Hydrophobic Carbon Nanotubes Research Articles

Enhanced solar desalination with photothermal hydrophobic carbon nanotube-infused PVDF membranes in air-gap membrane distillation

This work aims to increase the efficiency of the solar powered-air gap membrane distillation (SP-AGMD) process; a desalination method driven by solar energy, providing an eco-friendly and sustainable approach to addressing global water shortages. The innovation lies in integrating photothermal hydrophobic multiwalled carbon nanotubes (h-MWCNTs), in varying weight percentages from 5 % to 60 %, into polyvinylidene fluoride (PVDF) membranes using the phase inversion membrane fabrication technique. The h-MWCNTs were synthesized through oxidation and functionalization with oleylamine (OL) to improve their photothermal properties. Their successful integration was confirmed via scanning electron microscopy (SEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy. The h-MWCNTs-based SP-AGMD membranes were further evaluated for wettability, liquid entry pressure (LEP), surface temperature, and solar absorbance, demonstrating significant solar light absorption and localized surface heating. This generated the necessary driving force for the AGMD process. Performance metrics such as vapor flux, salt rejection, specific thermal energy consumption, photothermal efficiency, and temperature polarization (TP) coefficient were significantly improved, especially with a 20 % h-MWCNTs addition, which tripled the solar-energy-driven flux and increased photothermal efficiency by 326 % under standard solar conditions, compared to unmodified membranes. All h-MWCNTs-based SP-AGMD membranes achieved over 99 % salt rejection. Lastly, the membranes were tested with real seawater to confirm their applicability for desalination. This photothermal approach offers a scalable, sustainable solution for water purification, making a significant advancement in membrane distillation technology.

Hydrophobic and oleophilic lauric acid-grafted carbon nanotubes for recyclable efficient oil/water separation

This work demonstrates a novel nanoscale surface modification procedure to enhance the selectivity of multi-walled carbon nanotubes (MWCNTs) in recovering oil from water. Herein, we developed a novel, cost-effective, and facile method to produce highly hydrophobic and superoleophilic lauric acid (LA)-grafted multi-walled carbon nanotubes (MWCNTs-LA) as an absorbent for effective oil spill remediation. The MWCNTs were first oxidized with sodium hydroxide to anchor hydroxyl groups on their surface (MWCNTs-OH) followed by LA grafting via an esterification reaction. Spectroscopic analyses confirmed the grafting of LA onto the MWCNTs' surface, and this treatment made the water contact angle (WCA) of MWCNTs-LA reach 145.26 ± 1.57°, thus showing excellent hydrophobicity and superoleophilicity. The as-prepared absorbent demonstrates good absorption selectivity and absorption capacity of 20.5–33.5 times weight gain for numerous organic solvents and oils. After 5 cycles of absorption-desorption tests, such highly hydrophobic MWCNTs-LA absorbent maintained high oil absorption performance, therefore displaying good reusability and desirable regeneration for practical uses. The MWCNTs-LA absorbent with superb hydrophobicity, superoleophilicity, proper selectivity, and acceptable reusability appears to be promising for the efficient separation and retrieval of spilled oils and organic solvents from water.

Aiming the water transport issues of anion exchange membrane fuel cells by introducing hydrophobic carbon nanotube diffusion layer

The gas diffusion layer (GDL) enhances the transport efficiency of reaction gases and facilitates the removal of accumulated liquid water, thereby improving water management in anion exchange membrane fuel cells (AEMFCs). Carbon nanotubes (CNTs) are recognized as one of the promising materials to optimize mass transport within GDLs. In this study, we successfully synthesized an abundance of CNTs on the surface of commercial gas diffusion media. The as-prepared CNT layer exhibits exceptionally high hydrophobic properties and forms a hierarchically hydrophobic structure combined with the gas diffusion media, effectively enhancing the mass transfer of the membrane electrode assembly (MEA) and reducing ohmic impedance. Under supersaturation conditions, the power density of the MEA containing CNTs reaches 1031.7 mW/cm2, significantly higher than the 760.64 mW/cm2 observed for the commercial GDL. Further testing demonstrates that the MEA containing CNTs exhibits a limiting current density of 2507.4 mA/cm2, which is much superior to the benchmark MEA with the commercial GDL (1591 mA/cm2). Electrochemical impedance spectroscopy analysis reveals that the mass transfer resistance of MEAs with CNTs is lower than that of MEAs with the commercial GDL. More importantly, the phase-field modeling is performed to simulate the transport of the liquid water in the hierarchical GDL.

