With superior low-carbon emission and low-resource consumption, geopolymer concrete (GPC) is receiving increasing attention as an optimal alternative to conventional building materials for cleaner and sustainable construction. However, the practical application of GPC poses great challenges since its dynamic mechanical performance remains far from well understood. In this study, via a split Hopkinson pressure bar (SHPB) system, a series of dynamic compression tests at strain rates of 45 s-1 to 150 s-1are conducted on GPC specimens with different alkaline activators (AAS)-binder mass ratios (i.e., 10%, 15%, 20%, and 25%) and ground granulated blast furnace slag (GGBFS)-binder mass ratios (i.e., 0%, 30%, 50%, 70%, and 100%). Our testing results comprehensively explored the influence of mix proportions and loading rates on the dynamic mechanical performance of GPC, including the dynamic strength and deformation characteristics, energy evolution and utilization, and progressive failure behavior. The permanent strain, energy dissipation density, and dynamic strength of GPC specimens generally increase with increasing strain rate, while the average fragment size decreases. Under higher loading rates, GPC specimens are featured by denser microcracks, shorter propagation paths, and more prominent stepwise fractures. In addition, GGBFS has a greater impact on dynamic strength, strain rate sensitivity, and energy utilization than AAS. Micro-fracture effect of GPC with different mix proportions is investigated. An appropriate content of alkaline activator (i.e., 20%) and higher GGBFS content (i.e., 100%) promotes the binder depolymerization-aggregation reaction, reduces initial defects inside concrete specimens, and facilitates a more compact block structure.