Increase Of Mg Content Research Articles

Enhancing the Pitting Corrosion Resistance of Fe‐36Ni Invar Alloy via Introducing Mg

The primary objective of this study is to investigate the corrosion resistance of Fe‐36Ni Invar alloys with varying Mg contents in a 3.5 wt% sodium chloride solution. The electrochemical results reveal that the incorporation of Mg amplified the corrosion behavior of Fe‐36Ni Invar alloy. The inclusion compositions undergo a transformation with the increase of Mg content, evolving from MnO–MnS in 0 Mg alloy to MnO–MnS–MgO in 0.0015 Mg alloy, and ultimately to MnS–MgO–MgS in 0.0030 Mg alloy. During the corrosion process, the small‐sized MnS–MgO–MgS inclusions exhibit greater stability compared to the MnO–MnS inclusions, rendering them less susceptible to attack and dissolution. Adding Mg diminishes the size and number density of inclusions, which effectively decreases the susceptibility to pitting initiation. The introduction of Mg refines the microstructure and elevates the fraction of twin boundaries, which also is responsible for the enhancement of corrosion resistance.

Mudstone diagenesis with depth and thermal maturity in the Cenomanian–Turonian Eagle Ford group. PART II: Diagenetic processes and paragenetic sequence

The Cenomanian–Turonian (C–T) Eagle Ford Group (EFG) is composed of massive, laminated, and/or burrowed limestones, marls, and lime mudstones deposited on the drowned south Texas shelf below storm-wave base. A burial diagenesis investigation using seven cored wells from shallow to deep burial (depth ranges from 7684 to 13,670 ft [2342 to 4166.6 m]; BHT from 183 to 285 °F [83.9–140.6 °C]) and from east (San Marcos Arch) to west (Maverick Basin) delineated a complex diagenetic history as a result of changes in water chemistry, redox condition, and burial history. The second part of this comprehensive study shows the variety of diagenesis and paragenesis. This study focuses especially in the organic-rich Lower Eagle Ford (LEF) member deposited largely under anoxic/euxinic conditions. Processes such as near seafloor sulfate-reduction, Fe-reduction, and methanogenesis drive various chemical reactions during lithification. Feldspar diagenesis included albitization and transformation of K-feldspar to kaolinite and albite, and from kaolinite to Mg-chlorite with depth. Clay mineral diagenesis is complex with authigenic kaolinite, mixed kaolinite/Mg-chlorite, and Mg-chlorite form in biota tests and matrix. Additionally, calcite dissolution, burial dolomitization, late Fe-chlorite replacement, and oxidation of pyrite to marcasite are also observed. Detritus-derived smectite starts to transform to mixed layered clay, illite-smectite (I/S) in the oil window; however, illitization trends were not observed in depth. This is because most smectite forms from alteration of volcanic ashes and the volcanic origin of the disorientated smectite did not follow regular illitization kinetics. The increase in Mg content from illitization transforms not only the kaolinite to chlorite, but precipitates authigenic dolomites. The clay minerals precipitated in the original interparticle pores, further reducing porosity, and impacted permeability, fluid saturation, wettability, and capillary pressure. With thermal maturation, bitumen and oil conversion increases oil-wetness of the rock and the resistivity measurement from wireline logs.

Effect of Mg modification on the catalytic performance of zinc malachite for methanol synthesis

The complex conditions of methanol production from coke-oven gas have brought challenges to the copper-based methanol synthesis catalyst. In this work, a series of zinc-malachite samples with different Mg contents were prepared. The zinc-malachite and calcined samples were characterized by in-situ X-ray diffraction (XRD), thermogravimetry-mass spectrometry (TG-MS), N2 physical adsorption, H2 programmed temperature reduction (H2-TPR), CO2 programmed temperature desorption (CO2-TPD) and other methods. The effects of Mg addition on the structure of zinc-malachite and its catalytic performance of methanol synthesis were investigated. The results showed that the addition of Mg increased the degree of Cu substitution inside the zinc-malachite structure and promoted the formation of high temperature carbonates in the catalyst after roasting. With the increase of Mg content, the specific surface area of the calcined catalyst increased gradually, and the Cu grain size decreased simultaneously. In-situ XRD results showed that a small amount of Mg could effectively inhibit the growth of copper grain size during the heat treatment. The evaluation showed that the initial activity of the catalyst increased first and then decreased with Mg addition, and the activity of the Mg-doped catalyst remained at a relatively high level after heat treatment. The appropriate Mg addition is beneficial to the initial activity and thermal stability of Cu-based methanol synthesis catalyst.