Water at the nanoscale: From filling or dewetting hydrophobic pores and carbon nanotubes to "sliding" on graphene.

In this work, we study the effect of nanoconfinement on the hydration properties of model hydrophobic pores and carbon nanotubes, determining their wetting propensity and the conditions for geometrically induced dehydration. By employing a recently introduced water structural index, we aim at two main goals: (1) to accurately quantify the local hydrophobicity and predict the drying transitions in such systems, and (2) to provide a molecular rationalization of the wetting process. In this sense, we will further discuss the number and strength of the interactions required by the water molecules to promote wetting. In the case of graphene-like surfaces, an explanation for their unexpectedly significant hydrophilicity will also be provided. On the one hand, the structural index will show that the net attraction to the dense carbon network that a water molecule experiences through several simultaneous weak interactions is sufficient to give rise to hydrophilic behavior. On the other hand, we will show that an additional effect is also at play: the hydrating water molecule is retained on the surface by a smooth exchange of such simultaneous weak interactions, as if "sliding" on graphene.

Concentric Structure of Coexistent KCl Core Solution and Water Adlayer Inside a Highly Hydrophobic Single-Wall Carbon Nanotube

Concentric Structure of Coexistent KCl Core Solution and Water Adlayer Inside a Highly Hydrophobic Single-Wall Carbon Nanotube

Solid-State Microfabricated Potentiometric Sensors for Selective Assessment of Diclofenac Sodium Utilizing Pentafluorophenyl Diazonium Modified Carbon Nanotubes Transducer Layer

In the pharmaceutical field, analytical chemistry is evolving and one area that is experiencing enthusiasm is the design and implementation of solid contact ion-selective electrodes. We have developed two potentiometric sensors for the selective assay of a widely used drug diclofenac sodium. Diclofenac sodium was targeted in one of its most recommended dosage forms (Arthrotec® tablets) in the presence of misoprostol. A cost-effective copper printed circuit board as a substrate has been coated with a PVC sensing membrane to fabricate sensor I. Hydrophobic carbon nanotubes (CNTs) have been modified through in situ reduction of pentafluorophenyl diazonium using sodium borohydride. An interlayer of the modified CNTs was inserted as a transducer layer between the Cu substrate and the ion-sensing membrane in sensor II to enhance its electrochemical performance and stability. The microfabricated electrodes demonstrated encouraging outcomes upon the direct assay of diclofenac sodium in combination with misoprostol and other additives without sample preparation steps. The responses presented a linear Nernstian pattern in the range of 1.0 × 10−4 to 1.0 × 10−2 mol l−1 with a slope of −58.2 and −58.4 mV/decade for sensors I and II, consequently. Finally, the sustainability of the developed technique was assured using advanced green metrics.

Selective Oxidation of sp-Bonded Carbon in Graphdiyne/Carbon Nanotubes Heterostructures to Form Dominant Epoxy Groups for Two-Electron Oxygen Reduction.

Two-electron oxygen reduction reaction (2e- ORR) is of great significance to H2O2 production and reversible nonalkaline Zn-air batteries (ZABs). Multiple oxygen-containing sp2-bonded nanocarbons have been developed as electrocatalysts for 2e- ORR, but they still suffer from poor activity and stability due to the limited and mixed active sites at the edges as well as hydrophilic character. Herein, graphdiyne (GDY) with rich sp-C bonds is studied for enhanced 2e- ORR. First, computational studies show that GDY has a favorable formation energy for producing five-membered epoxy ring-dominated groups, which is selective toward the 2e- ORR pathway. Then based on the difference in chemical activity of sp-C bonds in GDY and sp2-C bonds in CNTs, we experimentally achieved conductive and hydrophobic carbon nanotubes (CNTs) covering O-modified GDY (CNTs/GDY-O) through a mild oxidation treatment combined with an in situ CNTs growth approach. Consequently, the CNTs/GDY-O exhibits an average Faraday efficiency of 91.8% toward H2O2 production and record stability over 330 h in neutral media. As a cathode electrocatalyst, it greatly extends the lifetime of 2e- nonalkaline ZABs at both room and subzero temperatures.

