Surface Infiltration Research Articles

Application of Nitrate–Ammonium Nitrogen Fertilization Reduced Nitrogen Loss in Surface Runoff and Infiltration by Improving Root Morphology of Flue-Cured Tobacco

Nitrogen loss in water from farmland has become an environmental issue. Nitrogen fertilizer is the main cause of agricultural non-point source pollution in the Lake Basin, Yunnan. However, it is unclear how different nitrogen fertilizer forms affect water loss from farmland and how the root systems of crops respond. We established five nitrogen fertilizer treatments (100–0% [T1], 75–25% [T2], 50–50% [T3], 25–75% [T4], and 0–100% [(T5)] nitrate–ammonium) and performed an investigation to determine nitrogen loss in water and root morphological parameters of tobacco in Mile County and Chengjiang County. Compared with in the T1, T4, and T5 treatments, the total nitrogen loss in surface runoff was reduced by 4.67%, 11.85% and 9.56% in the T2 treatment and 27.32%, 23.20%, and 31.43% in the T3 treatment, respectively. Similar results were observed for the nitrogen loss due to infiltration. The root biomass was negatively correlated with nitrogen loss. There was greater root biomass, root surface area, and root spatial distribution in T2 and T3 compared with in T1, T4, and T5. These results indicate that 50–50% nitrate–ammonium nitrogen fertilizer can facilitate the root growth of tobacco and reduce nitrogen loss, which provides a reference for agricultural sustainable development.

Effect of Water Content on Light Nonaqueous Phase Fluid Migration in Sandy Soil

Contamination from light nonaqueous phase fluids (LNAPLs) and their derivatives during mining, production, and transportation has become a concern. Scholars have extensively studied LNAPL contamination, but the role of water content variation on its migration process in the unsaturated zone has not been sufficiently researched. The specific issue addressed in this study is the impact of water content on the migration of light nonaqueous phase liquids (LNAPLs) in sandy soils, a critical yet under-researched aspect of subsurface contamination. To tackle this, we employed indoor simulated vertical, one-dimensional, multiphase flow soil column experiments, utilizing the orthogonal experimental method to systematically evaluate the effects of varying water contents on the occurrence state and migration rate of LNAPLs. The experimental results indicate the following: (1) The migration rate of LNAPL exhibits an L-shaped trend during subsurface imbibition and a nonlinear relationship with migration time. The migration rate and migration time of surface infiltration have a linear growth relationship. (2) The residual rate of LNAPL is negatively correlated with water content and positively correlated with oil content in the homogeneous non-saturated state. With the increase in the amount of leaked oil, 40% of the leaked LNAPL is sorbed within the soil. (3) When the water content of the test medium is below 14%, and the oil content is below 11%, LNAPL appears in the unsaturated zone in a solid phase. As the water content increases, the adsorption rate of the oil phase gradually decreases and eventually reaches the oil saturation point. (4) When the water content of the medium exceeds 8%, over time, LNAPL will be subject to oil–water interfacial tension, and the rate of LNAPL movement first decreases and then increases, displaying nonlinear growth. The innovation of this work lies in the comprehensive analysis of LNAPL migration under controlled laboratory conditions, providing results that enhance the understanding of LNAPL behavior in sandy soils. These quantitative insights are crucial for developing targeted remediation strategies for LNAPL-induced pollution in the unsaturated zone.

Impact of Trichoderma spiralis Treatment on the Photothermal Water Evaporation Capacity of Poplar

