Effect Of Hydrostatic Pressure Research Articles

The effect of hydrostatic pressure on invasive coronary pressure measurements: Comparison with [15O]H2O-positron emission tomography flow data.

Fractional flow reserve (FFR) has emerged as the invasive gold standard for assessing vessel-specific ischemia. However, FFR measurements are influenced by the hydrostatic effect, which might adversely impact the assessment of ischemia. This study aimed to investigate the impact of hydrostatic pressure on FFR measurements by correcting for the height and comparing FFR with [15O]H2O positron emission tomography (PET)-derived relative flow reserve (RFR). The 206 patients were included in this analysis. Patients underwent coronary computed tomography angiography (CCTA), [15O]H2O PET, and invasive coronary angiography with routine FFR in every epicardial artery. Height differences between the aortic guiding catheter and distal pressure sensor were quantified on CCTA images. An FFR ≤ 0.80 was considered significant. The study found a reclassification in 7% of the coronary arteries. Notably, 11% of left anterior descending (LAD) arteries were reclassified from hemodynamically significant to nonsignificant. Conversely, 6% of left circumflex (Cx) arteries were reclassified from nonsignificant to significant. After correcting for the hydrostatic pressure effect, the correlation between FFR and PET-derived RFR increased significantly from r = 0.720 to r = 0.786 (p = 0.009). The average magnitude of correction was +0.05 FFR units in the LAD, -0.03 in the Cx, and -0.02 in the right coronary artery. Hydrostatic pressure has a small but clinically relevant influence on FFR measurements obtained with a pressure wire. Correcting for this hydrostatic error significantly enhances the correlation between FFR and PET-derived RFR.

A CO-HSDT isogeometric analysis for free vibration of matrix cracked FG-GPLRC plates coupled with stationary fluid

This paper for the first time proposes an efficiently C0-higer order shear deformation theory (HSDT) and isogeometric analysis (IGA) for the free vibration analysis of matrix cracked functionally graphene nanoplatelets reinforced composite (FG-GPLRC) plate coupled with stationary fluid. This case represents essential components of sophisticated structures utilized in industries such as shipbuilding, nuclear, marine, and naval. The properties of the four GPLs distributions of FG-GPLRC are evaluated by using a combination of the modified Halpin-Tsai micromechanics model and the rule of mixtures, while the degraded stiffness of cracked layers is predicted by the self-consistent micromechanical (SCM) model. The fluid is assumed to be homogeneous, inviscid, incompressible and irrotational, so the free-surface waves and hydrostatic pressure effects on structures are neglected. The governing equation of motion is derived by the Hamilton's principle, where three different fluid-plate interaction systems are taken into consideration. After validating the proposed method against existing literature, the effect of various parameters such as crack density, interaction boundary conditions (IBC), fluid level, GPLs distribution pattern, total number of layers, and geometric parameter on the free vibration of matrix cracked FG-GPLRC plate are investigated. It is believed that the finding in this paper may be helpful for the accurate design and analysis of matrix cracked FG-GPLRC plate submerged in fluid.

Numerical prediction of beam capacity using the new constitutive model based on concrete biaxial behavior

The biaxial strength of concrete exhibits intriguing nonlinearity and scattering, posing challenges to the assessment of building structural safety. Experiments have confirmed that biaxial strength envelopes can manifest concave, quasi-linear, and convex shapes. Despite various empirical formulas being proposed to describe this behavior, they cannot be applied to finite element simulations due to the absence of a constitutive perspective. To study the mechanisms forming the shape of strength envelopes, a novel three-invariant model constitutive model is proposed, which reveals the characteristics of the envelopes resulting from the coupling effect of hydrostatic pressure and Lode angle. By adjusting the model parameters, it effectively describes concave, quasi-linear, and convex envelopes. The model's accuracy and compatibility were validated against experimental data spanning various concrete types, with compression strengths ranging from 19.29 to 96.5 MPa and tension-compression ratios form 0.056 to 0.095. To investigate how biaxial strength impacts the capacity of beams, numerical experiments were conducted on notched and intact beams based on the proposed model. The results underscored that beams prepared using concrete with convex envelopes exhibited higher capacity compared to those with quasi-linear envelopes. Therefore, conducting biaxial tension-compression experiments is recommended to accurately evaluate beam bearing capacity. The proposed model is expected to have further applications in the safety evaluation of building structures.

