Increasing Film Thickness Research Articles

Gender-based risk analysis of vehicle control loss due to localized water puddles: an analytical approach

Adverse weather conditions significantly increase the risk of traffic accidents, yet most studies focus on uniform conditions across all tires. This study investigates the impact of asymmetric drag forces when only one tire encounters a local water puddle, causing potential vehicle control loss. Using analytical methods, we calculate drag forces and their transmission to the steering wheel, accounting for variations in water film thickness, vehicle speed, and driver gender. The results indicate that female drivers face higher risks of control loss, with critical speeds decreasing as water film thickness increases. The study highlights that localized water puddles, especially at low speeds and water depths exceeding 3 cm, pose significant risks. These findings can inform road safety guidelines and vehicle design standards to mitigate accident risks in adverse weather conditions.

Annealing Temperature Effect on the Properties of CoCe Thin Films Prepared by Magnetron Sputtering at Si(100) and Glass Substrates

This study explores cobalt–cerium (Co90Ce10) thin films deposited on silicon (Si) (100) and glass substrates via direct current (DC) magnetron sputtering, with thicknesses from 10 nanometer (nm) to 50 nm. Post-deposition annealing treatments, conducted from 100 °C to 300 °C, resulted in significant changes in surface roughness, surface energy, and magnetic domain size, demonstrating the potential to tune magnetic properties via thermal processing. The films exhibited hydrophilic behavior, with thinner films showing a stronger substrate effect, crucial for surface engineering in device fabrication. Increased film thickness reduced transmittance due to photon signal inhibition and light scattering, important for optimizing optical devices. Furthermore, the reduction in sheet resistance and resistivity with increasing thickness and heat treatment highlights the significance of these parameters in optimizing the electrical properties for practical applications.

Variation of Packing Densities and Liquid Film Thicknesses in Alkali Solution and Water in Natural Pozzolan Calcium Hydroxide Pastes and Mortars

The characteristic properties of concrete depend on the quality of mortar. In order to improve the properties of hardened concrete, the mortar needs to have good performance. The property of mortar is affected by wet packing density, liquid film thickness, type and quality of binder, gradation of fine aggregates, and binder-to-fine-aggregate ratio. The commonly used alkali solutions to produce polymer mortar and concrete are cursed by carbon dioxide emissions. This study used alkali solution and water to investigate the variation of packing densities and film thicknesses on paste and mortar mixes. of natural pozzolan and calcium hydroxide at a ratio of 75P25CH and standard sand. The standard proctor compaction tools and procedures were adopted to attain the maximum values of packing density of 0.937 for mortar mixed with alkali solution, 0.919 for mortar mixed with water, 0.906 for paste mixed with alkali solution, and 0.829 for paste mixed with water. For the case of film thicknesses, the optimum values obtained were 0.548 μm for mortar mixed with alkali solution, 0.248 μm for mortar mixed with water, 0.398 μm for paste mixed with alkali solution, and 0.09 μm mixed with water. The results indicate that alkali solution produced higher packing density and liquid film thickness than water for both paste and mortar, and the packing density and liquid film thickness increase with the increase of the number of compacting blows with 9 blows to 36 blows. The study recommends the establishment of standard compaction effort and procedure.

Ultra-thin Atomic Layer Deposited HfO2: Tailoring Dielectric Thickness for Low-Operating Voltage Thin-Film Transistors

To achieve low-power consumption and high performance in TFTs, it is crucial to reduce the thickness of the dielectric gate layer while maintaining a defect-free structure and high dielectric properties. This study explores the effects of varying HfO2 layer thickness on TFT performance. X-ray photoelectron spectroscopy analysis indicates a decrease in oxygen defects as the film thickness increases. The morphological and topological properties of the films were characterized using grazing incidence small and wide-angle X-ray scattering and atomic force microscopy. Impedance spectroscopy was utilized to analyze the dielectric properties, showing that the 10 nm HfO2 film exhibited a low leakage current density of 13 nA cm−2 at 1 V and a permittivity of 5.98. The fabricated ZnO TFT with a 10 nm HfO2 gate dielectric layer operated at an ultra-low voltage of -1.59 V, achieving a high current on/off ratio exceeding 106. These findings highlight the importance of controlling dielectric layer thickness for the development of high-performance TFTs and their potential for low-power microelectronic applications.

