Increasing Mn Content Research Articles

Microstructure, Corrosion Resistance and Tensile Properties of Modified Al-0.7Mn Alloy

A modified alloy (Al-0.7Mn) was designed and fabricated with an increased Mn content up to 0.7wt.% and a controlled Fe content of 0.1wt.% and compared with the conventional Al3102 (Al-0.3Mn) alloy using the air-slip casting process. Both alloys were homogenized at 510°C for 10 hours and then air-cooled. The microstructure, corrosion resistance, and mechanical properties of these materials were investigated. In the modified Al-0.7Mn alloy, the Mn/Fe ratios were found to be higher in both the α-Al matrix and the intermetallic compound of Al<sub>6</sub>(Mn, Fe) compared to those of the Al3102 alloy. Additionally, the size and volume fraction of the Al<sub>6</sub>(Mn, Fe) phase were relatively larger and higher in the modified Al-0.7Mn alloy, while the grain size of the α-Al matrix was significantly smaller. The galvanic corrosion test results indicated that the corrosion potential (E<sub>corr</sub>) of the conventional Al3102 alloy was higher than that of the modified Al-0.7Mn alloy (Al-0.7Mn: -682.1mV, Al3102: -652.4mV). In contrast, the corrosion current (I<sub>corr</sub>) and corrosion rate were measured to be 49.86 μA and 0.541 mm/year for the Al-0.7Mn alloy, and 53.91 μA and 0.585 mm/year for the Al3102 alloy, respectively. Thus, it was confirmed that the corrosion rate of the Al-0.7Mn alloy was slower compared to the conventional alloy, indicating better corrosion resistance. Room temperature tensile results showed that the tensile strengths of the modified and conventional alloys were 92.55 MPa and 78.39 MPa, respectively, demonstrating that the modified Al-0.7Mn alloy achieved higher strength without a significant decrease in ductility. This improvement is attributed to the higher Mn/Fe wt.% ratio in the Al<sub>6</sub>(Mn, Fe) phase of the modified Al-0.7Mn alloy, which can reduce the detrimental effect of Fe element and enhance the corrosion resistance. Additionally, the larger size and higher volume fraction of Al<sub>6</sub>(Mn, Fe) in the modified alloy, along with the smaller grain size, may contribute to the higher tensile strength. Based on these results, the corrosion mechanisms and deformation behavior of the modified Al-0.7Mn alloy were also discussed.

Development of Fe-Cr-C alloys with high Mn content for bone implant

The object of this study is to combine the properties of Mn and the advantages of Fe-Cr-C to improve biomaterial compatible characteristics. Three alloys of Fe-Cr-C with compositions of 12 wt. % Mn, 16 wt. % Mn, and 20 wt. % Mn, were investigated. Microstructural analysis was carried out using a scanning electron microscope (SEM), and a Vickers hardness test kit was used to evaluate the hardness. The pin-on-disc method was used for the dry slide wear test, and the corrosion test was carried out using the three-electrode cell polarization method. The hardness value of Fe-Cr-C alloy increased by 28.7 % with the increase of Mn content from 12 wt. % (231.8 VHN) to 20 wt. % (298.4 VHN). The tensile strength value increased by 30.3 % with an increase in Mn content from 12 wt. % (522.69 MPa) to 20 wt. % (680.89 MPa), while the strain value decreased by 30.9 %. However, impact toughness did somewhat decline, from 0.213 J/mm2 at 12 wt. % Mn to 0.169 J/mm2 at 20 wt. % Mn. The wear rate results for Fe-Cr-C 20 wt. % Mn 0.000156 mm3/kg. show a reduction of more than 15 wt. % when compared to Fe-Cr-C 12 wt. % Mn because of an increase in the hard-intermetallic area. Additionally, corrosion resistance improved significantly, with the corrosion rate decreasing from 0.005814 mm/yr at 12 wt. % Mn to 0.001780 mm/yr at 20 wt. % Mn, demonstrating that higher Mn content reduces material degradation in corrosive environments. Based on the experimental results, Fe-Cr-C 20 wt % Mn alloy has the highest mechanical and corrosion resistance of the three types of alloys. Fe-Cr-C with high Mn alloys are promising candidates for application as biomaterials for bone implants by optimizing the Mn content and corrosion resistance