Pressure tuning of the Se-substituted BiS2-based superconductor LaO0.5F0.5Bi(S1−xSex)2

Abstract We report the effect of hydrostatic pressure on LaO0.5F0.5Bi(S 1 − x Se x )2 with chemical pressure applied to a conducting layer by means of electrical resistivity and ac-magnetic susceptibility measurements up to 2.5 GPa. We confirmed the bulk superconductive nature of the low superconducting (low-SC) and high superconducting (high-SC) phase using ac-magnetic susceptibility under hydrostatic pressure. The T c of the high-SC phase was observed to decrease with an increase in the Se substitution. The critical pressure P c shifted toward the higher P and the P-induced transition broadened with an increase in the Se content. The T c of the low-SC phase can be expressed by assuming an applied hydrostatic pressure of 0.75 GPa as the Se substitution of x = 0.1. The broad P c transition is likely to be ascribed to the inhomogeneity of the Se substitution.

Buckling and vibro-acoustic behavior analysis of laminated immersed cylindrical shells with hydrostatic pressure based on Chebyshev-Fourier spectral approach

The buckling and vibroacoustic behaviour of laminated cylindrical shell structures is vital for the safety and operational efficiency of underwater vehicles. This paper introduces a Chebyshev-Fourier spectral approach for the comprehensive analysis of buckling and vibro-acoustic behaviour in water-immersed laminated cylindrical shells under external hydrostatic pressure. The approach combines Chebyshev polynomials and Fourier series to approximate the displacement of shell and acoustic pressure of the fluid-structure-interaction (FSI) surface in cylindrical coordinates. An approximate solution is used in the axial direction, while an analytical solution is used in the circumferential direction, allowing for the analysis of different circumferential wave numbers n. The influence of external fluid pressure is characterized through the Helmholtz boundary integral equation, while the effect of hydrostatic pressure is deduced using linear elastic theory. From a theoretical derivation standpoint, hydrostatic pressure leads to a reduction in equivalent stiffness, while the external fluid contributes to an increase in the effective mass matrix. Validated against established literature analysis, the study finds that hydrostatic pressure decreases the natural frequencies, though the impact is less significant for lower circumferential wave numbers. For these lower wave numbers, the overall radiated sound power remains largely independent of external hydrostatic pressure, regardless of being in air or water. However, at higher circumferential wave numbers, the effect is more pronounced. This study not only advances the theoretical framework for analysing submerged cylindrical shells but also provides crucial insights into designing more robust structures for underwater applications.

A theoretical analysis of the effect of hydrostatic pressure on cerium oxide for renewable energy applications

The characteristics of cubic cerium oxide (CeO2) have been investigated using density functional theory (DFT) using the PBE-GGA exchange–correlation functional. This study mainly focused on the structural, elastic, and optoelectronic properties of the CeO2 under the application of external hydrostatic pressure. It is observed that lattice constants and volume tend to decrease with increasing pressure. Based on the observed trends in lattice constants variations, CeO2 exhibits compressibility at high-pressure conditions, although it remains structurally unchanged throughout the pressure range of 0 to 100 GPa. Applying pressure within the range of 0 to 100 GPa reveals a distinct characteristic associated with the emergence of electronic bandgap opening. The material displays an indirect energy bandgap, with its magnitude increasing from 2.659 eV to 4.055 eV under rising pressure. To deeply understand the impact of external pressure on the optical behaviour of CeO2, extensive investigation has been conducted on several optical parameters such as the dielectric function, refractive index, optical reflectivity, absorption coefficient, optical conductivity, and loss function throughout the energy range up to 50 eV. However, there is a tendency for optical parameters to show sharpening peaks that shift somewhat towards higher energies. Furthermore, we have also tested the impact of bandgap modulation induced in CeO2 by proposing a CsSnBr3-based solar cell with the One-Dimensional Solar Cell Capacitance Simulator software. Based on our findings, the use of cubic cerium oxide may find its potential to enhance the performance of optoelectronic and renewable energy devices.