Effect of film thickness on phase structure of epitaxial non-doped hafnium oxide films

HfO2 has been widely used in the electronics industry as a dielectric material with excellent properties. It has attracted much attention since HfO2 was first reported to be ferroelectric in 2011. With the continuous advancement of research, various methods such as oxygen vacancy control and interface control have been proven to be able to stabilize the metastable polar o-phase structure in doped hafnium oxide thin films. However, there are still some shortcomings in the relevant issues concerning non-doped hafnium oxide thin film materials. Here, polycrystalline non-doped HfO2 thin films were grown on SrTiO3 substrates by pulsed laser deposition (PLD). Atomic force microscopy investigation suggests that the surface roughness of HfO2 thin films increases as the film thickness increases. X-ray photoelectron spectroscopy analyses indicate that the HfO2 thin film has a high purity and contain only Hf4+ ions. The band gap of HfO2 was measured by valence EELS and UV–visible spectra. Atomic structures of the HfO2/SrTiO3 heterointerface have been studied by the aberration-corrected transmission electron microscopy and energy-dispersive X-ray spectroscopy. The HfO2/SrTiO3 heterointerface is atomically abrupt and incoherent. Our findings suggest that non-doped HfO2 films with o-phase structure through PLD technology.

Ultra-low Gilbert damping and self-induced inverse spin Hall effect in GdFeCo thin films

Ferrimagnetic materials have garnered significant attention due to their broad range of tunabilities and functionalities in spintronics applications. Among these materials, rare earth-transition metal GdFeCo alloy films have been the subject of intensive investigation due to their spin-dependent transport properties and strong spin–orbit coupling. In this report, we present self-induced spin-to-charge conversion in single-layer GdFeCo films of different thicknesses via an inverse spin Hall effect. A detailed investigation of spin dynamics was carried out using broadband ferromagnetic resonance measurements. The anisotropy constant and the effective g-factor are found to decrease with thickness, and they become nearly constant for thicknesses beyond 25 nm. A remarkably low damping constant of 0.0029 ± 0.0003 is obtained in the 43 nm-thick film, which is the lowest among all previous reports on GdFeCo thin films. Furthermore, we have demonstrated a self-induced inverse spin Hall effect, which has not been reported so far in a single-layer of GdFeCo thin films. Our analysis shows that the inverse spin Hall effect becomes increasingly dominant over the spin rectification effect with increasing film thickness. The in-plane angular-dependent voltage measurement of the 43 nm-thick film reveals a spin pumping voltage of 1.64 μV. The observation of spin-to-charge current conversion could be due to the high spin–orbit coupling element Gd in the film as well as the interface between GeFeCo/Ti and substrate/GdFeCo of the films. Our findings underscore the potential of GdFeCo as a prime ferrimagnetic material for emerging spintronic technologies.

Fabrication of Orientation-Controlled Fluorine-Doped SnO2 Film Grown By Atmospheric Spray Pyrolysis

Wide bandgap oxide semiconductors are attracting attention for applications such as optical devices, liquid crystal displays, and solar cells. In particular, Sn-doped In2O3 (ITO) is the most widely used transparent conductive oxide (TCO) material. Recently, due to the problem of decreasing indium resources, ZnO has been investigated as an alternative TCO material. Similarly, F-doped SnO2 (FTO) has been investigated in gas sensors, photovoltaic solar energy conversion devices, and electrochromic devices. FTO is an n-type semiconductor with a tetragonal structure similar to the rutile structure and a wide energy gap. Although various dopants are possible, films doped with fluorine exhibit high transparency and good conductivity. Many techniques have been used to prepare SnO2 thin films, including radiofrequency magnetron sputtering, chemical vapor deposition, metal-organic chemical vapor deposition, sol-gel methods, and spray pyrolysis. Spray pyrolysis is attractive for thin film growth because plasma damage to the substrate is avoided, high vacuum is not required, and equipment costs are low. However, there are not many papers on the FTO grown by spray pyrolysis. In our previous work [1], FTO films were successfully grown on glass substrates by the spray pyrolysis at 500 °C. The (200) orientation became strong with increasing fluorine concentration. In addition, F-doping caused the resistivity to decrease and the carrier concentration to increase. The lowest resistivity, 1.4 × 10-3 Ω cm, was obtained at a fluorine concentration of 4 mol%. Its carrier concentration and mobility were 6.2 × 1020 cm-3 and 7 cm2 V-1 s-1, respectively. Furthermore, the average optical transmittance in the visible region was nearly constant (at more than 80%) with increasing fluorine concentration. In this study, FTO films with various thicknesses (70 - 1550 nm) were successfully grown on glass substrates by spray pyrolysis method below 500 °C under atmospheric atmosphere. All the peak positions of XRD spectrum of the synthesized FTO film were in good agreement with the peak positions of ICDD. Furthermore, no fluorine related signals were observed in the spectra. The three-dimensional growth was associated with an increase in both grain size and film thickness and a change in orientation from (110) to (101) and (200). The preferred orientation of FTO changed at a film thickness of approximately 600 nm. It was considered to be influenced by the critical film thickness. Additionally, as the film thickness increased, the transmittance in the infrared region decreased. This was due to the absorption of free carriers at the electron plasma frequency within the film. The resistivity showed a tendency to decrease as the film thickness increased. On the other hand, the carrier concentration remained constant, but the mobility increased with increasing film thickness. This meant that the grain boundary scattering due to increasing grain size was dominant. Carrier concentration, surface structure, and film thickness were important factors in solar cells. In this study, the IR absorption increased despite the carrier concentration being constant. This result implied that at a constant high carrier concentration, the absorption was enhanced by increasing the film thickness. [1] M. Oshima and K. Yoshino: J. Electron. Mater. 39 (2010) 819.

