Impact Melt Glass Research Articles

Linking impact melt redox with crustal weathering regime

Impact melting and outgassing of impact melts were important processes shaping the crust and atmosphere of early Earth and Mars. The redox state of impact melts influences the gases they release, but the controls on impact melt redox are not well understood. Here, we present Fe micro−X-ray absorption near edge structure (μ-XANES) measurements of a suite of impact melt glasses from Lonar crater, India. As an impact into continental flood basalts, Lonar crater is an ideal analog for impacts into basaltic crust on early Earth and Mars. The Fe-μ-XANES technique permits robust characterization of the Fe3+/ΣFe ratio and therefore redox conditions in Lonar glasses. We found a range in Fe3+/ΣFe of 0.21−0.49 among Lonar glasses, including substantial intraclast variations. We conclude that a primary factor driving these variations was pre-impact oxidative weathering of target rocks. The coupling between crustal weathering regime and speciation of gases released from impact melts implies that impact melt outgassing could act as a feedback mechanism to reinforce prevailing surface redox conditions.

Isotopic and trace element data of Tissint indicate a homogeneous strewn field, mobilization of Sr, REE, and Pb during shock metamorphism, and limits on the incorporation of martian surficial materials in impact melt glass

The Tissint strewn field has produced over 16 kg of material that has minimal terrestrial weathering and/or contamination. Tissint, along with 16 other incompatible trace element (ITE)-depleted shergottite specimens with igneous crystallization ages spanning 327–2403 Ma, were ejected together from Mars 1.1 m.y. ago. Despite the geochemical similarities of fragments from the Tissint strewn field, there are reported discrepancies in age determinations from different fragments that raise the possibility that the strewn field may be heterogenous. There are also questions about whether the shock ejection event incorporated martian soil components into impact glass, and the sources of radiogenic Sr and Pb that have been measured from leachate fractions in previous studies. An impact melt-rich fragment of Tissint was analyzed by LA-ICPMS for rare-earth element (REE) and highly siderophile element (HSE) concentrations and Pb isotopic compositions. Leachate and residues from 8 specimens representing separate individual fragments collected from the strewn field were analyzed for Rb-Sr. Unleached fractions of the 8 specimens were also analyzed for Sm-Nd and Lu-Hf.The measured REE and HSE concentrations of impact melt glass and associated sulfide measured by LA-ICPMS are consistent with bulk rock compositions of Tissint and show no evidence for incorporation of more ITE-enriched martian surface components. Measured Pb isotopic compositions confirm that the impact melt glass and associated sulfide contain no evidence for incorporation of more radiogenic materials than the Pb compositions inherited from the primary magma. In situ Pb isotopic data from sulfide likely represents the most robust method for constraining initial Pb isotopic compositions of shergottites whereas approaches that rely on leaching and digestion may not remove all mineral and/or crack surface contaminants.Rubidium-strontium analyses of the 8 Tissint specimens indicate that labile components hosting HCl-soluble Rb and Sr are not in isotopic equilibrium with the igneous assemblage and that the washed residues are in isotopic equilibrium with the igneous assemblage. The Sr isotopic compositions of the leachate are within the range of ‘more ITE-enriched’ depleted shergottites, perhaps indicating sources from the igneous pile on Mars. The radiogenic Sr component could represent crack and mineral surface coatings of volatilized materials derived from nearby depleted shergottite rock units during the impact ejection process but are not radiogenic enough to represent ITE-enriched crust or mantle components.The Lu-Hf isotopic data from the specimens indicate no evidence of contamination or element mobility, whereas the Rb-Sr and Sm-Nd isotopic systems show evidence for element mobility and potential mixing with an isotopic component not in equilibrium with the igneous phases. The calculated ages using data compiled from Brennecka et al. (2014), and Grosshans (2013) for Lu-Hf, Rb-Sr, and Sm-Nd are 571 ± 84 Ma, 590 ± 49 Ma and 559 ± 39 Ma, respectively. These data indicate that the specimens analyzed here are cogenetic and the Tissint strewn field appears to be homogeneous.

