Industrial Sources Research Articles

The source of volatile organic compounds pollution and its effect on ozone in high-altitude areas

Volatile organic compounds (VOCs) are crucial precursors in the formation of ozone (O3). The sources of pollution are complex and significantly impact O3 generation. Long-term exposure to high-concentration O3 environments causes serious damage to organisms. High-altitude areas experience continuous high temperatures and strong solar radiation, which can easily produce O3 through photochemical reactions, making these areas prone to frequent air pollution. This study utilizes the National Positioning Station of the Yinchuan Urban Ecosystem in Ningxia to conduct field synchronous observations, gathering data on VOCs, meteorological variables, and O3. By employing machine learning algorithms, we examined the seasonal distribution characteristics of VOCs, their pollution sources, and their impact on O3. The results show that the seasonal distribution of VOCs areas is low in spring and autumn and high in summer and winter. The components with higher volume fraction contribution are m-tolualdehyde in spring and summer, ethane in autumn, and acetylene in winter. The main emission sources of VOCs pollution are hydrocarbon volatile emission in spring and winter, solvent volatilization emission in summer, and industrial sources in autumn. VOCs have a negative effect on O3, with a greater impact in winter and spring, evidenced by standardized effect values of −0.26 and −0.24. The key components affecting O3 in VOCs vary by season. Aromatic hydrocarbons are the key components in spring and winter, with contribution rates of 22 % and 21.3 %. Alkenes are the key components in summer and autumn (24.5 % and 26.8 %). Among meteorological variables, temperature is the key factor affecting O3, while wind speed is the key factor affecting O3 only in winter. This study aims to clarify the sources of VOCs pollution in different seasons and their impact on O3, providing a theoretical basis and technical support for the prevention and control of VOCs and O3 pollution in high-altitude areas.

Assessing the health risks from flooding and chemical contamination: a scoping review

Abstract Flooding can increase the mobilization of hazardous chemicals in the environment. This scoping review provides an overview of the evidence on how flood events effect our health through chemical contamination and describes the exposure pathways to guide prevention and response measures. Flooding includes surface water flooding, coastal flooding, river flooding, storm surge, monsoon rainfall and high tide. We found 110 papers that looked at the association between flooding and chemicals in the environment, with most studies looking at heavy metals, polyhydroxyalkanoates (PAHs), and arsenic. There was a lack of information on rural populations and studies on mobilisation of pesticides. Very few studies mapped or modelled human exposures, including for high-risk populations (e.g., children), and this remains an important evidence gap. Studies considering climate change highlighted the likelihood of chemical contamination and health risks to be exacerbated. Our results highlighted new pathways by which flood events mobilise chemicals and pose risks to human health (i.e., urban runoff, industrial sources). Although found extensively in the environment, gaps were identified in the evidence for pesticides, microplastics and heavy metals. Limited studies reported response measures to address the chemical contamination linked to flooding despite the health risks likely to increase due to poor infrastructure and management measures despite the extent of contaminated land and landfill sites. A dual risk management strategy (i.e., the coordinated management of both flood-related and chemical release risks is required to address flooding events, chemical releases, and health impacts.

Capacity of an aquatic macrophyte, Pistia stratiotes L., for removing heavy metals from water in the Oued Fez River and their accumulation in its tissues.

Water resources, particularly rivers, are increasingly exposed to pollutants, especially heavy metals of chemical origin, which are difficult to monitor and can pose risks to both ecosystems and human health. This study assesses heavy metal contamination in the Oued Fez River, focusing on the bioaccumulation by the invasive plant Pistia stratiotes. The methodology involves measuring and comparing metal concentrations in water and plant tissues. Results revealed that while aluminium (Al) slightly exceeded recommended levels at 0.2978 mg L-1, other metals like zinc (Zn), iron (Fe), copper (Cu), lead (Pb) and cadmium (Cd) remained within acceptable limits. The study demonstrates P. stratiotes' effectiveness in heavy metal phytoremediation, with its roots showing high bioaccumulation up to 19,726 mg kg-1 for Fe and 15,128 mg kg-1 for Al, indicating its potential for water decontamination. Eco-toxicological assessments, including bioconcentration and translocation factors, confirm the plant's capacity to mobilize toxic metals. Statistical analysis also points to possible industrial, urban, or agricultural contamination sources based on correlations between Al, Fe and Zn. The study underscores P. stratiotes' role in phytoremediation while emphasizing the need for monitoring and controlling contamination sources and managing the spread of this invasive species to ensure sustainable water resources.