Enhanced Surface Mechanical and Tribological Properties of H13 Die Steel with TiAlSiN Coating Deposited by HiPIMS

TiAlSiN is a potential protection coating for die steel to improve the surface hardness, anti-wear performance and suitability. In the present study, TiAlSiN is deposited on H13 die steel by high power impulse magnetron sputtering and the effects of bias voltage, deposition temperature, and film thickness on the performance of coatings are studied. The microstructure, mechanical and tribological properties of coatings are analyzed by energy dispersive spectrometer, X-ray diffraction, nanoindentation, friction and wear tests. The results show that with the changes of sputtering parameters, the content of Ti, Al, Si, and N fluctuates slightly. With the increase of bias voltage, deposition temperature and film thickness, the diffraction peaks of Ti3Al2N2 phase become wider. Higher bias voltage, deposition temperature, and film thickness are beneficial for obtaining coatings with high hardness, and strong wear resistance. By observing the surface morphology of coatings after grinding with Si3N4 balls, it was found that the wear mechanism of coatings contains abrasive wear, fatigue wear, and oxidative wear.

Achieving Ultra-High Heat Flux Transfer in Graphene Films via Tunable Gas Escape Channels.

Graphene films have been applied in the thermal management of electronic devices due to their high thermal conductivity. However, the ever-increasing power and local heat flux density of electronic chips require graphene films with excellent heat flux carrying capacity. Enhancing the heat flux carrying capacity is highly challenging, and the key is to maintain high thermal conductivity while increasing film thickness. Gases released during film assembly and the resulting catastrophic structural destruction should be responsible for the trade-off between film thickness and thermal conductivity. Herein, the evolution of the pore structure is investigated during the assembly of graphene films and propose the construction of gas escape channels for the preparation of thick graphene films. The process involves using humidification treatment and freeze-drying GO films to pre-construct the ordered flat pore structure. The microstructure optimization of graphene films with more order, fewer wrinkles and defects, and larger grain size is achieved. After optimization, graphene films with ultra-high thermal conductivity (1781Wm-1K-1) and a thickness over 100µm are realized. These films exhibit exceptional heat dissipation and cooling capabilities in high heat flux density (≈2000Wcm-2). This finding holds significant potential for guiding the thermal management of high-power devices.

Low thickness effect on the properties of Mn-doped ZnO thin films synthesized by sol-gel spin coating technique

In this study, 7% manganese-doped zinc oxide (MZO) thin films with varying low thicknesses were synthesized using the spin coating method. The structural, optical, and morphological properties of MZO films with different film thickness, were systematically investigated. The crystallite structure, superficial morphology, and optical characteristics were analyzed using X-ray diffraction (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM), and ultraviolet–visible spectroscopy (UV-Vis). Structural analysis confirmed that all films exhibit a hexagonal wurtzite phase with a pronounced peak along the c-axis, and slight variation in low thickness significantly affected the structural parameters. The surface morphology demonstrated good uniformity, characterized by rounded grain shapes in the plane, while surface roughness was found to be increased with increasing film thickness. Optical analysis revealed that as the number of coatings increased, both transmittance and band gap energy decreased, accompanied by a redshift in the absorption edge across all samples. This behavior is attributed to light scattering, as well as an increase in the refractive index and dielectric function with visible light energy, influenced by the number of layers and corresponding crystallite size.