Effect of Mn element on shock response in CoCrFeNiMnx high entropy alloys

Abstract The effect of Mn element on shock response of CoCrFeNiMn x high entropy alloys (HEAs) are investigated using molecular dynamics simulations. Structural analysis shows that Mn-rich CoCrFeNiMn x HEA has a larger average atomic volume. The elastic properties of CoCrFeNiMn x HEAs under various hydrostatic pressures are studied, revealing that the elastic modulus decreases with increasing of Mn content. The shock thermodynamic parameters are quantitatively analyzed. The Mn-dependent shock Hugoniot relationship of CoCrFeNiMn x HEAs is obtained: U s = 1.25 + (5.21–0.011x)U p. At relatively high shock pressure, the increase in Mn content promotes the formation of clustered BCC structures and hinders the development of dislocations. In addition, more FCC structures in Mn-rich CoCrFeNiMn x HEAs transform into disordered structures during spallation. Spall strength decreases with increasing Mn content. This study can provide a reference for the design and application of CoCrFeNiMn HEAs under shock loading.

Structural, optical, and dielectric properties of Mn-doped Ce1-xMnxO2 nanocrystals for frequency-dependent device applications

Cerium oxide (CeO2) is a significant oxide semiconductor known for its advantageous electrical, optical, and dielectric properties. This study investigates the effects of manganese (Mn) doping on the structural, optical, and dielectric characteristics of CeO2. Pure and Mn-doped Ce1-xMnxO2 nanocrystalline powders, with Mn concentrations of 0, 1, 3, 5, and 7 %, were synthesized using a co-precipitation method. Structural analysis confirmed the formation of a cubic crystal structure, while surface morphology revealed agglomerated spherical particles. Notably, the band gap of Ce1-xMnxO2 decreased from 2.80 eV to 2.30 eV with increasing Mn content, indicating enhanced electronic properties due to doping. The dielectric properties exhibited a pronounced frequency dependence, with significant variations in dielectric constant and loss, demonstrating the potential of Mn-doped CeO2 as a diluted magnetic semiconductor. These findings underscore the material's applicability in biosensors and optoelectronic devices, paving the way for advancements in frequency-related technologies.

Study of multiferroic properties of Mn substituted Bi0.8Sm0.1Dy0.1Fe1-xMnxO3 ceramics

Abstract Transition metal Mn substituted various multiferroic Bi0.8Sm0.1Dy0.1Fe1-xMnxO3 (x = 0.00, 0.01, 0.03 and 0.05) ceramics samples were fabricated by the solid-state reaction technique. The distorted rhombohedral perovskite structure with some phase impurity of all samples is confirmed by X-ray diffraction analysis. Field Emission Scanning Electron Microscope and Energy Dispersive X-ray spectroscopy are used for microstructural and quantitative analysis, respectively. Densities are decreased and the average grain size is increased with Mn contents. The initial permeability and relative quality factor (RQF) have found to be increased with Mn contents in the samples. The peaks in RQF shifts toward the lower frequency region with increasing Mn contents can be attributed by Snoek’s relation. All the samples show paramagnetic behavior at room temperature and magnetization slightly increases with Mn contents. The frequency dependent dielectric constant is investigated and found to consequence of space charge polarization. The dispersion behavior in dielectric constants can be explained by the Maxwell-Wagner model. The dielectric constants and dielectric loss decrease with increasing of Mn contents for all the samples. The value of electric modulus is observed to increases with the increasing of frequency and this dispersion phenomena is due to short range mobility of charge carriers in conduction. The effect of grain and grain boundaries on electric properties of samples are investigated by complex impedance analysis. The ac conductivity increases with frequency due to small polaron hopping and it can be attributed according to Jonscher’s power law.