In recent years, research on interfacial photothermal water evaporation has been thriving. Due to its inherent porosity, exceptional hydrophilicity, and renewable characteristics, wood has garnered significant attention as a material for interfacial photothermal evaporation absorbers. In order to enhance the cellular channels of poplar and improve its water migration capacity, Trichoderma spiralis was selected to inoculate and culture poplar specimens from different sections for 3, 5, and 7 weeks. Simultaneously, a solar radiation intensity of 1 kW·m⁻2 was simulated to perform photothermal evaporation tests on the specimens. This validated the water migration capabilities of different sections of poplar treated with Trichoderma spiralis under light and heat exposure. The characteristic changes were analyzed using electron microscope scanning, infrared spectrum analysis, X-ray photoelectron spectroscopy analysis, surface infiltration performance, and automatic specific surface porosity. The results suggested that the moderate degradation of cellulose and hemicellulose in poplar by Trichoderma spiralis could dredge the cell channels and improve the permeability of poplar, particularly with regard to lateral permeability. The maximum photothermal evaporation rate of the poplar specimen reached 1.18 kg m⁻2 h⁻1, while the evaporation efficiency increased to 72.2%.

Lithosphere infiltrometer: A low cost, automated infiltrometer (permeameter) for measurement of soil health, infiltration, and hydraulic conductivity

Accurate measurement of infiltration rate and hydraulic conductivity is important for assessing soil physical health, irrigation management and catchment modelling. Commercially available infiltrometers are often expensive, fragile, and require specialist knowledge to operate and perform complex post-measurement calculations. We developed the Lithosphere Infiltrometer (permeameter) to be usable for both experienced soil researchers, and users without prior technical or scientific expertise in soil science. The Lithosphere Infiltrometer is able measure both surface and subsoil infiltration rate and hydraulic conductivity. It is manufactured using 3D-printed parts and off-the-shelf electronic components. It has a robust, quad-leg design that allows for rapid leveling of the device and accurate setting of water depth via a novel 3D-printed bell chamber. The water level is measured using a U85 JRT laser with ±1 mm accuracy connected to an Adafruit Huzzah 32 microcontroller. Infiltration rate and hydraulic conductivity are calculated at 1 to 10 min time steps, and data is presented in real-time on an OLED display. Data is stored on the device and available for download to a mobile device by Wi-Fi.

Ferroptosis - a potential feature underlying neratinib-induced colonic epithelial injury.

Neratinib, a small-molecule tyrosine kinase inhibitor (TKI) that irreversibly binds to human epidermal growth factor receptors 1, 2 and 4 (HER1/2/4), is an approved extended adjuvant therapy for patients with HER2-amplified or -overexpressed (HER2-positive) breast cancers. Patients receiving neratinib may experience mild-to-severe symptoms of gut toxicity including abdominal pain and diarrhoea. Despite being a highly prevalent complication in gut health, the biological processes underlying neratinib-induced gut injury, especially in the colon, remains unclear. Real-time quantitative polymerase chain reaction (RT-qPCR) and histology were integrated to study the effect of, and type of cell death induced by neratinib on colonic tissues collected from female Albino Wistar rats dosed with neratinib (50mg/kg) daily for 28 days. Additionally, previously published bulk RNA-sequencing and CRISPR-screening datasets on human glioblastoma SF268 cell line and glioblastoma T895 xenograft, and mouse TBCP1 breast cancer cell line were leveraged to elucidate potential mechanisms of neratinib-induced cell death. The severity of colonic epithelial injury, especially degeneration of surface lining colonocytes and infiltration of immune cells, was more pronounced in the distal colon than the proximal colon. Sequencing showed that apoptotic gene signature was enriched in neratinib-treated SF268 cells while ferroptotic gene signature was enriched in neratinib-treated TBCP1 cells and T895 xenograft. However, we found that ferroptosis, but less likely apoptosis, was a potential histopathological feature underlying colonic injury in rats treated with neratinib. Ferroptosis is a potential feature of neratinib-induced colonic injury and that targeting molecular machinery governing neratinib-induced ferroptosis may represent an attractive therapeutic approach to ameliorate symptoms of gut toxicity.

