Impervious areas are one of the important indicators for evaluating the urbanization process, while surface temperature is one of the reference factors for evaluating the urban environment. In order to investigate whether the spatial distribution of an impervious surface has any influence on urban surface temperature, Xuzhou City was selected as the study area, and the impervious surface information was extracted based on the maximum likelihood classification method for Xuzhou City for the period of 2013–2022, and surface temperature inversion was performed using Landsat 8 remote sensing imagery and nighttime lighting data. In order to reduce the confusion between bare soil and impervious surfaces, the study area was divided into built-up and non-built-up areas for the selection of impervious and pervious surface samples using nighttime lighting data, and, finally, the maximum likelihood classification method was used to realize the extraction of impervious surfaces. The experimental results show that, by extracting the impervious surface of Xuzhou City, the impervious surface of Xuzhou City continued to increase from 2013 to 2022, in which the growth rate was faster in 2014–2016 and 2019–2021, and slower in 2017–2018 and 2021–2022, after performing surface temperature inversion as well as temperature grading. The results of impervious surface extraction and surface temperature inversion were subjected to overlay analysis and linear regression analysis. It was found that most of the impervious surface area is in high-temperature areas, and the density of the impervious surface is proportional to the surface temperature in the impervious surface and its surrounding area. Therefore, it can be concluded that the expansion of impervious surfaces is one of the reasons for the increase in urban surface temperature.
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