Hydrostatic Pressure as a Tool for the Study of Semiconductor Properties-An Example of III-V Nitrides.

Using the example of III-V nitrides crystallizing in a wurtzite structure (GaN, AlN, and InN), this review presents the special role of hydrostatic pressure in studying semiconductor properties. Starting with a brief description of high-pressure techniques for growing bulk crystals of nitride compounds, we focus on the use of hydrostatic pressure techniques in both experimental and theoretical investigations of the special properties of nitride compounds, their alloys, and quantum structures. The bandgap pressure coefficient is one of the most important parameters in semiconductor physics. Trends in its behavior in nitride structures, together with trends in pressure-induced phase transitions, are discussed in the context of the behavior of other typical semiconductors. Using InN as an example, the pressure-dependent effects typical of very narrow bandgap materials, such as conduction band filling or effective mass behavior, are described. Interesting aspects of bandgap bowing in In-containing nitride alloys, including pressure and clustering effects, are discussed. Hydrostatic pressure also plays an important role in the study of native defects and impurities, as illustrated by the example of nitride compounds and their quantum structures. Experiments and theoretical studies on this topic are reviewed. Special attention is given to hydrostatic pressure and strain effects in short periods of nitride superlattices. The explanation of the discrepancies between theory and experiment in optical emission and its pressure dependence from InN/GaN superlattices led to the well-documented conclusion that InN growth on the GaN substrate is not possible. The built-in electric field present in InGaN/GaN and AlGaN/GaN heterostructures crystallizing in a wurtzite lattice can reach several MV/cm, leading to drastic changes in the physical properties of these structures and related devices. It is shown how hydrostatic pressure modifies these effects and helps to understand their origin.

The independent effects of hydrostatic pressure and hypercapnic breathing during water immersion on ventilatory sensitivity and cerebrovascular reactivity.

Head out water immersion (HOWI) induces ventilatory and hemodynamic changes, which may be a result of hydrostatic pressure, augmented arterial CO2 tension, or a combination of both. We hypothesized that the hydrostatic pressure and elevated CO2 tension that occur during HOWI will contribute to an augmented ventilatory sensitivity to CO2 and an attenuated cerebrovascular reactivity to CO2 during water immersion. Twelve subjects (age: 24±3 y, BMI: 25±3 kg/m2) completed HOWI, waist water immersion with CO2 (WWI+CO2), and WWI where a rebreathing test was conducted at baseline, 10, 30, and 60 minutes, and post. PETCO2, minute ventilation, expired gases, blood pressure, heart rate, and middle cerebral artery blood velocity were recorded continuously. PETCO2 increased throughout all visits (p£0.011), was matched during HOWI and WWI+CO2 (p³0.264), and was greater during WWI+CO2 vs. WWI at 10, 30, and 60 minutes (p<0.001). When HOWI vs. WWI+CO2 were compared, the change in ventilatory sensitivity to CO2 was different at 10 (0.59±0.34 vs. 0.06±0.23 L/min/mmHg, p<0.001), 30 (0.58±0.46 vs. 0.15±0.25 L/min/mmHg, p<0.001), and 60 minutes (0.63±0.45 vs. 0.16±0.34 L/min/mmHg, p<0.001), while there were no differences between conditions for cerebrovascular reactivity to CO2 (p³0.163). When WWI+CO2 vs. WWI were compared, ventilatory sensitivity to CO2 was not different between conditions (p³0.642), while the change in cerebrovascular reactivity to CO2 was different at 30 minutes (-0.56±0.38 vs. -0.30±0.25 cm/s/mmHg, p=0.010). These data indicate that during HOWI ventilatory sensitivity to CO2 increases due to the hydrostatic pressure, while cerebrovascular reactivity to CO2 decreases due to the combined effects of immersion.

