Initial System-bath Correlations Research Articles

Influence of initial correlations on evolution over time of an open quantum system

A novel approach to accounting for the influence of initial system–bath correlations on the dynamics of an open quantum system, based on the conventional projection operator technique, is suggested. To avoid the difficulties of treating the initial correlations, the conventional Nakajima–Zwanzig inhomogeneous generalized master equations (GMEs) for a system’s reduced statistical operator and correlation function are exactly converted into the homogeneous GMEs (HGMEs), which take into account the initial correlations in the kernel governing the evolution of these HGMEs. In the second order (Born) approximation in the system–bath interaction, the obtained HGMEs are local in time and valid at all timescales. They are further specialized for a realistic equilibrium Gibbs initial (at t=t0) system+bath state (for a system reduced statistical operator an external force at t>t0 is applied) and then for a bath of oscillators (Boson field). As an example, the evolution of a selected quantum oscillator (a localized mode) interacting with a Boson field (Fano-like model) is considered at different timescales. It is shown explicitly how the initial correlations influence the oscillator evolution process. In particular, it is shown that the equilibrium system’s correlation function acquires at the large timescale the additional constant phase factor conditioned by survived initial system–bath correlations.

Quantum non-Markovianity of a qubit in presence of state dependent bath

In the field of quantum information theory, the intersection of the complex dynamics related to non-Markovianity and information is a crucial frontier. Non-Markovian effects, which take memory and temporal correlations into account, challenge conventional wisdom in the fields of quantum biology, metrology, cryptography, and communication. In this work, we analyze the non-Markovian dynamics of a dephasing model in presence of initial system-bath (SB) correlations. These SB correlations are generated via projective measurements on a predefined equilibrium state. Using the non-Markovian measures based on trace distance and quantum Fisher information, it is shown that these correlations have significant impact in the non-Markovian regime at high temperatures while it does not play any role in the Markovian case. Furthermore, it is shown that the oscillatory behaviour of the decoherence function does not always show non-Markovian behaviour.

Dephasing effects on quantum correlations and teleportation in presence of state dependent bath

Quantum information protocols are often designed in the ideal situation with no decoherence. However, in real setup, these protocols are subject to the decoherence and thus reducing fidelity of the measurement outcome. In this work, we analyze the effect of state-dependent bath on the quantum correlations and the fidelity of a single qubit teleportation. We model our system-bath interaction as qubits interacting with a common bath of bosons, and the state dependence of the bath is generated through a projective measurement on the joint state in thermal equilibrium. The analytic expressions for the time evolution of entanglement, discord and average fidelity of quantum teleportation are calculated. It is shown that due to the presence of initial system-bath correlations, the system maintains quantum correlations for long times. Furthermore, due to the presence of finite long-time entanglement of the quantum channel, the average fidelity is shown to be higher than its classical value.

Time evolution of quantum correlations in presence of state dependent bath

The emerging quantum technologies heavily rely on the understanding of dynamics in open quantum systems. In the Born approximation, the initial system-bath correlations are often neglected which can be violated in the strong coupling regimes and quantum state preparation. In order to understand the influence of initial system-bath correlations, we study the extent to which these initial correlations and the distance of separation between the qubits influence the dynamics of quantum entanglement and coherence. It is shown that at low temperatures, the initial correlations have no role to play while at high temperatures, these correlations strongly influence the dynamics. Furthermore, we have shown that the distance of separation between the qubits in presence of a collective bath helps to maintain entanglement and coherence at long times.

Non-Markovianity of a Central Spin Interacting with a Lipkin-Meshkov-Glick Bath via a Conditional Past-Future Correlation.

Based on conditional past–future (CPF) correlations, we study the non-Markovianity of a central spin coupled to an isotropic Lipkin–Meshkov–Glick (LMG) bath. Although the dynamics of a system is always non-Markovian, it is found that some measurement time intervals considering a specific process, with respect to a particular set of CPF measurement operators, can be zero, which means that in this case the non-Markovianity of the system could not be detected. Furthermore, the initial system–bath correlations only slightly influence the non-Markovianity of the system in our model. Significantly, it is also found that the dynamics of the system for LMG baths, initially in the ground states corresponding to the symmetric phase and symmetry broken phase, exhibit different properties, and the maximal value of the CPF at the critical point is the smallest, independent of the measurement operator, which means that the criticality can manifest itself by the CPF. Moreover, the effect of bath temperature on the quantum criticality of the CPF depends on the measurement operator.