Physicochemical and mechanical properties of cellulose nanofiber-shellac composite edible films

This study examined the physicochemical and mechanical properties of edible composite films made of cellulose nanofiber (CNF) and shellac (Sh). All films were conditioned at 25°C and 53% relative humidity (RH) for at least 48 h before analyses. Increasing the Sh ratio from 0% to 100% resulted in an increase in film thickness from 57.8 μm to 71.1 μm, while opacity decreased significantly from 22.3 mm−1 to 3.7 mm−1. With the increase in the Sh ratio, the moisture content, water solubility, and swelling of the film increased from 9.7% to 35.1%, 4.9% to 100%, and 3.0% to 10.5%, respectively. The CNF film (0% Sh) exhibited a lower water contact angle than the films with 80% and 100% Sh, but it was more water-resistant. As the Sh ratio increased, the tensile strength, yield stress, Young’s modulus, and work of break of the films decreased significantly from 17.9 MPa to 0.3 MPa, 1.00 MPa to 0.38 MPa, 220.7 MPa to 0.9 MPa, and 0.67 MJ/m3 to 0.13 MJ/m3, respectively. Conversely, the elongation at break increased dramatically from 10% to 253%. This study demonstrated that the thickness, opacity, moisture-related properties, and mechanical properties of CNF-Sh composite films could be tailored by varying the biopolymer ratio.

Thickness dependent crystallinity, hydrophilicity, and surface microtexture in CaF2 thin films deposited via thermal evaporation method

This study investigates the deposition and characterization of CaF₂ thin films with thicknesses ranging from 40 to 320 nm, fabricated via thermal evaporation onto glass substrates. X-ray diffractometry (XRD) revealed that increased film thickness leads to enhanced crystallinity, with larger crystallite sizes and reduced lattice strain. Wettability analysis demonstrated a transition from hydrophobic behavior (contact angle ∼70° for 40 nm) to hydrophilic behavior (contact angle ∼52° for 320 nm) as film thickness increased. Surface morphology, examined via atomic force microscopy (AFM), showed a significant reduction in surface roughness in thicker films, with smoother, more coalesced surfaces observed for films over 160 nm. Monofractal analysis further confirmed the evolution of surface microtexture, with thicker films exhibiting higher uniformity and reduced surface complexity. These findings provide critical insights into optimizing CaF₂ thin films for applications in optics, electronics, and surface coatings, where improved crystallinity and surface properties are essential.

Investigating the influence of RF power on the surface morphological and optical properties of sputtered TiO2 thin films

Thin films of titanium dioxide (TiO2), with thicknesses ranging from 105 to 231 nm, were deposited on glass substrates using radio-frequency (RF) magnetron sputtering in an argon atmosphere at four distinct RF power levels: 40, 70, 100, and 130 W, with the deposition time kept constant. The crystalline structure, surface morphology and optical and semiconductor properties of the obtained films were analyzed using X-ray diffraction (XRD), Atomic Force Microscopy (AFM) and UV–visible transmittance spectroscopy. These analyses revealed that the crystallinity of the films improves with increasing RF power, corresponding to an increase in film thickness. Consequently, the samples transition from poorly crystalline or amorphous structure to a monocrystalline rutile phase with a (110) texture. However, at the highest RF power studied, this texture is partially disrupted by the formation of nanocrystals with different orientations. The surface roughness exhibited multifractal characteristics, with complexity systematically decreasing and surface stiffness reducing as RF power increased. Refractive indices and optical band gap energies were determined using the Swanepoel and Tauc plot methods, respectively. The films exhibited a notable increase in the refractive index and a decrease in the optical band gap, from 3.81 eV to 3.52 eV, as the RF power was increased. This underscores the influence of RF power on the optical and semiconductor properties of TiO2 films.