Optical properties of a quantum dot confined in inverse square root truncated exponential potential under varied conditions of temperature, hydrostatic pressure, and electric/magnetic fields

In this study, we comprehensively investigate the effects of temperature, hydrostatic pressure, linear electric, and uniform magnetic fields on the electronic and optical properties of a quantum dot confined by an inverse square root truncated exponential potential. The bound state energy eigenvalues and corresponding normalized wave functions are calculated through the numerical solution of the Schrödinger equation using the Numerov method. We formulate the effective potential, which depicts the interaction of an electron with semiconductor atoms, as a function of external parameters, including temperature, hydrostatic pressure, and electric/magnetic fields. We elucidate how variations in the effective potential, induced by changes in these external parameters, affect electronic and optical observables.

Combined effects of high hydrostatic pressure and pulsed electric fields on quinoa starch: Analysis of microstructure, morphology, thermal, and pasting properties

The aim of this study was to evaluate the impact of non-thermal methods, using high hydrostatic pressure (HHP) and pulsed electric field (PEF), on the dual modification of quinoa starch and to analyze the microstructural, morphological, thermal, pasting, and texture properties. Starch was treated with HHP at 400 MPa for 10 min, while PEF was applied using voltages of 10 and 30 kV cm−1 for a total time of 90s. The modification techniques were effective in breaking down amylose molecules and amylopectin branches, where for the dual treatment, higher values of DP6–12 were found. The average diameter and gelatinization temperatures were elevated after HHP, thus forming clusters that require more energy for paste formation. The use of 30 kV cm−1 and 400 MPa (HP30) in starch facilitates the creation of new food products with better texture, stability and nutritional value, making them suitable for use in food emulsions and the cosmetics industry.

The effect of absorbed moisture and resin pressure on porosity in autoclave cured epoxy resin

AbstractOne of the main issues in epoxy‐based composite manufacturing is the formation of porosity derived from moisture absorption during storage and layup due to the high hydrophilicity of epoxy matrices. During the curing process, the presence of moisture and other volatile compounds can initiate the nucleation and growth of voids. In this study, the effect of both the initial water content absorbed in the uncured resin and the pressure on the porosity development in an epoxy resin was investigated. In particular, Kardos' and Ledru's models, aimed at predicting void formation in polymers, were applied to study the effect of different hydrostatic pressures in an epoxy resin during curing up to the gel point, after conditioning it at two different relative humidity levels, 50% and 95%. Subsequently, the porosity of the cured resin samples was quantified through density measurements. Comparative analysis of the microscopy images of cured samples and the predictions of both models revealed an overestimation of the final void sizes by both models, with the Kardos' model exhibiting a higher deviation. Additionally, a finite element model was employed to investigate the conditions leading to void formation, aiming to understand the factors influencing the porosity development and properly set the process parameters during composite manufacturing.Highlights Evaluation of the conditions leading to void growth in epoxy resin during curing Moisture sorption in uncured epoxy resin Effect of curing pressure on pore development Finite element analysis for void growth during resin curing

Analytical study on hybrid thrust foil bearing, structural characterization and measurement of static performance

