Ice Meltwater Research Articles

Hydrogeochemical Characteristics and Genesis of Hot Springs in Da Qaidam Area, Northern Qaidam Margin of the Qaidam Basin

Hydrogeochemical research on fluids is an effective method to understand the formation mechanism, occurrence environment, and circulation process of groundwater. The groundwater sampling sites are located in the town of Dachaidan on the northeastern edge of the Tibetan Plateau, which was selected as the study object. Samples were collected from hot and cold springs and surface water in the area. This study is based on the analysis of water chemistry and isotopes, and aims (1) to discuss the chemical characteristics of groundwater in Da Qaidam, (2) to estimate the deep reservoir temperatures, recharge elevation and circulation depth of geothermal waters, and (3) to figure out the heat source beneath the geothermal area and its genetic mechanism. The result showed the following: The hydrochemical type of the hot spring is Cl·SO4-Na and Cl-Na, and the hydrochemical type of cold spring is SO4·HCO3-Na·Ca and Cl·HCO3·SO4-Ca·Na. The main source of groundwater recharge is snow and ice melt water. The recharge elevation ranges from 4666.8 m to 5755.9 m. The geothermal reservoir temperature is about 119.15–126.6 °C. Ice and snow melt water infiltrate into the high mountainous areas on the north side of Da Qaidam and circulate underground through the developed deep and large fractures. Part of the groundwater migrates upwards under the water conduction of the Da Qaidam fault fracture zone to form cold springs, while another part is heated by deep circulation and exposed to the surface in the form of medium to low temperature tectonic hot springs. The research results can provide a scientific basis for geothermal resource exploitation and utilization in Qinghai Province.

Diverse impacts of sea ice and ice shelf melting on phytoplankton communities in the Cosmonaut Sea, East Antarctica

Abstract Antarctic sea ice and glacier melt profoundly impacts marine ecosystems. Our study in the Cosmonaut Sea summer measures seawater oxygen isotopes, size-fractionated chlorophyll-a, and phytoplankton communities. We quantify sea ice meltwater, meteoric water, and winter water contents using a Bayesian isotope-mixing model. Contrary to common belief, our findings suggest that the reduced net export of sea ice to the north and the basal melting of ice shelves have deepened the mixed layer in coastal waters, altering the survival depth of phytoplankton. Freshwater primarily stimulates phytoplankton growth by supplying dissolved iron rather than by increasing water stability, which influences the size distribution and species composition of the phytoplankton community. These insights highlight the complex interplay between freshwater inputs, nutrient dynamics, and phytoplankton communities, and are crucial for understanding the dynamics of Antarctic ecosystem and its vulnerability to climate change.

Origin of Intercrystalline Brine Formation in the Balun Mahai Basin, Qaidam: Constraints from Geochemistry and H-O-Sr Isotopes

The Balun Mahai Basin (BLMH), located in the northern Qaidam Basin (QB), is endowed with substantial brine resources; however, the genetic mechanisms and potential of these brine resources remain inadequately understood. This study investigated the intercrystalline brine (inter-brine) in BLMH, performing a comprehensive geochemical analysis of elemental compositions and H-O-Sr isotopes. It evaluated the water source, solute origin, evolutionary process, and genetic model associated with this brine. Moreover, a mass balance equation based on the 87Sr/86Sr isotopic ratio was developed to quantitatively evaluate the contributions of Ca-Cl water and river water to the inter-brine in the study area. The results suggest that the hydrochemical type of inter-brine in the north part of BLMH is Cl-SO4-type and in the south part is Ca-Cl-type. The solutes in brine are mainly derived from the dissolution of minerals such as halite, sylvite, and gypsum. The hydrochemical process of brine is controlled by evaporation concentration, water–rock interaction, and ion exchange interaction. Hydrogen and oxygen isotopes suggest that the inter-brine originates from atmospheric precipitation or ice melt water and has experienced intense evaporation concentration and water–rock interaction. The strontium isotopes suggest that the inter-brine was affected by the recharge and mixing of Ca-Cl water and river water, which controlled the spatial distribution and formation of brine hydrochemical types. The analysis of ionic ratios suggest that the inter-brine is derived from salt dissolution and filtration, characterized by poor sealing and short sealing time in the salt-bearing formation. The differences in hydrochemical types and spatial distribution between the north and the south are fundamentally related to the replenishment and mixing of these two sources, which can be summarized as mixed origin model of “dissolution and filtration replenishment + deep replenishment” in BLMH.

