was further mixed by light tillage at 0‐ to 15‐cm depth, followed by planting winter cover crop mixtures (cereal rye, crimson clover, and winter pea). The crop rotation was cotton and corn with cover crop mixtures planted in the winter fallow season. Soils (0–15 cm) were collected in August 2021 and subjected to physio‐biochemical analyses. Clay amendment increased soil clay content to 3.4%, which improved nitrogen (N) availability by 51% but inhibited the activities of C (β‐d‐cellubiosidase [CB]; β‐xylosidase [BX]; N‐acetyl‐β‐glucosaminidase [NAG]) and N (leucine aminopeptidase [LAP]) cycling enzymes, resulting in up to 78% reduction in microbial respiration. A follow‐up kinetic study on BG and LAP enzymes suggested that clay addition can have different impacts on enzymes with diverse biological origins through distinct mechanisms. Clay addition can potentially improve sandy soils by stabilizing the organic inputs in soils. However, more research is required to understand its long‐term impacts making this approach practical.

Use of potentially toxic elements in sedimentable industrial dust to trace their input in soils (Northern France)

Use of potentially toxic elements in sedimentable industrial dust to trace their input in soils (Northern France)

Distribution of branched glycerol dialkyl glycerol tetraether (brGDGT) lipids from soils and sediments from the same watershed are distinct regionally (central Chile) but not globally

Quantitative reconstructions of past continental climates are vital for understanding contemporary and past climate change. Branched glycerol dialkyl glycerol tetraethers (brGDGTs) are unique bacterial lipids that have been proposed as universal paleothermometers due to their correlation with temperature in modern settings. Thus, brGDGTs may serve as a crucial paleotemperature proxy for understanding past climate variations and improving regional climate projections, especially in critical but under constrained regions. That said, complications can arise in their application due to varying source contributions (e.g., soils vs. peats vs. lacustrine). As such, this study investigates brGDGT distributions in Chilean lake surface sediments and corresponding watershed soils to determine the source of brGDGTs to lake sediments. Global datasets of brGDGTs in lake sediments and soils were additionally compiled for comparison. Distinct brGDGT distributions in Chilean lakes and soils indicate minimal bias from soil inputs to the lacustrine sediments as well as in situ lacustrine production of brGDGTs, which supports the use of brGDGTs in lake sediments as reliable paleotemperature proxies in the region. The ΣIIIa/ΣIIa ratio, initially promising as a brGDGT source indicator in marine settings, shows global complexities in lacustrine settings, challenging the establishment of universal thresholds for source apportionment. That said, we show that the ratio can be successfully applied in Chilean lake surface sediments. Direct comparisons with watershed soils and further research are crucial for discerning brGDGT sources in lake sediments and improving paleotemperature reconstructions on regional and global scales moving forward. Overall, this study contributes valuable insights into brGDGT variability, essential for accurate paleoreconstructions.

Labile and recalcitrant carbon inputs differ in their effects on microbial phosphorus transformation in a flooded paddy soil with rice (Oryza sativa L.)

Organic carbon (C) can greatly affect soil microbial activity and thus alter the nutrient availability in soil. However, little is known about the microbial-mediated P transformation processes with organic C inputs in flooded soils. This study used high-throughput sequencing technology to investigate the effects of labile (glucose) and recalcitrant (lignin) organic C inputs on P availability and microbial communities in the bulk and rhizosphere soil under rice growth, aiming to clarify the key microorganisms involved in soil P transformation. Glucose addition enhanced microbial P immobilization and decreased P availability in the rhizosphere soil, while lignin amendment increased available P concentration in bulk soil through increased soil pH and altered bacterial community. Organic C inputs stimulated the growth and cooperation of specific P-solubilizing bacteria (e.g., Acetobacter and Phenylobacterium), facilitating the transformation of non-labile P to labile P in bulk soils, but also stimulated the growth of Clostridium_sensu_stricto, immobilizing labile P into their biomass. Irrespective of C supply, soil P availability was correlated positively with the abundances of Phenylobacterium and Desulfosporosinus but negatively with those of Acetobacter, Clostridium_sensu_stricto, Clostridium_IV, Gluconacetobacter and Syntrophomonas. This study emphasized the contrasting effects of labile and recalcitrant C on microbial mechanisms of P transformation in a flooded paddy soil. These findings provide potential strategies for microbially mediated P management in paddy fields.