Corrosion behavior, antibacterial properties and in vitro and in vivo biocompatibility of biodegradable Zn-5Cu-xMg alloy for bone-implant applications

Reasonable optimization of degradation rate, antibacterial performance and biocompatibility is crucial for the development of biodegradable zinc alloy medical implant devices with antibacterial properties. In this study, various amounts of Mg elements were incorporated into Zn5Cu alloy to modulate the degradation rate, antibacterial properties and biocompatibility. The effects of Mg contents on the microstructure, corrosion behavior, antibacterial properties and biocompatibility of Zn-5Cu-xMg alloy were extensively investigated. The results revealed that with an increase of Mg content, the amount of Mg2Zn11 phase increased and its galvanic effect with the Zn matrix was enhanced, which accelerated the corrosion process and led to higher corrosion rate and high degradation rate of the alloy. Additionally, there was an increased release of Mg2+ and Zn2+ ions from the alloy which imparted excellent resistance against Escherichia coli and Staphylococcus aureus bacteria and improved biocompatibility, subcutaneous antibacterial and immune microenvironment regulation properties. Zn-5Cu-2 Mg exhibited superior antibacterial ability, cell compatibility, proliferation effect, subcutaneous antibacterial and immune microenvironment regulation performances, which can work as a promising candidate of biodegradable antibacterial medical implants.

Electrical Conduction Mechanism of Mg-Doped ZrO2 Thin Films.

Amorphous ZrO2 thin films with increasing Mg content were deposited on quartz substrates, by dip coating method. The films are transparent in the visible domain and absorbent in UV, with an optical band gap that decreases with the increase of Mg content, from 5.42 eV to 4.12 eV. The temperature dependent conductivity measurements showed typical semiconductor comportment. The decrease of the electrical conductivity by Mg doping was related to the increase of the OH groups (37% to 63%) as seen from X-ray Photoelectron Spectroscopy. It was found out that the electrical conductivity obeys the Meyer-Neldel rule. This rule, previously reported for different disordered material systems is obtained for ZrO2 for the first time in the literature. Exploring novel aspects of Mg-doped ZrO2, the present study underscores the origin of the Meyer-Neldel rule explained by the small-polaron hopping model in the non-adiabatic hopping regime. Determination of the presence of such a conduction mechanism in the samples hold promise for comprehending the important aspects, which might be a concern in developing various devices based on Mg-doped ZrO2.

Significantly enhanced reliability in defect-engineered BaTi1-xMgxO3 ceramics

BaTiO3-based ceramic is considered to be a fascinating dielectric material with high reliability for ultra-thin multilayer ceramic capacitors (MLCC). Here, we fabricated a series of acceptor-doped BaTiO3 (Mg: 0.2, 0.5, 1.0, 1.5, 2.0, and 5.0 mol%) ceramics with Al2O3 and SiO2 as sintering additives. With an increase in Mg concentration, the insulation resistance of the BaTi1-xMgxO3 ceramics initially increases and then decreases, in which the 0.5 mol% Mg-doped ceramic achieves superior degradation behavior. The reason is that with the incorporation of the acceptor ion Mg2+, the charge compensation mechanism in the system changes. Initially, barium vacancy is generated, which is gradually dominated by oxygen vacancy. Analysis indicates that the segregation of the acceptor state barium vacancy to the grain boundary increases the schottky barrier of the grain boundary, while the gradual increase of the donor state oxygen vacancy reduces the reliability of the ceramic. This study provides a comprehensive overview illustrating the significant role of point defects in the potential barrier of the grain boundary in acceptor-doped BaTiO3 ceramics. It identifies a pathway to achieve high reliability in BaTiO3-based MLCC.

Exploring the impact of non-magnetic ion Mg2+ into M- type Ba0.5Ca0.5Fe12-xO19 (x = 0.0, 0.1 and 0.2) hexaferrites on structural, magnetic and magnetocaloric effect properties

