Hydrothermal-magmatic Systems Research Articles

Formation conditions and geochemistry of the Tütün Tepeleri (Baskil-Elazig/Türkiye) Fe-oxide-Cu-Au (IOCG) mineralization

The Tütün Tepeleri Fe-Oxide-Cu-Au (IOCG) mineralization is located in the Eastern Taurus Mountains (Baskil-Elazığ/Turkey) and it is associated with Baskil magmatites (diorite, gabbro and tonalite) cut by Late Cretaceous Bilaser Tepe magmatites (quartized diorite, granite, granodiorite, tonalite porphyry, monzosyenite, monzonite, aplite and diorite porphyry). Baskil Magmatites are Coniacian-Santonian (82–86 Ma), calc-alkaline in character and I-type. Bilaser Tepe Magmatics are Campanian (73–74 Ma) and represent an extensional environment after the collision of oceanic arc and the Taurus platform. In this study, the Sodic-calcic alteration zone in the Tütün Tepeleri region, which was determined as Porphyry type mineralization by different researchers, was determined for the first time and the mineralizations were evaluated in terms of Fe-Oxide-Cu-Au (IOCG) deposits. Three types of alteration zones have been identified in the region, including the sodic-calcic alteration zone. These are sodic-calcic (tremolite-actinolite, albite, epidote, chlorite, magnetite), potassic (biotite, quartz, chlorite, K-feldspar, anhydrite) and sericitic (sericite, carbonate, quartz, chlorite, illite) alterations. Sodic-calcic alteration is more widespread in the region than >1 km2, reaches thicknesses of 500 m, and is occasionally overlain by potassic alterations, just like similar Fe-Oxide-Cu-Au (IOCG) deposits in the world. Tütün Tepeleri mineralizations are in the form of rare magnetite veins with intense magnetite dispersion within the sodic-calcic alteration developed in diorites. Mineral paragenesis is in the form of magnetite, molybdenite, pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, hematite, malachite and azurite, and Ti content in magnetites is determined as 0.13–0.64%. Fe content is 20.13% on average. Formation temperatures in fluid inclusions measured in ore-bearing quartz veins are 320.3 °C on average and salinity is 11.32% NaCl equivalent on average. Isotope analysis results of these mineralizations show δ34Spyrite = 6–8.9; δ34Sc.pyrite = 3.8–5.5; δ18Oquartz was determined in the range of 10.8–13.2 and δD = (−37) – (−53). When the alteration types determined with isotope analysis results showing that the mineralization occurred in a magmatic-hydrothermal system, the low Ti content in the magnetites, the formation temperature and salinity values are evaluated together, it was anticipated that Tütün Tepeleri mineralization is an example of Fe-Oxide-Cu-Au (IOCG) deposits formed in a hydrothermal-magmatic system.

Detecting and recovering critical mineral resource systems using broadband total-field airborne natural source audio frequency magnetotellurics measurements

Airborne geophysical methods offer a substantial advantage compared to ground-based techniques in exploring territories of different sizes, ranging from entire metallogenic provinces to the deposit scale, including those hosting critical minerals. An airborne method with measurements of natural magnetic field variations, known as audio frequency magnetotellurics (a passive field method), significantly increases the depth of investigation and expands the resistivity detection range compared with some controlled-source primary-field methods. We describe the technical solutions used in an airborne electromagnetic passive system with a mobile sensor of the total magnetic field variations and the stationary sensor of electric field variations, and its applications to recovering the complex geology of hydrothermal-magmatic systems often associated with critical minerals. The system’s ability to explore depths, typically beginning from the near-surface and down to 1–2 km, by recording responses in three orthogonal inductive coils over a broad bandwidth from 22 Hz to 21,000 Hz allows for mapping resistivities across a broad range. This capability is crucial for obtaining more comprehensive exploration models. Field case studies of the natural field system include application in exploring for unconformity uranium mineralization, along with other associated minerals, epithermal gold and polymetallic-bearing structures, and ferromanganese and polymetallic deposits formed in a continental rift valley. An extra case study involving kimberlites was incorporated as a proven example of the natural field system’s capability in conducting near-surface and deep investigations. The case histories illustrate the airborne natural electromagnetic field technology capabilities in recovering geoelectric models and their specific patterns.