Key processes controlling the variability of the summer marine CO2 system in Fram Strait surface waters

The aim of this study was to decouple and quantify the influence of various biological and physical processes on the structure and variability of the marine carbonate system in the surface waters of the eastern part of the Fram Strait area. This productive region is characterized by its complex hydrographic and sea ice dynamics, providing an ideal set up to study their influence on the variability of the marine carbonate system. Different variables of the marine CO2 system: Total Alkalinity (TA), Dissolved Inorganic Carbon (DIC), partial pressure of CO2 (pCO2), and pH, were analysed together with temperature, salinity, sea ice extension, and chlorophyll a distribution during three consecutive summers (2019, 2020 and 2021), each of them having a unique oceanographic setting. The data revealed that TA and DIC are mostly controlled by the mixing of Atlantic water and sea ice meltwater. The combined effects of organic matter production/remineralization, calcium carbonate precipitation/dissolution, and air/sea CO2 gas exchange cause deviations from this salinity-related mixing. The scale of these deviations and the proportion between the effects observed for TA and DIC suggest interannual shifts in net primary production and dominant phytoplankton species in the area. These shifts are correlated with the sea ice extent and the spread of the Polar Surface Waters in the region. Net primary production is the main factor controlling the temporal and spatial variability of pH and pCO2 in the study area followed by the influence of temperature and, mixing of water masses expressed with salinity (seawater freshening). Surface waters of the Fram Strait area were generally undersaturated in CO2. The lowest pCO2 values, coinciding with an increase in oxygen saturation, were observed in areas of mixing of Arctic and Atlantic-derived water masses. However, as shown for 2021, a reduction of the sea ice extent may induce a westward shift of the chlorophyll maximum, resulting in pCO2 increase and pH decrease in the eastern part. This indicates that sea ice extent and associated spread of Polar Surface Waters may be important factors shaping primary production, and thus pCO2 and pH, in the Fram Strait area.

Multidecadal decline in sea ice meltwater volume and Pacific Winter Water salinity in the Bering Sea revealed by ocean observations

Large amounts of freshwater and nutrients pass through the Bering Strait to the Arctic Ocean, making the Bering Sea a crucial marginal sea of the North Pacific Ocean. The hydrography and biological production of the Bering Sea are strongly influenced by the amount of sea ice produced and melted. The sea ice extent and production exhibited large interannual variability but no visible trend until 2016 when a strong decrease began. However, records of sea ice before 1979 and the beginning of satellite-based estimates do not exist. In this paper, we devised a methodology using historical temperature and salinity data, supplemented by historical oxygen isotope (δ18O) data, to estimate sea ice melt and its temporal variability in the Bering Sea from 1950 onward. Our results, consistent with estimates of sea ice thickness, indicate that the sea ice melt volume has declined significantly —following lower sea ice extent and production— with a decrease between 35 and 50 km3 (from 442 km3) between pre-1980 and post-1980 climatologies. In particular, our meltwater time series reveals a decline of 160 km3 between 2012 and 2018, which also reflects the strong decrease in sea ice volume between 2016 and 2018 that numerous previous studies have highlighted. We also evaluated the change in the salinity of the Pacific Winter Water (PWW), whose formation is also related to sea ice production. The time series of PWW salinity exhibits a strong decreasing trend, with a freshening of about 0.3 between the mid-1950 s and the mid-2010 s, that we attribute to a combination of a reduced sea ice production and the freshening of the Alaskan Coastal Current water. The decline in meltwater volume and PWW salinity that we observed strongly influences the stratification over the Bering shelf, with a significant weakening of the stratification in coastal polynya regions, and a stronger and increasingly temperature-controlled stratification in the rest of the shelf. These changes could have adverse consequences on the biological productivity of the northern Bering Sea.