The Mg substituted Ba-Ca Hexaferrites Ba0.5Ca0.5Fe12-xMgxO19 (BCFMO) (x = 0.0, 0.1 and 0.2) were prepared through the conventional ceramic technology. The microstructure, morphology, magnetic and magnetocaloric Effect (MCE) of all samples were investigated by XRD, SEM, EDX and BS1 and BS2 magnetometer. XRD analysis revealed the formation of Magnetoplumbite structure with P63/mmc space group and minor secondary phase R-3 m and having crystallites in the range of 121–108 nm. The XRD refinement indicates a preference for Mg2+ ions to occupy the octahedral 12k site. SEM analysis showed the presence of the hexagonal shape for all products. The saturation magnetization Ms decreases from 69.77 to 65.55 emu/g and the coercive field Hc increases from 1.29 to 3.54 kOe with the increase in Mg concentration. The increase of Hc with increasing Mg concentration is attributed to the reduction in crystallite sizes. Additionally, the magnetocrystalline anisotropy parameters (obtained by the "Law of Approach to Saturation method") such as the anisotropy field (Ha) and the effective magnetic anisotropy constant (Keff) were found to be 16.59–24.18 kOe and 5.15–6.94 105 emu/cm for x = 0.0–0.2, respectively.The MFC-MZFC curves for all compounds show a paramagnetic (PM) to ferromagnetic (FM) phase transition at the Curie Temperature TC. Doping with Mg2+ in BCFO lowers the Curie temperature TC down to T ∼700 K. The maximum entropy (-ΔSmmax) (x = 0.1) and the corresponding RCPmax (x = 0.2) at 5 T are found to be 1.80 J.kg-1.K-1 and 114.29 J.kg-1 respectively. The above results demontrate that the samples have great potential for permanent magnets and guide for the Magnetocaloric Effect (MCE) applications.

Investigating mechanism of photo refractivity in Mg substituted ZnO thin films using pump and probe technique

In the current investigation magnesium (Mg) has been incorporated in the ZnO matrix to induce photo refractivity thereby adding an extra dimension to its already present multi-functionality. Undoped and MgxZn1-xO (x = 0.25, 0.30, 0.35, 0.40, 0.45) thin films have been grown using Chemical Solution Deposition (CSD) technique. Obtained X-Ray Diffraction (XRD) spectra exhibits a slight shift in the peak value along (002) plane whereas UV–visible spectra indicates corresponding widening of ZnO band gap values (3.24–3.64 eV) with increase in Mg content. Mg substituted ZnO films were then investigated for their ferroelectric properties using a P-E hysteresis loop tracer. It was noted that ZnO film with 35 % Mg content (x = 0.35) exhibited the high values for saturation (Ps = 1.8 μC/cm2) and remnant (Pr = 0.7 μC/cm2) polarization. Hence the ZnO with same Mg concentration was investigated for nonlinear optical properties (two wave mixing phenomenon) using pump and probe technique. In order to enhance the beam amplification gain and impart stability Au micro-dots were thermally evaporated onto MgxZn1-xO (x = 0.35) films. The maximum beam amplification gain was noted to shoot up to 2.7 post patterning of MgxZn1-xO (x = 0.35) film surface by Au micro-dots.

Properties of hydroxyapatite with various substitutions: specific effects of Mg/Ca substitution in different Ca1 and Ca2 positions

Hydroxyapatite (HAP) structures with cationic substitutions are studied. Paper presents results obtained using DFT calculations for Mg/Ca substitutions in HAP depending on Mg concentration. Data obtained showed agreement with the experiment: the lattice parameters decreased with increase in Mg concentration. A symmetry violation was found upon the Mg/Ca substitution in the Ca2 position compared to the Ca1 position, due to OH distortion and the Mg-O pair shift relative to OH channel axis. The change in piezoelectric coefficients upon these Mg/Ca2 substitutions was higher by a factor of 1.5 than those of Mg/Ca1. The corresponding changes was in the IR spectrum.

Mg doping effect on the properties of SnO2 thin films synthesized by dip-coating method

Undoped and Mg doped SnO2 thin films were deposited on glass substrates using dip-coating method for the first time. X-ray diffraction analysis of the films revealed a tetragonal rutile phase. A decrease in crystallite size is observed as the Mg doping increases. The transmittance spectrum exhibits a decrease in transmittance from 87% to 62% as the Mg content is increased. The optical band gap narrows from 3.97 eV to 3.93 eV with the increasing of Mg content. MEB showed an increase of grain sizes with increase in Mg concentration. The RMS roughness increases with Mg doping content. FTIR showd O–Sn–O, Sn–OH, Mg–O, and OH–Mg–OH vibration modes. PL spectra indicated that the incorporation of more Mg2+ into the lattice of SnO2 creates additional oxygen vacancies, leading to an increase in the PL emission intensity in the films. A transition from n-type to p-type conduction was observed at 9 wt% Mg doping.