Myauchan Ore Field (Northeastern Asia), an Example of Weakly Eroded Ag–Pb–Zn Volcanoplutonic Mineralization

Abstract —The Myauchan ore field located in the Omsukchan zone of the Okhotsk–Chukotka Volcanic Belt is described. The Korennoe and Malyutka Ag–Pb–Zn ore occurrences forming this field are localized at the center of anticlinal fold of NW strike made up of Upper Triassic carbonate-terrigenous deposits intruded by stock-like bodies and dikes of Upper Cretaceous andesite, monzodiorite, granite-porphyry, and rhyolite-porphyry. Sulfide–carbonate–fluorite–quartz veins and vein–veinlet zones with arsenopyrite, pyrite, sphalerite, galena, chalcopyrite, and Ag-tetrahedrite are localized both in intrusions and in terrigenous strata. The field bears As–Sb–Ag–Pb–Au–Bi–Cu–Zn–W mineralization. Study of fluid inclusions and REE and ore element patterns show that the field ores formed from chloride solutions with the participation of surface waters in hydrothermal-magmatic system under epithermal conditions. The ores were deposited from solutions with TDS = 0.5–9.0 wt.% NaCl equiv. in the temperature range 106–287 ºC. The ores containing ca. 70 ppm Ag and up to 1.2% Pb formed through boiling-off of solutions enriched in iron salts. The ores with Ag < 7 ppm and Pb ≤ 25 ppm were generated from diluted hydrothermal solutions with predominant sodium salts and potassium admixture. Mineralization of the Myauchan ore field marks the upper level of the Ag–Pb–Zn ore system similar to the Gol’tsovoe deposit.

Sulfur origin and flux variations in fumarolic fluids of Vulcano Island, Italy

A sharp increase in volatiles, especially SO2 fluxes from the solfataric plume and diffuse CO2 from the soils of the La Fossa crater area, started in June 2021, and subsequently from the Levante Bay area, suggests renewed unrest at Vulcano Island, Italy. This event has encouraged monitoring activities and stimulated new research activities aimed at understanding the recent evolution of the volcanic system. In this study, the chemical and isotopic composition of fumaroles, thermal waters, and soil gases from the main degassing areas of Vulcano Island with a special focus on sulfur isotopes, are used to investigate the fluid transfer mechanism inside the volcano. Sulfur is one of the most abundant volatile elements present in magmas and volcanic fluids from the La Fossa crater, where it mostly occurs as SO2 and H2S at variable relative concentrations depending on oxygen fugacity and temperature. The isotope composition and the chemical ratio of sulfur species depict a complex hydrothermal-magmatic system. In addition, we utilize the installed SO2 monitoring network that measures the total outgassing of SO2 with the UV-scanning DOAS technique. The SO2 fluxes from the La Fossa crater fumaroles, coupled with the SO2/CO2 and SO2/H2O ratios, were measured to evaluate the total mass of fluids emitted by the shallow plumbing system and its relationship with the status of volcanic activity. Combining the whole chemical composition of fumaroles analyzed with a discrete, direct sampling of high-temperature fumaroles located on the crater summit, the output of discharged water vapor has been estimated (5,768 t·d−1). On the basis of the water output, we estimated the total thermal energy dissipated by the crater during the last enhanced degassing activity (167 MW). This strong and sharp increase in energy observed during the current crisis confirms the long-growing trend in terms of mass and energy recorded in recent decades, which has brought the surface system of Vulcano Island to a critical level that has never been recorded since the last eruptive event of 1888–91.

Genesis of the Questa Mo Porphyry Deposit and Nearby Polymetallic Mineralization, New Mexico, USA