Nonlinear optical parameters and electronic properties of plasma polymerized methyl acrylate thin films

Plasma polymerized methyl acrylate (PPMA) thin films were fabricated on a borosilicate glass substrate at a plasma power of 28 W to study nonlinear optical parameters and electronic properties. X-ray Diffraction analysis confirmed the amorphous nature of the PPMA films, while Attenuated total reflectance Fourier transform infrared spectroscopy indicated monomer fragmentation due to plasma polymerization. Field emission scanning electron microscope images of the films display a water wave-like structure. PPMA films demonstrated thermal stability up to approximately 574 K in both N2 and air environments. The values of direct band gap energies increase from 3.30 to 3.41 eV with increasing film thicknesses, whereas the Urbach energy values show in an opposite manner. The Wemple-DiDomenico model was employed to analyze both the oscillator energies ranging from 5.54 to 6.44 eV and the dispersion energies ranging from 10.56 to 12.89 eV. The static linear refractive index showed typical dispersion behavior, with film thickness conforming to Moss's rule. The nonlinear refractive index and 2nd and 3rd order nonlinear susceptibilities decrease with increasing the studied films. The lattice dielectric constant values exceeded the high-frequency dielectric constant, indicating the presence of lattice vibrations and free carriers. Electronic parameters are fluctuating with increasing film thickness. The observed changes in nonlinear optical parameters and electronic properties highlight the potential of PPMA films for applications in photovoltaic and optoelectronics.

Lubrication mechanism analysis of textures in journal bearings using CFD simulations

Purpose This paper aims to study the lubrication mechanism of textured journal bearings. Design/methodology/approach CFD models for textured journal bearings are established. The effect of texture coverage on the pressure distribution is studied to find the proper texture distribution. To enhance the local load-carrying capacity at textures, the micro-hydrodynamic pressure and microflow at different texture depth ratios are captured. The interaction between the texture-induced microflow and the bearing lubrication film is analyzed from the microflow perspective. Findings The bearing performance is on the one hand enhanced by the micro-hydrodynamic pressure generated by textures. On the other hand, the main bearing land and maximum pressure can be interfered by textures, leading to the reduction of load-carrying capacity. To minimize the interference effect, textures are suggested to distribute downstream of the minimum film thickness location. As the lubrication film thickness increases, the corresponding optimum texture depth ratio rises. The vortices influence the local flow rate through the lubrication film at textures and further affect the micro-hydrodynamic pressure and local load-carrying capacity. The texture depth ratio, at which vortices begin to occur, generates the maximum micro-hydrodynamic pressure. Originality/value The proper texture distribution is introduced, which is capable to generate the micro-hydrodynamic pressure without interfering with the primary load-carrying capacity of the bearing. The microflow effect is found to considerably influence the local load-carrying capacity at textures. The necessity of sub-regional optimization in textured journal bearings is pointed out. This study provides the fundamental reference for the design and optimization of textured journal bearings.

Iron Gall Ink Revisited: Visible Light-Induced, Eosin-Mediated Acceleration of Fe2+ Oxidation in Pattern Nanoarchitectonics of Fe3+-Tannic Acid Films.

Inspired by iron gall ink (IGI), the Fe2+ ion is utilized for the continuous formation of Fe3+-tannic acid (TA) films through its in situ oxidation to the Fe3+ ion. Although several IGI-based strategies have been developed to meet different application requirements, there remains a need for the precise kinetic control for Fe2+ oxidation, along with one-step spatial controllability. This work demonstrates a visible light-induced method for oxidizing Fe2+ to Fe3+ ions, achieving the kinetic control over Fe3+-TA film formation. Photoexcitation of eosin Y leads to significantly accelerated film formation in a continuous manner, as shown by an 11-fold increase in film thickness compared with the air oxidation-based IGI method. Mechanistic studies reveal that the process is O2-dependent, and the kinetics of the film-forming process could be easily tuned by changing the light intensity or eosin Y concentration. Furthermore, the spatiotemporal controllability of the photoreaction allows for the pattern generation of Fe3+-TA complexes, proteins, and cells.

Effect of thin film thickness of ferrofluid on inclined bioconvective flow

This research examines the effect of variable thin film thickness on the bioconvective ferrofluid flow through a rotating sloped surface when a magnetic field (dipole) is present. Similarity transformation is used to standardize the current model's governing equations. By using a finite element method, the normalized nonlinear differential equations are numerically solved. Variable thickness of ferrofluid thin film and bioconvective parameters (bioconvective Lewis number, bioconvective Peclet number, and micro-organism concentration difference) yield the following results: velocity profiles (radial, tangential, and axial), gravity flow (drainage velocity and induced velocity), temperature profile, concentration profile and microorganism profile. In addition, this investigation examines the density of moving microorganisms as well as local heat and mass transport. The temperature, concentration, radial, axial, drainage, induced, and motile microbe velocity are all improved with increasing film thickness. Variable thickness increases local heat transfer whereas increasing Brownian motion and thermophoresis parameters decreases it. This study could be helpful for self-sterilizing applications and biomedical engineering.