Excitation energy transfer with initial system-bath correlations for coherent initial conditions in a toy donor-acceptor model

A theory of coherent resonant energy transfer with initial system-bath correlations [Qin et al., Phys. Rev. A 99, 032111 (2019)] is extended for a coherent initial system condition, which is a linear superposition of donor and acceptor excitations, and is more general and actual in many respects. The nonequilibrium bath state, containing initial system-bath correlations, is expanded in powers of coupling strength within the polaron formalism of second-order time-convolutionless quantum master equation. Detailed expressions for both homogeneous and inhomogeneous terms are derived and calculations are performed under the assumption of super-Ohmic spectral densities where the case of common bath modes is also included. Numerical results indicate that, for certain initial system conditions, the nonequilibrium due to the initial system-bath correlations brings about larger amplitude of population oscillation. And the initial system condition is of crucial importance in determining whether the initial system-bath correlations would play a significant role in the transfer dynamics. We identify a sensitive window in which the transfer dynamics is especially vulnerable to the bath such that there exists a greatly obvious difference between the dynamics with and without initial correlations. Besides, the system-bath coupling strength, the evolution time, and the nature of common bath modes are also shown to contribute to these effects. Rate equations based on F\orster-Dexter energy transfer theory are derived for comparison.

Excitation-energy transfer from weak to strong coupling: Role of initial system-bath correlations

Excitation-energy transfer problems in molecular aggregates have attracted intensive research interests for their fundamental importance. It is usually supposed that the total density operator at time $t=0$ is a factorized product of single-excitation system state and thermal equilibrium bath state. The Franck-Condon principle ensures that it is a good approximation for a rapid photoexcitation. For natural photosynthesis, however, the transfer process in light-harvesting complexes mostly is initialized from an excited molecule, not direct absorption of a photon. Such intermolecular excitations span the same time scale as the transfer dynamics, and longer than the characteristic time of bath relaxation. Therefore, the initial system-bath correlations should be reconsidered. This work extends the coherent resonant energy transfer theory by including initial system-bath correlations. Within the approach of a second-order time-convolutionless quantum master equation in the polaron frame, a general time evolution equation for the reduced system density operator is obtained, including detailed expressions for both homogeneous and inhomogeneous terms. Two essentially distinct kinds of nonequilibrium are identified: one stems from subsistent initial system-bath correlations, while the other is from the theory of polaron transformation itself. The two kinds of nonequilibrium can accelerate or slow down the dynamical evolution for different energetic situations. Rate equations based on F\orster-Dexter theory with and without initial correlations are also derived for comparison. Besides, our conclusions provide a positive perspective accounting for the quantum coherence induced by initial system-bath correlations, which may help to clarify the long-lasting issue of whether quantum phenomenons might be observed under natural conditions of excitation by incoherent solar light, and deepen understandings of the physical mechanisms underlying the natural photosynthesis process.

Quantum Speed Limit for Dynamics of Central Spin Model with Initial System-Bath Correlations

We investigate the quantum speed limit (QSL) time of an electronic spin coupled to a bath of nuclear spins. We consider three types of initial states with different correlations between the system and bath, i.e., quantum correlation, classical correlation, and no any correlation. Interestingly, we show that the QSL times of the central spin for these three types of initial correlations are identical when the couplings are homogeneous. However, it is remarkable different for inhomogenous couplings. The QSL time of the central spin is sensitive to the initial states, the average coupling strength, the distribution of the couplings between the system and bath and the number of the nuclear spins in the bath. Furthermore, we find that the coherence in the initial state has significant influences on the QSL time of the system, and can lead to the increase of QSL time for homogeneous couplings.

Initial correlation in a system of a spin coupled to a spin bath through an intermediate spin

The strong system-bath correlation is a typical initial condition in many condensed matter and some quantum optical systems. Here, the dynamics of a spin interacting with a spin bath through an intermediate spin are studied. Initial correlations between the spin and the intermediate spin are taken into account. The exact analytical expression for the evolution operator of the spin is found. Furthermore, correlated projection superoperator techniques are applied to the model and a time-convolutionless master equation to second order is derived. It is shown that the time-convolutionless master equation to second order reproduces the exact dynamics for time scales of the order $1/\ensuremath{\gamma},$ where $\ensuremath{\gamma}$ is the coupling of the central spin to the intermediate spin. It is found that there is a strong dependence on the initial system-bath correlations in the dynamics of the reduced system, which cannot be neglected.