Facile and Nondestructive Transformation of Intrinsic Hydrophobic Behavior of a Carbon Nanotubes Sheet to Hydrophilic.

It is imperative to induce hydrophilicity in intrinsically hydrophobic carbon nanotubes (CNTs) without losing their superior properties for applications that specifically deal with aqueous media. A method for transforming a CNTs sheet from hydrophobic to hydrophilic by treatment with N-methyl-2-pyrrolidone (NMP) is explored. The NMP-treated CNT sheets are assessed based on complementing characterization, and it is concluded that the binding of NMP to a CNTs surface is through noncovalent interaction without the incorporation of defects in CNTs. The induced hydrophilicity in the CNTs sheet is stable for water exposure over a longer duration while it displays a semireversible nature upon heat treatment. The mechanical and electrical properties of the NMP-treated CNTs sheet revealed enhancement in the tensile strength from 221 to 421 MPa while maintaining a good electrical conductivity of ∼1.22 × 104 S/m because of the improved interfacial properties. The hydrophilic CNTs exhibited excellent adsorption capacity for methylene blue dye. The NMP-treated CNTs sheets demonstrated their suitability in flexible hybrid supercapacitor (FHSC) devices with improved electrochemical performance with enhancement in the capacitance from 5.4 to 7.6 F/g and a decrease in the equivalent series resistance from 53 to 34 Ω compared to pristine CNTs-based devices. These solid-state FHSC devices displayed excellent cyclic charge-discharge performance along with robust behavior over thousands of bending cycles without significant performance degradation. The excellent dye removal capability and superior electrochemical performance of the NMP-treated CNTs sheet is a consequence of their improved interface with aqueous media, which is governed by the hydrophilic nature of the CNTs sheet.

Characterization of Water Structure and Phase Behavior within Metal-Organic Nanotubes.

Water behavior under nanoconfinement varies significantly from that in the bulk but also depends on the nature of the pore walls. Hybrid compound offers the ideal system to explore water behavior in complex materials, so a model metal-organic nanotube (UMONT) material was utilized to explore the behavior of water between 100 and 293 K. Single-crystal X-ray and neutron diffraction revealed the formation of a filled Ice-I arrangement that was previously predicted to only occur under high pressures. 17O NMR spectra suggest that the onset of melting for the water in the UMONT channels occurs at 98 K and the presence of ice-like water up to 293 K, indicating that the complete ice-water transition does not occur before dehydration of the material. Overall, the water behavior differs significantly from hydrophobic single-walled carbon nanotubes indicating precise control over water can be achieved through rational design of hybrid materials.

Implantable anti-biofouling biosupercapacitor with high energy performance

Biofluidic open-type supercapacitors offer significant advantages over batteries in implantable electronics. However, poor energy storage in bioelectrolytes and performance degradation owing to electrode biofouling remain challenges and hamper their implementation. In this study, we present a flexible polydopamine (PDA)-infiltrated carbon nanotube (CNT) yarn (PDA/CNT) supercapacitor with high performance in biofluids, encapsulated by a hydrogel-barrier circular knit that provides anti-biofouling protection. Infiltration of the biopolymer PDA provide a hydrophilic coating to obtain a hydrophobic CNT electrode under aqueous conditions and an energy density 250-fold higher than that of the pristine CNT in the biofluid. The PDA/CNT supercapacitor exhibited remarkable energy performance in biological fluids in terms of the maximum areal capacitance (503.91 mF cm−2), energy density (274 μWh/cm2), and power density (25.52 mW cm−2). Moreover, it demonstrated negligible capacitance loss after 10,000 repeated charge/discharge cycles and bending tests. To prevent biofouling, the PDA/CNT electrode was encapsulated in an agarose-coated circular knit that allows free movement of the electrolyte. Notably, implanting an encapsulated PDA/CNT supercapacitor into the abdominal cavity of rat resulted in stable in vivo energy storage performance without biofouling for 21 d, and the charged supercapacitor was used successfully to power a light-emitting diode in vivo.