Features and processes of rock weathering in central Dronning Maud Land, Antarctica

In this study, we have investigated rock weathering phenomena in the central part of Dronning Maud Land, Antarctica. The area is characterized by low mean annual temperatures (−18 °C), strong katabatic winds, and minimal liquid water at the surface. Weathering features, including ventifacts, tafoni, and grus accumulations, are characterized through field observations, rock surface temperature measurements, and microscopic analysis. Abrasion by sand and ice particles transported by strong winds has locally resulted in ridge-shaped ventifacts and rock surfaces with elongated pits, furrows, and grooves. The abrasion-caused features, such as polished facets, keels, and grooves, indicate a northeast-facing wind direction, aligning with the present-day wind regime. The dominant weathering processes in coarse-grained intrusive rocks are oxidation and granular disintegration. Fe-oxidation induces cracking, increasing the porosity and enhancing susceptibility to further weathering. Additionally, temperature fluctuations on rock surfaces caused by solar radiation create thermal stress, which can lead to the formation of microcracks. These microcracks, formed due to thermal expansion, are likely to propagate through subcritical cracking, which is a slow, long-term process. Together, Fe-oxidation, thermal expansion, and subcritical cracking are important mechanisms contributing to long-term weathering and rock decay. Salt weathering, facilitated by snow and ice meltwater, particularly within tafoni, leads to flaking and disintegration of the parent rock. These findings shed light on the complex interactions shaping the geomorphology of central Dronning Maud Land and provide insights into long-term weathering processes operating in Antarctica's extreme environment.

Summer sea ice melting enhances phytoplankton and dimethyl sulfide production

AbstractThe relationships among sea ice melting, phytoplankton assemblages, and the production of climate‐relevant trace gases in the Southern Ocean are gaining increasing attention from the scientific community. This is particularly true for dimethyl sulfide (DMS), which plays an important role in atmospheric chemistry by influencing the formation of sulfated aerosols with radiative impacts and constituting cloud condensation nuclei. In the current study, chlorophyll a (Chl a), DMS and its precursors dimethylsulfoniopropionate (DMSP), were quantified in the Weddell–Scotia Confluence (WSC) during the 2018 record ice extent minimum period. Mixed layer changes were found to be generally associated with spatial variation in sea ice melt, with the depth being six times deeper in ice‐free, well‐mixed regions than in seasonal ice‐melting zones. The surface Chl a concentration increased from ice‐free to ice‐melting regions with elevated sea ice meltwater percentages and drawdown surface nutrient concentrations. The concentrations of surface and depth‐integrated Chl a in the upper 150 m reached maxima in the ice‐melting region with the highest fraction of sea ice meltwater, illustrating that sea ice melting promoted the occurrence of phytoplankton blooms. The DMS and DMSP concentrations in the vicinity of the ice‐melting zone were approximately three times higher than those in the ice‐free waters. The observations of this study show that the regions of ice melting in the WSC were a zone of particularly high sea–air fluxes of DMS, which could significantly contribute to the atmospheric budget of DMS in the polar regions.

Arctic Freshwater Sources and Ocean Mixing Relationships Revealed With Seawater Isotopic Tracing

AbstractThe Arctic Ocean and adjacent seas are undergoing increased freshwater influx due to enhanced glacial and sea ice melt, precipitation, and runoff. Accurate delineation of these freshwater sources is vital as they critically modulate ocean composition and circulation with widespread and varied impacts. Despite this, the delineation of freshwater sources using physical oceanographic measurements (e.g., temperature, salinity) alone is challenging and there is a requirement to improve the partitioning of ocean water masses and their mixing relationships. Here, we complement traditional oceanographic measurements with continuous surface seawater isotopic analysis (δ18O and deuterium excess) across a transect extending from coastal Alaska to Baffin Bay and the Labrador Sea conducted from the US Coast Guard Cutter Healy in Autumn 2021. We find that the diverse isotopic signatures of Arctic freshwater sources, coupled with the high freshwater proportion in these marine systems, facilitates detailed fingerprinting and partitioning. We observe the highest freshwater composition in the Beaufort Sea and Amundsen Gulf regions, with heightened freshwater content in eastern Baffin Bay adjacent to West Greenland. We apply isotopic analysis to delineate freshwater sources, revealing that in the Western Arctic freshwater inputs are dominated by meteoric water inputs—specifically the Mackenzie River—with a smaller sea ice meltwater component and in Baffin Bay the primary sources are local precipitation and glacial meltwater discharge. We demonstrate that such freshwater partitioning cannot be achieved using temperature‐salinity relationships alone, and highlight the potential of seawater isotopic tracers to assess the roles and importance of these evolving freshwater sources.