NMR Spectral Characteristics of Ultrahigh Pressure High Temperature Impact Glasses of the Giant Kara Crater (Pay-Khoy, Russia)

In this study, we carried out the analysis of the impact melt vein glasses from the Kara impact crater (Russia) in comparison to low-pressure impact melt glasses (tektites) of the Zhamanshin crater (Kazakhstan). 27Al, 23Na, and 29Si MAS NMR spectra of the samples of these glasses were analyzed. The samples of the natural glass contained inclusions of crystalline phases, paramagnetic elements that greatly complicate and distort the NMR signals from the glass phase itself. Taking into account the Mossbauer distribution of Fe in these glasses, the analysis of the spectra of MAS NMR of glass network-former (Si, Al) and potential network-modifiers (Na) of nuclei leads to the conclusion that the Kara impact melt vein glasses are characterized by complete polymerization of (Si,Al)O4 tetrahedral structural units. The NMR features of the glasses are consistent with the vein hypothesis of their formation under conditions of high pressures and temperatures resulting in their fluidity, relatively slow solidification with partial melt differentiation, polymerization, and precipitation of mineral phases as the impact melt cools. The 70 Ma stability of the Kara impact vein glass can be explained by the stabilization of the glass network with primary fine-dispersed pyroxene and coesite precipitates and by the high polymerization level of the impact glass.

Preliminary Petrological and Geochemical Studies of Dolerite Dikes at the Kara Astrobleme Central Uplift, Comparison with UHPHT Impact Melt Glasses (Pay-Khoy, Russia)

Recent find of the ultra-high pressure high-temperature (UHPHT) impact melt glasses among the impactites of the Kara astrobleme has a high interest in nicely preserved 70 Ma glass with potentially unusual structure and properties. By the moment, it is important to understand about the substance source for the UHPHT glasses. The Kara target is characterized with complicated rock material preferably presented with Paleozoic sedimentary units. At the same time, the target has in a sequence Devonian sills and dikes of gabbro-dolerites. The latter appear on the surface at the Kara dome being a material which probably have been affected by the most strong impact. Here we for the first time describe the results of preliminary analysis of petrological and geochemical features of the magmatic dikes of the central uplift with the aim to understand their probable genetic source for the UHPHT impact melt veins matter. The provided studies point to essential difference between the compared materials, that means the UHPHT impact melts do not correspond to the magmatic material of the Khengursky complex of gabbro-dolerites of the Pay-Khoy Ridge (Russia).

Iron-rich microstructure records of high temperature multi-component silicate melt behavior in nuclear fallout

Above-ground nuclear explosions that interact with the surface of the earth entrain materials from the surrounding environment, influencing the resulting physical and chemical evolution of the fireball, which can affect the final chemical phase and mobility of hazardous radionuclides that are dispersed in the environment as fallout particles. The interaction of iron with a nuclear explosion is of specific interest due to the potential for iron to act as a redox buffer and because of the likelihood of significant masses of metals to be present in urban environments. We investigated fallout from a historic surface interacting nuclear explosion conducted on a steel tower and report the discovery of widespread and diverse iron-rich micro-structures preserved within the samples, including crystalline dendrites and micron-scale iron-rich spheres with liquid immiscibility textures. We assert these micro-structures reflect local redox conditions and cooling rates and can inform interpretation of high temperature events, enabling new insights into fireball condensation physics and chemistry when metals from the local environment (i.e. structural steel) are vaporized or entrained. These observations also significantly expand the availability of silicate immiscibility datasets applicable to rapidly quenched systems such as meteorite impact melt glass.

Hydrogen Isotopic Variations in the Shergottites

Hydrogen isotopes in the shergottite Martian meteorites are among the most varied in Mars laboratory samples. By collating results of previous studies on major hydroxyl, deuterium, and H2O bearing phases, we provide a compendium of recent measurements in order to elucidate crustal-rock versus mantle-rock processes on Mars. We summarize recent works on volatile and δD measurements in a range of shergottite phases: from melt inclusions, apatite, merrillite, maskelynite, impact melt glass, groundmass glass, and nominal anhydrous minerals. We interpret these observations using an evidence-based approach, considering two particular scenarios: (1) water-rock crustal interactions versus (2) magmatic-based processes. We consider the implications of these measurements and the scope they have for future studies, paying particular attention to future works on H, S, and Cl isotopes in situ, shedding light on the nature of volatiles in the hydrosphere and lithosphere of Mars.

