A basic question in the analysis of kinetic relations for the change in viscosity during solidification is the effect of deformation, since the viscosity change itself unavoidably gives rise to mechanical loading of the material being tested. Diverse information about the behavior of polymers in mechanical fields is presented in the literature, but most investigations concern mechanochemical effects, i.e., destruction of polymer molecules under mechanical action [1]. It is obvious that in such cases quite high mechanical loads, capable of breaking covalent bonds, are studied. There are only a few works [2-7] on relatively weak mechanical actions associated with any technological operation (synthesis of polymers in devices with mixers, transport in pipelines, etc.). Investigations of the influence of mechanical fields on reaction systems show that for homogeneous systems, in the absence of any isothermal distortions of the solidification process, no appreciable effect of deformation on viscosity kinetics is observed [8-10]. The kinetic role of deformation is manifested, as a rule, only when the reaction system becomes two-phase. Then the shear stress changes the rate of the process, affecting the conditions of phase separation [2]. For this reason it is of interest to study the influence of the intensity of deformation of the rheokinetic solidification of an initially inhomogeneous system, such as a water suspension of urea-formaldehyde oligomers. We investigated water suspensions of urea-formaldehyde oligomer with total molar ratio urea:formaldehyde 1:1.2, employed in industry as a binder for preparing wood-chip boards and plywood. The mass content of the oligomer in the suspension ranged from 40 to 60. The experiments were performed under different conditions of deformation on VPN-02 (under conditions of constant shear stress r = const) and Reotest2 (under different shear rates) rotational viscosimeters at stresses ranging from 10 to 600 Pa in the temperature range 40-65~ The typical experimental results on the viscosity change of resin as a function of time under different shear stresses are displayed in Fig. 1. These curves have a characteristic maximum, similar to the one observed during gelling of a number of homogeneous resins [2, 11]. In contrast to homogeneously solidifying systems, however, the characteristic section of the viscosity drop is associated not with microgelling, but rather with sedimentation instability of the suspension due to an increase in particle size. The applied stress significantly influences the kinetics of the viscosity change, but this influence is not unique. When the shear stress increases to r ~-. 300 Pa, the process slows down. Essentially analogous results, characterizing the influence of mechanical action, were obtained in the study of the influence of periodic deformation on solidification kinetics of epoxy resins [3] and viscosimetric study of solutions of ureaformaldehyde oligomers [12]. Further increase of the stress gives rise to the opposite effect - the gelling rate increases. This nature of the influence of mechanical action was observed for pressure processing of rigid thermosetting plastics [1]. Figure 2 displays the gelling time t* and the precipitation time tp (which corresponds to the maximum on the curves ~/(t)) as functions of the applied stress. This extremal character of the influence of the shear stress on the gelling kinetics is connected with the different aspects of the mechanical action of solidification of heterogeneous systems. Slowing of gelling, in all probability, is connected with inhibition of the growth of particles of the dispersed phase in the mechanical field. Acceleration of the process is probably due to dissipative losses, resulting in an increase of the temperature of the reaction mass, as shown in [13] in a study of the reprocessing of rigid thermosetting plastics. The case at hand concerns relatively low stresses, which, in all probably, can result in small temperature disturbances. As shown in [2, 14], the viscosity properties of gelling systems are described satisfactorily by the equation
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