Quantitative Assessment of Factors Contributing to Variations in Sea Surface pCO2 in the Pacific Sector of the Arctic Ocean

AbstractTo quantitatively assess seasonal variations in the partial pressure of carbon dioxide (pCO2) in the Pacific sector of the Arctic Ocean (Canada Basin and Chukchi Sea) in 2021, water temperature, salinity, chlorophyll‐a, pCO2, dissolved inorganic carbon (DIC), total alkalinity (TA), and nutrients were measured. During summer 2021, surface water pCO2 in our study area (315 ± 41 μatm) was undersaturated with respect to the atmosphere (404 ± 4 μatm), and the ocean was a sink for atmospheric CO2 (−10.5 ± 11.0 mmol C m−2 day−1). Using DIC, TA, and nutrients in the temperature minimum layer, we estimated the under‐ice pCO2 in the water during the previous winter and calculated changes in pCO2 (δpCO2) due to temperature changes, freshwater inflow, biological activity, and other factors (gas exchange and advection) from winter to summer. In the Chukchi Sea, biological activity and temperature changes had significant impacts on pCO2, whereas in the Canada Basin, the influx of freshwater caused a significant decrease in pCO2. Our results suggested that different types of freshwaters had different effects on pCO2, with sea ice meltwater having a greater effect on reducing pCO2 than river water or snowmelt water. We therefore emphasize the importance of freshwater type and proportion, as well as freshwater supply, for prediction of future pCO2 changes.

Isotope Hydrograph Separation Reveals Rainfall on the Glaciers Will Enhance Ice Meltwater Discharge to the Himalayan Rivers

AbstractThe Indian Summer Monsoon (ISM) and meltwater from the Himalayan are the two most important sources of water in the Indian subcontinent. However, the impact of ISM on Himalayan glaciers and subsequent stream hydrology remains largely unknown. To provide new insight into the impact of rainfall on glacial hydrology, here we present hydro‐meteorological and time‐series observations of meltwater stable water isotope compositions from the snout of the Chorabari glacier in the Upper Ganga Basin, Central Himalayas across the ablation season corresponding to 2019. We observe that rainfall events (>2 mm d−1) on the glacier enhance discharge driven by ice meltwater in River Mandakini. Energy balance calculations reveal that one of the drivers behind enhanced ice meltwater contribution could be rain‐induced melting of the glacier where rainfall on the ice surface melts the glacier producing up to 13% of the total discharge at the glacier snout. Further, rainfall on glacier surface have other control on glacial processes—for example, snow metamorphism, ice flow dynamics such as short‐term acceleration in ice speed flow, and reorganization of the englacial and subglacial drainage network—that are poorly studied and needs further investigation. We conclude rainfall events on the glacier have a complex control on mountain hydrology. This study, therefore, provides an interpretative framework that calls for additional assessments of the direct and indirect impact of rainfall in glacial hydrology.

Order-to-Disorder Transition and Hydrogen Bonding in the Jahn-Teller Active NH4CrF3 Fluoroperovskite.

Large quantities of high-purity NH4CrF3 have been synthesized using a wet-chemical method, and its structural chemistry and magnetic properties are investigated in detail for the first time. NH4CrF3 is a tetragonal fluoroperovskite that displays an ordering of the ammonium (NH4+) groups at room temperature and C-type orbital ordering. The ammonium groups order and display distinct signs of hydrogen bonds to nearby fluoride anions by buckling the Cr-F-Cr angle away from 180°. The ammonium ordering remains up to 405 K, much higher than in other ammonium fluoroperovskites, indicating a correlation between the flexibility of the Jahn-Teller ion, the hydrogen bond formation, and the ammonium ordering. At 405 K, an order-to-disorder transition occurs, where the ammonium groups disorder, corresponding to a transition to higher symmetry. This is accompanied by a contraction of the unit cell from breaking hydrogen bonds, similar to the phenomenon observed in water ice melting. The compound orders antiferromagnetically with a Neél temperature of 60 K, an effective paramagnetic moment of 4.3 μB, and a Weiss temperature of -33 K. An A-type antiferromagnetic structure is identified by neutron diffraction, with an ordered moment of 3.72(2) μB.