Enhancement in ZnO-based self-powered photodetector by inserting Mn dopant

In this study, the effect of Mn doping on the photovoltaic properties of ZnO films deposited on a p-Si substrate via spray pyrolysis has been evaluated. The Mn concentration was varied at 0, 1, and 3 wt%. The spray was carried out at 400 °C for 10 min. As a result, the X-ray diffraction pattern shows that the crystallite size decreases linearly with increasing Mn doping, from 44 nm (0% Mn) to 31 nm (3% Mn). Scanning electron microscopy images show that the increase in Mn concentration causes the nanostructure size to be smaller, from 325 nm (0% Mn) to 112.3 nm (3% Mn). Interestingly, the best photosensitivity and response time are found in the doped sample (3% Mn) at a bias voltage of 0 V rather than 1 V and 5 V, indicating the photovoltaic effect. This result is important to develop future self-powered devices.

20 Trace metal homeostasis in growing cattle

Abstract Apparent trace metal absorption and tissue retention upon incremental levels of supplemental Zn, Cu, and Mn were studied in growing cattle. A total of 60 Holstein bulls were enrolled for the study and fed for 28 d a diet consisting of barley straw (15%), molasses (10%) and pelleted concentrate (75%; Zn = 78 ppm, Cu = 15 ppm, Mn = 91 ppm). Thereafter, 20 bulls were randomly selected and slaughtered for determination of baseline tissue trace metal composition. The remaining 40 bulls [body weight (BW) = 394 ± 20 kg] were then blocked based on BW in 8 blocks of 5 bulls each. Bulls within a block were randomly assigned one of the diets differing in supplemental levels of Zn, Cu, and Mn (all from sulfate form) with the following dietary contents of Zn, Cu and Mn, respectively: No supplement (38, 7, and 47 ppm), Dose 1 (61, 11, and 68 ppm), Dose 2 (78, 15 and 91 ppm), Dose 3 (123, 26, 136 ppm) or Dose 4 (195, 43, and 214 ppm). These diets were fed for 12 wk, and complete collection of feces and urine were performed on wk 4, 8 and 12 for assessment of trace metals balance and apparent absorption. Gastrointestinal tissues, whole organs (heart, liver, spleen, and kidney), bile, cervical vertebra, and tibia were collected at slaughterhouse from all bulls. All samples were dried, ground, and analyzed for minerals. Data were processed using dietary treatment as a continuous variable and also as categorial variable. Both approaches adjusted for the fixed effect of block (Proc Mixed, SAS 9.4). Whole-body Zn, Cu and Mn balance quadratically increased (P < 0.05) with supplementation, with a significantly higher values for Dose 4 compared with all other dietary treatment (Figure 1, P < 0.05). Dose 4 also led to a 2-fold increase in urinary Zn and Cu excretions (P < 0.05), and a 4-fold increase in urinary Mn excretion (P < 0.01). Although magnitudes of change were moderate (8 to 15%), increasing dietary Zn supply linearly increased spleen Zn content (P = 0.03), and tended to increase ruminal and hepatic Zn content (P < 0.10). Hepatic Cu linearly increased from 264 to 667 mg/kg DM with increasing dietary Cu supply (P < 0.01), whereas Cu concentration in bile only increased at Doses 4 and 5 (P < 0.01). Increasing Mn supply resulted in quadratic increase of ruminal and biliary Mn content from 340 to 1140 mg/kg DM, and from 0.32 to 1.38 mg/L, respectively. Small intestine and cecum Mn concentrations linearly and quadratically increased (about 2-fold increase, P < 0.05) with incremental supply of Mn. Homeostatic regulation mechanisms were apparently overwhelmed at the greatest Zn, Cu and Mn supplementation levels evaluated in this study.

Manipulation of Mn/Ce ratio for deep chlorobenzene oxidation: Catalytic mechanisms and byproducts analysis