Evaluating water balance components in a tropical ecological zone under land use changes

Water availability for domestic, institutional, and agricultural production is threatened by the continuous change in land use land cover (LULC). These changes in LULC features affect the dynamics of the hydrological processes such as surface runoff, infiltration, and evapotranspiration, resulting in variations in water availability especially, for human consumption and crop yield. Therefore, the Soil and Water Assessment Tool (SWAT) hydrological model was deployed to simulate the Pra River Basin (PRB)’s water balance response to changing LULC from 1986 to 2020. Open and closed forests reduced from an area of 11,071 km2 to 5902 km2 and 5125 km2 to 4990 km2 while settlement and cropland increased from 1100 km2 to 2392 km2 and 5303 km2 to 9320 km2 representing an average annual expansion rate of +24.7 km2/yr and +118 km2/yr respectively over the three decades. The growth in settlement and cropland resulted in an upsurge of more than 33 % and 20 % in surface runoff and water yield respectively, but decreases of over 4 % and 17 % in evapotranspiration and baseflow respectively. These changes have resulted in a seasonal increase in surface runoff, baseflow, and evapotranspiration (ET) during the wet season but a decrease during the dry season. The PRB has experienced a dramatic decline in forest areas, chiefly in areas where settlement and farmlands have been expanded. The areas where surface runoff and water yield showed significant upsurge and reduction in ET are the northwestern and southern enclaves of the basin. These findings can aid in effectively planning and managing land use to control the gradually depleting water resources in the basin.

Integrated assessment for groundwater quality and flood vulnerability in coal mining regions.

Coal mining activities greatly damage water resources, explicitly concerning water quality. The adverse effects of coal mining and potential routes for contaminants to migrate, either through surface water or infiltration, into the groundwater table. Dealing with pollution from coal mining operations is a significant surface water contamination concern. Consequently, surface water resources get contaminated, harming nearby agricultural areas, drinking water sources, and aquatic habitats. Moreover, the percolation process connected with coal mining could alter groundwater quality. Subsurface water sources can get contaminated by toxins generated during mining activities that infiltrate the soil and reach the groundwater table. The aims of this study are the creation of models and the provision of proposals for corrective measures. Twenty-five scenarios were simulated using MODFLOW; according to the percolation percentage and contamination, 35% of the study area, i.e., the middle of the research area, was the most affected. About 38.08% of the area around the mining zones surrounding Margherita is prone to floods. Agricultural areas, known for applying chemical fertilizers, are particularly vulnerable, generating a risk of pollution to surrounding water bodies during flooding. The outputs of this research contribute to identifying and assessing flood-vulnerable regions, enabling focused measures for flood risk reduction, and strengthening water resource management.

Assessing Water Erosion Improvement in Beach Sand Treated with Bioslurry Using a Surface Percolation Technique

Assessing Water Erosion Improvement in Beach Sand Treated with Bioslurry Using a Surface Percolation Technique

Study on the effect of heat treatment on the structure, mechanical and electrical properties of alumina fiber insulation

In this paper, the heat treatment of alumina fiber was studied. The infiltration agent on the fiber surface was removed after heat treatment at 450 °C for 6 h. TG-DSC, scanning electron microscope, x-ray diffraction, Fourier infrared spectrometer, energy dispersive spectrometer, and patterning were used to analyze the thermal weight loss, fiber surface morphology, crystal structure, and composition of alumina fibers. The results show that the aluminum oxide fiber has excellent temperature resistance and does not undergo crystal phase transformation during thermal weight loss. After heat treatment, the fiber surface infiltration agent ablates and dissolves from the fiber surface, and the internal crystal structure of the fiber remains stable. The tensile testing machine was utilized to test the breaking strength of alumina fiber. The fiber still maintained high strength after heat treatment, and the retention rate of breaking strength was greater than 74%. ZC-90G high insulation resistance measuring instrument and WDY-Ⅱ automatic voltage tester were utilized to analyze the insulation resistivity and breakdown strength of alumina fiber before and after heat treatment. The results show that heat treatment can effectively improve the insulation performance and breakdown strength of alumina fiber.

