The Yellow River basin, an area of extreme water scarcity, has faced significant challenges in water quality management due to rapid economic and social development since the 1980s. This study analyzes the water quality evolution over nearly 40 years, focusing on primary pollutants like chemical oxygen demand (COD), ammonia nitrogen (NH3-N), and permanganate index (CODMn). In the 1990s, sections of the river were severely polluted, with some areas failing to meet the lowest national standards. In 2000, 32% of the river water was classified as inferior Class V. However, enhanced water resource management and stricter pollutant regulations introduced after 2000 have significantly improved water quality. By 2010, water quality reached its nadir, with 16% of water classified as inferior Class V and 25% as Class IV–V. By 2020, water quality showed marked improvement, with a significant reduction in segments classified as inferior Class V and Class IV–V. Recent years have seen water quality stabilize, with COD meeting Class I standards and NH3-N and CODMn meeting Class II standards based on national criteria. The study also highlights discrepancies in water quality between the mainstream and tributaries of the Yellow River. While the mainstream generally maintains good water quality, many tributaries remain severely polluted. In 2022, 85% of the water in tributaries was classified as Class I to III, 12.3% as Class IV to V, and only 2.7% as Class V. However, all water in the mainstream reached Class I–III, with 86% achieving Class II and 14% achieving Class I. A detailed analysis of the Huayuankou section over the past three decades shows a general decline in pollution indicators. Seasonal water quality fluctuations, correlated with flow rates and temperatures, were observed, often exhibiting normal distribution patterns. These findings underscore the effectiveness of sustained pollution control and the need for continuous, adaptive management strategies to improve and maintain water quality in the Yellow River basin.
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