Abstract The Oligocene Latir magmatic center in northern New Mexico is an exceptionally well exposed volcano-plutonic complex that hosts a variety of magmatic-hydrothermal deposits, ranging from relatively deep, F-rich porphyry Mo mineralization to shallower epithermal deposits. We present new whole-rock chemical and isotopic data for plutonic rocks from the Latir magmatic center, including extensive sampling of drill core samples of intrusive rocks from the Questa porphyry Mo deposit. These data document temporal chemical trends of porphyry-related mineralization that occurred after caldera-forming magmatism and during postcaldera batholith assembly. Silicic magmas were generated multiple times throughout the history of the Latir magmatic center, but few are associated with the formation of a mineral deposit. Whole-rock trace element ratios and Sr, Nd, and Pb isotope compositions vary throughout the protracted history of silicic magmatism. The caldera-forming ignimbrite and early phase of postcaldera intrusions are unmineralized, more enriched in high field strength elements, and generally contain less radiogenic Sr and Pb and more radiogenic Nd than later intrusions. The Questa porphyry Mo deposit formed immediately after the most isotopically primitive phase of the batholith was assembled, ruling out simple reworking of juvenile mantle-derived crust as the source for mineralizing magmas. Rhyolite dikes associated with polymetallic sulfide deposits intruded ~800 k.y. after Mo mineralization, and Nd isotope data indicate that these dikes are associated with different batches of magma and are unrelated to the Mo-mineralizing intrusions at the Questa mine. Together, these data indicate that the source of magmas changed significantly throughout the 10-m.y. history of the magmatic center. We assess multiple genetic models for porphyry-related magmatism against this data set, favoring models with discrete periods of magma genesis from a deep hybridized zone in the lower crust giving rise to the punctuated periods of mineralization. These observations suggest that the formation of mineral deposits within a central magmatic locus is likely the result of the piecemeal assembly of individual hydrothermal-magmatic systems, and that distal and younger polymetallic mineralization commonly observed near known porphyry deposits represents decoupled processes.

EVALUATION OF GEOTHERMAL RESERVOIR CONDITIONS BASED ON WELL PADS GEOCHEMICAL DATA IN LX GEOTHERMAL FIELD

The research was conducted at the Geothermal Company Energy Lx Area. The research area includes three well pads of geothermal power plants, namely X1, X2, and X3, which are stratigraphically composed of quaternary volcanic rocks. Based on the geochemical data of the well pad, it shows that the chloride type fluid is in equilibrium/partial equilibrium with the reservoir temperature in the range of 230 – 300°C from the silica and Na-K geothermometer analysis. The geothermal system in the research area is a hydrothermal magmatic system with two-phase fluid dominated by water. Evaluation of reservoir conditions from monitoring the X3 well pad shows a decrease in temperature for the last 3 years from 320°C in 2018 to 290°C in 2020. Graphical analysis of several chemical elements including Ca, Cl, SiO2, Boron and HCO3 shows a trend with the same pattern on several elements/compounds so it can interpret that there are no mixing process occurs in the reservoir, especially mixing with drill pipe wall cement or groundwater. Utilization of two-phase geothermal fluid in the Lx Geothermal Field produces electricity with a capacity reaches more than 100 MW and is still being developed in several areas that are currently in the geothermal geochemical exploration stage.

Identification of Ruptures and their Interaction with Hydrothermal–Magmatic Systems on Northern Paramushir Isl. (Kuril Islands, Russia): 3D Modeling of Tectonic Fragmentation

Correlation of ruptures with volcanic activities, and related hydrothermal-magmatic systems are studied. In our research we used a set of methods that included analysis of satellite data, identification lineaments and voxel modeling of crustal fragmentations. The main geological structure that ensures transportation of thermal energy in the hydrothermal-magmatic systems in the northern part of Paramushir Isl., and the a sill-dike complex associated with the system of north-eastern and sub-latitudinal fractures is considered. The formation of the northeast oriented ruptures is perpendicular to stretch of the submerged plate and reflects the stress regime in the island-arc setting. In the north of Paramushir Isl. ruptures with sub-latitudinal directions are recorded. The ruptures are located on the extension of the regional fault which is perpendicular to the main axis of the back-arc Kuril basin.