This work presents a novel hybrid foil thrust bearing (HFTB) with an outer diameter of 154 mm, along with simulation and test results. The HFTB incorporates a high-pressure air/gas injection to the taper portion of the thrust foil bearing, boosting the hydrodynamic effect on the main bearing surface and hydrostatic load capacity at zero speed. The bearing has high load capacity, low power loss, and no friction/wear during startup and shutdown. Firstly, push-pull tests were conducted on a double-acting HFTB configuration to evaluate the nonlinear structural stiffness of the bump foil structure. The measured nonlinear stiffness model was adopted to predict the overall bearing performance under various speeds and loads. The simulation uses an advanced model which predicts the 2D plate top foil deflection with physical bump locations mapped from the actual hardware. The simulation confirms that the hybrid operation significantly increases the load capacity compared to hydrodynamic bearing due to the boost effect of hydrostatic pressure in the main film. Tests were conducted at 10krpm, 15krpm, and 20krpm to measure load capacity, power loss, and average film thickness. At 20krpm, a maximum axial load of 1711 N was achieved before bearing failure. Ultimately, the novel HFTB shows excellent static performance with potential for use in Organic Rankine Cycle (ORC) generators and other large oil-free turbomachines.

Effects of hydrostatic pressure, temperature, and position-dependent mass on the nonlinear optical properties of triple delta-doped GaAs quantum well

In this study, we thoroughly investigate the impacts of hydrostatic pressure, temperature, and position-dependent mass (PDM) on the nonlinear optical properties of asymmetric triple δ-doped GaAs quantum wells. Our analysis covers total optical absorption coefficients, relative refractive index changes, nonlinear optical rectification, second harmonic generation, and third harmonic generation. Initially, we employ PDM to solve the time-independent Schrödinger equation using the diagonalization method under effective mass and parabolic band approaches, considering pressure and temperature dependencies. Utilizing the first four energy eigenvalues and eigenfunctions, we apply the compact density matrix method to compute the system’s nonlinear optical properties numerically. The results indicate a shift in optical property peak positions toward lower (higher) energy spectra with increasing hydrostatic pressure (temperature). Furthermore, the influence of PDM shifts the system’s optical properties toward the higher energy spectrum, resembling the effect of temperature. From an experimental and theoretical perspective, one of the topics that researchers work on most is GaAs-based δ-doped systems (δ-doped heterojunction bipolar transistors, δ-doped field effect transistors, δ-multiple independent gate field effect transistors, etc.). We believe these findings will provide valuable insights for the researchers involved in GaAs-based δ-doped optoelectronic device design.

Integrated metabolomics analysis of chill-stored rose shrimp (Parapenaeus longirostris) treated with different pressure levels of high hydrostatic pressure by 1H-NMR spectroscopy.

The antimicrobial effects of high hydrostatic pressure (HHP) treatments on chill-stored seafood are well-documented, while their impact on the metabolic profile of seafood, especially the metabolome of fish flesh, and remains underexplored. Addressing this gap, this study investigates the effects of HHP on the metabolome of chill-stored rose shrimp by conducting multivariate data analysis based on untargeted proton nuclear magnetic resonance observations. Vacuum-packed rose shrimp samples were subjected to HHP at 0, 400, 500, and 600MPa for 10 min and then stored at 2-4°C. The microorganism analysis and metabolic analysis were carried out on days 1 and 14. HHP treatment effectively deactivated Lactobacillus spp., Escherichia coli, Pseudomonas spp., total Coliforms, and sulfite-reducing anaerobic bacteria. Consequently, HHP treatment significantly reduced the formation rate of decay-related metabolites, such as hypoxanthine, trimethylamine, and biogenic amines, which exhibited significant accumulation in untreated samples. Multivariate unsupervised analyses provided insights into the overall changes in the metabolite profile induced by HHP. Metabolic pathway analysis revealed several pathways underlying spoilage, including pyruvate metabolism, valine, leucine, and isoleucine biosynthesis, purine metabolism, methane metabolism, glycine, serine, and threonine metabolism, citrate cycle (TCA cycle), glycolysis/gluconeogenesis, alanine, aspartate, and glutamate metabolism, sulfur metabolism, pantothenate and CoA biosynthesis, glutathione metabolism, and glyoxylate and dicarboxylate metabolism. Importantly, these pathways underwent alterations due to the application of HHP, particularly at high-pressure levels. In summary, the results unveil the potential mechanisms of HHP effects on chill-stored rose shrimps.

