Ideal Gas State Research Articles

Vaporization enthalpies of self-associated aromatic compounds at 298.15 K: A review of existing data and the features of heat capacity correction. Part III. Polyphenols, polyanilines and aminophenols

The experimental data on the phase transition enthalpies and heat capacities of numerous polyphenols, polyanilines and aminophenols in the condensed and ideal gas state were analyzed to obtain the reliable values at 298.15 K. For this purpose, we combined experimental data on the crystal, liquid, and ideal gas heat capacities and fusion, sublimation and vaporization enthalpies. Significant part of these data, including the ideal gas heat capacities of 16 molecules, vapor pressures and vaporization enthalpies of 1,3-diaminobenzene and 1,6-dihydroxynaphthalene, were obtained in this work. A modified approach for the estimation of the temperature dependence of vaporization enthalpies of polyphenols, polyanilines and aminophenols showing performance competitive with the experimental one was proposed based on the analysis performed.

Pyrolytic conversion of glucose into hydroxymethylfurfural and furfural: Benchmark quantum-chemical calculations.

Quantum chemical methods have been intensively applied to study the pyrolytic conversion of glucose into hydroxymethylfurfural (HMF) and furfural (FF). Herein, we collect the most relevant mechanistic proposals from the recent literature and organize them into a single reaction network. All the transition structures (TSs) and intermediates are characterized using highly accurate ab initio methods and the possible reaction pathways are assessed in terms of the Gibbs energies of the TSs and intermediates with respect to β-glucopyranose, selecting a 2D ideal-gas standard state at 773 K to represent the pyrolysis conditions. Several pathways can lead to the formation of both HMF and FF passing through rate-determining TSs that have ΔG‡ values of ~49-50 kcal/mol. Both water-assisted mechanisms and nonspecific environmental effects have a minor impact on the Gibbs energy profiles. We find that the HMF → FF + CH2O fragmentation has a small ΔrxnG value and an accessible ΔG‡ barrier. Our computational results, which are in consonance with the kinetic parameters derived from lumped models, the results of isotopic labeling experiments and the reported HMF/FF molecular ratios, could be useful for modeling studies including on nonequilibrium kinetic effects that may render more information about product yields and the relevance of the various pathways.

Analysis of the flow and thermal-fluid–solid coupling of crude oil in circular pipe caused by variable pressure gradient

Abstract Globally, enhanced oil recovery (EOR) has become a pressing issue as the demand for crude oil continues to increase. This study investigates the flow and thermal-fluid–solid coupling of crude oil in a rod pump during hot water recovery and obtains the maximum recovery of crude oil in a vertical pipeline through numerical analysis. The pressure gradient in the pump barrel was first developed and deduced based on the ideal gas state equation and Bernoulli’s equation. According to the rheological experiment results, it was proven that the light crude oil conforms to the Newtonian constitutive equation. Subsequently, the momentum equation of crude oil flowing in the pipeline and fluid–solid coupling heat transfer equations were established and solved using the finite difference method. The effects of the thermal recovery temperature T w , wall thickness c, and stroke time n of the rod pump on flow Q are discussed. In particular, the flow Q within 1 min first increases and then slows down with the increase in stroke time n and reaches its maximum value at n = 7 r/min. Furthermore, flow Q decreases with an increase in c but increases as T w increases; c = 1.2 cm, T w = 363 K is the best oil recovery scheme.

Experimental and simulation study on the expansion mechanism of polyurethane grout

Understanding the expansion mechanism of polyurethane polymer grout can supply guidance for accurate grouting. However, most of the polymer grout expansion calculations were defined simplistically by the polymer density-expansion pressure empirical relationship expression, which failed to meet the time history of the expansion pressure during the polymer reaction process. The objective of this paper was to investigate the expansion mechanism of polyurethane foam in various constraint conditions during the whole polymer reaction process. A model describing the expansion mechanism of polyurethane foam was established based on the energy conservation principle, the chemical reaction kinetic equation solved by the Runge-Kutta method, and the ideal gas state equation. The model was proved applicable compared to the experiments under fixed volume and fixed confining pressure boundaries. In addition, the effects of grouting quantity, confining pressure, initial temperature, and physical foaming agent content on the grout expansion pressure, density, and components conversions were discussed. The results showed that the expansion pressure of polymer grout gradually increased with time under the fixed volume conditions, and the grout expansion pressure increased as the density increased. The final grout expansion pressure will increase with the increase of initial temperature or the content of physical blowing agent. Under the fixed confining pressure condition, the polymer grout density gradually decreased with time, the grout density increased as the confining pressure increased while the conversions of the two components alcohol and isocyanate increased. The final density decreases with the increase of initial temperature or the content of physical blowing agent.