First gas and thermal measurements at the frequently erupting Gamalama volcano (Indonesia) reveal a hydrothermally dominated magmatic system

The first gas and thermal measurements at the summit of the Gamalama volcano indicate that the system is dominated by hydrothermal processes. This is highlighted by the prevalence of H2S over SO2 (H2S/SO2 = 2–8), a high CO2/SO2 ratio (76–201), and a low heat transfer (3.0 MW) to the surface. A relative variation in gas composition is observed along the degassing fracture zone, possibly due to partial S scrubbing. Despite this surface hydrothermal signature, the system exhibits high gas equilibrium temperatures (425–480 °C), indicating that fluids are not exclusively derived from a boiling hydrothermal aquifer, but also sourced by cooling and crystallizing basaltic magma at deep that continues to inject magmatic fluids into the system. This hydrothermally dominated activity on Gamalama possibly persisted over the last two decades, during which a high number of eruptive events were witnessed. The period coincides with the opening of large fractures at the summit that subsequently shifted the volcanic activity from the crater center to the peripheral fractures zones. These fractures that possibly developed in response to the regional geodynamics, have weakened the hydrothermal seal, allowing the pressure developed by the hydrothermal-magmatic system and promoted by the high annual rainfall, to rapidly exceeds the tensile strength of the seal leading to the numerous phreatic eruptions.

High temperature glacial meltwater–rock reaction in the Neoproterozoic: Evidence from zircon in-situ oxygen isotopes in granitic gneiss from the Sulu orogen

To seek the occurrence of negative δ18O magmas in the Neoproterozoic, we conducted in-situ zircon O isotope analysis and U–Pb dating for granitic gneiss from the northeastern Sulu orogen, east-central China. Zircon U–Pb dating yields protolith ages of 753±15Ma to 780±13Ma and metamorphic ages of 209±3 to 244±7Ma. The Neoproterozoic cores with concordant U–Pb ages exhibit a wide δ18O range from −11.0‰ to 5.8‰, which is nearly the same as those for cores with discordant U–Pb ages. The Triassic rims of some samples have homogeneous δ18O values of around −10‰ whereas the rims of the other samples show a wider range from −9.8‰ to 5.0‰. The δ18O values as negative as −11.0‰ for zircons with concordant Neoproterozoic U–Pb ages are reported for the first time, representing the primary record of negative δ18O magma in the Neoproterozoic. The continental subduction-zone metamorphism in the Triassic did not erase the abnormal δ18O record in the protolith zircon cores despite metamorphic dehydration and partial melting under high-pressure to ultrahigh-pressure conditions. A conservative estimate suggests that the hydrothermal fluid reacted with the rocks should have δ18O values lower than −9.2‰, corresponding to the meteoric water in cold paleoclimate or the meltwater of local continental glaciation. The spatial variation in the O isotope compositions of Neoproterozoic zircons is a manifestation of the O isotope heterogeneity in the extinct hydrothermal-magmatic system. The hydrothermal alteration during the Neoproterozoic was incongruent, which was lately recorded by the wide range of δ18O values in the metamorphic zircons of Triassic age. The extensive O isotope exchange between the surface water and the deep rock requires high temperature and high water–rock ratios in continental rifting zones. This is ascribed to Neoproterozoic splitting of the South China Block from the Rodinia supercontinent.

Variation in the physical and mechanical properties of rocks: The North Paramushir hydrothermal magmatic system, Kuril Islands

This study is concerned with structural and mineralogic transformations and changes in the physical and mechanical properties of volcanogenic sedimentary rocks in the North Paramushir hydrothermal magmatic system as a result of the interaction with thermal waters of various compositions and origins. We identified the following hydrothermal metasomatic facies that developed in tuffites and tuffs: opalites (monoopalite, opal–clay, and opal–alunite), as well as low- and moderate-temperature propylites. We show the position of each new facies in the structure of the hydrothermal magmatic system. We obtained correlative relationships of the physical and mechanical properties of the rock to the intensity and character of secondary alteration. It is pointed out that all of these rocks obey a common trend in the interrelationships between their properties, which may provide evidence of a common origin and progressive direction of hydrothermal processes in the interior of the North Paramushir system.