In this research, a sequence of spatial porous MnCeOx catalysts with varying Mn/Ce from 3:1 to 1:7 were synthesized using the sol–gel method for chlorobenzene (CB) oxidation. Mn1Ce1 exhibited the best performance due to its high lattice oxygen content and the strong interaction between Ce and Mn. The increase in Mn content in CeO2 catalysts resulted in enhanced redox properties and acidity, which was beneficial for the adsorption and activation of CB, thus enhancing the selectivity and the desorption of HCl on the catalyst surface. Carbon deposition and the formation of metal chloride were the main reasons for catalyst deactivation. At low temperature regions (150 ∼ 300 °C), insufficient oxidation capability and the chlorine deposition on the catalyst surface resulted in the formation of various chlorinated compounds. As the temperature increases (300 ∼ 450 °C), the release of HCl and more reactive oxygen species is available on the catalytic interface, generating various oxygen-containing degradation intermediates. This work proposed a fine-designed, low-cost mixed metal oxide catalysts for low temperature CB oxidation, and provided novel in-depth understandings of degradation intermediate formation thermodynamics. Our findings would be helpful for deep purification of chlorinated VOCs polluted industrial tail gas.

Theoretical Analysis of Stacking Fault Energy, Elastic Properties, Electronic Properties, and Work Function of MnxCoCrFeNi High-Entropy Alloy.

The effects of different Mn concentrations on the generalized stacking fault energies (GSFE) and elastic properties of MnxCoCrFeNi high-entropy alloys (HEAs) have been studied via first-principles, which are based on density functional theory. The relationship of different Mn concentrations with the chemical bond and surface activity of MnxCoCrFeNi HEAs are discussed from the perspectives of electronic structure and work function. The results show that the plastic deformation of MnxCoCrFeNi HEAs can be controlled via dislocation-mediated slip. But with the increase in Mn concentration, mechanical micro twinning can still be formed. The deformation resistance, shear resistance, and stiffness of MnxCoCrFeNi HEAs increase with the enhancement of Mn content. Accordingly, in the case of increased Mn concentration, the weakening of atomic bonds in MnxCoCrFeNi HEAs leads to the increase in alloy instability, which improves the possibility of dislocation.

Research on a new type of ureteral stent material Zn-2Cu-0.5Fe-xMn with controllable degradation rate

The placement of ureteral stents plays a crucial role in the treatment of ureteral strictures, therefore requiring high material performance standards. In addition, depending on the etiology of ureteral strictures, there are significant differences in the retention time of ureteral stents, thus requiring different degradation rates for the stents. Therefore, it is crucial to develop stent materials with high performance and controllable degradation rates. This study explores the potential of Zn-2Cu-0.5Fe-xMn alloy as a ureteral stent material, utilizing the antibacterial effect of copper ions, the strengthening effect of Fe element on Zn-based alloys, and the accelerated degradation effect of Mn element. The research found that with the increase in Mn content, the average grain size of the alloy and the size of (Fe, Mn)Zn13 phase gradually increased, leading to a decrease in hardness. The corrosion rate of the alloy increased with the increase in Mn content, attributed to changes in grain size and standard electrode potential differences between elements. Due to the antibacterial effects of Zn ions and Cu ions, the Zn-2Cu-0.5Fe-xMn alloy exhibits good anti-stone formation capabilities. Furthermore, the alloy also demonstrates acceptable cytotoxicity. Therefore, the Zn-2Cu-0.5Fe-xMn alloy is expected to become an important implant material in urological surgery.

An experimental study on material removal rate and surface roughness of Cu-Al-Mn ternary shape memory alloys using CNC end milling

Abstract This study investigates the impact of Computer Numerical Control (CNC) milling parameters on Cu-Al-Mn SMAs (Shape memory alloys) to evaluate the effects on Surface Roughness (SR) and Material Removal Rate (MRR). The primary variables examined comprise of cutting speed, feed rate, and depth of cut. Results indicate that the Shape Memory Effect (SME) is higher in Copper Aluminium Manganese (CAM 3) compared to CAM 1 and CAM 2, with SME improving from 3.5% to 5.5% as Manganese (Mn) content increases, reflecting an increase in dislocations within the metal's crystal structure. Surface roughness increases with higher feed rates and depths of cut but decreases with increased cutting speed. MRR shows a positive correlation with feed rate, depth of cut, and cutting speed, though it decreases with higher Mn content. Notably, CAM 3 exhibits lower MRR compared to CAM 1 and CAM 2. Scanning Electron Microscopy (SEM) reveals that at lower feed rates (0.10 mm/rev), the surface is smooth and free of ridges or feed marks, while at higher feed rates (0.18 mm/rev), noticeable surface imperfections and plastic deformation occur. The addition of Mn improves surface smoothness and machinability, it also affects MRR. Further suggesting that Mn content and milling parameters significantly influence both the mechanical properties and machinability of Cu-Al-Mn SMAs respectively.