Internal Pressure-Temperature Coupling Analysis Method for Thermal Decomposition of GFRP Composites Based on the Overlapping Elements Method.

A method of internal pressure-temperature coupling analysis for the thermal decomposition of GFRP composites under high-temperature conditions was established, which incorporates coupled calculations of heat transfer equations, the Arrhenius equation, Darcy's law, and the ideal gas state equation. Using the overlapping mesh method, the coupling calculation of temperature and internal pressure is realized based on the UMATHT and USDFLD user subroutines developed. Specifically, two user subroutines, UMATHT-1 and UMATHT-2, are used to define the heat transfer equation and gas diffusion equation separately. Numerical simulations are conducted to simulate the polymers' thermal decomposition in high-temperature environments. For glass fiber/vinyl ester composites and glass fiber/phenolic composites, the predicted temperature and pressure values are in good agreement with experimental measurements, and porosity and permeability are then analyzed. Due to the accumulation of thermal decomposition gases, inter-pressure within the material surged and reached a peak value. After that, it began to decrease, but the factors affecting the pressure decrease vary at different positions. Specifically, the pressure closest to the heating surface is influenced by the combined effects of decomposition rate, permeability, and porosity, while the pressure far away from the heating surface is only affected by the initial permeability. The pressure in the intermediate region may be influenced by both increased porosity and initial permeability.

Properties of ground state and quench dynamics of one-dimensional contact repulsive single-spin flipped Fermi gases

Based on the exact solution method, the ground state and quench dynamics properties of one-dimensional single-spin flipped Fermi gas with repulsion interaction are studied. With the Bethe wave function, the single-body correlation function and two-body correlation function of the ground state and those between different eigen-states can be reduced into a summation of simple functions, thereby greatly reducing the computational difficulty. For the system in the ground state, the single-body correlation functions and two-body correlation functions as well as momentum distributions for spin-up particles are investigated in real space with different interaction strengths. As the interaction strength increases, the number of nodes in the single-body correlation function remains unchanged, while the amplitude of oscillation decreases. Meanwhile, the number of peaks in the two-body correlation function increases by one due to interaction, indicating that the spin-down particle behaves as a spin-up particle. The momentum distribution becomes more smooth around Fermi surface with the interaction strength increasing. The interaction quench dynamics is investigated. The system is prepared in the ground state of ideal Fermi gas, and then the interaction strength is quenched to a finite positive value. The system evolves under time-dependent Schrödinger equation. The overlap between the initial state and eigen-state of post-quench interaction strength is expressed in the form of continued multiplication. The square of the modulus of this overlap, which represents the occupation probability, is calculated. We find that the occupation probabilities of the ground state and doubly degenerated excited state always have the first and the second largest value for an arbitrary interaction strength, respectively, which means that the difference in eigenenergy between these two states gives the primary period of oscillation. For relatively large particle number (<inline-formula><tex-math id="M2">\begin{document}$ N\geqslant10$\end{document}</tex-math><alternatives><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="2-20231425_M2.jpg"/><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="2-20231425_M2.png"/></alternatives></inline-formula>), the primary period always does not change under different interaction strengths.It is found that in the case of interaction quenching, the momentum distribution and the correlation function show periodic oscillations. When the interaction strength is adjusted to a relatively small value, the oscillation periodicity is well-defined and the oscillation amplitude is small. The system can be approximated by a two-level model. When the interaction strength increases to a very large value, the oscillation periodicity worsens and the amplitude increases, but a primary period remains unchanged. Although the overall deviation is far from the initial state, it is very close to the initial state at time <inline-formula><tex-math id="M3">\begin{document}$ t=mL^2/(2\pi\hbar)$\end{document}</tex-math><alternatives><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="2-20231425_M3.jpg"/><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="2-20231425_M3.png"/></alternatives></inline-formula>. This is because the difference between most energy eigenvalues is almost an integral multiple of energy unit <inline-formula><tex-math id="M4">\begin{document}$ 2\times\left(2\pi/L\right)^{2}$\end{document}</tex-math><alternatives><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="2-20231425_M4.jpg"/><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="2-20231425_M4.png"/></alternatives></inline-formula>.