The mangazeya Ag–Pb–Zn vein deposit hosted in sedimentary rocks, Sakha-Yakutia, Russia: Mineral assemblages, fluid inclusions, stable isotopes (C, O, S), and origin

The succession of mineral assemblages, chemistry of gangue and ore minerals, fluid inclusions, and stable isotopes (C, O, S) in minerals have been studied in the Mangazeya silver–base-metal deposit hosted in terrigenous rocks of the Verkhoyansk Fold–Thrust Belt. The deposit is localized in the junction zone of the Kuranakh Anticlinorium and the Sartanga Synclinorium at the steep eastern limb of the Endybal Anticline. The deposit is situated at the intersection of the regional Nyuektame and North Tirekhtyakh faults. Igneous rocks are represented by the Endybal massif of granodiorite porphyry 97.8 ± 0.9 Ma in age and dikes varying in composition. One preore and three types of ore mineralization separated in space are distinguished: quartz–pyrite–arsenopyrite (I), quartz–carbonate–sulfide (II), and silver–base-metal (III). Quartz and carbonate (siderite) are predominant in ore veins. Ore minerals are represented by arsenopyrite, pyrite, sphalerite, galena, fahlore, and less frequent sulfosalts. Three types of fluid inclusions in quartz differ in phase compositions: two- or three-phase aqueous–carbon dioxide (FI I), carbon dioxide gas (FI II), and two-phase (FI III) containing liquid and a gas bubble. The homogenization temperature and salinity fall within the ranges of 367–217°C and 13.8–2.6 wt % NaCl equiv in FI I; 336–126°C and 15.4–0.8 wt % NaCl equiv in FI III. Carbon dioxide in FI II was homogenized in gas at +30.2 to +15.3°C and at +27.2 to 29.0°C in liquid. The δ34S values for minerals of type I range from–1.8 to +4.7‰ (V-CDT); of type II, from–7.4 to +6.6‰; and of type III, from–5.6 to +7.1‰. δ13C and δ18O vary from–7.0 to–6.7‰ (V-PDB) and from +16.6 to +17.1 (V-SMOW) in siderite-I; from–9.1 to–6.9‰ (V-PDB) and from +14.6 to +18.9 (V-SMOW) in siderite-II; from–5.4 to–3.1‰ (V-PDB) and from +14.6 to +19.5 (V-SMOW) in ankerite; and from–4.2 to–2.9‰ (V-PDB) and from +13.5 to +16.8 (V-SMOW) in calcite. The data on mineral assemblages, fluid inclusions, and ratios of stable isotopes allow us to speak about the formation of the Mangazeya deposit in relation to the activity of the hydrothermal–magmatic system. The latter combines emplacement of subvolcanic granitic stocks and involvement of fluids variable in salinity and temperature in ore deposition zone. The fluids released from crystallizing felsic magma and were formed in a convective cell by heating of meteoric and marine waters. The mechanism of ore deposition is related to phase separation (boiling) and mixing of fluids.

Compositional spatial zonation and 2005–2013 temporal evolution of the hydrothermal-magmatic fluids from the submarine fumarolic field at Panarea Island (Aeolian Archipelago, southern Italy)

The November 2002 submarine gas blast at Panarea Island (Sicily, southern Italy) was an unexpected reactivation event able to locally affect this hydrothermal-magmatic system whose the youngest eruptive products were dated at 20,000±2000years BP. The presence of magmatic gases (SO2 and HF) in the fumarolic gas discharges after the violent exhalative event was indicative of a magmatic input that temporary displaced the hydrothermal system. A few months later these acidic gases were indeed not detected in any of the studied fumaroles. Nevertheless, new geochemical data obtained by periodical sampling up to June 2013 suggest that the chemical–physical conditions of the hydrothermal-magmatic system at Panarea were not completely restored with respect to the geochemical data obtained in the early nineties. Thus, the 2002 gas burst has unequivocally caused a permanent modification to the fluid circulation system feeding the submarine fumaroles. In addition, strong compositional differences were observed by the 46 gases collected in 2012–2013 from submarine fumaroles located in different sites of the studied area, allowing to distinguish three different groups of fumaroles: A) H2- and CO-rich gases, which also show relatively low Ar concentrations, B) H2S-rich gases, having variable CO/CH4 ratios, and C) Ar-rich gases, having relatively low H2 concentrations. Gases from group A are distributed along NW- and NE-trending fault systems, whereas those of groups B and C discharge at increasing distance from the intersection of the two fault systems, indicating a spatial and compositional control by the local tectonic setting. The H2/CO ratios of groups A and B gases are significantly lower than those measured prior to 2012. This would imply an increase of gas pressure at depth, possibly caused by continuous addition of gas and energy from the magmatic source to the hydrothermal reservoir. Continuation of this process may lead to the occurrence of gas burst events in the next future, a hypothesis that is supported by the strong ongoing degassing activity at the surface notwithstanding a decrease of temperatures at depth. A geochemical, seismological and ground deformation monitoring of the Panarea submarine fumarolic field is highly recommended to obtain precursory signals of new strong degassing phenomena.