Quantum discord dynamics in the presence of initial system–bath correlations

We investigate the influence of the initial correlations between a two-qubit system and a family of baths on the dynamics of quantum discord of these two qubits. We show that the initial states with entanglement between the two-qubit system and the bath can prompt two qubits to gain more quantum discord. Moreover, for the initial states only with discord but null entanglement between the two-qubit system and the bath, the effects depend on whether two qubits or one of the two qubits interact with the bath. We also find that there exist some specific initial states for which the entanglement between two qubits is invariant as time evolves, but the quantum discord is not, and for some other initial states although the states evolve, both the entanglement and the quantum discord remain invariant.

New features of entanglement dynamics with initial system–bath correlations

We investigate the influence of initial correlations between two qubits and a family of baths on the entanglement dynamics of these two qubits. We show that initial system–bath correlations can effectively avoid the occurrence of entanglement sudden death, and for the initial states with quantum correlations the entanglement between two qubits can be larger than its initial value. Significantly, we find that there exist initial states which we called entanglement preserving states, such that, although the state of the qubit subsystem evolves the entanglement of two qubits does not evolves at all.

Non-Markovian effects in the quantum noise of interacting nanostructures

We present a theory of finite-frequency noise in non-equilibrium conductors. It is shown that Non-Markovian correlations are essential to describe the physics of quantum noise. In particular, we show the importance of a correct treatment of the initial system-bath correlations, and how these can be calculated using the formalism of quantum master equations. Our method is particularly important in interacting systems, and when the measured frequencies are larger that the temperature and applied voltage. In this regime, quantum-noise steps are expected in the power spectrum due to vacuum fluctuations. This is illustrated in the current noise spectrum of single resonant level model and of a double quantum dot --charge qubit-- attached to electronic reservoirs. Furthermore, the method allows for the calculation of the single-time counting statistics in quantum dots, measured in recent experiments.

The importance of initial correlations in rate dynamics: A consistent non-Markovian master equation approach

The non-Markovian master equation is applied to the calculation of reaction rates. Starting from the flux-side correlation function form, we treat both the thermal and real time evolution consistently within second order perturbation theory in the system–bath coupling. It is shown that the non-Markovian dynamics enter formally not only in the time propagation but also in the expressions for the initial system–bath correlations. We show that these initial correlations can have a significant effect on the reaction rate. The method presented, although approximate, is an effective way to calculate reaction rates for weakly coupled systems over a wide range of temperatures. As such it provides a complementary approach to the exact treatment based on the ML-MCTDH method of Craig et al. [1], which serves as reference in this work.

Nonequilibrium quantum dynamics in the condensed phase via the generalized quantum master equation

The Nakajima-Zwanzig generalized quantum master equation provides a general, and formally exact, prescription for simulating the reduced dynamics of a quantum system coupled to a quantum bath. In this equation, the memory kernel accounts for the influence of the bath on the system's dynamics, and the inhomogeneous term accounts for initial system-bath correlations. In this paper, we propose a new approach for calculating the memory kernel and inhomogeneous term for arbitrary initial state and system-bath coupling. The memory kernel and inhomogeneous term are obtained by numerically solving a single inhomogeneous Volterra equation of the second kind for each. The new approach can accommodate a very wide range of projection operators, and requires projection-free two-time correlation functions as input. An application to the case of a two-state system with diagonal coupling to an arbitrary bath is described in detail. Finally, the utility and self-consistency of the formalism are demonstrated by an explicit calculation on a spin-boson model.

Coherent-state path integral approach to the damped harmonic oscillator

The time evolution of a system of bilinearly coupled bosonic modes is investigated using the real-time path integral technique in the coherent-state representation. In order to get the stationary trajectories, the corresponding Lagrangian function is diagonalized and then the path integrals are evaluated by means of the stationary-phase method. The present treatment is applied to a dissipative harmonic oscillator within the Caldeira–Leggett model. The time evolution of the reduced density matrix in the basis of coherent states is given in simple analytic form for weak system–bath coupling, i.e. the so-called rotating-wave terms can be evaluated exactly but the non-rotating-wave terms only in a perturbative manner. The validity range of the rotating-wave approximation is discussed from the viewpoint of spectral equations. In contrast to many perturbative approaches, the bath degrees of freedom are treated explicitly. In addition, it is shown that systems without initial system–bath correlations can exhibit initial jumps in the population dynamics even for rather weak dissipation. Only with initial correlations can the classical trajectories for the system coordinate be recovered.

Quantum relaxation with initial system-bath correlations.

Quantum relaxation with initial system-bath correlations.