MWCNTs dispersion adopting GA and its application towards copper tailings-based cementitious materials

Hydrophobic carbon nanotubes are hardly to disperse in water and prone to agglomerate when poured with Copper Tailing-Based Cementitious Material (CTCM). Multi-walled carbon nanotubes (MWCNTs) + Arabic Gum (GA) dispersions were prepared by a novel method of synergistic optimization of concentration, controlling low-frequency ultrasonic time and setting the ambient temperature with non-toxic anionic surfactant GA as surfactant. The results of UV–Vis spectroscopy showed that the high stability MWCNTs + GA dispersion with low aggregation area (< 1.2%) and low aggregation beam size (< 219 nm) have been prepared by using 1.7 mmol/l GA. The effects of highly stable MWCNTs dispersion on the mechanical properties, microstructure and durability of CTCM were studied. The 28 days compressive strength increased by 21.5%, and the flexural strength increased by 20.5%, almost reaching the mechanical level of the control group. The results of SEM, XRD and EDS showed that GA significantly enhanced the dispersion of MWCNT in aqueous solution at a suitable concentration (mass ratio of GA:CNTs = 1:1). The microstructure of the prepared CTCM by high stability MWCNTs dispersion was optimized obviously, and the mechanical properties and durability were improved significantly. This method solves the dual problem of MWCNTs not being fully dispersed in aqueous solution and being easily re-agglomerated in cementitious materials, as well as finding a breakthrough for the low cost and industrialization of tailings cement-based composite cementitious materials.

Hydrophobicity prediction model of hydrophobic nano-SiO2/carbon nanotube composite coating and influence of structural fluctuation on deicing performance

An SiO2-CNT composite hydrophobic coating (abbreviated as S-C coating) was constructed using hydrophobic nano-SiO2 particles with mixed particle size, hydrophobic carbon nanotube particles and fluorine-silicone resin. A hydrophobicity prediction model of the S-C coating was also constructed by response surface methodology to accurately predict and control the hydrophobicity of the coating. An S-C superhydrophobic coating with similar hydrophobicity but different structure fluctuation was successfully prepared using the prediction model. The structural fluctuation of the coating was mainly formed by the entanglement of CNT particles. The SiO2 particles of the mixed particle size acted to fix and further enhance the structural fluctuation of the coating structure. The most suitable structural fluctuation of the S-C superhydrophobic coating for deicing performance is between 2 and 3 µm. This study has significant implications for the construction of superhydrophobic deicing surfaces.

Preliminary Study on Electrodeposition of Copper Platings and Codeposition of Carbon Nanotubes from Organic Solvent

Metal/carbon composite plating is an effective strategy for improving and adding properties to metal plating by incorporating carbon materials into the metal matrices. Copper (Cu) is widely applied, particularly in the areas of heat management and electronic packaging owing to its high thermal and electrical conductivities, which can be further improved together with improvements in mechanical properties by compositing it with carbon nanotubes (CNTs). However, because hydrophobic CNTs are hardly dispersible in aqueous solutions, additional intense acid treatment or the addition of dispersants is required for their dispersion. Moreover, previous studies have reported that these methods suffer from deterioration of composite material performance through the destruction of the CNT surface or the inclusion of dispersants into the plating. Therefore, in this study, the electrodeposition of a Cu/CNT composite in a non-aqueous solvent that can disperse CNTs without any additional treatment is investigated. The experimental results show that it is possible to deposit Cu from a N-methyl-2-pyrrolidone containing copper iodide and potassium iodide. Furthermore, Cu/CNT composite platings containing CNTs up to 0.12 mass% were prepared by constant current electrolysis, and applying pulse electrolysis can increase the CNTs content up to 0.22 mass%.

Adsorption Efficiency and Photocatalytic Activity of Silver Sulfide Nanoparticles Deposited on Carbon Nanotubes

A multimode, dual functional nanomaterial, CNTs-Ag2S, comprised of carbon nanotubes (CNTs) and silver sulfide (Ag2S) nanoparticles, was prepared through the facile hydrothermal process. Before the deposition of Ag2S nanoparticles, hydrophobic CNTs were modified to become hydrophilic through refluxing with a mixture of concentrated nitric and sulfuric acids. The oxidized CNTs were employed to deposit the Ag2S nanoparticles for their efficient immobilization and homogenous distribution. The CNTs-Ag2S could adsorb toxic Cd(II) and completely degrade the hazardous Alizarin yellow R present in water. The adsorption efficiency of CNTs-Ag2S was evaluated by estimating the Cd(II) adsorption at different concentrations and contact times. The CNTs-Ag2S could adsorb Cd(II) entirely within 80 min of the contact time, while CNTs and Ag2S could not pursue it. The Cd(II) adsorption followed the pseudo-second-order, and chemisorption was the rate-determining step in the adsorption process. The Weber−Morris intraparticle pore diffusion model revealed that intraparticle diffusion was not the sole rate-controlling step in the Cd(II) adsorption. Instead, it was contributed by the boundary layer effect. In addition, CNTs-Ag2S could completely degrade alizarin yellow R in water under the illumination of natural sunlight. The Langmuir-Hinshelwood (L-H) model showed that the degradation of alizarin yellow R proceeded with pseudo-first-order kinetics. Overall, CNTs-Ag2S performed as an efficient adsorbent and a competent photocatalyst.