Uranium fluorides in hydrothermal-magmatic systems

Uranium fluorides in hydrothermal-magmatic systems

The influence of rheologic crustal properties of the crust on the location of ore-forming hydrothermal magmatic systems

Based on a comprehensive study of hydrothermal magmatic systems at island arcs and a review of available mechanisms that cause elasto-plastic deformation in rocks, we considered the conditions for interaction between a convective magmatic cell and a convective hydrothermal cell in different rheologic zones of the crust. Three models have been developed to describe the generation of hydrothermal circulation systems: (1) the magma chamber is localized in a plastic zone, (2) partial and (3) complete penetration of the chamber into a brittle crust. It is shown that the last of these models is highly consistent with the structure of presentday high-temperature hydrothermal magmatic systems at depths greater than 1.0–1.5 km and with the structure of Miocene to Pliocene ore-bearing volcano-plutonic complexes that are eroded to different depths in different geologic blocks within these complexes.

Patterns in the transformation of the composition and properties of volcanogenic rocks in hydrothermal-magmatic systems of the Kuril-Kamchatka island arc

Hydrothermal-magmatic systems of the Kuril-Kamchatka island arc were formed in Neogene-Quaternary volcanic rocks. Acting on host rocks, thermal waters induced their alteration and transformation into hydrothermal-metasomatic rocks, such as propylites, secondary quartzites, zeolitic rocks, argillic rocks, opalites, quartz-adularia metasomatites, etc. The dynamics of changes in rock properties during the hydrothermal process depends on a number of factors, including the features of primary rocks, temperature, pressure and composition of thermal fluids, fluid phase, fluid pH, and duration of fluid-rock interaction. Deep high-temperature fluids cause consolidation and hardening of the rocks, an increase in deformational properties, and a decrease in porosity and permeability, regardless of fluid composition. The chemical composition and acidity-alkalinity of thermal fluids have a significant influence on the alteration of rock properties during low-temperature hydrothermal processes.

Water–rock interaction in the magmatic-hydrothermal system of Nisyros Island (Greece)

In this work, we investigated the water–rock interaction processes taking place in the hydrothermal reservoir of Nisyros through both: (1) a review of the hydrothermal mineralogy encountered in the deep geothermal borehole Nisyros-2; and (2) a comparison of the analytically-derived redox potentials and acidities of fumarolic-related liquids, with those controlled by redox buffers and pH buffers, involving hydrothermal mineral phases. The propylitic zone met in the deep geothermal borehole Nisyros-2, from 950 to 1547 m (total depth), is characterised by abundant, well crystallised epidote, adularia, albite, quartz, pyrite, chlorite, and sericite–muscovite, accompanied by less abundant anhydrite, stilpnomelane, wairakite, garnet, tremolite and pyroxene. These hydrothermal minerals were produced in a comparatively wide temperature range, from 230 to 300 °C, approximately. Hydrothermal assemblages are well developed from 950 to 1360 m, whereas they are less developed below this depth, probably due to low permeability. Based on the R H values calculated for fumarolic gases and for the deep geothermal fluids of Nisyros-1 and Nisyros-2 wells, redox equilibrium with the (FeO)/(FeO 1.5) rock buffer appears to be closely attained throughout the hydrothermal reservoir of Nisyros. This conclusion may be easily reconciled with the nearly ubiquitous occurrence of anhydrite and pyrite, since R H values controlled by coexistence of anhydrite and pyrite can be achieved by gas separation. The pH of the liquids feeding the fumarolic vents of Stephanos and Polybote Micros craters was computed, by means of the EQ3 code, based on the Cl– δD relationship which is constrained by the seawater–magmatic water mixing occurring at depth in the hydrothermal–magmatic system of Nisyros. The temperature dependence of analytically-derived pH values for the reservoir liquids feeding the fumarolic vents of Stephanos and Polybote Micros craters suggests that some unspecified pH buffer fixes the acidity of these reservoir liquids at values of 4.72–4.85 and 4.88–5.23, respectively. Many of these pH values are lower than those expected for the full-equilibrium condition, although they are close to those of the reservoir liquids of Nisyros-1, 5.16, and Nisyros-2, 4.87. It is likely that this excess of acidity-producing species, chiefly CO 2, promotes release of Fe(II) and Fe(III) to the reservoir liquids through rock dissolution, permitting the attainment of redox equilibrium with the (FeO)/(FeO 1.5) rock buffer, as already suggested by the late Werner Giggenbach.