Enhanced Assessment of Water Quality and Pollutant Source Apportionment Using APCS-MLR and PMF Models in the Upper Reaches of the Tarim River

To evaluate the pollution sources and dynamics of the upper reaches of the Tarim River, 10 typical sampling points were selected, and 23 water quality parameters from 2020 to 2022 were analyzed using one-way analysis of variance, the comprehensive Water Quality Identification Index (WQI), and Principal Component Analysis (PCA). The pollution status, sources, and contribution rates of water quality were investigated using the Absolute Principal Component-Multiple Linear Regression Model (APCS-MLR) and Positive Matrix Factorization (PMF). The results indicated that the water quality parameters of dissolved oxygen (DO), chemical oxygen demand (CODMn), biochemical oxygen demand after 5 days (BOD5), total nitrogen (TN), total phosphorus (TP), fluoride ions (F-), and ammonia-nitrogen (NH3-N) in the upper reaches of the Tarim River exceed standards, with noticeable spatial variations observed for each parameter. The water quality evaluation grades in the upper reaches of Tarim River primarily indicate “moderate” and “good” levels, with DO, TN, NH3-N, and electrical conductivity (EC) being the key parameters influencing variations in water quality. The source analysis results from APCS-MLR and PMF yielded similar outcomes, identifying six potential pollution sources. Among these, soil weathering, livestock and poultry breeding, and agricultural activities exhibited higher contribution rates. Specifically, the contribution rates for these sources according to APCS-MLR were 44.11%, 19.63%, and 11.67%, respectively; while according to PMF they are 24.08%, 17.88%, and 27.54%, respectively. Furthermore, industrial pollution sources contributed at a rate of 6.01% according to APCS-MLR, while urban living sources contributed at a rate of 2.13%. However, based on PMF analysis, the contribution rates for industrial pollution sources increased significantly to 16.71%. Additionally, APCS-MLR identified natural sources as contributing at a rate of 16.45%, whereas PMF suggested that a combination of agricultural activities and natural sources contributed at a lower rate of only 9.52%. In conclusion, the water quality within the upper reaches of the Tarim River is predominantly satisfactory. Nonetheless, localized pollution, primarily attributable to human activities, presents a substantial challenge. These observations provide critical insights into improving and protecting the fragile water quality of the Tarim River.

Heavy metals in roadside soil along an expressway connecting two megacities in China: Accumulation characteristics, sources and influencing factors.

Transportation is widely recognized as a significant contributor to heavy metal (HM) pollution in roadside soils. A better understanding of HM pollution in soils near expressways is crucial, particularly given the rapid expansion of expressway transportation in China in recent years. In this study, 329 roadside topsoil samples were collected along the Beijing-Tianjin Expressway, which connects two megacities in China. Chemical analysis showed that HM concentrations in the soil samples were generally below national limits. The mean pollution index (Pi) values for As, Cr, Cu, Ni, Pb, and Zn ranged from 0.94 to 1.01, while Cd and Hg exhibited slightly higher mean Pi values of 1.19 and 1.13, respectively. The Nemerow integrated pollution index values for all samples ranged from 0.71 to 4.97, with a mean of 1.26. This suggests a slight enrichment of HM above natural background levels, especially for Cd and Hg. Source apportionment using positive matrix factorization revealed that natural sources contributed the most to soil HMs (64.51 %), followed by agricultural sources (19.15 %), traffic sources (9.77 %), and industrial sources (6.57 %). The Shapley additive explanation analysis, based on the random forest model, identified soil organic carbon, deep soil HM content, altitude, total soil K2O, urbanization composite impact index, and total soil P as primary influencing factors. This indicates that the impact of transportation on roadside soils along the Beijing-Tianjin Expressway is currently relatively limited. The prominent influence of soil properties and altitude underscored the importance of "transport" and "receptor" in the soil HMs accumulation process at the local scale. These findings provide critical data and a scientific basis for decision-makers to develop policies for expressway design and roadside soil protection.