Research on Enhancing Copper-Ammonia-Thiosulfate Eco-Friendly Gold Leaching by Magnetization of Lixiviant Solution and Their Kinetic Mechanism

In thiosulfate leaching of gold, the copper-ammonia complex serves as an oxidant and catalyst. This study examined the impact of magnetizing the copper-ammonia thiosulphate lixiviant solution on gold leaching from refractory oxidized ores. Magnetization reduced surface tension, improved wettability and infiltration, and enhanced the diffusion of leaching agents. It also increased dissolved oxygen content and boosted the catalytic efficiency of copper-ammonia complexes. These changes led to more efficient gold extraction, with column leaching showing a 4.74% improvement in extraction rates compared to non-magnetized methods and a 3.67% improvement over cyanide processes. These findings suggest that magnetized copper-ammonia thiosulphate lixiviant is a promising, environmentally friendly alternative to cyanide for refractory oxidized gold ores.

The effects of herbs on the runoff and sediment-producing mechanism in Jinyang Ancient City

Abstract To study the effects of herbs on the runoff and sediment producing mechanism of Jinyang Ancient City, this study used the method of field artificial rainfall experiments to compare the earthen sites slope effects on the runoff producing, sediment producing, and soil infiltration of the plant slope surface in different periods. The conclusions are as follows. The phenomenon of petrichor was related to the withered herb coverage on the surface of the slope. The fluctuation amplitude of the soil volume moisture content was related to its distance to the surface. The runoff producing effects of different slopes were in descending order of Bare Soil slope, Fresh Herbs slope, and Withered Herbs slope. The sediment producing effects were in descending order of Bare Soil slope, Withered Herbs slope, and Fresh Herbs slope. The sediment yield intensity was positively correlated with runoff intensity, but its variation peak lagged slightly behind the latter. The runoff intensity and sediment yield was influenced by the dual effects of rainfall intensity and rainfall time, and sometimes the impact of rainfall time was higher than that of rainfall intensity. A research assistance in can be hopefully provided in this study on protecting earthen sites from rainfall erosion through plant covering.

Characteristics and risk assessment of heavy metals in groundwater at a typical smelter-contaminated site in Southwest China

To explore the characteristics and evaluate the risk of heavy metals in groundwater at a typical smelter-contaminated site, this study focuses on a representative a historical arsenic smelting plant in Southwest China, where the primary historical products were metallic arsenic (∼1000 tons/year) and arsenic trioxide (∼2000 ton/year). The results demonstrated As and Pb as the main pollutants in soil, and As and Cd as main pollutants in groundwater through soil profiling and quarterly groundwater analysis. The maximum As and Pb in the surface soil were 76800 and 2290 mg/kg, respectively, with As vertically infiltrating the deep gravel–sand layer (18–20 m). The groundwater pollution distribution progressively increased along flow direction, influenced by seasonal surface runoff and infiltration fluctuations. The groundwater pollutant concentrations during the dry season notably surpassed those during the wet season, with maximum As and Cd concentrations of 111.64 mg/L and 19.85 μg/L during the dry season, respectively. Furthermore, the analytic hierarchy process (AHP) was applied to evaluate the comprehensive risk of contaminated-site across pollution source load, regional groundwater intrinsic vulnerability, and evaluation of nearby sensitive receptors. The results revealed that the carcinogenic risk of lead in surface soil was moderate to high, while arsenic posed a high carcinogenic risk, contributing to an overall carcinogenic risk proportion of 89.6% in surface soil. Exposure through groundwater intake was identified as the primary pathway, with carcinogenic and noncarcinogenic risks exceeding those through skin contact. The final weights result demonstrated that the principal risk factors are the intrinsic arsenic load and protective target characteristics of regional groundwater at this site. This study provides a reference for comprehensive assessments of similarly contaminated industrial and smelting sites.

The Use of Microfiltration for the Pretreatment of Backwash Water from Sand Filters.