Portevin-Le Chatelier characterization of annealed Al-Mg alloy sheets with different Mg contents

The stress-strain flow curves of solid solution treated and annealed Al-(2.86-9.41)Mg aluminum alloy sheets were investigated during tensile process at room temperature at a strain rate of 1 × 10−3 s−1, in order to reveal the effect of solute Mg atoms and β-phase nanoparticles in the α-Al matrix on their Portevin-Le Chatelier (PLC) characteristics. The results show that with the increase of Mg contents of alloys, the concentration of solute Mg atoms and the volume fraction of β-phase nanoparticles in the α-Al matrix of the annealed alloy sheets increase. The β-phase nanoparticles promote the PLC effect during the tensile process, causing the increase of stress drop amplitude Δσ of the tensile curves of the alloy sheets. However, the β-phase nanoparticles have little influence on the strain period ΔεTmax of rectangular waves. The flow strain difference Δεc−σ between the yield point and the beginning of PLC effect decreases monotonically from 5.4 × 10−4 to 5 × 10−5 as the Mg contents of alloy sheets increase from 2.86 wt.% to 9.41 wt.%. The strain period ΔεTmax of the rectangular waves corresponding to the high flow stress and stress drop amplitude Δσ obtained for the serrated stress-strain curves of the alloy sheets gradually increase with the increasing Mg contents of alloy sheets.

First principle and experimental investigations on Mg-doped ZrO2 thin films for electronic, thermoelectric, and optical application

To study the Mg-doped ZrO2, the electronic, thermoelectric, and optical properties were characterized by first principle as well as experimental techniques. For experimental observations, the samples for pure ZrO2 and Mg-doped ZrO2 thin films were prepared. A noticeable difference was observed between the results of electronic, thermoelectric, and optical properties of pure and Mg-doped ZrO2 thin films. The electronic properties extracted from simulations show that Mg-doped ZrO2, Mg-s, Zr-d, and O-p states provide the main contributions. The electrical conductivity and Seebeck coefficient present an increasing trend with doping of Mg content. The absorption coefficient trend shows that the material becomes more absorbing with the increase in Mg content. The refractive index reduces from ∼2.2 to ∼1.8. The content of Mg carries corroborates the substantial variation in optical parameters with varying energy ranges. The comparison is carried out between the results of optical properties deduced through simulations and spectroscopic ellipsometry.

Experimental investigation and kinetic analysis of Al–Zn–Mg alloy coating

The hot-dip 55 wt%Al–Zn-1.6 wt%Si-(0–3)wt.%Mg alloy coatings were experimentally investigated, and the solidification behaviors and hot cracking susceptibility were simulated by means of CALPHAD (CALculation of PHAse Diagrams) method. The scanning electron microscopy (SEM), electron probe micro-analyzer (EPMA) and glow discharge spectrometer method (GDS) were utilized to determine the microstructures and the distribution of elements of the Al–Zn–Mg alloy coatings with different Mg contents. It is discovered that with the increase of Mg content, the percentage of the eutectic microstructure scales up, and the surface quality of the alloy coating is improved. Meanwhile, the bending properties of Al–Zn–Mg coatings with different Mg contents still requires further improvement according to the present bending test. Subsequently, the equilibrium solidification processes of the coatings were calculated using thermodynamic approach. In general, the calculated results reflect the solidified phases and the precipitated temperatures according to theory of equilibrium solidification. However, there still exist discrepancies between the thermodynamic calculation results and the observed experimental results during the practical galvanizing process, because the cooling rates were not taken fully into consideration. Consequently, the kinetic analysis was carried out to obtain the secondary dendrite arm spacing under different cooling rates. The cracking susceptibility index (CSI) was also calculated to predict the hot workability of the Al–Zn–Mg alloy coating. In summary, the appropriate increase of the cooling rate turns out be the effective approach to benefit the microstructure and the corrosion resistance of the Al–Zn–Mg coatings in the practical galvanizing process, and the coating is not suitable for the hot stamping process.