1-D electrical inversion sensitivity applied to CO2 geological storage monitoring

Discussions on the effects of anthropogenic emissions of greenhouse gas and their consequences on climate change have gained public notoriety in recent decades. The capture of carbon dioxide (CO2) from industrial sources and its subsequent storage in geological reservoirs has the potential to play an important role in reducing the harmful effects of the atmosphere CO2 emissions in the medium and long term. Based on their physical properties for applying geophysical techniques, studying and evaluating the behavior of rocks in the presence of CO2 has shown high relevance. This study deals with monitoring geological reservoirs in the presence of CO2 through the electrical resistivity method to estimate the electrical properties of the rocks involved, such as CO2 saturation and electrical resistivity of the medium. Simulations were performed on a four-layer synthetic model. The results validated the applicability of the electrical method in monitoring CO2 injection and leakage.

Changes in Sources of Information about the Risks and Benefits of Cannabis in a National Cohort of US Adults from 2017 - 2021.

As more states legalize cannabis in the US, marketing from the cannabis industry and news coverage of cannabis have increased. Sources of information on cannabis can influence beliefs about risks and benefits. Yet, little is known about how the use and influence of specific sources of information have changed over time. We conducted a longitudinal study of 5053 US adults between 2017 and 2021. Participants were asked about sources of information on cannabis risks and benefits and which sources were most influential using a web-based survey at three different time points (2017, 2020, 2021). We evaluated changes in the use/influence of multiple sources of information from 2017 to 2021 and examined interactions with age, cannabis use and state cannabis legal status. The largest increases in sources of information on cannabis benefits and risks were in use of health professionals (+5.5% for benefits and +17.4% for risks). The largest declines were in use of traditional media (TV, radio, newspapers) (-12.3% and -11.4%). Use of cannabis advertisements and dispensaries/other industry sources also significantly increased. Health professionals were the most influential source of information in all three waves regardless of age, cannabis use or state legal status. Participants sought information from different sources, and increasingly relied on health professionals as a primary source, highlighting the need to train healthcare providers about cannabis risks and benefits. While fewer people used traditional media, use of industry sources increased, underscoring the need for accurate cannabis information sources.

Neural Network-Based Design of a Buck Zero-Voltage-Switching Quasi-Resonant DC–DC Converter

In this paper, a design method using a neural network of a zero-voltage-switching buck quasi-resonant DC–DC converter is presented. The use of this innovative approach is justified because the design of quasi-resonant DC–DC converters is more complex compared to that of classical DC–DC converters. The converter is a piecewise linear system mathematically described by Kirchhoff’s laws and represented through switching functions. In this way, a mathematical model is used to generate data on the behavior of the state variables obtained under various design parameters. The obtained data are appropriately normalized, and a neural network is trained with them, which in practice serves as the inverse model of the device. An example is considered to demonstrate how this network can be used to design the converter. The key advantages of the proposed methodology include reducing the development time, improving energy efficiency, and the ability to automatically adapt to different loads and input conditions. This approach offers new opportunities for the design of advanced DC–DC converters in industries with high efficiency and performance requirements, such as the automotive industry and renewable energy sources.

Thraustochytrids and Algae as Sustainable Sources of Long-Chain Omega-3 Fatty Acids for Aquafeeds

There is limited ability to biosynthesize long-chain omega-3 fatty acids such as EPA and DHA in food webs leading to humans. Seafood is the key source of ω3 LC-PUFA, with aquaculture expected to meet rising global demand; however, marine fish have a high dietary requirement for EPA and DHA themselves. This was traditionally met using unsustainable dietary fish oil and fish meal, but limited supply and environmental concerns have dictated research on replacements. Among the industrial sources of EPA and DHA, microalgae and especially thraustochytrids stand out as resources with high concentrations. Although unicellular, thraustochytrids are not microalgae as they are not photosynthetic but instead are microheterotrophs. This removes the light requirement and facilitates high yields of monoculture for the production of single-cell oils. The availability, in high concentrations, of usually one or the other essential fatty acid permits a calibration of the EPA and DHA dose, which is especially useful as their effects have mainly been considered together in medical and aquaculture research. EPA and DHA have different effects on cell function and are precursors of different bioactive compounds. Using thraustochytrids, microalgae, and heterotrophic dinoflagellates, the importance of DHA has been investigated. DHA was essential for optimizing the growth of the early life stages of scallops and finfish and was preferentially incorporated into fish membrane phospholipids. The production of microalgae and microheterotrophs can contribute to the treatment of wastewater and waste gas, further enhancing their sustainability and reducing the environmental costs of aquaculture.

