Influence Of Plastic Properties Research Articles

Leaching of triphenyl phosphate and tri-n-butyl phosphate from polystyrene microplastics: influence of plastic properties and simulated digestive fluids.

Microplastics have gained considerable attention as a growing environmental problem owing to their potential to serve as vectors for harmful chemicals. However, the leaching of these chemicals from microplastics is unclear. In this study, we investigated the leaching of two organophosphate flame retardants, triphenyl phosphate and tri-n-butyl phosphate, from polystyrene microplastics in simulated digestive fluids and water, and polypropylene microplastics were simultaneously used for comparison with polystyrene microplastics. The results indicated that the first-order kinetic model best explained the leaching process, suggesting that leaching was related to the release of organophosphate flame retardant molecules at the polymer surface. Additionally, the size and crystalline state of the microplastics had a significant effect on the leaching, whereas organophosphate flame retardant content had a minimal impact. Simulated digestive fluids facilitated the leaching to a different extent, and under these influencing conditions, leaching percentages from polystyrene microplastics did not exceed 0.51%. Therefore, leaching from PS microplastics may not be an important source of OPFRs in the environment. However, the release of organophosphate flame retardants can be considerably enhanced with the breakdown of polystyrene microplastics to polystyrene nanoplastics.

Dibutyl phthalate release from polyvinyl chloride microplastics: Influence of plastic properties and environmental factors

In recent years, great efforts have been made to understand the capacity of microplastics to adsorb environmental pollutants; however, relatively little is known about the ability of microplastics to release inherent additives into peripheral environments. In this study, we investigated the leaching behavior of phthalate plasticizer from polyvinyl chloride (PVC) microplastics, in aqueous solutions relevant to aquatic and soil environments. It was found that plastic properties, such as particle size, plasticizer content and aging of plastics had a great effect on the leaching of dibutyl phthalate (DnBP). Phthalate release was generally higher in smaller particles and particles with higher phthalate content. Whereas, plastic aging caused by solar irradiation could either enhance phthalate release by increasing plastic hydrophilicity or decrease the leaching by reducing readily available fractions of phthalate. Regarding environmental factors, solution pH (3–9) and ionic strength (0–0.2 M NaCl) were found to have minor effect on phthalate release, while fulvic acid (0–200 mg/L) greatly promoted the release by improving phthalate solubility and solution-plastic affinity. Interestingly, we found that more DnBP was leached out when fulvic acid and NaCl coexisted, and the results from dissolved organic carbon (DOC) and three-dimensional fluorescence spectroscopy analyzes suggested that the leaching of other fulvic acid-like additives might have played a role. These findings would be helpful for predicting the potential of microplastics to release toxic additives under different environmental conditions.

The Influence of Plastic Properties of a Suspension on the Separation Index of a Cylindrical-Conical Hydrocyclone

The Influence of Plastic Properties of a Suspension on the Separation Index of a Cylindrical-Conical Hydrocyclone

Influence of plastic properties on the grain size effect on twinning in Ti and Mg

Deformation twinning is an inevitable mode of plastic deformation in hexagonal close packed (HCP) crystals and has been considered a hinderance to achieving formability and ductility. It has long been recognized that reductions in grain size can lower the propensity for twinning. In prior work, EBSD statistical analyses on big data sets of twins in pure Ti and Mg were carried out for the same twin type, loading conditions, initial texture, and range of grain sizes. Here, we revisit these data sets to investigate the role of material plastic properties on grain size effects on deformation twinning. We show that while reductions in grain size dramatically lower the number of twins per grain and the twin thickness in both metals, these effects are several times stronger in Ti than that for Mg. To rationalize this difference, full-field, 3D crystal plasticity calculations are performed. The analysis indicates that the stronger grain size effect in Ti arises due to the larger critical resolved shear stress (CRSS) of its easiest slip system, making Ti less accommodating of the twin shear than Mg. This result points to plastic properties as additional variables that can be tuned towards developing HCP materials for structural applications.

Plastic Buckling of Metallic and Nonmetallic Thin-Walled Tubes under Static Axial Compression

An experimental study for series of tests were conducted on stainless steel 304 and polyvinylchloride circular tubes loaded statically and axially at room temperature. The specimens tested with same variation of slenderness ratio for both materials with constant axial length. Load-deflection characteristics for stainless steel 304 and polyvinylchloride circular tubes specimens and the influence of plastic properties and collapsing load were illustrated .The experimental results are compared with other experimental published and give good agreement. It is showed that the values of initial peak load ,yield end load and plastic work increase with increasing slenderness ratio at constant length. Also it is observed that the collapse modes are different for both materials.

Hydrodynamics of nonlinear viscoplastic fluid in cylindrical hydrocyclone

A flow of non-linear viscoplastic fluid film in a cylindrical hydrocyclone was simulated. The distribution of the velocity component and also a dependence of a fluid film thickness on an axial coordinate were determined by numerical solution of a set of rheodynamic model equations for various rheological properties of the liquid and dimensionless quantities. An influence of plastic properties of the liquid on damping of the circumferential component of the velocity was examined. The results were physically substantiated.

Measurement of viscoplastic properties of a liquid in experiments with a torsion viscosimeter

The results of a numerical solution of the problem of vibrations of a torsion viscosimeter filled with an incompressible viscoplastic liquid are presented. It has been shown that in the vicinity of the rotation axis there appears a dead zone, whose boundary changes in the process of vibrations. The influence of plastic properties of the liquid on the characteristics of viscosimeter vibrations has been determined. A method for identifying viscoplastic properties by the observed parameters of vibrations is proposed.

The influence of plastic properties on chip formation

A two-dimensional finite-element model of the chip formation process is used to study the influence of the material law determining plastic flow on chip formation of titanium alloys at high cutting speeds. For simplicity, friction and thermo-mechanical properties of the tool are neglected in the simulations. Titanium chips are strongly segmented and therefore especially suitable to study the role of segmentation for the cutting force and other cutting parameters. Of special interest is the influence of the thermal softening parameter in the material law. Increasing thermal softening leads to a drastic decrease in the cutting force and a corresponding increase in chip segmentation. A variation of the hardening exponent is also performed. It is shown that the simulation results can be understood by using adiabatic flow stress curves. The variation of the hardening exponent leads to strongly differing chip shapes, although the cutting force stays nearly constant. This shows that mean cutting forces should not be used as simulation verification parameters.

The influence of plastic properties of the probe tip/Si contact on spreading resistance analyses

Analyses of spreading resistance measurements in Si samples with dopant profiles of the dopant sequence lowly doped on highly doped yield unreliable results if the dopant profiles are extremely steep or ultra-shallow. Reasons for this behavior are seen in effects of penetration of the probe tips into the Si sample and in the presence of a zone of a metallically conducting Si phase beneath the probe tip. Atomic force microscopy has been used to investigate the geometry of probe tip indents and scanning electron microscopy to investigate the geometry of the probe tip itself. Results of loading–unloading experiments by means of nanoindentation with a conventional spreading resistance probe tip as indenter enable us to estimate the depth of the metallic Si phase zone. It ranges from about the fourfold up to the sevenfold of the residual depth after unloading the probe tip.