A length-free phase field model for epoxy adhesive materials based on modified Drucker–Prager criterion

Characterizing the cracking behavior of epoxy adhesive material is of great importance for composite structures. Recently, the phase field model has emerged as the preferred method for predicting the crack propagation. This paper presents a length-free phase field model considering the characteristics of epoxy adhesive materials. The proposed model is formulated within a framework that decomposes the phase field fracture driving force, ensuring that it adequately considers the tension/compression asymmetry of the epoxy adhesive materials. The effects of hydrostatic pressure, deviational stress, and friction are incorporated into the model by employing a modified Drucker-Prager failure criterion. The failure criterion is included in the phase field model using the effective stress invariants. Furthermore, the internal length scale, previously considered to lack real physical meaning, is reformulated based on material strength. This model addresses the challenge of measuring the internal length of epoxy materials. It serves as a valuable reference for applying phase field models to epoxy materials. The accuracy of the model is validated through an L-shaped plate simulation, and an attempt using the model to predict the crack development in thick epoxy adhesive joints is undertaken. Several representative samples are simulated, including three double cantilever beams with different configurations. The numerical results demonstrate a good correlation with experimental data, highlighting the potential of the model in simulating the crack propagation in epoxy adhesive joints.

Effect of pressure on the phase stability, elastic anisotropy, and physical properties of CuZr structures

AbstractThe effect of hydrostatic pressure on the relative stabilities of the four main structures in CuZr has been estimated using first‐principles calculations. The results indicate that hydrostatic pressure induces the B19′ → B19 transformation at ~40 GPa and Cm → B19 transformation at ~68 GPa. At 0 GPa, these CuZr structures exhibit analogous values of B, G, and E and small difference in σ. However, the differences between these structures become appreciable in B, G, E, and σ values. 3D graphs of Young's modulus reflect the elasticity is directional. Pressure promotes the increase of elastic anisotropy degree of B2. For B19′ and Cm, the variation trends under pressure firstly decrease, then slightly increase, while that is opposite for B19. The quasi‐harmonic Debye model is used to evaluate the effects of temperature and pressure on the thermodynamic properties (heat capacity, thermal expansion coefficient, Debye temperature, and Grüneisen parameter) of the CuZr structures.

Investigating the effects of hydrostatic pressure on the physical properties of cubic Sr3BCl3 (B = As, Sb) for improved optoelectronic applications: A DFT study

This article explores changes in the structural, electronic, elastic, and optical properties of the novel cubic Sr3BCl3 (B = As, Sb) with increasing pressure. This research aims to decrease the electronic band gap of Sr3BCl3 (B = As, Sb) by applying pressure, with the objective of enhancing the optical properties and evaluating the potential of these compounds for use in optoelectronic applications. It has been revealed that both the lattice parameter and cell volume exhibit a declining pattern as pressure increases. At ambient pressure, analysis of the band structure revealed that both Sr3AsCl3 and Sr3SbCl3 are direct band gap semiconductors. With increasing pressure up to 25 GPa the electronic band gap of Sr3AsCl3 (Sr3SbCl3) reduces from 1.70 (1.72) eV to 0.35 (0.10) eV. However, applying hydrostatic pressure enables the attainment of optimal bandgaps for Sr3AsCl3 and Sr3SbCl3, offering theoretical backing for the adjustment of Sr3BCl3 (B = As, Sb) perovskite's bandgaps. The electron and hole effective masses in this perovskite exhibit a gradual decrease as pressure rises from 0 to 25 GPa, promoting the conductivity of both electrons and holes. The elastic properties are calculated using the Thermo-PW tool, revealing that they are anisotropic, ductile, mechanically stable, and resistant to plastic deformation. Importantly, these mechanical properties of both compounds are significantly enhanced under pressure. Optical properties, including the absorption and extinction coefficients, dielectric function, refractive index, reflectivity, and loss function, were calculated within the 0–20 eV range under different pressure conditions. The calculated optical properties highlight the versatility and suitability of Sr3AsCl3 and Sr3SbCl3 perovskites for pressure-tunable optoelectronic devices.