COMPREHENSIVE CHARACTERISATION OF TEMPORAL VARIATIONS IN CONCENTRATIONS OF GASEOUS AMMONIA AND NITROGEN OXIDES IN TYPICAL URBAN ATMOSPHERE

Atmospheric ammonia (NH3) is a well-known contributor to secondary particle formation and canlead to severe environmental degradation and human health outcomes. In the context of the verylimited knowledge about updated data on NH3 levels in urban areas, this paper presents the results ofa one-year (Apr 2023 – Mar 2024) measurement campaign of NH3 concentrations conducted at theurban background site in Zabrze, located in the central part of the Upper Silesian Industrial District(USID) (southern Poland), which could be considered one of the European hotspots. The research wasperformed using an automatic ammonia analyzer Model T201 by Teledyne API, which provides dataon the levels of NH3 and other gaseous nitrogen compounds (NO (nitrogen oxide), NO2 (nitrogendioxide), NOx (nitrogen oxides) at hourly time resolution. Consequently, this enabled an analysisof specific temporal variations of NH3 concentrations, and therefore allowed the identification ofits possible emission sources and insight into processes involving ammonia. The results obtained inthis study revealed that ammonia stood out from nitrogen oxides and other atmospheric pollutants– with high NH3 concentrations recorded during spring and summer, which is related to the highintensity of gaseous NH3 formation under warm meteorological conditions. A different situationwas observed in the hourly NH3 concentration distribution scheme, which was manifested by muchless visible diurnal variations of NH3 levels, with no characteristic morning maximum, as well asthe occurrence of a broad afternoon maximum in the summer. In summary, anthropogenic sourceshad a significant impact on NH3 concentrations in the area under consideration, with a greater roleof traffic in the case of NOx, and a biomass and fossil fuel combustion and/or industrial sources –for NH3. Local meteorological conditions also had a notable influence on NH3 levels, of which airtemperature (positive correlation) and wind speed (negative correlation) were found to be the mostimportant. The ongoing research is planned to be continued, as it can provide valuable scientific datafor the development of air quality protection strategies and programmes in urban areas, especially inthe field of reducing emissions of gaseous precursors of particulate matter.

Particle Size and Morphological Evaluation of Airborne Urban Dust Particles by Scanning Electron Microscopy and Bidimensional Empirical Mode Analysis

Airborne particles affect the health of the population. As particles decrease in size, they can penetrate deeper into the respiratory system, reaching the terminal bronchioles and alveoli. Particles as small as 0.1 µm in diameter may translocate into the bloodstream, potentially impacting various organs. Additionally, the smaller the particle size, the longer they remain suspended in the air, thereby increasing their deleterious damages. The aim of this work is to study the size distribution of airborne particles emitted from anthropogenic sources of air pollution, with a special emphasis on estimating the distribution of micro and nanoparticles considered the most harmful to health. The Bidimensional Empirical Mode Decomposition (BEMD) algorithm was used on micrographs of the particles obtained by Scanning Electron Microscopy (SEM). BEMD is a current empirical computational tool applied to image analysis that allows extracting non-linear heterogeneous oscillations of brightness. We studied ROFA (Residual Oil Fly Ash) from industrial sources and DEP (Diesel Exhaust Particles) from vehicular emissions as airborne particles. After collecting the particles on filters, micrographs were taken using SEM at different magnifications to which the BEMD algorithm was applied. Particle size and asymmetry distributions were obtained for each mode, allowing the identification of the most deleterious particles. The methodology employed herein is relatively simple and effective for inferring the impact of airborne particulate matter on health and the environment.

