Individual Quantum States Research Articles

Collisional alignment and molecular rotation control the chemi-ionization of individual conformers of hydroquinone with metastable neon.

The relationship between the shape of a molecule and its chemical reactivity is a central tenet in chemistry. However, the influence of the molecular geometry on reactivity can be subtle and result from several opposing effects. Here, using a crossed-molecular-beam experiment in which individual rotational quantum states of specific conformers of a molecule are separated, we study the chemi-ionization reaction of hydroquinone with metastable neon atoms. We show that collision-induced alignment of the reaction partners caused by geometry-dependent long-range forces influences reaction pathways, which is, however, countered by molecular rotation. The present work provides insights into the conformation-specific stereodynamics of complex polyatomic systems and illustrates the capability of advanced molecule-control techniques to unravel these effects.

Quantum control of trapped polyatomic molecules for eEDM searches.

Ultracold polyatomic molecules are promising candidates for experiments in quantum science and precision searches for physics beyond the Standard Model. A key requirement is the ability to achieve full quantum control over the internal structure of the molecules. In this work, we established coherent control of individual quantum states in calcium monohydroxide (CaOH) and demonstrated a method for searching for the electron electric dipole moment (eEDM). Optically trapped, ultracold CaOH molecules were prepared in a single quantum state, polarized in an electric field, and coherently transferred into an eEDM-sensitive state where an electron spin precession measurement was performed. To extend the coherence time, we used eEDM-sensitive states with tunable, near-zero magnetic field sensitivity. Our results establish a path for eEDM searches with trapped polyatomic molecules.

An Examination of Quantum Information Processing Through Quantum Cryptography; A study

"Along with these developments, personal microwave technology has enabled strong non-linear effects at the photon level, leading to readily observable novel parameter regimes in quantum optics. Circuit QED has opened up new opportunities to explore the rich physics of quantum information processing (QIP) and quantum optics (QO), making them scalable on the road to quantum computing. However, we must also discuss some of the challenges involved. Quantum Technologies (QT) is a cross-disciplinary field that has made great progress in recent years. Technologies that can explicitly represent individual quantum states, as well as superposition and entanglement, are now being developed to exploit the 'strange' properties of quantum mechanics. In quantum communication, individual or entangled photons are used to securely send data, while quantum simulation utilizes well-controlled quantum systems that are less accessible. Interest is growing in higher dimensional quantum states and quantum communication, as the extended availability of Hilbert space and greater information capacity, along with increased noise elasticity, offer many advantages and new research possibilities. Let's focus our attention on the benefits of higher dimensional quantum states for quantum communication, as shown by Kuditz and others. Nevertheless, it has been demonstrated that higher dimensional quantum states can also provide improvements in many other areas."

Controlling wave-particle duality with entanglement between single-photon and Bell states

Wave-particle duality and entanglement are two fundamental characteristics of quantum mechanics. All previous works on experimental investigations in wave{particle properties of single photons (or single particles in general) show that a well-defined interferometer setting determines a well-defined property of single photons. Here we take a conceptual step forward and control the wave-particle property of single photons with quantum entanglement. By doing so, we experimentally test the complementarity principle in a scenario, in which the setting of the interferometer is not defined at any instance of the experiment, not even in principle. To achieve this goal, we send the photon of interest (S) into a quantum Mach-Zehnder interferometer (MZI), in which the output beam splitter of the MZI is controlled by the quantum state of the second photon (C), who is entangled with a third photon (A). Therefore, the individual quantum state of photon C is undefined, which implements the undefined settings of the MZI for photon S. This is realized by using three cascaded phase-stable interferometers for three photons. There is typically no well-defined setting of the MZI, and thus the very formulation of the wave-particle properties becomes internally inconsistent.

Quantum technologies in the telecommunications industry

Quantum based technologies have been fundamental in our world. After producing the laser and the transistor, the devices that have shaped our modern information society, the possibilities enabled by the ability to create and manipulate individual quantum states opens the door to a second quantum revolution. In this paper we explore the possibilities that these new technologies bring to the Telecommunications industry.