Evaluation of photobiomodulation therapy (PBMT) on salivary flow and composition in head and neck cancer patients undergoing radiation therapy

Assess the impact of photobiomodulation therapy (PBMT) on xerostomia, salivary flow rate (SFR) and composition in patients undergoing radiotherapy (RT) for head and neck cancer (HNC). Thirty patients undergoing RT (65 Gy) for HNC were enrolled. Saliva and xerostomia evaluations collected pre- and post-PBMT-RT. PBMT involved irradiation of extra and intraoral points, 15-20 sessions, 2-3 times/week. SFR, trace elements, total protein, alkaline phosphatase, xerostomia, and pH were analyzed. The average age was 60.7 years. After treatment, there was not a significant reduction in SFR and there was no difference on xerostomia. Significant reductions in Al, Cd, Fe, Ni, P, and Sb concentrations were observed, along with a significant increase in Mg concentration. Sample data were organized into 3 groups based on a self-organizing map. Low concentrations of Al, As, Co, Cr, Cu, Fe, Mn, Mo, S, Sr, and Zn were the primary discriminatory factors for group A, while group B consisted of post-PBMT-RT samples with high concentrations of Ca, K, Mg, Na, and S. PBMT prevented a significant reduction in SFR and xerostomia induced by radiation therapy. These findings suggest that PBMT prevents salivary gland damage minimizing the decline in salivary flow.

Poly(l-lactic acid)-based double-layer composite scaffold for bone tissue repair.

Bone defect is a serious threat to human health. Osteopractic total flavone (OTF) extracted from Rhizoma Drynariae has the effects of promoting bone formation. Panax notoginseng saponin (PNS) has the function of activating blood circulation and removing blood stasis. Therefore, combining OTF and PNS with poly(l-lactic acid) (PLLA) to prepare scaffolds containing PNS in the outer layer and OTF in the inner layer is a feasible solution to rapidly remove blood stasis and continue to promote bone formation. In addition, degradation rate of the scaffold can affect the release time of two drugs. Adding Mg particles in outer layer can control the degradation rate of the scaffold and the drug release. Therefore, a double-layer drug-loaded PLLA scaffold containing OTF in the inner layer, PNS and Mg particles in the outer layer was prepared and characterized to verify its feasibility. The experimental results showed that the scaffold can realize the rapid release of PNS and the continuous release of OTF. With the increase of Mg content, the drug release rate became faster. Animal experiments showed that the scaffold containing 5% Mg particles could effectively promote the formation of new bone in the bone defect of male New Zealand white rabbits, and the area and density of new bone formed were much better than those in the control group. These results demonstrated that the double-layer drug-loaded scaffold had good ability to promote bone repair.

Nickel nanoparticles supported on magnesium silicate MWW molecular sieve as an efficient catalyst for dry reforming of methane

Magnesium silicate delaminated MWW layers (Mg-DMLs) with two-dimensional (2D) crystal morphology were synthesized by a single-step hydrothermal conversion of borosilicate MWW precursor using magnesium nitrate aqueous solution. As hydrothermal temperature increased from 100 to 180 °C, the crystal structures of Mg-DMLs were changed from crystalline three-dimensional (3D) tectosilicate to amorphous 2D phyllosilicate via delaminated MWW structure. Meanwhile, the substitution of framework B by Mg occurred resulting in the continuous increase of Mg content and basicity of Mg-DMLs as a function of hydrothermal temperature. The X-ray photoelectron spectroscopy study differentiated the framework Mg species on Mg-DML-x (x = 100–160 °C) and MgO on Mg-DML-180. Owing to the strong metal-support interaction originated from framework Mg species, the highest dispersion of Ni species was obtained on Ni/Mg-DML-160, resulting in the outstanding catalytic activity and stability. The present study suggests that the synergic effect of appropriate framework Mg species with Lewis basicity and the structural 2D MWW character can result in a promising catalyst for dry reforming of methane.

Features of hole transport and density of localized states in CuCr1-xMgxO2 and CuCr1–yMgyO2/(MgCr2O4)x–y polycrystalline ceramics

Magnesium doped polycrystalline ceramic samples of cooper chromite (I) with 0.6-4.0 at % Mg content have been synthesized. Phase composition of ceramics has been investigated by X-ray diffraction. Temperature dependencies of electrical resistivity and Seebeck coefficient have been measured by four probe method and analyzed in frame of variable range hopping conductivity. The density of localized electronic states and characteristic energy of its variation near Fermi energy have been estimated. It was obtained that the density of localized states at Fermi energy increases with an increase of Mg content, while characteristic energy of variation of localized state density near Fermi energy decreases. Obtained results show that relatively large values of Seebeck coefficient in Mg doped copper chromite (I) can be understood within variable range hopping transport of holes with rapidly increasing density toward valence band maximum.

Effect of Composition Adjustment on the Thermoelectric Properties of Mg3Bi2-Based Thermoelectric Materials.