Modelling of structure and concentration characteristics of water-alcohol solutions

Water-alcohol solutions are widely used in pharmacy, food industry, engineering, etc. The study of their physical and chemical properties has a long history. Nevertheless, due to the complexity of these systems, there is still an interest in their research stimulated by the development of biochemistry in terms of the study and protection of the environment, global climate change, renewable energy resources and cosmochemistry. The purpose of the presented study is the quantum-chemical investigation of water clusters with methyl and ethyl alcohol molecules, as well as the modelling of concentration dependences of the excess molar volume of ethyl alcohol solution in water at different temperatures. Based on quantum-chemical calculations of paired and mixed complexes of water with methanol and ethanol, taking into account solvation effects, study reveals the formation of thermodynamically efficient complexes in liquid, in contrast to the ideal gas state, while in the mixture both individual solvated alcohol molecules and complexes will be in equilibrium. We noted a relative difference in the free energies of solvation of paired and mixed methanol and ethanol complexes. The paper proposes a technique for calculating the excess molar volume in water-alcohol mixtures by approximating the experimental dependences by Lejandre polynomials of the ninth degree. The calculation results showed high accuracy. Hence, continuous functions describe the dependences of the calculated coefficients of Lejandre polynomials on temperature.

Моделирование структуры и концентрационных характеристик водно-спиртовых растворов

Water-alcohol solutions are widely used in pharmacy, food industry, engineering, etc. The study of their physical and chemical properties has a long history. Nevertheless, due to the complexity of these systems, there is still an interest in their research stimulated by the development of biochemistry in terms of the study and protection of the environment, global climate change, renewable energy resources and cosmochemistry. The purpose of the presented study is the quantum-chemical investigation of water clusters with methyl and ethyl alcohol molecules, as well as the modelling of concentration dependences of the excess molar volume of ethyl alcohol solution in water at different temperatures. Based on quantum-chemical calculations of paired and mixed complexes of water with methanol and ethanol, taking into account solvation effects, study reveals the formation of thermodynamically efficient complexes in liquid, in contrast to the ideal gas state, while in the mixture both individual solvated alcohol molecules and complexes will be in equilibrium. We noted a relative difference in the free energies of solvation of paired and mixed methanol and ethanol complexes. The paper proposes a technique for calculating the excess molar volume in water-alcohol mixtures by approximating the experimental dependences by Lejandre polynomials of the ninth degree. The calculation results showed high accuracy. Hence, continuous functions describe the dependences of the calculated coefficients of Lejandre polynomials on temperature.

On the Development of Descriptor-Based Machine Learning Models for Thermodynamic Properties: Part 1—From Data Collection to Model Construction: Understanding of the Methods and Their Effects

In the present work, a multi-angle approach is adopted to develop two ML-QSPR models for the prediction of the enthalpy of formation and the entropy of molecules, in their ideal gas state. The molecules were represented by high-dimensional vectors of structural and physico-chemical characteristics (i.e., descriptors). In this sense, an overview is provided of the possible methods that can be employed at each step of the ML-QSPR procedure (i.e., data preprocessing, dimensionality reduction and model construction) and an attempt is made to increase the understanding of the effects related to a given choice or method on the model performance, interpretability and applicability domain. At the same time, the well-known OECD principles for the validation of (Q)SAR models are also considered and addressed. The employed data set is a good representation of two common problems in ML-QSPR modeling, namely the high-dimensional descriptor-based representation and the high chemical diversity of the molecules. This diversity effectively impacts the subsequent applicability of the developed models to a new molecule. The data set complexity is addressed through customized data preprocessing techniques and genetic algorithms. The former improves the data quality while limiting the loss of information, while the latter allows for the automatic identification of the most important descriptors, in accordance with a physical interpretation. The best performances are obtained with Lasso linear models (MAE test = 25.2 kJ/mol for the enthalpy and 17.9 J/mol/K for the entropy). Finally, the overall developed procedure is also tested on various enthalpy and entropy related data sets from the literature to check its applicability to other problems and competing performances are obtained, highlighting that different methods and molecular representations can lead to good performances.