Effect of 1,4-Napthaquinone (NQ) and benzophenone (BPH)on the photodegradation and biodegradation of methyl cellulose film

The induced photodegradation of methyl cellulose (MC) films in air was investigated in the absence and presence of aromatic carbonyl compounds(photosenssitizers): 1,4-naphthaquinone (NQ) and benzophenone (BPH) by accelerated weathering tester. The addition of (0.01 wt %) of low molecular weight aromatic carbonyl compounds to cellulose derivatives films(25µm in thickness) enhanced the photodegradation of the polymer films.The photodegradation rate was measured by the increase in carbonyl absorbance. Decreases in solution viscosity and reduction of molecular weight were also observed in the irradiated samples. Changes in the number-average chain scission, the degree of deterioration and in the quantum yield of chain scission values are also observed, and it was concluded that branching or cross-linking has occurred for cellulose derivative with NQ and BPH. Findings from all analytical techniques indicated that the 1,4-naphthaquinone (NQ) photosensitizer enhance the photodegradation of methyl cellulose more than benzophenone (BPH). The effect of the photosensitizer concentration, (ranging from 0.01 to 0.1 %), on the rate of photodegradation was also monitored for MC films. The rates are increased with increasing the photosensitizer concentration. The effect of film thickness is also studied at fixed sensitizer concentration (0.05%), and results show that the rate of cellulose derivative photodegradation decreases with increasing film thickness. The rate constants of the photodegradation of the photosensitizers deduced in cellulose derivatives films, [at concentration of (0.1%)by weight and thickness (25µm)]. Biodegradation of irradiated cellulose derivatives films was conclusively established with bacteria type Pseudomonas aeuroginosa Rb-19 isolated from crude oil. The amount of bacteria growth on MC after 30 days was lower, while there was no growth observed in MC with BPH

Structural, Morphological, and Optoelectronic Properties of RF Sputtered AZO Thin Films on Glass and Polymer Substrates: A Comparative Study

This paper investigates the thickness-dependent structural, morphological, and optoelectronic properties of Al-doped ZnO (AZO) thin films deposited on glass and flexible polyethylene terephthalate (PET) substrates via confocal magnetron sputtering. The film’s thickness ranged from 50 to 130 nm. X-ray diffraction results show that all AZO films on glass have better structural properties than those on PET. Furthermore, the (002) peak intensity and crystallite size on both substrates improved progressively with thickness. Field emission scanning electron microscopy and atomic force microscopy images revealed that the film morphology and surface roughness are dependent on substrate and thickness. According to the UV–vis-NIR measurement results, the air-referenced transmittance spectra of films on PET were slightly lower than those on glass; however, compared to films on glass, the substrate-referenced transmittance of PET films was higher. Moreover, for both substrates, it is found that the bandgap of fabricated thin films decreases with thickness. Photoluminescence spectra show that for glass and PET substrates, the total luminescence of AZO decreases with increasing film thickness and that green and red emissions are absent from AZO films deposited on PET substrates. AZO films deposited on glass substrates exhibit superior electrical and optoelectronic characteristics.

Phase composition of sputter deposited tungsten thin films

Sputter deposited tungsten thin films are studied by X-ray diffraction. Two phases can be identified: α-W and β-W based on the observed (110), and (200) and (210) Bragg reflections, respectively. With increasing film thickness (50 to 200 nm), the phase composition shifts from β-W towards α-W. No influence of the base pressure (3 × 10−3–3 × 10−5 Pa) on the phase composition is observed. Also the influence of the argon pressure (0.3 to 0.7 Pa) is rather weak. The strongest shift towards α-W composed thin films is obtained by increasing the discharge power (50 to 250 W). This trend is further studied by energy flux measurements using a calorimetric probe. These measurements rule out a strong change of the substrate temperature, and an impact of the energy flux scaled by the deposition rate (total energy per deposited atom). Test particle Monte Carlo simulations reveal the importance of the momentum of the reflected argon neutrals on the phase composition. The maximum energy of these species is mainly defined by the discharge voltage, and is higher than the directional dependent displacement energy of W. Despite the significant correlation between phase composition and the number of displacement per deposited atom, there is a strong scatter of the phase composition. As the deposition conditions were varied in random way, changes of the target erosion profile, and the changing discharge voltage over each series are probably partially responsible for the observed scatter. This scatter is also enhanced by the long term changes in the phase composition towards the more thermodynamic stable α-W phase.