For the issue of jet impingement on the wall in industrial cooling processes, an experimental setup based on high-speed photography for oblique jet impingement onto the wall was constructed. The experimental focus was on the study of liquid droplet splashing behavior after oblique jet impingement on the wall, discussing the liquid droplet splashing behavior under three jet impingement modes: Rayleigh regime, first wind-induced regime, and secondary wind-induced regime. By employing methods such as trajectory imaging and particle image velocity for liquid droplet parameter image measurement, obtaining the particle size, velocity, and distribution of splashed droplets after oblique jet impact on walls under different working conditions. The impact of jet impingement velocity and angle on droplet splashing parameters was analyzed. The results showed that when the impingement point is before the breakup length, with increasing flow velocity, the surface wave of the liquid column, and the spreading liquid film became more pronounced, but the loss of liquid-phase components due to splashing was relatively small. When the impingement point is after the breakup length, the secondary breakup resulting in a “crown”-shaped liquid film after droplet impingement leads to a significant loss of liquid-phase components through splashing. As the inlet velocity of the jet increases, there is a decreasing trend in droplet size and an increasing trend in droplet velocity. With an increase in jet angle, there is a decreasing trend in droplet size and velocity. Based on the concentration, size, and velocity distribution characteristics of splashing droplets, the area after oblique jet impingement on the wall can be divided into the impingement zone, low-concentration low-velocity zone, high-concentration high-velocity zone, and lateral splashing zone. This has significant implications for understanding the splashing mechanism after oblique jet impingement on the wall and optimizing operating conditions.