Due to the influence of the water environment, it is a serious challenge to achieve high-quality and high-performance on-site restoration of the underwater equipment in the underwater environment. In this paper, TC4 was used as the modulation material to strengthen the Fe-based material by its better wettability with the Fe-based material and the TC4/316L composites with excellent properties was successfully prepared by the underwater laser directed energy deposition technology. And the effect of TC4 on the microstructure evolution, tribo-corrosion resistance and mechanical properties of the composite was studied. The result showed that with increase of TC4 content, the eutectic reaction occurred at the ferritic grain boundary to form Fe2Ti precipitates. And the grain size of the composite showed the tendency to decrease first and then increase due to the increase of solute elements at the solid/liquid interface and the influence of thermal conductivity. The addition of TC4 content also promoted the increase of microhardness and ultimate tensile strength of the composite, and the ultimate tensile strength increased from 492 MPa to 675 MPa. When the TC4 content was 10 wt%, the wear resistance of the composite was the best, and the wear rate was 8.65 × 10−7 mm3N−1 m−1. This research can open up a new idea for the design of underwater directed energy deposition materials, which is of great significance in the field of underwater restoration field.
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