Biophysical characterization of summer Arctic sea-ice habitats using a remotely operated vehicle-mounted underwater hyperspectral imager

The impact of a rapidly shifting sea-ice cover on climate, ecosystem processes and biophysical habitat properties is not yet fully understood, particularly in the central Arctic Ocean, due to a lack of spatially representative observations. From June to July 2020 during the year-long Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC, leg 4) in the Transpolar Drift, we deployed an underwater hyperspectral imager (UHI) mounted on a remotely operated vehicle (ROV) to characterize the biophysical properties of different sea-ice habitats. We conducted UHI surveys along two transects: i) under level first-year sea ice (FYI), which had a mean sea-ice draft of 1.4 m and was composed of primarily level FYI but also had a relatively shallow ridge (keel depth ∼2.6 m); and ii) under the flank of a ridge, named Jaridge, with a mean ice draft of 1.7 m, which was composed of a mix of level ice and thicker ridge blocks with over 3 m draft. We present a new unsupervised bio-optical quantification algorithm for hyperspectral surveys, the relative ice algal biomass index (RBI), using spectral mixture analysis (SMA). We compare this method to the supervised machine learning habitat classification algorithm, Support Vector Machine (SVM). The RBI showed good agreement to literature-based normalized difference indices (NDI) and PCA analyses, which confirm the RBI as a reliable unsupervised index for ice algal biomass. Our biophysical characterization of the two surveyed regions showed an association of sea-ice algal biomass with sea-ice ridge features. Our surveys also indicate that ice algal spatial distribution may be influenced by ice melt rates, and the formation of under ice meltwater layers and false bottoms. With high spatial coverage (>100 m) at microscale resolution (∼cm) we documented large spatial variability of summer Arctic sea-ice algal biomass and different patterns between adjacent ice habitats. We further demonstrate the need for improved understanding of sea-ice algal spatial variability as a complementary tool for sea-ice biogeochemical sampling using destructive ice core sampling.

Oceanographic factors determining the distribution of nutrients and primary production in the subpolar Southern Ocean

To investigate the spatial distributions and determinants of nutrient concentrations, we measured NO3−+NO2−, PO43−, and Si(OH)4 concentrations in the eastern Indian Ocean sector of the Antarctic Ocean (80 − 150°E, south of 60°S) between December 2018 and February 2019. In the region influenced by the Antarctic Circumpolar Current, nutrient concentrations were increased by nutrients supplied from the deep layer and by organic matter decomposition and remineralization within the seasonal pycnocline after the development of strong stratification. Strong stratification also enhanced phytoplankton growth and nutrient consumption by photosynthesis. In contrast, in the subpolar region, nutrient concentrations were increased by nutrients supplied by brine discharged during sea ice formation and decreased by dilution with sea ice meltwater. Although high salinity in the surface and subsurface layers corresponded well to upwelling areas around subpolar subgyres, high salinity was not necessarily correlated with nutrient concentrations. We estimated primary production both from in situ nutrient data and from satellite-acquired chlorophyll-a data. According to both estimation methods, primary production was high in the subpolar region, especially around 120 − 130°E. However, nutrient-based estimation also showed high production in coastal areas where, because of sea ice and cloud cover, estimation based on satellite data was not possible. To understand primary production in seasonal ice areas, the best estimation method should be selected for the research goals or multiple methods should be used in combination.