Absence of a water depth signal in archaeal tetraether lipids from surface lake sediments in areas with intensive human activity: A case study from Daihai Lake, Inner Mongolia

Indices based on isoprenoid glycerol dialkyl glycerol tetraethers (isoGDGTs) and hydroxylated GDGTs (OH-GDGTs), such as %Cren, Cren/Cren', and %OH-GDGTs, have been widely used as lake-level proxies in lake sediment cores. However, the interpretation of these indices is potentially complex and more research is needed to determine the contexts in which they can reliably be used for paleohydrological reconstruction. We analyzed the isoGDGTs and OH-GDGTs of multiple sample types (watershed surface soils, lake surface sediments, and sediments from a 70-cm sediment core) from Daihai Lake. Our results show that while the widely-used lake level proxies are not correlated with water depth for the surface sediments, this correlation exists in the samples from the sediment core over the past 60 years. We propose that archaeal GDGTs of modern surface sediments in Daihai Lake may be modified by intensive human activities, including eutrophication and potential terrestrial soil input, which prevents their use for lake-level reconstruction. Data from three other lakes (Qinghai, Lugu, and Yangzong) confirm that lake level proxies based on surface sediments are applicable for Qinghai Lake and Lugu Lake (both of which are in regions with relatively weak human activity), but not for Yangzong Lake (in a region with intensive human activity). Interestingly, the transition zone between Qinghai Lake/Lugu Lake and Daihai Lake/Yangzong Lake corresponds to the Hu Line, which divides China into two parts with contrasting human population densities. We propose that future research should consider these findings when using surface lake sediments for paleoenvironmental calibration in areas with intensive human activity, and that sediment cores may sometimes be more reliable for modern validation studies. Although more studies are needed to verify our conclusions, our findings contribute to the application of archaeal GDGTs to lake-level reconstruction, and they are potentially also significant for the validation of other proxies.

Understanding the impact of within-field Olsen P variation on common wheat production in Olsen P deficient soils

This study investigates the influence of Olsen phosphorus (Ps) within-field variability on common wheat production in Ps-deficient soil. It covers a comprehensive investigation conducted over two growing seasons in Tuscany, Italy, aiming to evaluate the impact of within-field Ps variation on common wheat production and crop responses to different agronomic treatments. Field experiments were undertaken, employing 24 treatments, including 4 wheat varieties, 2 seeding densities, and 3 nitrogen fertilization levels. Soil samples were collected to determine within field variability of main soil properties. At harvesting, aboveground biomass was collected to determine grain yield, straw, and total protein content. Firstly, an ANOVA was performed to account for the effect of the agronomical treatments on crop parameters, namely the Agronomical Input Model (AIM). Then, soil total nitrogen (Ns) and Ps, were added as covariates in a new model, namely the Agronomical and Soil Input Model (ASIM). Results showed a significant spatial variability of Ps within the fields, ranging between 13.7 and 17.4 mg kg-1. Despite this minimal variation in Ps, we observed a linear increase in GY of about 1430 kg ha-1 for each increase of 1 mg kg-1 in Ps. Further studies should be conducted to account for non-linear responses at both lower and higher Ps levels. The ASIM model outperformed AIM, indicating a notable increase in predictive accuracy for both grain yield and protein concentration due to its incorporation of soil parameters. The variance explained by ASIM in predicting the grain yield and protein concentration in grain increased by about 11.0 % and 17.3 %, respectively, with respect to AIM. The study emphasizes the necessity of managing within-field Ps variability through targeted fertilization strategies to enhance wheat production in Ps-deficient soils. By addressing soil nutrient variability, this research aims to contribute to more precise and efficient common wheat production systems.