Numerical simulation of the diesel engine starting considering air pre-heating in the intake system

BACKGROUND: Low temperature of the intake air is one of the reasons of difficult starting of a cold diesel engine in conditions of negative outside temperatures. For a reliable staring of a cold diesel engine, it is necessary to have the temperature at the end of the compression stroke higher than the fuel self-ignition temperature. As the temperature at the end of the compression stroke is defined, first, by the temperature at the end of the intake stroke, the mentioned condition can be satisfied with preliminary warming of the air entering in a cylinder. AIMS: The article is devoted to solving the task related to development of a mathematical model of a diesel engine taking into account air pre-heating in the intake system and ensuring simulation of the pre-starting mode, starting and operation of a diesel engine in conditions of low negative outside temperature. METHODS: The enhanced mathematical model of a diesel engine basing on heat mechanics (thermodynamics of opened systems) which reflects main features of an internal combustion engine (ICE) as the system transforming energy in time domain is proposed in the article. The mathematical model’s equation system is based on laws of conservation of energy and mass, solid bodies’ motion equation and includes differential equations of changing of temperature and density of the working body in a cylinder, in the intake system and in the ICE’s crankcase, the ideal gas state equation as well as differential equations of changing of rotation velocity and rotation angle of an engine’s crankshaft. RESULTS: The mathematical model was tried out on the example of the 1Ch9.5/8.0 multi-purposed air-cooled diesel engine. The results of simulation of the pre-starting mode, starting and operation of the diesel engine taking into account air pre-heating in the intake system are presented in the article. CONCLUSIONS: Implementation of air pre-heating at the intake in the design of diesel engines is the most effective way of ensure starting of the engines at low negative outside temperature. The obtained results help to develop recommendations of choosing power and operation modes of pre-heating devices for ensuring starting and operation of diesel engines in conditions of low negative outside temperatures.

Vaporization enthalpies of self-associated aromatic compounds at 298.15 K: a review of existing data and the features of heat capacity correction. Part II. Anilines

Due to the low volatility, hygroscopicity, oxidation on air exposure, and association in the vapor-phase, the experimental study of the phase transition thermochemistry of hydrogen-bonded aromatic compounds, particularly amines, is complicated. As such, the available literature data is often scattered. In this respect, the critical analysis and reconciliation of the independent experiments performed at different temperatures are well merited.In this work, two goals were set. The first goal was to obtain a reliable dataset of the vaporization enthalpies for aniline and its derivatives at the reference temperature of 298.15 K. Second, we aimed to develop an approach for the estimation of the temperature dependence of their vaporization enthalpies. For these purposes, we collected the independent measurements of the vaporization, fusion, and sublimation enthalpies at different temperatures, as well as the heat capacities of the compounds in liquid, crystalline, and ideal gas states, required to adjust the phase transition enthalpies to 298.15 K. Possible non-ideality of the gaseous phase at elevated temperatures and pressures was accounted for to avoid systematic errors. Reconciliation of the collected data enabled to derive a set of consistent vaporization enthalpies of 22 compounds at 298.15 K and propose an approach for adjusting the vaporization enthalpies of aniline derivatives to an arbitrary temperature with an accuracy comparable to that of a direct experimental measurement.

New impressive performances for the analytical solutions to the (1 + 1)-dimensional van der-waals gas system against its numerical solutions

This article includes the extended simple equation method (ESEM) and the Paul-Painlevé approach method (PPAM), two different methodologies, to offer a variety of novel analytical performances for the (1 + 1)-dimensional Van Der Waals (VDW) gas system. The variational iteration method (VIM), whose initial condition will be obtained from these solutions, will also be used to construct the appropriate numerical solutions for all achieved exact solutions. This article aims to provide abundant new performances of the analytical solutions to the VDW gas system through transforming this coupled system to one equation in terms of the gas volume that is sufficient to get the velocity of gas flow by calculating the wave speed C.The suggested model represents the equation of ideal gas state law that extends to contain the effects of interaction between gas molecules, as well as calculating the finite size of molecules. Furthermore, it describes the one dimensional (1D) longitudinal isothermal motion in elastic bars or fluids. Diverse class of analytical solutions has been extracted by using these inspective methods that are arranged with the same vein, in sequence. Our achieved solutions will contribute not only to understand this important model but also for all related phenomena. A brief comparison is made between our exact and numerical solutions as well as those previously acquired by other researchers who employed other methodologies.