Fabrication and Characterization of Carbon Nanotube Filled PDMS Hybrid Membranes for Enhanced Ethanol Recovery.

Ethanol separation via the pervaporation process has shown growing application potential in solvent recovery and the bioethanol industry. In the continuous pervaporation process, polymeric membranes such as hydrophobic polydimethylsiloxane (PDMS) have been developed to enrich/separate ethanol from dilute aqueous solutions. However, its practical application remains largely limited due to the relatively low separation efficiency, especially in selectivity. In view of this, hydrophobic carbon nanotube (CNT) filled PDMS mixed matrix membranes (MMMs) aimed at high-efficiency ethanol recovery were fabricated in this work. The filler K-MWCNTs was prepared by functionalizing MWCNT-NH2 with epoxy-containing silane coupling agent (KH560) to improve the affinity between fillers and PDMS matrix. With K-MWCNT loading increased from 1 wt % to 10 wt %, membranes showed higher surface roughness and water contact angle was improved from 115° to 130°. The swelling degree of K-MWCNT/PDMS MMMs (2 wt %) in water were also reduced from 10 wt % to 2.5 wt %. Pervaporation performance for K-MWCNT/PDMS MMMs under varied feed concentrations and temperatures were evaluated. The results supported that the K-MWCNT/PDMS MMMs at 2 wt % K-MWCNT loading showed the optimum separation performance (compared with pure PDMS membranes), with the separation factor improved from 9.1 to 10.4, and the permeate flux increased by 50% (40-60 °C, at 6 wt % feed ethanol concentration). This work provides a promising method for preparing a PDMS composite with both high permeate flux and selectivity, which showed great potential for bioethanol production and alcohol separation in industry.

A Microwave-Assisted, Solvent-Free Approach for the Versatile Functionalization of Carbon Nanotubes

While the functionalization of carbon nanotubes (CNTs) has attracted extensive interest for a wide range of applications, a facial and versatile strategy remains in demand. Here, we report a microwave-assisted, solvent-free approach to directly functionalize CNTs both in raw form and in arbitrary macroscopic assemblies. Rapid microwave irradiation was applied to generate active sites on the CNTs while not inducing excessive damage to the graphitic network, and a gas-phase deposition afforded controllable grafting for thorough or regioselective functionalization. Using methyl methacrylate (MMA) as a model functional group and a CNT sponge as a model assembly, homogeneous grafting was exhibited by the increased robust hydrophobicity (contact angle increase from 30 to 140°) and improved structural stability (compressive modulus increased by 135%). Therefore, when our MMA-functionalized CNTs served as a solar absorber for saline distillation, high operating stability with a superior water evaporation rate of ∼2.6 kg m-2 h-1 was observed. Finally, to highlight the efficacy and versatility of this functionalization approach, we fabricated asymmetrically hydrophobic CNT sponges by regioselective functionalization to serve as a moisture-driven generator, which demonstrated a stable open-circuit voltage of 0.6 mV. This versatile, solvent-free approach can complement conventional solution-based techniques in the design and fabrication of multifunctional nanocarbon-based materials.

Self-Diffusion in Confined Water: A Comparison between the Dynamics of Supercooled Water in Hydrophobic Carbon Nanotubes and Hydrophilic Porous Silica.