Thermoelectric materials are widely used in refrigeration chips, thermal power generation, catalysis and other fields. Mg3Bi2-based thermoelectric material is one of the most promising thermoelectric materials. Herein, the Mg3Bi2-based samples were prepared by high temperature synthesis, and the influence of Mg/Sb content on the electrical transport properties and semi-conductivity/semi-metallicity of the materials has been studied. The results indicate that the efficiency of introducing electrons from excess Mg prepared by high temperature synthesis is lower than that introduced by ball milling, due to the high vapor pressure of Mg. The doping of Sb/Te at the Bi site would make it easier for the material to change from p-type conduction to n-type conduction. With the increase in Mg content, the semi-conductivity of the material becomes weaker, the semi-metallicity becomes stronger, and the corresponding conductivity increases. With the increase in Sb content, the samples exhibit the opposite changes. The highest power factor of ~1.98 mWm-1K-2 is obtained from the Mg3.55Bi1.27Sb0.7Te0.03 sample.

Study on the effect of magnesium on leaf metabolites, growth and quality of tea tree.

Magnesium (Mg) is one of the essential elements for the growth of tea trees. In this study, we investigated changes in metabolites, photosynthetic fluorescence parameters and quality indexes of tea leaves under different concentrations of magnesium treatment, and the results showed that there were no significant differences in the quantity and total content of metabolites in tea leaves under different Mg concentrations. The results of volcano map analysis showed that the content of 235 metabolites in tea leaves showed an increasing trend and the content of 243 metabolites showed a decreasing trend with the increase of Mg concentration. The results of the combined analysis of the OPLS-DA model and bubble map showed that 45 characteristic metabolites were screened at different concentrations of Mg. Among these, the content of 24 characteristic metabolites showed an increasing trend and 21 characteristic metabolites showed a decreasing trend with the increase of Mg concentrations. The results of KEEG pathway enrichment showed that 24 characteristic metabolites with a upward trend were significantly enriched in saccharides metabolism, nucleic acid metabolism and vitamin metabolism, while the 21 characteristic metabolites with a downward trend were enriched in the synthesis of plant secondary metabolites, phenylpropanoid biosynthesis, biosynthesis of terpenoids, synthesis and metabolism of alkaloids, and synthesis and metabolism of amino acids. It can be inferred that Mg regulation was beneficial to enhance the photosynthetic capacity of tea trees, improve the accumulation and metabolism of carbohydrate substances in tea trees, and thus promoted the growth of tea trees, but was not conducive to the synthesis of secondary metabolites and amino acids related to tea quality. The results of photosynthetic fluorescence parameters and quality indexes of the tea tree confirmed the conclusion predicted by metabolomics. This study provided a reference for regulating of the growth and quality of tea trees with Mg fertilizer in tea plantations.

Structural, dielectric, electric and magnetic properties of magnesium substituted lithium nanoferrites

Magnesium substituted Li-ferrites nanoparticles with chemical composition Li0.5-0.5xMgxFe2.5-0.5xO4 (x = 0.0, 0.2, 0.4, 0.6, 0.8, and 1) synthesized by sol-gel auto combustion method. Synthesized materials were sintered at 600 °C for 4 h in the air and heated samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive x-ray spectroscopy (EDS) techniques. Rietveld refinement of XRD patterns confirmed the formation of the spinel structure where the lattice constant varied with the increase of Mg content. The crystallite size of magnesium-substituted lithium ferrites was calculated using Scherrer's equation and showed slight changes while the W-H plot shows more changes. The electrical conductivity and activation energy of Mg-substituted lithium ferrite were strongly affected by Mg content and by which they appear to confirm to semiconductor nature. The paramagnetic transition to ferrite was confirmed by the change in the Arrhenius plot, which showed a large variation between two regions that differ in the values of the activation energy, where the values of activation energies in the ferrite region were greater than those that appeared in the para region, as well as the variation between the activation energy values in the non-substituted lithium ferrite. The dielectric parameters such as the real part of the dielectric constant and loss tangent of the samples were analyzed in the range of 50 Hz to 5 MHz at room temperature, 100, 300, and 500 °C. Curie's temperature showed a decrease with the increase in Mg content. Hysteresis loops were measured using a vibrating sample magnetometer (VSM) where both the temperature and the applied magnetic field were changed. The FC result of Li0.5-0.5xMgxFe2.5-0.5xO4 (x = 0.2, 0.4, and 0.6) is almost flat below TB which demonstrates that the Li–Mg nano ferrites show a super-spin glass behaviour.