Thermochemical properties of oxepane

In this work, the vapor pressures of oxepane (CAS 592-90-5) have been determined for the first time within the temperature range 276.2–303.2 K using the transpiration method. The enthalpy of vaporization of hexamethylene oxide was evaluated from the experimental vapor pressure data measured by using this method. Values of the enthalpies of combustion and formation have been determined for the first time by combustion calorimetry in a static bomb. A conformational analysis of oxepane in the gas has been performed using methods of molecular mechanics and ab initio computations; the structure of the most stable conformer has been identified. The enthalpy of formation of oxepane in the gaseous state was calculated with the composite G4 method. The thermodynamic functions of oxepane in the ideal gas state over wide temperature range (298.15–1500 K) have been evaluated. Values of the strain energies in a series of cyclic and heterocyclic compounds have been estimated.

Chemical Modeling of Constant-Volume Combustion of the Mixture of Methane and Hydrogen Used in Spark Ignition Otto Cycles

This paper develops a chemical model for a closed constant-volume combustion of a gaseous mixture of methane and hydrogen. Since the combustion is strongly dependent on temperature, pressure and fuel composition, these had chosen the actual corresponding thermodynamic systems in this kind of combustion, i.e., spark ignition (SI) reciprocating engines, to assess combustion parameters and flue gas composition. The actual cycles impose extra restrictive operational conditions through the engine’s-volumetric-compression ratio, the geometry of the combustion volume, the preparation method of the mixture of methane and hydrogen, (e.g., one fueling way of a homogeneous mixture obtained in a specific device or by two separate fueling ways for components), the cooling system and the delivered power. The chemical model avoided the unknown influences in order to accurately explain the influence of hydrogen upon constant-volume combustion and flue gas composition. The model adopted hypotheses allowing to generalize evaluated results, i.e., the isentropic compression and expansion processes, in closed constant-volume combustion caused by two successive steps that obey the energy and mass conservation laws, and the flue gas exhaust, which is also described by two steps, i.e., isentropic expansion through the flow section of exhaust valves followed by a constant pressure stagnation (this process, in fact, corresponds to a direct throttling process). The chemical model assumed the homogeneous mixtures of gases with variable heat capacity functions of temperatures, the Mendeleev—Clapeyron ideal gas state equation, and the variable chemical equilibrium constants for the chosen chemical reactions. It was assumed that the flue gas chemistry prevails during isentropic expansion and during throttling of exhaust flue gas. The chemical model allowed for evaluation of flue gas composition and noxious emissions. The numerical results were compared with those recently reported in other parallel studies.

Vapor Composition and Vaporization Thermodynamics of 1-Ethyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid

The processes of the sublimation and thermal decomposition of the 1-ethyl-3-methylimidazolium hexafluorophosphate ionic liquid (EMImPF6) were studied by a complex approach including Knudsen effusion mass spectrometry, IR and NMR spectroscopy, and quantum chemical calculations. It was established that the vapor over the liquid phase primarily consists of decomposition products under equilibrium conditions. Otherwise, the neutral ion pairs are the only vapor components under Langmuir conditions. To identify the nature of the decomposition products, an experiment on the distillation of the ionic liquid was performed and the collected distillate was analyzed. It was revealed by the IR and NMR spectroscopy that EMImPF6 decomposes to substituted imidazole-2-ylidene (C6N2H10PF5) and HF. The measured vapor pressure of C6N2H10PF5 reveals a very low activity of the decomposition products (<10−4) in the liquid phase. The absence of a significant accumulation of decomposition products in the condensed phase makes it possible to determine the enthalpy of sublimation of the ionic liquid assuming its unchanged activity. The thermodynamics of the EMImPF6 sublimation was studied by Knudsen effusion mass spectrometry. The formation enthalpy of EMImPF6 in the ideal gas state was found from a combination of the sublimation enthalpy and formation enthalpy of the ionic liquid in the condensed state. The obtained value is in good agreement with those calculated by quantum chemical methods.