Effects of hydrostatic pressure, aluminium composition, and external magnetic field on intersubband and intrasubband transitions characteristics in symmetric potential quantum wells

Aluminium composition (λ), magnetic field (B), and hydrostatic pressure (P) influences on magneto-optical (MO) properties of intra- and inter-subband transitions in GaAs/AlλGa1−λAs symmetric QWs for four models of confined optic phonons are studied and compared. The findings indicate: the MO characteristics of intra- and inter-subband transitions are significantly influenced by B, λ, and P for phonon absorption and emission. The e–p interaction intensity decreases as P increases, whereas it increases as λ increases. The influences of λ and P on phonon absorption are more significant than those on emission. E–p interaction intensity dependence on λ and P for intra-subband transitions is stronger than that for inter-subband ones. The e–p interaction in QWs is well described by Knipp–Reinecke and Huang–Zhu models. To reduce the influence of P on MO properties, we can increase T and λ or decrease B. At T≈600 K, the influence of P is insignificant and can be neglected.

Effects of High Hydrostatic Pressure on the Distribution of Oligosaccharides, Pinitol, Soysapapogenol A, and Fatty Acids in Soybean.

The effects of high hydrostatic pressure (HHP) treatment (100-600 MPa for 10-60 min) and thermal treatment (boiling for 10-60 min) on oligosaccharides, pinitol, and soyasapogenol A as taste ingredients in soybean (Glycine max (L.) Merr.) (cv. Yukihomare) were evaluated. Additionally, soybean-derived fatty acids such as α-linolenic acid, linoleic acid, oleic acid, palmitic acid, and stearic acid in pressurized soybeans were quantitatively analyzed. Sucrose, stachyose, and raffinose concentrations were decreased in all tested pressure and time combinations; however, pinitol concentrations were increased by specific pressure and time combinations at 100-400 MPa for 10-60 min. While the soyasapogenol A content in boiled soybeans decreased with increasing boiling time, that of pressurized soybeans was altered by specific pressure and time combinations. At the lower pressure and shorter time combinations, the essential fatty acids such as α-linolenic acid and linoleic acid showed higher contents. Stearic acid and oleic acid contents of pressurized soybeans increased at mild pressure levels (300-500 MPa). In contrast, the combination of higher pressure and longer time results in lower essential fatty acid contents. Non-thermal-pressurized soybeans have the potential to be a high-value food source with better taste due to the enrichment of low molecular weight components such as pinitol, free amino acids, and the reduction of isoflavones and Group A soyasapogenol.

Effects of hydrostatic pressure on amorphous chiral materials: Impact on homochiral or heterochiral H-bond sequences

High pressure effects on static dielectric permittivity of homochiral and heterochiral N-acetyl-α-methyl-benzylamine (Nac-MBA) were investigated. For homochiral composition, the static permittivity increases of 178% with pressure at T = 388 K. Interestingly, as pressure continued increasing, εS drastically collapsed to reach ε∞=3±0.3. In the case of heterochiral composition, the static permittivity increases with pressure (in the same magnitude order as the pure enantiomer), and reaches a constant value depending on the isothermal temperature. Thus, the size of the H-bond aggregates is highly pressure sensitive, increasing up to a level that crystallization becomes unavoidable. For heterochiral composition, this process may be kinetically time consuming since the initial heterochiral H-bond aggregates need to be surrounded by their suitable neighbors in order to fulfilled the crystalline packing. The initial H-bond sequences are the precursors of the future crystalline arrangement under pressure application.