Molecular nitrogen is often used as a buffer gas in cells with alkali metals due to its known ability to quench resonant fluorescence. It is widely believed that the suppression of spontaneous emission decreases the width of coherent population trapping resonance. However, our recent results have not confirmed this positive action of molecular nitrogen within the typical range of 87Rb concentrations and buffer gas pressures. On the opposite, we have observed the negative influence of quenching, the decrease in contrast of the coherent population trapping resonance in $${{\sigma }^{ + }}$$–$${{\sigma }^{ + }}$$ configuration. In this work, we further confirm these results implementing the Ramsey spectroscopy, and compare the characteristics of the central fringe in nitrogen and neon, and show that the latter provides a significantly better contrast-to-width ratio.
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