Single-molecule laser nanospectroscopy with micro–electron volt energy resolution

Ways to characterize and control excited states at the single-molecule and atomic levels are needed to exploit excitation-triggered energy-conversion processes. Here, we present a single-molecule spectroscopic method with micro-electron volt energy and submolecular-spatial resolution using laser driving of nanocavity plasmons to induce molecular luminescence in scanning tunneling microscopy. This tunable and monochromatic nanoprobe allows state-selective characterization of the energy levels and linewidths of individual electronic and vibrational quantum states of a single molecule. Moreover, we demonstrate that the energy levels of the states can be finely tuned by using the Stark effect and plasmon-exciton coupling in the tunneling junction. Our technique and findings open a route to the creation of designed energy-converting functions by using tuned energy levels of molecular systems.

Single-molecule nanospectroscopy

Spectroscopy Microscopic understanding and molecular-level control of individual electronic quantum states of a single molecule are a long-standing challenge in spectroscopy. Imada et al. found that a narrow-line tunable laser combined with a scanning tunneling microscope was able to generate photoluminescence spectra of the electronic and vibrational states of single molecules with micro–electron volt energy resolution and submolecular spatial resolution. The authors also discovered a way to tune the energy levels through a linear Stark effect and plasmon-exciton coupling in the tunneling junction. The proposed technique paves the way to efficient exploitation of energy conversion dynamics in electronic excited states, which constitutes the bedrock principle of such systems as LEDs, photovoltaics, and photosynthetic cells. Science , abg8790, this issue p. [95][1] [1]: /lookup/doi/10.1126/science.abg8790

Set Coherence: Basis-Independent Quantification of Quantum Coherence.

The coherence of an individual quantum state can be meaningfully discussed only when referring to a preferred basis. This arbitrariness can, however, be lifted when considering sets of quantum states. Here we introduce the concept of set coherence for characterizing the coherence of a set of quantum systems in a basis-independent way. We construct measures for quantifying set coherence of sets of quantum states as well as quantum measurements. These measures feature an operational meaning in terms of discrimination games and capture precisely the advantage offered by a given set over incoherent ones. Along the way, we also connect the notion of set coherence to various resource-theoretic approaches recently developed for quantum systems.

Morphology of three-body quantum states from machine learning

The relative motion of three impenetrable particles on a ring, in our case two identical fermions and one impurity, is isomorphic to a triangular quantum billiard. Depending on the ratio κ of the impurity and fermion masses, the billiards can be integrable or non-integrable (also referred to in the main text as chaotic). To set the stage, we first investigate the energy level distributions of the billiards as a function of 1/κ ∈ [0, 1] and find no evidence of integrable cases beyond the limiting values 1/κ = 1 and 1/κ = 0. Then, we use machine learning tools to analyze properties of probability distributions of individual quantum states. We find that convolutional neural networks can correctly classify integrable and non-integrable states. The decisive features of the wave functions are the normalization and a large number of zero elements, corresponding to the existence of a nodal line. The network achieves typical accuracies of 97%, suggesting that machine learning tools can be used to analyze and classify the morphology of probability densities obtained in theory or experiment.

Morphology of three-body quantum states from machine learning

The relative motion of three impenetrable particles on a ring, in our case two identical fermions and one impurity, is isomorphic to a triangular quantum billiard. Depending on the ratio κ of the impurity and fermion masses, the billiards can be integrable or non-integrable (also referred to in the main text as chaotic). To set the stage, we first investigate the energy level distributions of the billiards as a function of 1/κ ∈ [0, 1] and find no evidence of integrable cases beyond the limiting values 1/κ = 1 and 1/κ = 0. Then, we use machine learning tools to analyze properties of probability distributions of individual quantum states. We find that convolutional neural networks can correctly classify integrable and non-integrable states. The decisive features of thewave functions are the normalization and a large number of zero elements, corresponding to the existence of a nodal line. The network achieves typical accuracies of 97%, suggesting that machine learning tools can be used to analyze and classify the morphology of probability densities obtained in theory or experiment.

Ultimate control in chemistry.