New lunar meteorite NWA 10986: A mingled impact melt breccia from the highlands—A complete cross section of the lunar crust

AbstractNorthwest Africa (NWA) 10986 is a new mingled lunar meteorite found in 2015 in Western Sahara. This impact melt breccia contains abundant impact melt glass and clasts as large as 0.75 mm. Clasts are predominantly plagioclase and pyroxene‐rich and represent both highland and basalt lithologies. Highland lithologies include troctolites, gabbronorites, anorthositic norites, and troctolitic anorthosites. Basalt lithologies include crystalline clasts with large zoned pyroxenes representing very low titanium to low titanium basalts. In situ geochemical analysis of minerals within clasts indicates that they represent ferroan anorthosite, Mg‐suite, and gabbronorite lithologies as defined by the Apollo sample collection. Clasts representing magnesian anorthosite, or “gap” lithologies, are prevalent in this meteorite. Whole rock and in situ impact glass measurements indicate low incompatible trace element concentrations. Basalt clasts also have low incompatible trace element concentrations and lack evolved KREEP mineralogy although pyroxferroite grains are present. The juxtaposition of evolved, basaltic clasts without KREEP signatures and highland lithologies suggests that these basaltic clasts may represent cryptomare. The lithologies found in NWA 10986 offer a unique and possibly a complete cross section view of the Moon sourced outside of the Procellarum KREEP Terrane.

Remnants of paleoflora in impact melt rocks of the El'gygytgyn crater (Chukotka, Russia)

AbstractRemnants of paleoflora were discovered in impact melt rocks from the El'gygytgyn crater, Chukotka, Russia. El'gygytgyn is a 3.58 Ma, 18 km diameter impact structure in Chukotka, northeastern Russia. A circular crater basin is surrounded by an uplifted rim. The crater floor is occupied by the El'gygytgyn Lake, 12 km in diameter, surrounded by lacustrine terraces up to 80 m in height. Impactites found at the El'gygytgyn crater include impact melt rocks, glass bombs, and shock metamorphosed volcanic rocks. Most impact melt rocks occur only in redeposited state in the terrace lake deposits. Floral remnants were discovered in impact melt rocks from various locations in the terrace deposits. The floral remnants include fragments of leaves, cell tissue, and undetermined organic matter that occur in vesicles within glassy melt rocks and impact melt breccias. After the discovery of floral remnants in impact melt breccias from upper Miocene strata in Argentina, and the description of floral imprints in the Dakhleh Glass of proposed impact origin in Egypt, the detection of paleoflora remnants in impact melt rocks of the El'gygytgyn structure is the first such occurrence in a confirmed impact crater on Earth.

Magnetism of a very young lunar glass

AbstractRecent paleomagnetic studies of Apollo samples have established that a core dynamo existed on the Moon from at least 4.2 to 3.56 billion years (Ga). Because there is no lunar dynamo today, a longstanding mystery has been the origin of magnetization in very young lunar samples (<~200 million years old (Ma)). Possible sources of this magnetization include transient fields generated by meteoroid impacts, remanent fields from nearby rocks magnetized during an earlier dynamo epoch, a weak late dynamo, and spontaneous remanence formed in a near‐zero field. To further understand the source of the magnetization in young lunar samples, we conducted paleomagnetic, petrographic, and 40Ar/39Ar geochronometry analyses on a young impact melt glass rind from the exterior of ~3.35 Ga mare basalt 12017. Cosmic ray track densities and our 40Ar/39Ar and cosmogenic 38Ar analyses constrain the glass formation age to be <7 Ma and most likely <20 thousand years (kyr), making it likely the youngest extraterrestrial sample yet studied with paleomagnetic methods. Despite its relatively high fidelity magnetic recording properties compared to most lunar rocks, we find that the glass carries no stable primary natural remanent magnetization and that it formed in a field <~7 μT (with a 2 σ upper limit of <11 μT). Given the poor magnetic recording properties of the majority of lunar samples, this provides further evidence that many or perhaps even all previous paleointensity estimates for ≤1.5 Ga rocks are upper limits on the true paleofield and therefore require neither a protracted strong (>10 μT) core dynamo field nor impact‐generated fields.