Effect of Mn content on the microstructure, mechanical properties and corrosion behavior of Ti–Nb–Zr–Mn alloys processed via spark plasma sintering

Herein, β-type Ti–Nb–Zr–Mn alloys were prepared by ball milling and spark plasma sintering. The effects of Mn addition and quenching treatment on the microstructure, mechanical properties, and corrosion behavior of the alloy were investigated. The Ti–Nb–Zr–Mn alloys are predominantly constituted of equiaxed β Ti grains with a small proportion of ω phase. An increase in Mn content inhibits the precipitation of the ω phase while promoting a more homogeneous solid solution. The tensile strength of the as-prepared alloys decreases and then increases, whereas the plasticity demonstrates the opposite trend. The Elastic modulus and hardness roughly show a trend of decreasing and then increasing. Additionally, the Ti–24Nb–4Zr–2Mn alloy, after undergoing a solid solution treatment at a temperature of 950 °C and subsequent water quenching (referred to as M2-950), demonstrates exceptional comprehensive performance, showing a yield strength of 956 ± 4 MPa, an ultimate strength of 995 ± 13 MPa, an elongation of 16.4 ± 1.6 %, a hardness of 312 ± 11 H V, and an Elastic modulus of 72.6 GPa. Moreover, the corrosion behavior in Ringer's solution was extensively investigated, and the M2-950 alloy has superior corrosion resistance.

Distribution of manganese in surface soils and ecological risk assessment: a case study in the Pb-Zn mining and smelting area in the Mitrovica Region, Kosovo

ABSTRACT This study was conducted on the distribution of manganese content in the soils of the city of Mitrovica and its surroundings in Kosovo. A total of 156 topsoil samples were taken in the entire study region (sampling grid of 1.4 × 1.4 km2). The average Mn content of the entire study area is 1600 mg/kg (range 170–17000 mg/kg), which is 4.2 times higher than the EU average and 3.3 times higher than the global average. The spatial distribution maps show that the higher Mn contents occur mainly in soils from Miocene latite as well as quartz-latite and from Triassic volcanic-sedimentary formations in the eastern and north-eastern part of the study area. The lower values were found in the Flysch and Cretaceous flysch outcrops. It was found that the increased Mn contents in soils from this area are mostly of lithogenic origin. The values of the enrichment factor (EF) show that the soils of the entire study area are very highly enriched with Mn (20 < EF < 40). The values of the geo-accumulation index (1< I-geo ≤ 2), show that the soils of the entire study area are moderately contaminated with Mn.

Hot compression recrystallization and processing characteristics of 18 %Cr lean duplex stainless steel with Mn addition

The deformation differences of hot compression tests for 18 % Cr lean duplex stainless steels, alloyed with 3.1 and 5.8 wt% Mn concentrations were comparatively investigated. The deformed microstructure revealed that more Mn promoted the formation of austenitic dislocation cells, inhibited the occurrence of dynamic recrystallization (DRX), and resulted in a decrease in the number of refined austenite grains at lower temperatures and strain rates. Meanwhile, more Mn addition promoted ferrite DRX, and delayed austenite DRX initiation deformed at higher strain rates and lower deformation temperatures. The nearly complete refinement of austenite grains formed due to DRX deformation at 950℃/0.01 s−1 with 3.1 % Mn addition, while fine grains caused by ferrite DRX mainly occurred at 850℃/1 s−1 with 5.8 wt% Mn addition. The relationships between the Zener–Hollomon parameter (Z) and critical strain (stress) were established using the power law relation. The stability processing domains with high power efficiency greater than 0.34 narrowed with increasing Mn content, are located in the temperature range of 1000–1150℃ and strain rate range of 0.01–0.03 s−1, and austenite DRX plays a significant role in compression deformation improvement. At a low deformation temperature of 850 ℃, the work hardening rate in the initial strain increased with increasing Mn addition, and a lower strain rate and deformation temperature contributed to the dynamic deformation softening caused by austenite DRX, but ferrite DRX slightly contributed to the improvement of compression deformation. The DRX kinetics models show that the trend of the volume fraction of DRX as a function of processing variables is in good agreement with experimental data.