Controlling reactions between molecules is a major fundamental goal in chemistry and doing so on the level of individual quantum states is very challenging. Now, control over the reactant state and full characterization of the product-state distribution of an ultracold bimolecular reaction has been demonstrated.

Final-state-resolved mutual neutralization of Na+ and D−

The present paper reports on a merged-beam experiment on mutual neutralization between ${\mathrm{Na}}^{+}$ and ${\mathrm{D}}^{\ensuremath{-}}$. For this experiment, we have used the DESIREE ion-beams storage-ring facility. The reaction products are detected using a position- and time-sensitive detector, which ideally allows for determination of the population of each individual quantum state in the final atomic systems. Here, the $4s, 3d$, and $4p$ final states in Na are observed and in all cases the D atom is in its ground state $1s ^{2}S$. The respective branching fractions of the states populated in Na are determined by fitting results from a Monte Carlo simulation of the experiment to the measured data. The center-of-mass collision energy is controlled using a set of biased drift tubes, and the branching fractions are measured for energies between 80 meV and 393 meV. The resulting branching fractions are found to agree qualitatively with the only available theoretical calculations for this particular system, which are based on a multichannel Landau-Zener approach using dynamic couplings determined with a linear combination of atomic orbitals model.

Quantum entanglement in nuclear Cooper-pair tunneling with γ rays

While Josephson-like junctions, transiently established in heavy ion collisions ($\tau_{coll}\approx10^{-21}$ s) between superfluid nuclei --through which Cooper pair tunneling ($Q$-value $Q_{2n}$) proceeds mainly in terms of successive transfer of entangled nucleons-- is deprived from the macroscopic aspects of a supercurrent, it displays many of the special effects associated with spontaneous symmetry breaking in gauge space (BCS condensation), which can be studied in terms of individual quantum states and of tunneling of single Cooper pairs. From the results of studies of one- and two- neutron transfer reactions carried out at energies below the Coulomb barrier we estimate the value of the mean square radius (correlation length) of the nuclear Cooper pair. A quantity related to the largest distance of closest approach for which the absolute two-nucleon tunneling cross section is of the order of the single-particle one. Furthermore, emission of $\gamma$-rays of (Josephson) frequency $\nu_J=Q_{2n}/h$ distributed over an energy range $\hbar/\tau_{coll}$ is predicted.

Evaluating Machine Learning Approaches for Discovering Optimal Sets of Projection Operators for Quantum State Tomography of Qubit Systems

Abstract Finding optimal measurement schemes in quantum state tomography is a fundamental problem in quantum computation. It is known that for non-degenerate operators the optimal measurement scheme is based on mutually unbiassed bases. This paper is a follow up from our previous work, where we use standard numerical approaches to look for optimal measurement schemes, where the measurement operators are projections on individual pure quantum states. In this paper we demonstrate the usefulness of several machine learning techniques – reinforcement learning and parallel machine learning approaches, to discover measurement schemes, which are significantly better than the ones discovered by standard numerical methods in our previous work. The high-performing quorums of projection operators we have discovered have complex structure and symmetries, which may imply that the optimal solution will possess such symmetries.

Heat and Work Along Individual Trajectories of a Quantum Bit.

We use a near quantum limited detector to experimentally track individual quantum state trajectories of a driven qubit formed by the hybridization of a waveguide cavity and a transmon circuit. For each measured quantum coherent trajectory, we separately identify energy changes of the qubit as heat and work, and verify the first law of thermodynamics for an open quantum system. We further establish the consistency of these results by comparison with the master equation approach and the two-projective-measurement scheme, both for open and closed dynamics, with the help of a quantum feedback loop that compensates for the exchanged heat and effectively isolates the qubit.

Optimal choice of state tomography quorum formed by projection operators

A minimal set of measurement operators for quantum state tomography has in the non-degenerate case ideally eigenbases which are mutually unbiased. This is different for the degenerate case. Here, we consider the situation where the measurement operators are projections on individual pure quantum states. This corresponds to maximal degeneracy. We present numerically optimized sets of projectors and find that they significantly outperform those which are taken from a set of mutually unbiased bases.