Microscopic impactor debris in the soil around Kamil crater (Egypt): Inventory, distribution, total mass, and implications for the impact scenario

AbstractWe report on the microscopic impactor debris around Kamil crater (45 m in diameter, Egypt) collected during our 2010 geophysical expedition. The hypervelocity impact of Gebel Kamil (Ni‐rich ataxite) on a sandstone target produced a downrange ejecta curtain of microscopic impactor debris due SE–SW of the crater (extending ~300,000 m2, up to ~400 m from the crater), in agreement with previous determination of the impactor trajectory. The microscopic impactor debris include vesicular masses, spherules, and coatings of dark impact melt glass which is a mixture of impactor and target materials (Si‐, Fe‐, and Al‐rich glass), plus Fe‐Ni oxide spherules and mini shrapnel, documenting that these products can be found in craters as small as few tens of meters in diameter. The estimated mass of the microscopic impactor debris (<290 kg) derived from Ni concentrations in the soil is a small fraction of the total impactor mass (~10 t) in the form of macroscopic shrapnel. That Kamil crater was generated by a relatively small impactor is consistent with literature estimates of its pre‐atmospheric mass (>20 t, likely 50–60 t).

The Wabar impact craters, Saudi Arabia, revisited

AbstractThe very young Wabar craters formed by impact of an iron meteorite and are known to the scientific community since 1933. We describe field observations made during a visit to the Wabar impact site, provide analytical data on the material collected, and combine these data with poorly known information discovered during the recovery of the largest meteorites. During our visit in March 2008, only two craters (Philby‐B and 11 m) were visible; Philby‐A was completely covered by sand. Mapping of the ejecta field showed that the outcrops are strongly changing over time. Combining information from different visitors with our own and satellite images, we estimate that the large seif dunes over the impact site migrate by approximately 1.0–2.0 m yr−1 southward. Shock lithification took place even at the smallest, 11 m crater, but planar fractures (PFs) and undecorated planar deformation features (PDFs), as well as coesite and stishovite, have only been found in shock‐lithified material from the two larger craters. Shock‐lithified dune sand material shows perfectly preserved sedimentary structures including cross‐bedding and animal burrows as well as postimpact structures such as open fractures perpendicular to the bedding, slickensides, and radiating striation resembling shatter cones. The composition of all impact melt glasses can be explained as mixtures of aeolian sand and iron meteorite. We observed a partial decoupling of Fe and Ni in the black impact glass, probably due to partitioning of Ni into unoxidized metal droplets. The absence of a Ca‐enriched component demonstrates that the craters did not penetrate the bedrock below the sand sheet, which has an estimated thickness of 20–30 m.

Can alteration experiments on impact melts from El'gygytgyn and volcanic glasses shed new light on the formation of the Martian surface?

AbstractThis investigation involved three specimens: an altered felsic sample of impactite from the ICDP El'gygytgyn drill core D1c, and two reference volcanics from Iceland, namely a rhyolitic glass and a basaltic glass. The goal of this work was to better understand the alteration of impact melt and volcanic glass, and to apply the results to an investigation of alteration processes below the surface of Mars. Hydrothermal batch alteration experiments with the El'gygytgyn sample showed formation of various silica phases such as cristobalite, opal, and quartz. According to geochemical modeling, zeolites were also expected, but zeolite minerals already present in the impactite prior to the experiment may have masked possible experimental zeolite growth. Basaltic glass was altered to smectite, talc, and opal. The accompanying numerical modeling gave results that were similar or comparable to the laboratory experiments. Rhyolitic glass was kinetically more stable than basaltic glass, and showed only minor formation of calcite and feldspar during the 3‐week experiment. The study showed that closed‐system isochemical alteration of both siliceous and mafic glasses and melts results in the formation of smectites and zeolites. Therefore, to link alteration features on Mars to specific physical conditions, the exact identity of the mineral phases present in surface rocks must be known. Moreover, our simulations on closed‐system isochemical alteration showed that the fraction of zeolites and silica formed relative to smectite depends on the source mineral altered. Therefore, fractions of these mineral groups present in the Martian soil may be used to better predict source rock characteristics.