Continuous-Flow Synthesis of Zn1-xMnxS Nanoparticles at Ambient Conditions.

With its large direct band gap and good chemical stability, ZnS is suitable for many applications, including light-emitting diodes, panel displays, and photodetection. Here, nanoparticles of ZnS are synthesized phase pure under ambient conditions by precipitation in a simple and scalable continuous-flow reactor. Furthermore, different degrees of Zn substitution with Mn have been investigated, Zn1-xMnxS, with x = 0.05, 0.19, and 0.25 according to X-ray fluorescence measurements. The products are analyzed with multitemperature synchrotron powder X-ray diffraction (PXRD) and X-ray total scattering. The analysis reveals phase-pure synthesis products with the sphalerite structure and crystallite sizes in the range of 3.8-4.7 nm in agreement with scanning transmission electron microscopy. Only Zn0.75Mn0.25S shows traces of Mn3O4, indicating that x = 0.25 is above the substitution limit as the impurity appears. Substitution of Zn with Mn in the nanoparticles is confirmed by energy-dispersive X-ray spectroscopy, as well as an observed decrease in the band gap, decrease in the sphalerite-to-wurtzite phase transition temperature, and increase in the unit cell dimensions with increasing Mn content. Based on the modeling of the PXRD Rietveld refined atomic displacement parameters, the Debye temperature for ZnS and Zn0.95Mn0.05S is determined to be 322 ± 13 and 394 ± 22 K, respectively.

Cost‐Effective Layered Oxide – Olivine Blend Cathodes for High‐Rate Pulse Power Lithium‐Ion Batteries

AbstractSustainability and supply‐chain concerns require lithium‐ion batteries (LIBs) free from critical minerals, such as nickel and cobalt. While recent advances provide encouraging signs that cobalt can be removed, the question remains how much Ni can be removed from Co‐free layered oxide cathodes before sacrificing critical performance metrics. This study highlights the effect of reducing Ni by benchmarking several Co‐free cathodes with decreasing Ni content. Keeping the energy density the same by increasing the charge voltage, cathodes below 80% Ni content exhibit worsened capacity fade due to increasing oxygen release and electrolyte decomposition. Charge transfer and diffusion kinetics are also hindered with increasing Mn content and exacerbated by resistive surface phases formed at high voltages, rendering lower‐Ni, Co‐free cathodes less competitive than high‐Ni cathodes for high energy and power applications. It is demonstrated blending layered oxide with olivine as an effective alternative to deliver energy density and cycling stability comparable to lower‐Ni cathodes with moderate charging voltages. Blending with 30 wt% olivine LiMn0.5Fe0.5PO4 (LMFP) virtually eliminates the diffusion limitation of layered oxides at low state‐of‐charge, with enhanced pulse power characteristics rivaling the high‐Ni counterparts. Cathode blending can further reduce the overall Ni content and cost without the performance limitations of lower‐Ni, Co‐free cathodes.

Enhanced magnetic refrigeration capacities of Er6FeSb2 by manganese substitution

Er6FeSb2 is a potential magnetic refrigeration material that can work at the liquid hydrogen temperature range. This work enhances the magnetic refrigeration performance of Er6Fe1-xMnxSb2 by Mn substitution. Mn doping increases the cell volume while maintaining the compound’s crystal structure type. It also results in an increase in the charge density distribution between Er1 and Fe/Mn. As the Mn content increases, the ferromagnetic exchange is enhanced, and the TC continuously increases. The Mn doping induces spin reorientation at low temperature, transforming compounds from traditional magnetocaloric effects to table-like magnetocaloric effects, greatly enlarge the cooling temperature range. When the content of Mn increases from x = 0 to x = 0.3, the δTFWHM increases from 26 K to 62 K, the −(ΔSM)max decreases from 12.1 J/(kg·K) to 5.9 J/(kg·K), and the RCP first increases and then decreases, reaching the maximum value of 435.0 J/kg at x = 0.2. This study opens a new path for the search of magnetic refrigeration material with large cooling temperature range.