Tests of microfiltration efficiency used for the pretreatment of backwash water from sand filters were conducted at two water treatment plants treating surface water and infiltration water. Microfiltration efficiency was evaluated for three membrane modules: two with polymeric membranes and one with a ceramic membrane. This study showed that the contaminants that limit the reuse of backwash water from both plants by returning them to the water treatment line are mostly microorganisms, including pathogenic species (Clostridium perfringens). Additionally, in the case of backwash water from infiltration water treatment, iron and manganese compounds also had to be removed before its recirculation to the water treatment system. Unexpectedly, organic carbon concentrations in both types of backwash water were similar to those present in intake waters. Microfiltration provided for the removal of organic matter, ranging from 19.9% to 44.5% and from 7.2% to 53.9% for backwash water from the treatments of surface water and infiltration water, respectively. Furthermore, the efficiency of the iron removal from backwash water from infiltration water treatment was sufficient to ensure good intake water quality. On the other hand, manganese concentrations in the backwash water, from infiltration water treatment, pretreated using the microfiltration process exceeded the levels found in the intake water and were, therefore, an additional limiting factor for the reuse of the backwash water. In both types of backwash water, the number of microorganisms, including Clostridium perfringens (a pathogenic one), was a limiting parameter for backwash water reuse without pretreatment. The results of the present study showed the possibility for using microfiltration for the pretreatment of backwash water, regardless of its origin but not as the sole process. More complex technological systems are needed before recirculating backwash water into the water treatment system. The polyvinylidene fluoride (PVDF) membrane proved to be the most effective for DOC and microorganism removal from backwash water.

Seasonal assessment of groundwater quality in the Al Hoceima region, northern Morocco: Physicochemical parameters and fecal contamination indicators

AbstractThis study focuses on assessing the seasonal variation in groundwater quality within the Al‐Hoceima region, specifically examining physicochemical parameters and bacteriological indicators of water fecal contamination. The sampling campaign took place during the wet and dry seasons of 2019 and 2021. In situ measurements were conducted on 37 groundwater samples to determine the physicochemical parameters, while bacteriological analyses were performed using Escherichia coli (E. coli) as a fecal contamination indicator. The findings demonstrate significant variations in physicochemical parameters across seasons and reveal fecal contamination of the groundwater, predominantly indicated by increased levels of E. coli during wet periods. Possible contributing factors include water surface runoff and percolation processes. Additionally, the result showed a high concentration of E. coli expected 240 CFU/100 mL. Pollution was higher in the dry season than in the wet season. These results underscore the poor quality of the water in the Al Hoceima region, necessitating treatment before consumption.

Simulation and Characterization of Micro-Discharge Phenomena Induced by Glitch Micro-Defects on an Insulated Pull Rod Surface

The reliability of GIS (gas-insulated switchgear) circuit breakers significantly depends on the condition of the insulated pull rods, with micro-defects on their surface posing a potential risk for micro-discharges and breakdown incidents. Experimentally investigating these micro-discharges is challenging due to their minute nature. This study introduces a framework to examine the linkage between micro-defects and micro-discharges, coupled with numerical simulations of the micro-discharge process in insulated pull rods afflicted by surface infiltration flaws under operational conditions. Initially, samples containing micro-defects were sectioned via water jet cutting for microstructural analysis through white light interferometry. Subsequently, a two-dimensional axisymmetric model simulating positive corona discharge from a needle to a plate electrode was employed to derive the relationship between charged particle density and the electric field in SF6 and air. Building on these observations, a micro-discharge model specific to micro-defects was developed. Comparative analysis of micro-discharge behaviors in SF6 and air for identical defect types was conducted. This research framework elucidates the discharge dynamics of charged particles in SF6 and air during micro-discharge events, shedding light on the mechanisms underpinning micro-discharges triggered by insulation rod defects.