Rapid gate-based spin read-out in silicon using an on-chip resonator.

Silicon spin qubits are one of the leading platforms for quantum computation1,2. As with any qubit implementation, a crucial requirement is the ability to measure individual quantum states rapidly and with high fidelity. Since the signal from a single electron spin is minute, the different spin states are converted to different charge states3,4. Charge detection, so far, has mostly relied on external electrometers5-7, which hinders scaling to two-dimensional spin qubit arrays2,8,9. Alternatively, gate-based dispersive read-out based on off-chip lumped element resonators has been demonstrated10-13, but integration times of 0.2-2 ms were required to achieve single-shot read-out14-16. Here, we connect an on-chip superconducting resonant circuit to two of the gates that confine electrons in a double quantum dot. Measurement of the power transmitted through a feedline coupled to the resonator probes the charge susceptibility, distinguishing whether or not an electron can oscillate between the dots in response to the probe power. With this approach, we achieve a signal-to-noise ratio of about six within an integration time of only 1 μs. Using Pauli's exclusion principle for spin-to-charge conversion, we demonstrate single-shot read-out of a two-electron spin state with an average fidelity of >98% in 6 μs. This result may form the basis of frequency-multiplexed read-out in dense spin qubit systems without external electrometers, therefore simplifying the system architecture.

Quantum acousto-optic control of light-matter interactions in nanophotonic networks

We analyze the coupling of atoms or atom-like emitters to nanophotonic waveguides in the presence of propagating acoustic waves. Specifically, we show that strong index modulations induced by such waves can drastically modify the effective photonic density of states and thereby influence the strength, the directionality, as well as the overall characteristics of photon emission and absorption processes. These effects enable a complete dynamical control of light-matter interactions in waveguide structures, which even in a two dimensional system can be used to efficiently exchange individual photons along selected directions and with a very high fidelity. Such a quantum acousto-optical control provides a versatile tool for various quantum networking applications ranging from the distribution of entanglement via directional emitter-emitter interactions to the routing of individual photonic quantum states via acoustic conveyor belts.

Individual control and readout of qubits in a sub-diffraction volume

Medium-scale ensembles of coupled qubits offer a platform for near-term quantum technologies as well as studies of many-body physics. A central challenge for coherent control of such systems is the ability to measure individual quantum states without disturbing nearby qubits. Here, we demonstrate the measurement of individual qubit states in a sub-diffraction cluster by selectively exciting spectrally distinguishable nitrogen vacancy centers. We perform super-resolution localization of single centers with nanometer spatial resolution, as well as individual control and readout of spin populations. These measurements indicate a readout-induced crosstalk on non-addressed qubits below 4 × 10−2. This approach opens the door to high-speed control and measurement of qubit registers in mesoscopic spin clusters, with applications ranging from entanglement-enhanced sensors to error-corrected qubit registers to multiplexed quantum repeater nodes.

The quantum technologies roadmap: a European community view

Within the last two decades, quantum technologies (QT) have made tremendous progress, moving from Nobel Prize award-winning experiments on quantum physics (1997: Chu, Cohen-Tanoudji, Phillips; 2001: Cornell, Ketterle, Wieman; 2005: Hall, Hänsch-, Glauber; 2012: Haroche, Wineland) into a cross-disciplinary field of applied research. Technologies are being developed now that explicitly address individual quantum states and make use of the ‘strange’ quantum properties, such as superposition and entanglement. The field comprises four domains: quantum communication, where individual or entangled photons are used to transmit data in a provably secure way; quantum simulation, where well-controlled quantum systems are used to reproduce the behaviour of other, less accessible quantum systems; quantum computation, which employs quantum effects to dramatically speed up certain calculations, such as number factoring; and quantum sensing and metrology, where the high sensitivity of coherent quantum systems to external perturbations is exploited to enhance the performance of measurements of physical quantities. In Europe, the QT community has profited from several EC funded coordination projects, which, among other things, have coordinated the creation of a 150-page QT Roadmap (http://qurope.eu/h2020/qtflagship/roadmap2016). This article presents an updated summary of this roadmap.