The European Union has for several years been a critical export market and a significant source of imports for us, and the US has, in general, kept closed domestic players vis-à-vis the EU. However, given the variety of alternative market conditions and EU forms, the attractiveness of cross-border electronic commerce (CBEC) between China and the EU has fallen far short, and there is an urgency to create a harmonious and uniform environmental environment for the exchange of information to facilitate the convenience of cross border electronic commerce. This study examines the CBEC of agricultural goods and its cooperative management technique inside the logistical supply chain. It details the complete transaction model and fundamental components and presents a theoretical framework for the CBEC distribution network. The Block Chain can effectively bridge the obstacles to CBEC in Chinese and European countries by providing a valuable source of benefits from decentralization, trust, anti-counterfeiting, consensus, innovative procurement, and extraordinary techniques, which will provide the basis for building an Embedded Provider Platform for Electronic Commerce, Risk Management System for Deposit Risk Management, Supply Chain (SC) Management System, Cross Border Logistic System, Customs Supervisory Computer, etc. The paper examines how blockchain science can assemble CBEC SC computing devices for agricultural goods between global places in Central Europe. Firstly, it expounds on the theory and characteristics of the blockchain. Then, the paper introduces the troubles that arise in the CBEC supply chain. Then, the thesis proposes a blockchain-based CBEC SC structure, analyzes the aspects and relations among each other, and provides a framework for developing a China-European blockchain cross-border electronic Commerce. The test findings indicate that the system satisfies the criteria for tracking agricultural items and enhances fresh farm commodities' quality and security.