Particle Ratios in a Multicomponent Nonideal Hadron Resonance Gas

We have considered formation of a multicomponent nonideal hot and dense gas of hadronic resonances in the ultrarelativistic heavy ion collisions. In the statistical thermal model approach, the equation of state (EoS) of the noninteracting ideal hadron resonance gas (IHRG) does not incorporate either the attractive part or the short-range repulsive part of the baryonic interaction. On the other hand, in the nonideal hadron resonance gas (NIHRG) model, we can incorporate these interactions using the van der Waals (VDW) type approach. Studies have been made to see its effect on the critical parameters of the quark-hadron phase transition. However, it can also lead to modifications in the calculated relative particle yields. In this paper, we have attempted to understand the effect of such van der Waals-type interactions on the relative particle yields and also studied their dependences on the system’s thermal parameters, such as the temperature and baryon chemical potential μ B . We have also taken into account the decay contributions of the heavier resonances. These results on particle ratios are compared with the corresponding results obtained from the point-like, i.e., noninteracting IHRG model. It is found that the particle ratios get modified by incorporating the van der Waals-type interactions, especially in a baryon-rich system which is expected to be formed at lower RHIC energies, SPS energies, and in the forthcoming CBM experiments due to high degree of nuclear stopping in these experiments.

Correction: Thermophysical properties evaluation for a polar fluid on the basis of the experimentally determined heat capacity and dipole moment in the ideal gas states

Correction: Thermophysical properties evaluation for a polar fluid on the basis of the experimentally determined heat capacity and dipole moment in the ideal gas states

Thermophysical properties evaluation for a polar fluid on the basis of the experimentally determined heat capacity and dipole moment in the ideal gas states

Thermophysical properties evaluation for a polar fluid on the basis of the experimentally determined heat capacity and dipole moment in the ideal gas states

Modeling, control and analysis of a novel energy-saving oriented fuel cell anode system

Fuel cell hydrogen supply sub-system needs to provide sufficient mass flow and pressure of hydrogen to meet the working demand of the stack. The hydrogen circulation pump is often used, but causes additional parasitic power of fuel cell system. In this study, a new structure of hydrogen circulation pump is proposed to reduce the parasitic power by using the pressure potential energy of hydrogen flow. The hydrogen feeding system model is established based on the solution of differential equation of state of ideal gas, mass and energy balance. Then, considering the hydrogen intake pressure and the hydrogen excess ratio of the system, a reasonable control strategy is proposed for accurate control. Simulation results show that under the fuel cell work condition and the fuel cell vehicle operation condition, pressure difference between anode and cathode and the hydrogen excess ratio can be regulated to the conditions required by the stack, and the excess ratio error and pressure difference error between anode and cathode is 3.82e-3 and 4.52e-4 Bar, respectively. The parasitic power consumption of the circulating pump is effectively reduced about two-thirds under the fuel cell vehicle operation condition. Then, the effects of anode hydrogen pressure drop, hydrogen inlet pressure and entrainment ratio of ejector on the system are studied. Reducing the anode pressure drop, increasing the ejector entrainment ratio while reducing the hydrogen inlet pressure at low power and increasing it at high power are conducive to energy-saving of the system.

Investigation on the Alloy Mixing and Inclusion Removement through Using a New Slot-Porous Matched Tuyeres

A mathematical model was developed to investigate the refining process through using slot-porous matched dual tuyeres. In this model, the bubble expansion is considered through the ideal gas state equation. The density variation of bubbles is calculated through the mass conservation equation. The coalescence and breakup of bubbles are tracked using the discrete particle model (DPM). The transient flow is computed through the k-ε model with three continuous phases (air–slag–steel). Comparisons were made between traditional porous–porous and the new slot–porous tuyeres, mainly focusing on the mixing behavior and inclusion removement ratio. The results show that, for traditional porous–porous matched tuyeres (P-P mode), the inclusion removement ratio is 34.14%; by comparison, after employing the slot–porous matched tuyeres (S-P mode), the inclusion removements ratio rises to 36.34%. The mixing time is also shortened by 18.74% by using the S-P mode. The reason for this phenomenon is because the slot tuyere produces a strong asymmetry that drives more liquid at the bottom of the ladle. The new tuyere match takes advantage of porous and slot tuyeres, and the mixing behavior and inclusion removements are improved. The result is beneficial for future refining.