ABSTRACT This study evaluates the structural performance of Polyvinyl Alcohol Cementitious Composites (PVCC)-layered reinforced concrete beams with coal ash under static loading. Experimental investigations included first crack load, ultimate load, load-deflection behavior, ductility, stiffness, and energy absorption. Results highlight the influence of Polyvinyl Alcohol-(PVA) fiber dosage on structural behavior. The control specimen exhibited an initial crack load of 80kN, with subsequent specimens showing varied crack initiation loads influenced by PVA fiber content. Optimal performance was observed at 1.2% PVA fiber dosage, with higher dosages leading to earlier crack initiation. Ultimate load carrying capacity increased with PVA fiber addition, reaching a peak at 1.2% dosage before slight decreases occurred with higher dosages. Load-deflection behavior demonstrated the superior performance of PVCC layered beams, particularly specimen BP3, attributed to optimal fiber content. Ductility, stiffness, and energy absorption increased with PVA fiber reinforcement, with 1.2% dosage yielding optimal results. Excessive fiber content led to diminishing returns. Energy index analysis revealed superior energy dissipation in specimens with higher PVA fiber content, emphasizing the effectiveness of fiber reinforcement in enhancing structural performance. Overall, the study underscores the importance of optimizing PVA fiber dosage to maximize structural resilience and load-bearing capacity in PVCC-layered concrete beams with coal ash.