Calibration and validation of DRAINMOD to predict long-term permeable pavement hydrology

The hydrologic performance of permeable pavement varies widely due to underlying soil type, drainage configuration, contributing drainage area, surface infiltration rate, and aggregate depth. A long-term hydrologic model is needed to better understand the influence of these design variables on surface runoff, drainage, exfiltration, and evaporation from permeable pavement systems. Most permeable pavement models have not been calibrated with field monitored data, are usually unable to accurately model internal water storage (IWS) zones, and do not account for evaporation from the aggregate profile. Because permeable pavement employs drainage and exfiltration as primary hydrologic mechanisms, it was hypothesized that DRAINMOD, a model shown to accurately simulate bioretention hydrology, could be calibrated to predict the hydrologic response from permeable pavements. Hydrologic data were collected from two permeable pavement applications in North Carolina (Boone and Durham) and two permeable pavement applications in Ohio (Perkins Township and Willoughby Hills) to calibrate and test the model. The specific permeable pavements applications varied widely in aggregate depth, drainage configuration, underlying soil type, and contributing drainage area. Nash-Sutcliffe Efficiencies for drainage ranged from 0.77 to 0.95 during calibration and validation of all sites. Nash-Sutcliffe Efficiencies for exfiltration/evaporation ranged from 0.55 to 0.97 for Boone and Perkins Township, but prediction of exfiltration/evaporation volumes on an event basis was poor for the remaining two sites due to low exfiltration rates (less than 0.20 mm/hr). Despite this, the cumulative volume of exfiltration/evaporation was predicted to within 1–9 % of what was measured during monitoring. Modeled and monitored surface runoff from the Willoughby Hills application (8 % of the water balance) was equivalent. The model predicted the percentage of drainage, surface runoff, and exfiltration/evaporation to within 2 % of what was monitored/estimated at each site, suggesting long-term modeling of permeable pavement hydrology with DRAINMOD is viable.

Towards evaluating the conditional probability of waterborne microbial risks associated with critical rainfall events following land application of animal waste — A focus on Irish pastures

ABSTRACT Modelling surface runoff and infiltration in an agricultural watershed is essential for understanding the nutrient cycle and water quality management. This research evaluates the critical rainfall events causing maximum surface runoff and infiltration. Empirical models such as Soil Conservation Service (SCS) curve number and Explicit Green-Ampt (EGA) were analysed for different soil hydraulic conditions and storm events with specific return periods. The present study forecasted the maximum daily rainfall and intensity as 113.6 mm and 19.9 cm h–1, respectively, considering a 100-year return period storm. The deterministic part of the model calculates the daily maximum surface runoff as 5.51 cm (from the SCS model). The EGA model revealed that the rainfall intensity of 0.143, 0.163, 0.175, 0.179, 0.181, 0.182, and 0.182 cm h−1 (duration of 24 h) was found critical for 1, 2, 5, 10, 25, 50, 100 year return period of the storm, respectively in different soil texture classes (sand, loamy sand, sandy loam, loam, silt loam, sandy clay loam, clay loam, silty clay soils). Exceptions imply for three occasions where the intensity of 0.407 cm h−1 and duration of 18 h produced maximum infiltration for silty clay loam, and intensity of 0.352 and 0.354 cm h−1 with 9 h rainfall (each) produced maximum infiltration for clay. The probabilistic model revealed that a daily storm event probability of 2.74 × 10–5 is associated with a simulated mean runoff depth of 0.69 cm and infiltration of 20.7 cm. Critical rainfall probabilities calculated in this study can be multiplied with the overall microbial/pollutant human health risk assessment framework to calculate conditional probability and better estimate microbial risk through the drinking water pathway. This study is very relevant for the wet climatic condition of Ireland, where most land use is pastures.

Impacts of land use change on surface infiltration capacity and urban flood risk in a representative karst mountain city over the last two decades