Characteristics of Runoff Components in the Mingyong Glacier Basin, Meili Snow Mountains

As an important hydrological ecosystem component, the glacier basin has great significance for climate and environment, and it is also linked to regional water sustainability. In this paper, the sampling and isotope analysis of glacial ice, ice-melt water, river water (river midstream and river downstream), groundwater (spring), and precipitation were carried out in a hydrological year of the Mingyong Glacier basin, which is located at the Meili Snow Mountains, Southeastern Tibetan Plateau. At the same time, the hydrograph separation of the recharge sources of the lower mountain pass is studied. The results show that the range of δD, δ18O, and d-excess (deuterium excess) in natural water bodies are significantly different, and the precipitation is the most obvious. The high values of δD and δ18O in the water samples all appeared in spring and summer, and the low values appeared in autumn and winter, while glacial ice showed opposite trends. Meanwhile, the local meteoric water line (LMWL) of the Mingyong Glacier basin is δD = 8.04δ18O + 13.06. The End-Member Mixing Analysis (EMMA) was adopted to determine the sources proportion of river water (river downstream) according to the δD, δ18O, and d-excess ratio relationships. The results showed that the proportion of ice-melt water, groundwater, and precipitation in the ablation period was 80.6%, 17.2%, and 2.2% as well as 19.2%, 73.1%, and 7.7% in the accumulation period, respectively. Ice-melt water has a higher conversion recharge rate to groundwater and indirectly recharges river water, especially in nonmonsoon seasons. In other words, the main recharge source of river water in the lower reaches of the Mingyong Glacier basin during the ablation period is ice-melt water. In the accumulation period, the main recharge source of river water in the lower reaches of the Mingyong Glacier basin is groundwater, while nearly half of the recharge of groundwater comes from ice-melt water. Therefore, regardless of the ablation period or the accumulation period, ice-melt water is sustainable and important to this region.

The effect of freeze-thaw action on the dynamic change of supra-permafrost water sources: A stable isotope perspective

Due to the continuous degradation (gradual thawing) of permafrost, supra-permafrost water has become an important component of runoff that occurs in cold regions. However, current research has only focused on the amount of water provided by permafrost, and little has been reported regarding the source and formation mechanisms of supra-permafrost water. Due to the difficulty of observation and sampling in cold regions and insufficient data accumulation, model simulations face various difficulties in regard to solving problems related to hydrological processes. Considering the advantages of stable isotope tracer methods in hydrology, the source of supra-permafrost water in Qilian Mountain was analyzed based on 1,840 samples, and the source of supra-permafrost water was determined by end-member mixing analysis (EMMA). Negative line-conditioned excess (lc-excess), lower slope, and particularly the negative intercept of the evaporation line (EL) indicates strong evaporation effects on supra-permafrost water. Remarkably, the evolutionary process, influencing factors, and relationship with other water bodies all indicate that supra-permafrost water is replenished by precipitation, ground ice meltwater, and snow meltwater. The results indicated that from May to October, the contributions of precipitation to the supra-permafrost water were 79%, 83%, 90%, 84%, 87%, and 83%, respectively. Snow meltwater contributed 11%, 13%, 10%, 16%, 11%, and 9%, respectively. Permafrost degradation impacts the water cycle and can increase the minimum monthly runoff and increase groundwater storage. To mitigate the effects of this change, monitoring and early warning systems are essential for detecting signs of permafrost degradation in a timely manner so that appropriate measures can be taken. This may involve the use of remote-sensing technologies, sensor networks, and other methods for real-time monitoring. Establishing mechanisms for sharing information with the relevant departments is crucial. The research results provide scientific and technological support and aid in decision-making to mitigate the negative effects of continuous permafrost degradation in a changing environment.

The roles of river discharge and sea ice melting in formation of freshened surface layers in the Kara, Laptev, and East Siberian seas