Melt inclusions in Cr-Spinels from the Fe-Ti oxide intrusive complexes of the central Atlantic: Key to understanding the physicochemical parameters of hydrothermal-magmatic systems in slow-spreading ocean ridges

Melt inclusions in Cr-Spinels from the Fe-Ti oxide intrusive complexes of the central Atlantic: Key to understanding the physicochemical parameters of hydrothermal-magmatic systems in slow-spreading ocean ridges

REE behavior in tin-bearing hydrothermal-magmatic systems (An example of deposits of the Far East)

REE behavior in tin-bearing hydrothermal-magmatic systems (An example of deposits of the Far East)

Geochemistry and origin of the ore-forming fluids in hydrothermal-magmatic systems in tectonically active zones

Data on fluid inclusions and stable isotope compositions (O, H, C, and S) in minerals have been summarized for large-and middle-scale mesothermal gold deposits (Nezhdaninsk, Berezovsk, Kochkar’, Svetlinsk, Darasun, and Maisk), cassiterite-silicate-sulfide deposits of Sikhote Alin (Solnechnoe, Arsen’evsk, and Vysokogorsk), vein silver-base metal deposits in the Southern Verkhoyansk region (Prognoz and Kupol’noe), and epithermal copper-bismuth-silver-base metal deposits of the Karamazar district in Tajikistan (Kanimansur, Tary Ekan, and Zambarak). It is shown that ores precipitated from fluids with salinity varying from brines (up to 60 wt % NaCl equiv) to dilute fluids (1–3 wt % NaCl equiv). As a rule, fluids of different compositions entered the hydrothermal-magmatic system. A fluid mixture of H2O-CO2-NaCl±CH4±N2 predominated in the orogenic (mesothermal) gold-bearing hydrothermal systems, with deposition of the final-stage gold-bearing sulfosalts from aqueous-salt fluid. Brines played a significant role in the formation of cassiterite-silicate-sulfide and vein silver-base metal deposits. The brines often coexisted with a low-density vapor-rich fluid at the ore deposition site. The obtained data suggest a predominant magmatic component in the hydrothermal-magmatic systems, with a significant contribution of meteoric waters.

Fluid density control on vapor-liquid partitioning of metals in hydrothermal systems

Abstract Hot aqueous fluids, both vapor and saline liquid, are primary transporting media for metals in hydrothermal-magmatic systems. Despite the growing geological evidence that the vapor phase, formed through boiling of magmatic ore-bearing fluids, can selectively concentrate and transport metals, the physical-chemical mechanisms that control the metal vapor-liquid fractionation remain poorly understood. We performed systematic experiments to investigate the metal vapor-liquid partitioning in model water-salt-gas systems H2O-NaCl-KCl-HCl at hydrothermal conditions. Measurements show that equilibrium vapor-liquid fractionation patterns of many metals are directly related to the densities of the coexisting vapor and liquid phases. Despite differences in the vapor-phase chemistry of various metals that form hydroxide, chloride, or sulfide gaseous molecules of contrasting volatile properties, water-solute interaction is a key factor that controls the metal transfer by vapor-like fluids in Earth's crust. These findings allow quantitative prediction of the vapor-liquid distribution patterns and vapor-phase metal transport in a wide range of conditions. Our density model accounts well for the vapor-brine distribution patterns of Na, Si, Fe, Zn, As, Sb, and Ag observed in fluid inclusions from magmatic-hydrothermal deposits. For Au and Cu, the partitioning in favor of the liquid phase, predicted in a sulfur-free system, contrasts with the copper and gold enrichment observed in natural vapor-like inclusions. The formation of stable complexes of Cu and Au with reduced sulfur may allow for their enhanced transport by sulfur-enriched magmatic-hydrothermal vapors.