The PM2.5-bound visibility improvement remains challenging in China despite vigorous control on anthropogenic emissions in recent years. One critical issue could exist in the distinct physicochemical properties especially of secondary aerosol components. Taken the COVID-19 lockdown as an extreme case, we focus on the relationship between visibility, emission cuts, and secondary formation of inorganics with changing optical and hygroscopic behaviors in Chongqing, a representative city characterized with humid weather and poor diffusion conditions in Sichuan Basin, southwest of China.It is found that the increased secondary aerosol abundance (e.g., PM2.5/CO and PM2.5/PM10 as a proxy) with enhanced atmospheric oxidative capacity (e.g., O3/Ox, Ox = O3 + NO2), combined with insignificant meteorological dilution effect, might partly offset the benefit on the improved visibility from substantial reduction in anthropogenic emissions during the COVID-19 lockdown. This is in line with the efficient oxidation rates of sulfur and nitrogen (i.e., SOR, NOR), increasing more significantly with PM2.5 and relative humidity (RH) in comparison to O3/Ox. The resulted larger fraction of nitrate and sulfate (i.e., fSNA) would promote the optical enhancement (i.e., f(RH)) and mass extinction efficiency (MEE) of PM2.5, especially under highly humid conditions (e.g., RH > 80 %, with approximately half of the occurrence frequency). This could further facilitate secondary aerosol formation via aqueous-phase reaction and heterogeneous oxidation, likely due to enhanced water uptake and enlarged size/surface area upon hydration. In combination of gradually increased atmospheric oxidative capacity, this positive feedback would in turn inhibit the visibility improvement particularly at high RH environment.Considering the current air pollution complex status over China, further work on the formation mechanisms of major secondary species (e.g., sulfate, nitrate, and secondary organics), size-resolved chemical and hygroscopic properties, together with their interactions are highly recommended. Our results are hoping to assist in the atmospheric pollution complex mitigation and prevention in China.