Wide areas of the Siberian Arctic shelf are covered by freshened surface water layers, which are among the largest in the World Ocean. River discharge is the main freshwater source for formation of these layers; therefore, they are commonly referred to as river plumes (the Ob-Yenisei plume in the Kara Sea and the Lena plume in the Laptev and East Siberian seas). The contribution of sea ice meltwater (SIM) to the Ob-Yenisei and Lena plumes is pointed out to be small, albeit its actual volume remains unknown. In this study, we use a novel dataset of satellite-derived sea ice thickness in the Arctic Ocean during the melt period to quantify the annual volume of SIM, which was received by the Ob-Yenisei and Lena plumes during 2012–2020. We reveal that SIM is a significant source for the Lena plume providing, on average, 20% of total annual freshwater content. Moreover, the share of SIM in the Lena plume shows large inter-annual (14%–29%) variability, i.e., during certain years, SIM provides almost one-third of freshwater volume of the Lena plume. This variability is governed by inter-annual variability of ice thickness, as well as seasonal variability of sea ice melting conditions. Conversely, the contribution of SIM to the Ob-Yenisei plume is relatively low (8% on average), and its total annual share varies from 6% to 11% during the study period. This difference is mainly caused by significantly smaller area of the Ob-Yenisei plume as compared with the Lena plume. The forecasted earlier onset of ice melting in the Arctic Ocean in future decades due to climate change could decrease the contribution of SIM to the Ob-Yenisei plume, whereas its influence on the Lena plume remains unclear.

A gravity-induced desalination technology effectively improving the freshwater production efficiency of freeze desalination

Low desalination efficiency and water production efficiency limit the commercial application of freeze desalination (FD) technology. In this study, three freezing temperatures were set to carry out single-stage progressive freezing desalination of brackish water in southern Xinjiang, China. The ice were melted using conventional methods and gravity-induced desalination (GD), and the salt migration law during the icing and melting process was studied. The effect of GD technology on the improvement of the output of frozen desalinated produced water was quantitatively analyzed using scenario simulation. Experimental results showed that salts accumulated towards concentrated water during FD process. The ice total dissolved solids (TDS) increased with decreasing freezing temperature, which was linearly and positively correlated with the raw water TDS. GD efficiency was significantly affected by the salt concentration of ice crystals. In the first stage (the first 450 mL), ice-melt water was salt explosive dissolution, with salt drained mass accounted for more than 85% of the total salt mass. During GD process, exponential decay of ice-melt water TDS (TDSI) was observed with increasing ice-melt water amount. Through the simulation of the two exponential equation scenarios, it was found that Scenario II (mixed water TDSI as the target value) had significantly higher water yield and production rate than Scenario I (TDSI as the target value), with an increase of more than 23%. The algebraic relationship between TDSI of mixed water and the amount of ice-melt water was derived. GD technology can effectively improve the freshwater output efficiency of the FD process, which is manifested by the fact that the ice crystals of the FD process cannot produce freshwater using conventional melting. Scenario II can produce freshwater as high as 69.83% of the total amount of the GD ice-melt water. The GD technology performed increased multiplicatively in WPdv (decrease in water production) and WPRdv (decrease in water production rate) when the TDSI of the mixed water demanded by the user was low. When FD and GD are combined to desalinate salt water, lowering the freezing temperature can significantly increase the freshwater yield, breaking the limitation of freezing temperature for FD. Therefore, an automated, energy-saving freeze desalination-gravity desalination device capable of realizing the collection of the product water according to the users' needs was conceptualized. This study provides new ideas and algorithms for accurately assessing the efficiency of water production in the combined desalination of saltwater by FD and GD.

Influence of Physical Factors on Restratification of the Upper Water Column in Antarctic Coastal Polynyas

AbstractAntarctic coastal polynyas are hotspots of biological production with intensive springtime phytoplankton blooms that strongly depend on meltwater‐induced restratification in the upper part of the water column. However, the fundamental physics that determine spatial inhomogeneity of the spring restratification remain unclear. Here, we investigate how different meltwaters affect springtime restratification and thus phytoplankton bloom in Antarctic coastal polynyas. A high‐resolution coupled ice‐shelf/sea‐ice/ocean model is used to simulate an idealized coastal polynya similar to the Terra Nova Bay Polynya, Ross Sea, Antarctica. To evaluate the contribution of various meltwater sources, we conduct sensitivity simulations altering physical factors such as alongshore winds, ice shelf basal melt, and surface freshwater runoff. Our findings indicate that sea ice meltwater from offshore is the primary buoyancy source of polynya near‐surface restratification, particularly in the outer‐polynya region where chlorophyll concentration tends to be high. Downwelling‐favorable alongshore winds can direct offshore sea ice away and prevent sea ice meltwater from entering the polynya region. Although the ice shelf basal meltwater can ascend to the polynya surface, much of it is mixed vertically over the water column and confined horizontally to a narrow coastal region, and thus does not contribute significantly to the polynya near‐surface restratification. Surface runoff from ice shelf surface melt could contribute greatly to the polynya near‐surface restratification. Nearby ice tongues and headlands strongly influence the restratification through modifying polynya circulation and meltwater transport pathways. Results of this study can help explain observed spatiotemporal variability in restratification and associated biological productivity in Antarctic coastal polynyas.