Energy and Environmental Aspects of the Sustainability of Clothing Production

The textile and clothing industries are very often lumped together when it comes to the environmental aspect such that the negative connotation of the textile industry from an environmental aspect is automatically transferred to the clothing industry. However, the two industries should be considered separately, particularly with regard to the machinery used and energy consumption in the production process. The energy consumption of electricity, compressed air, vacuum, steam, and other energy sources in the clothing industry is low compared to other related industries. Furthermore, no carcinogenic and allergenic waste is generated during the production of clothing, which has a low carbon footprint, i.e., it practically does not pollute the air, soil, and water. The waste produced during cutting is clean and unused and is immediately recycled. All of this contributes to the sustainability of the clothing industry from the energy and environmental aspects. This article describes the cutting and joining techniques used in the manufacture of clothing, from the energy and environmental aspects as well as aspects of the weaves, the necessary machine elements and mechanisms, and the energy used in all joining techniques, from which the above claims and facts can be seen.

Recovery of electrical power from exhaust air—role of vertical axis wind turbine

AbstractThis article explores the potential of regeneration of power from unnatural wind sources with the help of vertical axis wind turbines (VAWT). Researchers are searching for urban as well as industrial wind sources, which can be useful as the natural wind source to obtain electrical energy and utilize it. The wind sources considered here are the exhaust of the cooling or ventilation fans used in buildings, industries, and other places. The Darrieus VAWT extracts wind power from the exhaust air and reduces the power consumption of the concerned electrical drives. These uncommon energy sources have an inherent capability to recover a significant amount of energy without polluting the environment with less payback period. Recovered energy can be suitably converted into electrical energy and may be fed back to the power grid without any pollution, thus minimizing the total energy consumption of the building and reducing the cost operations. A detailed study of experimental models with different types of assembly and turbine models is conducted here with power outputs and operational behaviors on the existing systems. Various parameters and factors for existing and new applications are in detail that show the system has no negative impact on regular operation.

Health impact of environmental and industrial noise - a narrative review.

Industrial noise sources are among the environmental noise sources that are ranked second among the causes of ill health in Europe by the World Health Organization. The aim of this paper is to summarize and review of published information focusing on noise annoyance from industrial activities and mining. A search for articles was performed using the bibliographic databases platforms. The epidemiological evidence shows that environmental noise may be associated with cardiovascular and metabolic diseases, impaired cognitive development in children, mental health, post-irritability, and sleep disturbances. As a result of efforts to minimize the effects of industrial noise on human health, the New South Wales Environment Protection Authority published A Guide to the Noise Policy for Industry in 2017, which sets out recommended noise levels, methods, and procedures for noise management based on the latest scientific evidence. Social networks can be used to assess the population's noise annoyance and to verify the effectiveness of the measures. The industrial noise sources are typically defined by low-frequency noise. Low-frequency noise has very low attenuation and is only slightly affected by obstacles, therefore it can be a major cause of night noise annoyance. An association was confirmed between exposure to low-frequency noise and sleep disturbance, psychological problems, cognitive impairment, increased social conflicts, anxiety, emotional instability, nervousness, and reduced mental performance - concentration, and visual perception. In view of the long tradition of mining and industry, the assessment of noise from these activities from the perspective of its impacts on human health is an inherent part of legislative processes. Med Pr Work Health Saf. 2024;75(5).

Exploring Gender Diversity in Aviation Education: A Comprehensive Review of Challenges, Initiatives, and the Path Forward

Gender diversity in aviation education has long been a significant issue for the aviation industry. This review investigates gender diversity by analyzing historical participation, key barriers, and initiatives to promote inclusivity. Using a systematic approach, academic databases such as Google Scholar, JSTOR, ResearchGate, Scholarly Commons, Academia.edu, and specialized aviation industry sources were searched. Peer-reviewed articles published within the last 10 years were selected based on inclusion criteria, including relevance to aviation education and gender diversity. A thematic analysis was performed to identify significant gaps, key challenges, initiatives and outcomes to assess the current state of gender diversity in the field. This review highlights the need for comprehensive efforts to create a more inclusive educational environment to close the gender gap in aviation education and improve the industry’s overall sustainability.