Chemical Composition of the Aboveground Tissues of Miscanthus × giganteus and Relationships to Soil Characteristics

To reduce the C footprint of human activities, there is a growing need for alternative energy sources including the production of bioenergy feedstocks. Miscanthus × giganteus is a high yielding grass with low environmental impact and high potential for feedstock use. Studying the composition of the aboveground tissues of Miscanthus is important for understanding feedstock quality for biofuel conversion and how crop residue quality may affect soil input management. Data on Miscanthus leaf and stem chemistry including carbon (C), nitrogen (N), macronutrient concentrations, and the optical characteristics of the water extractable organic matter (WEOM) was analyzed to identify differences in composition between aboveground tissues and modeled to identify soil variables that may be correlated with tissue chemistry. Leaves and stems were dominated by N, potassium (K), calcium (Ca), phosphorus (P), and magnesium (Mg), but overall, the leaves contained higher nutrient concentrations compared to the stems. The leaves displayed elevated Si:K (0.0935) and Ca:K (0.445) ratios and lower C:N (36) and C:P (323) ratios compared to the stems (0.0560, 0.145, 150, and 645, respectively). Leaf WEOM contained large, aromatic, and complex structures, while the stem WEOM was dominated by small, recently produced structures. Varying relationships were found between tissue C and the mobile C pool in surface (0–15 cm) and deep (45–60 cm) soils. Overall, Miscanthus leaves had a chemical composition indicative of reduced biofuel quality compared to the stems. The relationships with soil mobile C suggest a dynamic linkage between Miscanthus physiology and this active soil C pool. These results have implications for crop nutrient allocation and nutrient management practices.

Phosphorus recycling and loss from compost‐amended urban gardens: Results from a 7‐year study

AbstractUrban vegetable gardens provide an opportunity to recycle nutrients from food waste back into the human food system through the application of compost. However, a reliance on compost for soil fertility can lead to excess phosphorus (P) inputs that can build up in garden soil and potentially be exported via leachate or runoff. We report the results of a 7‐year experiment in a campus research garden in which replicated raised‐bed garden plots received manure‐based compost or municipal compost that was applied at a higher rate targeted to meet crop nitrogen demand or a lower rate targeted to meet crop P demand. Control plots received either no soil inputs or targeted synthetic fertilizer. Higher input treatments for both types of composts showed steadily increasing concentrations of soil plant‐available P, with a corresponding increase in leachate phosphate concentration. For both higher input compost treatments, approximately 30% of P added as compost was recovered in harvested crops over the 7‐year period, compared to >88% in the lower input compost treatments. In both high‐ and low‐input manure compost treatments, export of P as leachate accounted for approximately 10% of total P input, compared to 4% for the municipal compost. Over the 7‐year study period, P exported as leachate ranged from 0.8 g P/m2 in the no‐input treatments to 6.5 g P/m2 in the higher input manure compost treatments. These results show that tradeoffs are not inevitable as targeted compost applications can lead to high yield and low leachate export.

Selected conservation management strategies enhance maize yield stability in the sub-humid tropical agro-ecozone of Upper Eastern Kenya

Conservation management strategies have been recommended to enhance soil fertility, moisture retention, crop yield, and yield stability in rainfed agriculture. However, there is limited research on yield stability. We evaluated the effect of integrating soil inputs in conservation tillage on yield and yield stability in Meru South, Upper Eastern Kenya, for eleven consecutive cropping seasons. The trial treatments included conservation tillage without soil inputs (Mt), conservation tillage with soil inputs: sole inorganic fertilizer (F), residue + inorganic fertilizer (RF), residue + inorganic fertilizer + manure (RFM), residue + manure + legume Dolichos Lablab L. (RML), residue + Tithonia + manure (RTM), residue + Tithonia + phosphate rock (RTP) and conventional tillage (Control). Conservation tillage with RFM was the best-fit strategy for enhancing yields. There was heterogeneity in yield residual variance. A larger residual variance implied lesser yield stability. Mt treatment had the least yield residual variance of 0.12 Mg ha−2, followed by Ct and RML, 0.15 Mg ha−2, while RTM had the highest yield residual variance of 0.62 Mg ha−2. Contrarily, the most stable treatments had the least average yields. The study indicated a positive influence of incorporating soil inputs in conservation tillage on yield and suggests longer-term research for yield stability.