Confined liquids are model systems for the study of the metastable supercooled state, especially for bulk water, in which the onset of crystallization below 230 K hinders the application of experimental techniques. Nevertheless, in addition to suppressing crystallization, confinement at the nanoscale drastically alters the properties of water. Evidently, the behavior of confined water depends critically on the nature of the confining environment and the interactions of confined water molecules with the confining matrix. A comparative study of the dynamics of water under hydrophobic and hydrophilic confinement could therefore help to clarify the underlying interactions. As we demonstrate in this work using a few representative results from the relevant literature, the accurate assessment of the translational mobility of water molecules, especially in the supercooled state, can unmistakably distinguish between the hydrophilic and hydrophobic nature of the confining environments. Among the numerous experimental methods currently available, we selected nuclear magnetic resonance (NMR) in a field gradient, which directly measures the macroscopic translational self-diffusion coefficient, and quasi-elastic neutron scattering (QENS), which can determine the microscopic translational dynamics of the water molecules. Dielectric relaxation, which probes the re-orientational degrees of freedom, are also discussed.

(Digital Presentation) Hydrophilic and Hydrophobic Carbon Nanotubes Combined into a Buckypaper As an Electrode for Li-O2 Batteries

With the decreasing costs of wind and solar power, these two energy sources are set to gain a sizeable share of the electricity market in the next years. To cope with the intermittency of these electricity sources, grid operators are required to develop new, inexpensive, and efficient energy storage facilities. One of the technologies being considered for such application is the Li-O2 battery, whose main advantage compared to state-of-the-art lithium-ion batteries is the prospect of higher energy density which might lead to decreased installation costs. Nevertheless, these batteries depend upon efficient mass transport of O2 inside the electrode to present suitable power density. In this work, a mix of hydrophilic and hydrophobic carbon nanotubes (CNT) was used to produce an O2 electrode with enhanced mass transport properties. Hydrophobic CNT were prepared via thermal treatment under Ar atmosphere at 850 °C for 2 h. Hydrophilic CNT were prepared via refluxing in 7 mol L-1 HNO3 solution for 4 h (~120 °C). Raman spectroscopy was used to analyze the quality of both types of CNT. Different proportions of hydrophobic and hydrophilic CNT were dispersed in solution with a surfactant using a probe sonicator. The solution was filtered using a 0.22 μm membrane and vacuum to produce a buckypaper. Batteries were assembled in a glove box using a Li electrode, a separator membrane (glass fiber), and the buckypaper as the O2 electrode. Galvanostatic discharge tests were carried out at different currents to analyze the impact of different qualities of CNT used in the making of the O2 electrode in the increasing demand for O2 in the battery at high currents. Scanning electron microscopy images were used to compare the morphology of the different electrodes before and after discharge. Results are expected to demonstrate a new method to increase the mass transport rates for O2 in Li-O2 batteries.The authors gratefully acknowledge the support from FAPESP (the Sao Paulo Research Foundation, Grant Numbers 2018/16663-2 and 2017/11958-1), Shell, the strategic importance of the support given by ANP (Brazil’s National Oil, Natural Gas and Biofuels Agency) through the R&D levy regulation, and the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - Brasil (CAPES) - Finance Code 001.

Autonomous Chemistry Enabling Environment-Adaptive Electrochemical Energy Storage Devices

Autonomous Chemistry Enabling Environment-Adaptive Electrochemical Energy Storage Devices

An abrasion-resistant, photothermal, superhydrophobic anti-icing coating prepared by polysiloxane-modified carbon nanotubes and fluorine-silicone resin

Hydrophobic modification of carbon nanotubes was performed using poly(methyl-3,3,3-trifluoropropyl siloxane) (PMTFPS). Then a superhydrophobic anti-icing coating with photothermal effect was successfully prepared by using fluorine-silicone resin as a binder and building a micro-nano structure using hydrophobic carbon nanotubes. The coating has good hydrophobic properties with a contact angle of 160.8° and a sliding angle of 2°. The performance of the coating was also evaluated by sandpaper abrasion test, complete freezing time, ice adhesion strength, and infrared irradiation. The coating maintained good hydrophobicity even after 100 cycles of abrasion or after being immersed for 12 h in solutions with different conditions. The good abrasion resistance and chemical durability of the coating in aqueous solutions were demonstrated. The complete freezing time of 10 µl water droplet on the coating surface was prolonged by 11.6 times at − 15 °C. The ice adhesion strength of the coating was only 33.3 kPa, which was 92.1% lower than that of the tinplate. After 50 de-icing cycles, the ice adhesion strength on the coating was still relatively stable. The coating had significant photothermal properties, with the temperature rising 14.3 °C after 1 min irradiation by a 150 W infrared light.