Assessment of Ecological Hazards in the Inaouen Wadi and Its Tributaries Using the Presence of Potentially Toxic Elements in Its Sediments

Inaouen wadi is the second largest tributary of the Sebou river, one of Morocco’s major rivers, which holds significant economic and social importance. Unfortunately, this watercourse is severely impacted by pollution from various human activities, particularly industrial sources. However, available data on the presence of potentially toxic elements (PTEs) that could harm human health in this region remain limited. PTEs pose major environmental risks due to their toxicity, persistence, and bioaccumulation. This study aimed to assess the concentrations of PTEs in the sediments of Inaouen wadi and its main tributaries based on sediment samples collected from 12 locations in 2019. The concentrations of Cd, Pb, Cr, Ag, Al, Cu, Fe, and Zn were measured using inductively coupled plasma atomic emission spectroscopy (ICP–AES), and sediment contamination levels were evaluated using multiple indices: the enrichment factor (EF), the geo-accumulation index (Igeo), the potential ecological hazard index (RI), and the modified ecological risk index (MRI). The results indicate that concentrations of Pb, Cd, Cr, Cu, Fe, and Zn are significantly influenced by urban discharges, particularly at sites S1, S3, and S5 near the cities of Taza and Oued-Amlil. The maximum values recorded were 7.01 g/kg for Pb, 0.9 g/kg for Cd, 0.1 g/kg for Cr, 19.9 g/kg for Fe and 1.9 g/kg for Zn. The enrichment factor (EF) revealed anthropogenic sources of Fe and Pb, confirming the human origin of these elements. The geo-accumulation index (Igeo) showed that the areas around stations S1, S3, and S5 are highly contaminated by Pb, Cd, and Fe, a finding also supported by the MRI. The study identified potential ecological risks at stations S1, S3, and S5, highlighting the urgent need for improved pollution management practices to mitigate environmental risks.

Used in Urban Area for Landscape Planning and Design Spatial and Temporal Variations in Chromium (Cr) Concentrations in Picea orientalis L.

This study investigates the spatial and temporal variations in chromium (Cr) concentrations in Picea orientalis L., across different directions (north, east, south, and west) and plant organs (outer bark, inner bark, and wood) in a forested region. The research, conducted over eight age periods spanning 1980 to 2020, aimed to assess the effectiveness of Picea orientalis L. as a biomonitor for Cr pollution. The highest Cr concentrations were observed in the east direction, particularly in the inner bark and wood, while the lowest levels were found in the west. The study was conducted in an urban area near the industrial zone and highway, as well as in forested regions. A total of 100 trees were selected for the study, with samples collected from three different organs: outer bark (OB), inner bark (IB), and wood. Samples were taken from each organ at breast height (approximately 1.3 meters above the ground) to ensure consistency. The sampling covered various age periods, specifically 1980–2020, to analyze temporal changes in Cr concentrations. Statistical analysis revealed significant variations in Cr concentrations across most directions and periods, with notable increases during certain periods, especially in the west direction. These variations can be attributed to several factors, including the proximity to industrial sources of pollution, which typically release higher levels of chromium into the environment. The eastern direction likely experiences greater exposure to these emissions due to prevailing wind patterns and urban runoff, leading to increased accumulation in Picea orientalis L. Additionally, seasonal changes, temperature fluctuations, and soil characteristics may influence the bioavailability of chromium, affecting its uptake by the tree. The results suggest that Picea orientalis L. can effectively reflect Cr pollution levels, with significant directional and temporal variations that highlight the influence of these environmental factors on Cr accumulation. This study underscores the potential of Picea orientalis L. as a valuable tool for monitoring and managing Cr pollution in forested environments.

Co-tracing of groundwater emerging and conventional contaminants in karst area of Southwest China: Distribution, source, and source-specific health risks