Carbon and nutrient colimitations control the microbial response to fresh organic carbon inputs in soil at different depths

Despite the potential of subsoil carbon (C) to buffer or amplify climate change impacts, how fresh C and nutrients interact to control microorganismal effects on the C balance in deep soil horizons has yet to be determined. In this study, we aimed to estimate the impact of fresh C input at different soil depths on soil microbial activity. To conduct this study, Mediterranean soils from 3 layers (0–20, 20–50 and 50–100 cm of depth) were incubated over 28 days. Carbon and nutrient fluxes were measured after the addition of an amount of C equivalent to the postharvest root litter derived-C of a barley crop (4.3 atom% 13C), with and without nitrogen and phosphorus supply. We found that the microbial mineralization was C limited in the topsoil, while C and N colimited in the subsoil. These variations in stoichiometric constraints along the soil profile induced different microbial responses to C and/or nutrient addition. A stronger priming effect was observed in the topsoil than in the subsoil, and the sole C addition induced a negative C balance. Conversely, subsoil showed a positive C balance following fresh C addition, changing to critical soil C losses when nutrients were supplied with C. Our results show that fresh C input to subsoil (e.g., through deep-rooting crops) might foster soil C sequestration, but this positive effect can be reversed if such C inputs are combined with high nutrient availability (e.g., through fertilization), alleviating microbial limitation at depth.

Source, composition and molecular diversity of dissolved and particulate organic matter varied with riparian land use in tropical coastal headstreams

Source, composition and molecular diversity determine the reactivity and stabilization of organic matter (OM, dissolved [DOM]/particulate [POM]), affecting its behavior and fate. Here, multiple spectral and mass spectrometry techniques were applied to examine how riparian land-use shaped the source, composition and molecular diversity of POM and DOM (HDOM) in adjacent headstreams. Compared to HDOM with abundant lignins, microbially-transformed heteroatoms and carboxyl-rich alicyclic acids (CRAMs), POM exhibited higher allochthonous characteristics and more bioactive components, but lower molecular weight and diversity in different land-use-dominated streams. Compared to wetland-dominated headstreams, both POM and HDOM exhibited more terrestrial origin and condensed aromatics/tannins molecules for agriculture-impacted headstreams and bio-labile lipids, proteins and carbohydrates for forest-impacted headstreams. Structural equation mode (SEM) showed that soil-derived DOM (SDOM) showed the most prominent influence on the source, composition and molecular diversity of POM and the source of HDOM. The molecular composition and diversity of HDOM were mainly influenced by soil properties/SDOM and aquatic microorganisms, respectively. Redundancy analysis (RDA) revealed that autochthonous, bio-labile compositions of POM in forest and wetland streams were positively related to aquatic Bacteroidetes/Cyanobacteria, and carbohydrates/biogenic index of SDOM, while that of HDOM were positively linked with aquatic Bacteroidetes/Cyanobacteria, and SDOM molecular diversity. Terrestrial and aromatic POM in agricultural headstreams were associated with aquatic total nitrogen/Actinobacteria, and humification degree, aromatic/phenolic substances of SDOM, while that of HDOM were mainly regulated by aquatic nitrate/total nitrogen/Actinobacteria, and aromatic/carboxylic-containing moieties of SDOM. Noteworthily, the molecular diversity of agricultural OM increased along the soil-stream continuum due to the input of soil condensed aromatics and tannins. The opposite trend was observed in forest and wetland streams due to the input of bioactive carbohydrates and the microbial-degradation in-stream. These results are helpful to predict the behavior and fate of OM and determine effective management strategies in tropical coastal regions undergoing intense anthropogenic alterations.