Climatic and anthropogenic impacts on the water balance of Issyk-Kul Lake through its main catchments

Lake Issyk-Kul is an endorheic lake in arid Central Asia that is vital to the region's ecological sustainability and socio-economic development. Climate change and anthropogenic water consumption led to fluctuations in the lake's water level, which affected the water resource. The goal of this study was to examine the impacts of climate change and human activities on the Issyk-Kul water balance by combining the Coupled Model Intercomparison Project Phase 6 (CMIP6) scenarios with hydrological modeling. The Soil and Water Assessment Tool (SWAT) model was used to incorporate signals of future precipitation and temperature changes. According to the scenarios, the total discharge of the three catchments showed an overall increasing trend with a maximum value of 28.02%. The snow and ice-melt water from March to August was revealed, and the increasing trends only occurred from March to May, with the snow and ice melting peak variations ranging from 0.5% to 2%. The high increase in change appeared in northern catchment of the lake. There was an exceptional upward precipitation trend over the northern catchment, with annual increases ranging from 0.7 to 14.5%, and an average annual temperature of 1.72°C. With slight similarities, the total runoff would increase for all catchments, with an average annual value of 10.6%. The northern catchment was significantly more sensitive to precipitation and warming than the southeastern catchments. Under land use land cover change, average annual discharge decreased with agricultural expansion, with discharge differences ranging from −0.005 to −1.06 m3/s. The findings are useful for decision-makers addressing the challenges of climate change mitigation and local water resource management.

Rock and ice avalanche-generated catastrophic debris flow at Chamoli, 7 February 2021: New insights from the geomorphic perspective

Within mountainous landscapes neighboring glaciers, slope instabilities and consequent catastrophic mass flows are vital processes on Earth's surface, which have been of increasing interest for decades. These events commonly exhibit large volume, high velocity, and high mobility. Recently, a catastrophic debris flow occurred in India on 7 February 2021, which unfortunately claimed 70 lives and left 134 people missing. The failed mass comprises 80 % rock debris and 20 % glacier ice. Our remote sedimentological investigation of remnant deposition shows clear evidence of wet granular flow in upper Ronti Gad valley, which doesn't support the previous interpretation of immediate melting of the failed 20 % ice mass during the falling and impacting process. We further utilized the superelevation phenomenon to back-calculate the velocity downstream of the impact zone, and estimated the peak discharge, which is verified by field-documented data. Our results revealed an initial waning trend of rock and ice mass flow. As it entered the narrow valley of the lower Ronti Gad River, the extensive material erosion resulted in three-fold flow enlargement, which gave rise to a maximal peak discharge of up to 48–54 × 104 m3/s. The transition from granular flow to debris flow occurred in the 2-km-long channel downstream of the Ronti Gad-Rishigangga confluence. The sediment deposition of 4.8 × 104 m3 and the incorporation of stream water in this zone have dominated the rheologic transition. We inferred that the intense erosion of erodible sediment due to topographic constraint plays an essential role in maintaining the mobility of the flow. Therefore, the effect of glacier ice meltwater on high mobility may be overestimated. As long as the granular flow can access the stream water in major rivers, flow transformation can easily happen because of sufficient water supply in the channel. The valley morphology in the proglacial region is commonly featured by the shift from an upstream U-shaped valley carved by glacier erosion into a downstream fluvial-erosion-dominated V-shaped valley. This geomorphic setting of glaciated tributary favors the long-distance run-out of rock and ice avalanche.