Isotopic evidence for a Martian regolith component in shergottite meteorites

[1] The 80Kr excesses determined in the gas-rich impact-melt (GRIM) glasses in EET79001 and Shergotty correlate poorly with the 129XeM (Martian atmosphere) suggesting that the majority of the neutron-capture 80Krn was not shock-implanted along with 129XeM into these glasses during impact. This inference is consistent with the variations in δ80Krn excesses observed in these samples. The results reported here indicate that the 80Krn excesses in these glasses were produced in the same way as the 149Sm isotopic deficits, i.e., by thermal neutron (n) capture on Br and Sm occurring in the glass-precursor regolith materials on Mars. The thermal neutron fluences calculated from 80Krn excesses (∼0.3–1.0 × 1015 n/cm2) and from 149Sm deficits (1.0 ± 0.4 × 1015 n/cm2) agree with each other confirming that 80Krn was mostly produced in situ. In the Martian regolith, thermal (n) and fast (N) neutrons occur together. Also, in the GRIM glasses, the 83Kr/86Kr ratios correlate positively with 84Kr/86Kr indicating that the cosmogenic Kr contains a fast neutron-produced component in addition to Kr produced by galactic cosmic and solar cosmic irradiation. Using 83KrN and 84KrN excesses produced by fast neutron reactions on Rb and Sr targets in some of these glasses, we determine fast neutron fluences of ∼3–47 × 1015 N/cm2. The integrated fluences of thermal and fast neutrons in GRIM glasses suggest that the glass-precursor materials were irradiated at different depths in the top few meters of the water-ice-bearing regolith near the shergottite source regions on Mars.

Trace element geochemistry of K-rich impact spherules from howardites

The howardite–eucrite–diogenite (HED) achondrites are a group of meteorites that probably originate from the asteroid Vesta. Howardites are complex polymict breccias that sometimes contain, in addition to various rock debris, impact melt glasses which show an impressive range of compositions. In this paper we report on the geochemistry and O isotopes of a series of 6 Saharan polymict breccias (4 howardites and 2 polymict eucrites), and on the trace element abundances of high-K impact spherules found in two of them, Northwest Africa (NWA) 1664 and 1769, which are likely paired. The high-K impact spherules found in the howardites NWA 1664 and NWA 1769 display remarkable trace element patterns. Compared to eucrites or howardites, they all show prominent enrichments in Cs, Rb, K, Li and Ba, strong depletion in Na, while the REE and other refractory elements are unfractionated. These features could not have been generated during impact melting of their host howardites, nor other normal HED target materials. The involvement of Na-poor rocks, and possibly rocks of granitic composition, appears likely. Although these lithologies cannot be well constrained at present, our results demonstrate that the surface of Vesta is certainly more diverse than previously thought. Indeed, despite the large number of available HED meteorites (about 1000 different meteorites), the latter are probably not sufficient to describe the whole surface of their parent body.

The Obolon impact structure, Ukraine, and its ejecta deposits

Abstract— The Obolon impact structure, 18 km in diameter, is situated at the northeastern slope of the Ukrainian Shield near its margin with the Dnieper‐Donets Depression. The crater was formed in crystalline rocks of the Precambrian basement that are overlain by marine Carboniferous and continental Lower Triassic deposits. The post‐impact sediments comprise marine Middle Jurassic (Bajocian and Bathonian) and younger Mesozoic and Cenozoic deposits. Today the impact structure is buried beneath an about 300‐meter‐thick sedimentary rock sequence.Most information on the Obolon structure is derived from two boreholes in the western part of the crater. The lowest part of the section in the deepest borehole is composed by allogenic breccia of crystalline basement rocks overlain by clast‐rich impact melt rocks and suevites. Abundant shock metamorphic effects are planar deformation features (PDFs) in quartz and feldspars, kink bands in biotite, etc. Coesite and impact diamonds were found in clast‐rich impact melt rocks. Crater‐fill deposits are a series of sandstones and breccias with blocks of sedimentary rocks that are covered by a layer of crystalline rock breccia.Crystalline rock breccias, conglomeratic breccias, and sandstones with crystalline rock debris have been found in some boreholes around the Obolon impact structure to a distance of about 50 km from its center. Those deposits are always underlain by Lower Triassic continental red clay and overlain by Middle Jurassic marine clay. The K‐Ar age of impact melt glasses is 169 Ma, which corresponds to the Middle Jurassic (Bajocian) age. The composition of crater‐fill rocks within the crater and sediments outside the Obolon structure testify to its formation under submarine conditions.

