Abstract Experimental figures for the solid-liquid free energy, γSL, have been obtained for white phosphorus, for seven organic substances and for ice-water-sodium chloride systems having salt concentrations in the melt of 0 to 1 mol kg−1. The present work utilized observations made of grain-boundary grooves at solid-liquid interfaces in thin specimens; the latter were held in glass cells subjected to a temperature gradient. The groove shapes were characterized by employing the analysis of Nash and Glicksman in conjunction with electrical analogue models of heat flow in the specimen systems. In the case of the non-aqueous systems the interfacial energies obtained—expressed in mJm−2—were: white phosphorus, 12± 2; naphthalene, 61± 11; diphenyl, 50± 10; succinonitrile, 28± 4; camphene, 6± 1; ethylene dibromide, 35± 7; benzene, 44± 10; carbon tetrabromide, 10 to 20. In the case of the ice-water-sodium chloride system γSL, was found to vary roughly linearly with solute concentration and was 58± 15 mJm−2 for a salt concentration in the melt of 1 mol kg−1, as compared to 44± 10 mJm−2 for pure ice-water. The energies obtained for the aqueous systems relate to planes containing the c axis of ice. In most of the systems studied γSL was isotropic, but in the cases of naphthalene and diphenyl it was anisotropic to the extent of about 20%. In the case of the non-aqueous systems the interfacial energies obtained—expressed in mJm−2—were : white phosphorus, 12± 2; naphthalene, 61± 11; diphenyl, 50± 10; succinonitrile, 28± 4; camphene, 6± 1; ethylene dibromide, 35± 7; benzene, 44± 10; carbon tetrabromide, 10 to 20. In the case of the ice-water-sodium chloride system γSL, was found to vary roughly linearly with solute concentration and was 58± 15 mJm−2 for a salt concentration in the melt of 1 mol kg−1, as compared to 44± 10 mJm−2 for pure ice-water. The energies obtained for the aqueous systems relate to planes containing the c axis of ice. In most of the systems studied γSL was isotropic, but in the cases of naphthalene and diphenyl it was anisotropic to the extent of about 20%.