Groundwater pollution, especially the co-contamination of emerging contaminants (ECs) and conventional contaminants, is increasingly recognized as a critical global concern. Karst aquifers are found throughout the world, providing critical water sources and sustaining rivers and ecosystems, and are particularly vulnerable to pollution. In this study, the characteristics of the contamination, potential sources, and source-specific health risks related to ECs and trace elements (TEs) in groundwater were investigated in Guiyang (a typical karst city in southwest China). The distribution of TEs followed a descending pattern from urban to suburban to rural areas. Interestingly, the median concentrations (217 ng/L) of Caffeine (CAF) in rural areas surpassed those in urban areas (145 ng/L) and even exceeded these in densely populated areas. Additionally, ECs and TEs in groundwater are significantly influenced by population density and land use types within a 1000-meter buffer zone around the sampling sites. Hierarchical cluster analysis and positive matrix factorization suggested that five principal sources of contamination were identified: domestic wastewater (29.7 %), industrial production (25.2 %), agricultural activities (16.3 %), natural and industrial sources (14.9 %), and pharmaceuticals (13.9 %). Monte Carlo simulations revealed that the non-carcinogenic risks to children in urban areas are significant, with 30.0 % of these risks exceeding the safety threshold. Source-specific health risk assessments indicated that industrial production is the primary source of risk. Furthermore, this study introduces a co-tracing method to trace the sources of groundwater contamination in karst systems. The co-tracing method based on the ECs and TEs allows for a deeper understanding of contaminant transfer and its fate in karst groundwater.

Assessing Groundwater Vulnerability to Pollution in a Rapidly Urbanizing River Basin Using a Modified DRASTIC Land Use–Lineament Density Method

ABSTRACTGroundwater quality assessment is crucial for ensuring safe drinking water, protecting public health, and maintaining sustainable water resources for agricultural and industrial uses. The Awash River basin faces significant groundwater quality challenges due to rapid population growth, high urbanization, large‐scale irrigation, and industrial pollution. The main objective of this study is to evaluate the intrinsic vulnerability of aquifers to pollution in the Awash Basin and identify hotspots requiring urgent intervention using a modified DRASTIC overlay analysis method. In addition to the seven parameters considered in the generic DRASTIC overlay analysis (depth to the water table, recharge, aquifer media, slope, soil media, vadose zone, and hydraulic conductivity), we incorporated land use/land‐cover (LULC) and lineament density (LD) distributions (DRASTIC‐LU‐LD). This modification allowed us to produce more realistic groundwater vulnerability maps for the basin. To identify the most influential parameters in the overlay, sensitivity analysis was conducted using Map Removal Sensitivity Analysis (MRSA) and Single Parameter Sensitivity Analysis (SPSA). Initially, the generic DRASTIC index in the area ranges from 69 to 181, categorizing the area into four vulnerability zones: very low (21%), low (51%), medium (27%), and high (1%). After incorporating LU and LD, the index values ranged from 90 to 240. Based on the percentage of the total area studied, the inclusion of LU decreased the very low and low vulnerability zones from 72% to 44% and the inclusion of LD increased the high‐ and very‐high‐vulnerability zones from 14% to 27%. The areas most vulnerable to groundwater pollution are in the western (upper Awash), middle Awash, and northwestern regions, particularly in city centers where groundwater abstraction is significant. These high‐vulnerability zones coincide with municipal, industrial, and agricultural pollution sources. The vadose zone parameter has the highest impact in both MRSA and SPSA, with a variation index value of 3.08% and a mean effective weight of 27.93%, respectively. By identifying areas vulnerable to groundwater pollution, this study provides a valuable basis for informed decision‐making and the development of effective strategies for protecting groundwater from urban, industrial, and agricultural pollution sources.

Inter- and intra-annual carbon isotope fluctuations in Pinus sylvestris L. tree rings whole wood and cellulose in north-eastern Lithuania

In temperate regions trees typically exhibit growth sensitivity to climatic conditions during the growth season. Annual tree ring growth increments correlate with a variety of environmental factors. As an index of water use efficiency, δ13C is a preferred proxy to allow accurate interpretation of environmental factors critical for the tree growth, including changes in climate patterns, variation in the ambient temperature and precipitation. We assumed that isotopic differences within individual tree rings are likely to produce seasonal isotope fluctuations in the chronology that might be interpreted as response to environmental impacts. To verify the assumption, we measured δ13C in annual tree rings of Pinus Sylvestris L. split into 13 intra-annual segments each and checked δ13C correlations with temperature, precipitation, the number of sunshine hours and relative air humidity. For the investigation, we chose a site in north-eastern Lithuania, Zarasai, located in boreal latitude and remote from industrial pollution sources. The methodology of the research was based on high coherence of δ13C chronologies measured in the whole wood and α-cellulose extracted by means of two different methods. The experiment produced strong δ13C correlations with hydrometeorological parameters, especially in the earlywood formed in June