Dietary manganese supplementation decreases hepatic lipid deposition by regulating gene expression and enzyme activity involved in lipid metabolism in the liver of broilers.

This study aimed to characterize the effects of different dietary forms of supplemental manganese (Mn) on hepatic lipid deposition, gene expression, and enzyme activity in liver fat metabolism in 42-d-old broiler chickens. In total 420 one-day-old Arbor Acres (AA) broilers (rooster:hen = 1:1) were assigned randomly based on body weight and sex to 1 of 6 treatments (10 replicate cages per treatment and 7 broilers per replicate cage) in a completely randomized design using a 2 (sex) × 3 (diet) factorial arrangement. The 3 diets were basal control diets without Mn supplementation and basal diets supplemented with either Mn sulfate or Mn proteinate. No sex × diet interactions were observed in any of the measured indexes; thus, the effect of diet alone was presented in this study. Dietary Mn supplementation increased Mn content in the plasma and liver, adipose triglyceride lipase (ATGL) activity, and ATGL mRNA and its protein expression in the liver by 5.3% to 24.0% (P < 0.05), but reduced plasma triglyceride (TG), total cholesterol, and low-density lipoprotein (LDL-C) levels, liver TG content, fatty acid synthase (FAS) and malic enzyme (ME) activities, mRNA expression of sterol-regulatory element-binding protein 1 (SREBP1), FAS, stearoyl-coA desaturase (SCD), and ME, as well as the protein expression of SREBP1 and SCD in the liver by 5.5% to 22.8% (P < 0.05). No differences were observed between the 2 Mn sources in all of the determined parameters. Therefore, it was concluded that dietary Mn supplementation, regardless of Mn source, decreased hepatic lipid accumulation in broilers by inhibiting SREBP1 and SCD expression, FAS and ME activities, and enhancing ATGL expression and activity.

Microbial enhanced manganese-autotrophic denitrification in reactor: performance, microbial diversity, potential functions

Autotrophic denitrification technology has gained increasing attention in recent years owing to its effectiveness, economical, and environmentally friendly nature. However, the sluggish reaction rate has emerged as the primary impediment to its widespread application. Herein, a bio-enhanced autotrophic denitrification reactor with modified loofah sponge (LS) immobilized microorganisms was established to achieve efficient denitrification. Under autotrophic conditions, a nitrate removal efficiency of 59.55 % (0.642 mg/L/h) and a manganese removal efficiency of 86.48 % were achieved after bio-enhance, which increased by 20.92 % and 36.34 %. The bioreactor achieved optimal performance with denitrification and manganese removal efficiencies of 99.84 % (1.09 mg/L/h) and 91.88 %. ETSA and 3D-EEM analysis reveled manganese promoting electron transfer and metabolic activity of microorganisms. High-throughput sequencing results revealed as the increase of Mn(II) concentration, Cupriavidus became one of the dominant strains in the reactor. Prediction of metabolic functions results proved the great potential for Mn(II)-autotrophic denitrification of LS bioreactor.

Narrowing Band Gap of Zno Codoping (Al+Mn) as a Photocatalyst Candidate for Degraded Textile Dye Wastewater

Photocatalyst degradation is one method to reduce industrial textile dye pollution in water. In this study, ZnO material has been synthesized by codoping Al and Mn by chemical coprecipitation method to determine the structural properties and optical properties of the material. From this research, it was found that the structure of ZnO after codoping Al and Mn did not change the hexagonal wurtzite phase but changes in other lattice parameters. The addition of Mn and Al codoping is reported to affect the intensity of XRD peaks, especially on the 101 lattice. The higher the scattering peak, the more angular the shift, indicating the magnitude of oxygen vacancies. The reflectance confirms this result that increasing Mn concentration decreases the energy gap to 3.258 eV. From these structural properties and energy gap values, ZnO codoping Al and Mn materials can be included in candidate materials that can be used as photodegradation agents for textile dyes.