Generic optimization approach of soil hydraulic parameters for site-specific model applications

Site-specific crop management is based on the postulate of varying soil and crop requirements in a field. Therefore, a field is separated into homogenous management zones, using available data to adapt management practices environment to maximize productivity and profitability while reducing environmental impacts. Due to advancing sensor technologies, crop growth and yield data on more minor scales are common, but soil data often needs to be more appropriate. Crop growth models have shown promise as a decision support tool for site-specific farming. The Decision Support System for Agrotechnology Transfer (DSSAT) is a widely used point-based model. To overcome the problem of inappropriate soil input data problem, this study introduces an external plug-in program called Soil Profile Optimizer (SPO), which uses the current DSSAT v4.8 to calibrate soil profile parameters on a site-specific level. Developed as an inverse modelling approach, the SPO can calibrate selected soil profile parameters by targeting available in-season plant data. Root Mean Square Error (RMSE) and normalized RMSE as error minimization criteria are used. The SPO was tested and evaluated by comparing different simulation scenarios in a case study of a 3-yr field trial with maize. The scenario with optimized soil profiles, conducted with the SPO, resulted in an R2 of 0.76 between simulated and observed yield and led to significant improvements compared to the scenario conducted with field scale soil profile information (R2 0.03). The SPO showed promise in using spatial plant measurements to estimate management zone scale soil parameters required for the DSSAT model.

Effect of nutrient management and soil type on stoichiometric imbalances across the Yangtze River Basin pear districts, China

AbstractNutrition management affects soil carbon (C), nitrogen (N), and phosphorus (P) cycles, as well as their stoichiometry, causing further stoichiometric imbalances. However, research on the effect of nutrient management on soil stoichiometric imbalance is restricted to a single soil type, limiting our understanding of the interactions between these parameters. Therefore, we conducted a study comprising 212 sites throughout the Yangtze River Basin pear districts, for which nutrient management and soil properties were available under different soil types. Soil stoichiometric imbalances varied widely among the districts, with an average C:P imbalance value (C:Pim) of 6.67, higher than that of C:N imbalance (C:Nim; 6.43) and N:P imbalance (N:Pim; 2.83). Meanwhile, soil and microbial biomass stoichiometry, particularly for soil C:P and soil microbial biomass carbon and phosphorus (MBC:MBP), were significantly influenced by nutrient addition. Large N and P fertilizer inputs altered soil C:N and C:P in yellow–brown earth, while soil C:P was influenced by organic nutrient management in purplish soil. Moreover, adding organic nutrients altered the MBP, which further influenced MBC:MBP and MBN:MBP in saline–alkaline soil and yellow–brown earth. Furthermore, C:Pim increased with increasing organic nutrient input in purple soil and decreased with a large chemical fertilizer input in red soil. N:Pim and C:Nim were weakly associated with nutrient management in different soil types. In addition, nutrition management, soil type, soil properties, and microbe content collectively accounted for 45%, 32%, and 38% of the C:Pim, C:Nim, and N:Pim variation, respectively. Nutrient management also exerted a positive direct impact on C:Pim, while soil type elicited a negative direct impact on C:Nim and N:Pim. Meanwhile, all three stoichiometric imbalances were indirectly influenced by soil type. Taken together, our results indicate that soil stoichiometric imbalances, especially for C:Pim, are sensitive to nutrient management and soil type, providing novel insights into these imbalances that can inform the development of potential remedial strategies.

Determination of Some Heavy Metals Concentrations in Water and Irrigation Farms along Wulmi River in Pankshin Local Government, Plateau State, Nigeria