Urban areas are undergoing rapid expansion, resulting in diminished vegetation cover and an escalating urban flood problem, and posing substantial threats to aquatic ecosystems, human safety, and socioeconomic structures. However, research on urban flood risk using methods like the Analytic Hierarchy Process (AHP), further exploration of spatiotemporal variations is needed, especially within the context of karst mountainous urban clusters. This study focuses on Guiyang city within a karst mountainous urban cluster, investigating fractional vegetation cover (FVC), infiltration capacity, and urban flood risk. Methodologies encompass slope trend analysis, the utilization of the Google Earth Engine, and geographic detectors to assess the dynamics of FVC and infiltration capacity. AHP is employed to assign weights to infiltration capacity, land use and land cover (LULC), FVC, and elevation, culminating in the generation of flood risk maps through linear weighted overlay. The results showed that: (1) The average FVC in Guiyang City was 0.7440 in 21 years, with relatively low levels in the central and southern regions. The FVC increased by 0.21% per year from 2000 to 2020, driven mainly by land use change and human activities. (2) The infiltration capacity of the city of Guiyang has increased as a whole, mainly due to reforestation efforts in specific areas, while the infiltration capacity of impervious areas tends to decrease. (3) The central urban areas exhibit greater vulnerability, with an estimated ten-year average growth rate of 73.36% in very high flood risk areas by 2030, affecting 7.38% of Guiyang's total area. These urban flood risk maps serve as valuable tools for local governments to enhance urban management practices.

Fingerprinting dissolved organic compounds: a potential tool for identifying the surface infiltration environments of meteoric groundwaters

Current methods for tracing decades-old groundwaters rely on isotope geochemistry to determine groundwater age and altitude at the point of infiltration. Temporal and spatial variability in atmospheric conditions, and water–rock interactions, can make the interpretation of isotopes uncertain. Here, we propose a new method of groundwater tracing based on the fingerprinting of natural dissolved organics. We present our initial findings from the Grimsel Test Site in Switzerland, located within a fractured granite. Using 2D gas chromatography, we derive detailed organic fingerprints from surface soils at several locations and show that different soils produce distinctly different dissolved organic signatures. We then compare the soils with groundwater and lake water using a non-targeted approach employing principal component analysis and hierarchical cluster analysis. Our analysis finds three statistically significant clusters. Most groundwaters are clustered with the lake-water samples but two are clustered with soil from the highest altitude surface sampling location. We hypothesize that for samples to form a significant cluster, they must have been derived from a common environment, with a unique combination of organic compounds. For groundwaters to cluster with soil samples or lake water, we theorize there must be a hydraulic connection between the type of infiltration environment and the groundwater sampling locations within each cluster. Our research demonstrates that organic molecules derived from the surface environment can be used to discriminate near-surface environment(s) through which meteoric groundwater has infiltrated. Organic fingerprinting could prove a powerful tool for improved understanding of groundwater flow systems, particularly when combined with other complementary techniques. Supplementary material : Compound alignment data set and supplementary tables are available at https://doi.org/10.6084/m9.figshare.c.7129987 Thematic collection: This article is part of the Sustainable geological disposal and containment of radioactive waste collection available at: https://www.lyellcollection.org/topic/collections/radioactive

Enhancing water balance assessment in urban areas through high-resolution land cover mapping: Case study of Debrecen, Hungary

Land cover (LC) mapping in urban areas is one of the core applications in remote sensing (RS), and it plays an important role in modern urban planning and management. In order to support up-to-date simplified water balance calculation, LC modelling needs to be developed for precise and high-resolution operations to monitor rapidly expanding urban areas. This study provides a spatial decision support tool for urban water balance calculations considering hydrological parameters at pixel scale. The study is aimed to create a high-resolution LC map for more precise water balance calculations to identify and link the most important parameters, such as crop coefficient, for estimating crop evapotranspiration, runoff coefficients, and infiltration rate. Meteorological data from 2016 to 2019 were involved in evapotranspiration estimation. The study site is Debrecen, a city in northeast Hungary with a population of about 200,000. By integrating Landsat 8 imagery, Google Earth (GE), and Corine Land Cover (CLC), a LC map of 30 m resolution was created with 81.2 % overall accuracy (OA) and a coefficient of kappa greater than 0.78. For the classification of Landsat 8, seven classes were assigned (forests, sealed surfaces, areas with crop cover, grassland, semi-sealed surfaces, bare ground and surface water bodies). Classification results were validated by 101 ground truth samples using other satellite images and aerial photographs. Water balance parameters (i.e. surface runoff, infiltration and evapotranspiration) were then defined and calculated at a pixel scale and for larger areas. The technique developed in this study can also be utilized in other urban areas.