Impactites of the Haughton impact structure, Devon Island, Canadian High Arctic

Contrary to the previous interpretation of a single allochthonous impactite lithology, combined field, optical, and analytical scanning electron microscopy (SEM) studies have revealed the presence of a series of impactites at the Haughton impact structure. In the crater interior, there is a consistent upward sequence from parautochthonous target rocks overlain by parautochthonous lithic (monomict) breccias, through allochthonous lithic (polymict) breccia, into pale grey allochthonous impact melt breccias. The groundmass of the pale grey impact melt breccias consists of microcrystalline calcite, silicate impact melt glass, and anhydrite. Analytical data and microtextures indicate that these phases represent a series of impact-generated melts that were molten at the time of, and following, deposition. Impact melt glass clasts are present in approximately half of the samples studied. Consideration of the groundmass phases and impact glass clasts reveal that impactites of the crater interior contain shock-melted sedimentary material from depths of >920 to 200 to <760 m and are interpreted as remnants of the continuous ejecta blanket. The pale grey impact melt breccias, although similar to the impact melt breccias of the crater interior, are more carbonate-rich and do not appear to have incorporated clasts from the crystalline basement. Thus, the spatial distribution of the crater-fill impactites at Haughton, the stratigraphic succession from target rocks to allochthonous impactites, the recognition of large volumes of impact melt breccias, and their probable original volume are all analogous to characteristics of coherent impact melt layers in comparatively sized structures formed in crystalline targets.

Constraints on the U-Pb isotopic systematics of Mars inferred from a combined U-Pb, Rb-Sr, and Sm-Nd isotopic study of the Martian meteorite Zagami

Uranium-lead, Rb-Sr, and Sm-Nd isotopic analyses have been performed on the same whole-rock, mineral, and leachate fractions of the basaltic martian meteorite Zagami to better constrain the U-Pb isotopic systematics of martian materials. Although the Rb-Sr and Sm-Nd systems define concordant crystallization ages of 166 ± 6 Ma and 166 ± 12 Ma, respectively, the U-Pb isotopic system is disturbed. Nevertheless, an age of 156 ± 6 Ma is derived from the 238U- 206Pb isotopic system from the purest mineral fractions (maskelynite and pyroxene). The concordance of these three ages suggest that the 238U- 206Pb systematics of the purest Zagami mineral fractions have been minimally disturbed by alteration and impact processes, and can therefore be used to constrain the behavior of U and Pb in the Zagami source region. The μ value of the Zagami source region can be estimated, with some confidence from the 238U- 206Pb isochron, to be 3.96 ± 0.02. Disturbance of the U-Pb isotopic systems means that this represents a minimum value. The μ value of the Zagami source is significantly lower than the μ values estimated for most basaltic magma sources from Earth and the Moon. This is surprising given the high initial 87Sr/ 86Sr ratio (0.721566 ± 82) and low initial ε Nd value (−7.23 ± 0.17) determined for Zagami that indicate that this sample is derived from one of the most highly fractionated reservoirs from any known planetary body. This suggests that Mars is characterized by a low bulk planet U/Pb ratio, a feature that is consistent with its relatively volatile-rich nature. The leachates contain terrestrial common Pb that was probably added to the meteorite during handling, curation, or sawing. The mineral fractions, particularly those with significant amounts of impact melt glass, contain a second contaminant. The presence of this contaminant results in Pb-Pb ages that are older than the crystallization age of Zagami, indicating that the contaminant is characterized by a high 207Pb/ 206Pb ratio. Such a contaminant could be produced by removal of single-stage Pb from a relatively high μ martian reservoir before ∼1.8 Ga, and therefore could be an ancient manifestation of hydrous alteration of martian surface material.

The nature of the groundmass of surficial suevite from the Ries impact structure, Germany, and constraints on its origin

Abstract— Surficial suevites from the Ries impact structure have been investigated in the field and using optical and analytical scanning electron microscopy. The groundmass of these suevites comprises calcite, clay minerals, impact melt glass, crystallites (plagioclase, garnet, and pyroxene), francolite, and Ba‐phillipsite. The latter zeolite is a secondary phase. Abundant textures have been observed: intricate flow textures between the various groundmass phases, globules of each phase in the other phases, spheroids of pyrrhotite in calcite, the “budding‐off” of clay globules into silicate glass and/or calcite, euhedral overgrowths of francolite on apatite clasts, and quench‐textured crystallites in the groundmass. Groundmass‐forming calcite displays higher FeO, MnO, and SiO2 contents than limestone target material. The composition of suevite “clay minerals” is highly variable and not always consistent with montmorillonite. Three types of glasses are distinguished in the groundmass. Type 1 glasses are SiO2‐rich and are clearly derived from sandstones in the sedimentary cover, while the protoliths of the other two glass types remains unclear.Analytical data and micro‐textures indicate that the calcite, silicate glass, francolite, and clay minerals of the groundmass of the Ries suevites represent a series of impact‐generated melts that were molten at the time of, and after, deposition. On cooling, plagioclase, pyroxene, and garnet crystallized from the groundmass. These results are at variance with the current, traditional descriptive definition of suevite. Given that Ries is the original type occurrence of “suevite,” some modification to the traditional definition may be in order. As the results of this study are most consistent with the groundmass of Ries surficial suevites representing a mix of several types of impact‐generated melts, we suggest that a possible origin for these suevites is as some form of impact melt flow(s) that emanated from different regions of the evolving crater.