Levels of four heavy metals (Co, Cu, Pb and Cd) and three physico-chemical parameters (pH, temperature, total dissolved solids) were determined from Wulmi River at five sampling points (S1-S5) at an interval of 200m between points using atomic absorption spectrophotometer (AAS) and approved standard procedures respectively, and the control site located about 1000 meters away from the study area. Sampling was done monthly in wet season from May-December 2017. The weighted means of physico-chemical parameters determined at each sampling point in the river were in the range 6.53±0.21 - 6.85±0.17 for pH. 25.35±0.79 0C - 25.92±2.310C for temperature which is within the permissible limit of 300C (USEPA,2002), 9.43±3.90 mg/l - 26.71±2.75 mg/l for TDS which is also within the permissible limit of 1000 mg/l (USEPA,2002). The weighted mean of heavy metal concentrations in water at sampling points in the river ranged between 0.11±0.07 mg/l - 0.29 ± 0.19 mg/l for copper, 1.17±0.39 mg/l - 1.76± 0.31 mg/l for cadmium, 0.08 ± 0.05 mg/l - 0.91±0.03 mg/l for lead, 1.53± 0.39 mg/l - 6.48± 3.36 mg/l for cobalt. The soil samples from five irrigation farmlands (F1-F5) around the Wulmi River were also analysed for the heavy metals concentrations. The heavy metals concentrations in the soil ranged between 12.27 ± 3.46 μg/g - 28.05 ± 1.99 μg/g for copper, 5.49 ± 3.09 μg/g - 17.92 ± 2.18 μg/g for cadmium, 2.24 ± 0.02μg/g - 9.85 ± 1.43 μg/g for Lead, 13.48 ± 3.72 μg/g - 27.82 ± 2.65 μg/g for cobalt .Lead and cobalt concentrations in the soils are within the permissible limit set by USEPA (2002) and WHO [1] of 10μg/g and 50μg/g respectively. All the metals under investigation have geo-accumulation input in soils around Wulmi River, except in irrigation farms 2 and 4 which have geo-accumulation input of Pb to be 0.00. Analysis of variance indicates that there is significant difference in pH, concentrations of TDS, Cd, and Co from one sampling point to another throughout the periods of analyses. The data generated will be used to develop a computer based time series model, which can be used to predict the concentrations of the heavy metals in the near future at these sampling points in Wulmi River.

Environmental controls on the distribution of GDGT molecules in Lake Höglwörth, Southern Germany

Tetraether lipids, such as glycerol dialkyl glycerol tetraethers (GDGTs), are an increasingly used proxy for reconstructing paleoclimatic and paleoenvironmental dynamics. On a global scale, environmental drivers controlling the distribution of GDGTs in lake systems have been described extensively. However, the drivers that control down-core sedimentary GDGT composition within single lake systems are still poorly constrained. Here, we analysed GDGTs in a sediment core collected from Lake Höglwörth (Bavaria, Germany) covering the last ∼1100 years. The increase in ratio ΣIIIa/ΣIIa values (a ratio which captures the variation of 3 structural isomers of penta- and hexamethylated brGDGTs respectively) reflects a higher contribution of branched (br) GDGTs from aquatic sources after 1800 CE. This is synchronous with a high nutrient input as a result of increased local anthropogenic activities. The climate proxy methylation of branched tetraethers (MBT'5ME) reveals a pattern that deviates from the anticipated temperature changes during the last millennium. Instead, high MBT'5ME values from ∼880 to 1120 CE coincide with a period of increased soil input, resulting from lake damming and/or construction of the Höglwörth monastery. Decreased values after 1800 CE until present date correspond to a higher contribution of aquatic brGDGTs, with changes in the dependency between Ia and IIa suggesting a direct influence of bacterial community changes on the MBT'5ME. The proxy cyclisation of branched tetraethers (CBT') shows a linear increase with time, and a stepwise increase at 1700 CE, when a creek stream inflow channel was rerouted. Over time, MBT’5ME decreases gradually, while CBT’ and ΣIIIa/ΣIIa increase. This is hypothesized to be potentially caused by decreasing water depth over time and/or post- or syn-sedimentary production of GDGTs. The degree of cyclization (DC') shows variations on shorter timescales, possibly driven by the lake mixing regime and water column redox conditions. Our results indicate that caution must be taken when interpreting GDGTs for paleoclimate and paleoenvironmental reconstruction considering the possible influence of shifts in the provenance of brGDGTs. Further studies focusing on both sedimentary and intact polar lipids are highly recommended to constrain the source (water column, or sedimentary production) of GDGTs in lake sediments.