Impact melt rocks from the Ries structure, Germany: an origin as impact melt flows?

The production of impact melt rocks and glasses is a characteristic feature of hypervelocity impact events on Earth and other planetary bodies. This investigation represents the first detailed study of an unusual series of coherent impact melt rocks intermittently exposed around the periphery of the ~24-km diameter, ~14.5 Ma Ries impact structure, Germany. Optical and analytical scanning electron microscopy (SEM) reveals that the groundmass comprises sanidine, plagioclase, quartz and ilmenite (decreasing order of abundance) with the interstices filled by either fresh or devitrified glassy mesostasis. Primary crystallites display skeletal, dendritic and/or spherulitic textures indicating rapid crystallization from a melt. The mesostasis is characterized by extreme chemical heterogeneity (e.g., FeO and Al 2O 3 contents from ~1 to ~62–80 wt.%). This is likely due to a combination of crystal–liquid fractionation during rapid cooling and crystallization of an originally incompletely homogenized melt. Vapor phase crystallization of sanidine and cristobalite occurred in miarolitic cavities during late-stage cooling of the impact melts. The most likely protolith for the impact melt rocks are granitic rocks present in the crystalline basement target. The high volatile content of the mesostasis suggests that a large volatile component was retained from this protolith. Field observations together with analytical data and micro-textures indicate that the Ries impact melt rocks were molten at the time of, and after, deposition. Field relations with other impactites also suggest that these rocks were emplaced subsequent to the excavation stage of crater formation and that they are not, therefore, ballistic ejecta. Thus, it is proposed that the Ries impact melt rocks were emplaced as ground-hugging impact melt flows that emanated from different regions of the evolving transient cavity during the modification stage of crater formation. This is consistent with, and in fact predicted, by field relations, which indicate that these rocks overlie unequivocal ejecta. This represents the first recognition of impact melt flows near the rim of a terrestrial impact structure and is consistent with observations of such features on the Moon and Venus.

Shocked rocks and impact glasses from the El'gygytgyn impact structure, Russia

Abstract— The El'gygytgyn impact structure is about 18 km in diameter and is located in the central part of Chukotka, arctic Russia. The crater was formed in volcanic rock strata of Cretaceous age, which include lava and tuffs of rhyolites, dacites, and andesites. A mid‐Pliocene age of the crater was previously determined by fission track (3.45 ± 0.15 Ma) and 40Ar/39Ar dating (3.58 ± 0.04 Ma). The ejecta layer around the crater is completely eroded. Shock‐metamorphosed volcanic rocks, impact melt rocks, and bomb‐shaped impact glasses occur in lacustrine terraces but have been redeposited after the impact event.Clasts of volcanic rocks, which range in composition from rhyolite to dacite, represent all stages of shock metamorphism, including selective melting and formation of homogeneous impact melt. Four stages of shocked volcanic rocks were identified: stage I (≤35 GPa; lava and tuff contain weakly to strongly shocked quartz and feldspar clasts with abundant PFs and PDFs; coesite and stishovite occur as well), stage II (35–45 GPa; quartz and feldspar are converted to diaplectic glass; coesite but no stishovite), stage III (45–55 GPa; partly melted volcanic rocks; common diaplectic quartz glass; feldspar is melted), and stage IV (&gt;55 GPa; melt rocks and glasses). Two main types of impact melt rocks occur in the crater: 1) impact melt rocks and impact melt breccias (containing abundant fragments of shocked volcanic rocks) that were probably derived from (now eroded) impact melt flows on the crater walls, and 2) aerodynamically shaped impact melt glass “bombs” composed of homogeneous glass. The composition of the glasses is almost identical to that of rhyolites from the uppermost part of the target. Cobalt, Ni, and Ir abundances in the impact glasses and melt rocks are not or only slightly enriched compared to the volcanic target rocks; only the Cr abundances show a distinct enrichment, which points toward an achondritic projectile. However, the present data do not allow one to unambiguously identify a meteoritic component in the El'gygytgyn impact melt rocks.