Hydrogen Pressure Research Articles

Optimal power generation of proton exchange membrane fuel cell using ANFIS based MPPT algorithm

Fuel cells are the most promising energy source for the future energy demand. The automobile industry is looking at the integration of fuel cells with electric vehicles (EV). This integration comes with many challenges like dynamic operational behaviors. For operating the fuel cell with maximum efficiency, this work proposes an Adaptive Neuro Fuzzy Inference System (ANFIS) based Maximum Power Point Tracking (MPPT) method. The hydrogen flow rate, pressure and stack temperature are the parameters considered to track the maximum power point of the fuel cell. The ANFIS-MPPT algorithm has been integrated with the 1.26 kW fuel cell in MATLAB/Simulink® and validated in different scenarios like dynamic variation in hydrogen pressure, stack temperature, load variation. The performance has been observed and compared with the conventional MPPT algorithms of Perturb and Observe (P&O) algorithm and Incremental Conductance (InC) algorithm. The proposed ANFIS-MPPT algorithm improves the power stability by 10–15% than the P&O and InC methods. Also, the proposed ANFIS-MPPT has 30% faster response as compared to the P&O algorithm, and 23% than the InC algorithm. From the analysis, it is observed that the ANFIS, P&O and InC methods are having the response time of 2.5 s, 3.6 s and 4.5 s respectively. Also the ANFIS method delivers the maximum power output of 1.26 kW, whereas the P&O and InC deliver 1.13 kW, 1.19 kW respectively. The detailed simulation analysis and results are presented in this paper.

Enhanced catalytic performance of ethyl-levulinate to γ-valerolactone: Effect of copper loading on Ni/KIT-5 catalyst

A facile wet impregnation method was employed to prepare a bimetallic Ni–Cu catalyst on a mesoporous KIT-5 support, keeping the nickel loading constant (5 wt%) while varying the copper wt.% (xCu, where x = 8, 10, 12, 14). Several physico-chemical techniques, including X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) analysis, scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), temperature-programmed desorption of ammonia (NH3-TPD), temperature-programmed reduction of hydrogen (H2-TPR), and X-ray photoelectron spectroscopy (XPS), were utilized for catalyst characterization. An environmentally friendly NiCu bimetallic-supported catalyst system was developed in response to many problems, including metal leaching, sintering, and cost. A mesoporous KIT-5 silica support with a large surface area was used. The hydrogenation of ethyl levulinate to gamma-valerolactone was studied utilizing a high-pressure stirred reactor and a range of reaction temperatures (120–160 °C), hydrogen pressures (10–30 bar), and reaction periods. Various catalysts were used in the investigation. Among all tested catalysts, the 12Cu–5Ni/KIT-5 one shows excellent activity. The best GVL yield is 84% at a conversion of 100% after 8 h of treatment at 150 °C and 25 bar H2 pressure; the promotion is also 76.1%. Optimization of reaction conditions was shown to correlate the physicochemical parameters of the catalyst with its activity.

The Effect of Process Parameters on the Pore Structure of Lotus-Type Porous Copper Fabricated via Continuous Casting

The pores in lotus-type porous copper are formed due to the difference in hydrogen solubility between the liquid and solid phases of copper. In a pressurized hydrogen atmosphere, hydrogen gas is released at the gas release and crystallization temperature, which is the melting point of copper. This study systematically analyzes the effects of process parameters, including hydrogen ratio, total pressure, and continuous casting speed, on the pore structure of lotus-type porous copper, with the aim of identifying the most critical process parameters for controlling pore diameter and density. Within the hydrogen ratio up to 50%, it was observed that as the hydrogen ratio increases, the pores tend to increase in porosity, and the pore diameter increases. As the hydrogen ratio increased from 25% to 50%, the pore diameter increased from 300 μm to 400 μm, while the pore density decreased from 3.3 N·mm−2 to 2.8 N·mm−2. As the total pressure increased, the pore diameter tended to decrease, and the pore density increased. Specifically, when the total pressure increased from 0.2 MPa to 0.4 MPa, the pore diameter decreased from 1100 μm to 400 μm, while the pore density increased significantly from 0.5 N·mm−2 to 2.8 N·mm−2. In addition, as the continuous casting speed increased, 30 to 90 mm·min−1, the pore diameter decreased from 850 μm to 400 μm, and the pore density increased from 0.7 N·mm−2 to 2.8. N·mm−2. Specifically, the increase in total pressure led to a decrease in Gibbs free energy and a reduction in the critical pore nucleation radius, which promoted pore formation and resulted in the creation of more, smaller pores. These results suggest that total pressure is the primary factor influencing both pore diameter and density in lotus-type porous copper.

Mechanical Properties and Microstructural Characteristics of Steel Pipes after Long-Time Hydrogen Exposure

There are three possibilities to transport hydrogen by high pressure pipeline (i) blending hydrogen into the existing natural gas pipeline system, (ii) after checking the integrity, using the natural gas transporting pipeline system to transport hydrogen, (iii) building a new pipeline system to transport pure hydrogen. In all three cases should be known the behaviour of the pipe material and its welded joints influenced under high pressure hydrogen. For this aim pipeline sections made of P355NH base material were investigated without and with hydrogen exposure, where the exposure time was 41 days. Gas metal arc welding and hybrid tungsten arc welding / gas metal arc welding were applied for preparation of the girth weld joints. Tensile, three point bending and hardness tests, furthermore microstructural investigations were performed both on base materials and girth welds of the pipeline sections. The testing results were analysed and compared with each other (base material vs. welded joints, without exposure vs. with exposure) and with limit values can be found in the literature. Conclusions were drawn on the behaviour of the investigated pipe material and its welded joints.

Reaction kinetics for catalytic hydrogenation of quinoline to decahydroquinoline as liquid organic hydrogen carrier

The catalytic hydrogenation of quinoline to decahydroquinoline (DHQ) formation is studied for various parameters such as temperature, hydrogen pressure, reaction time, solvents, reactant-to-solvent ratio, and catalyst loading over 5%Pd loaded on alumina (Pd/Al2O3) to obtain optimal reaction conditions. The hydrogen uptake of quinoline in the liquid phase reaction using isopropylalcohol (IPA) is studied in an autoclave reactor. The optimum reaction parameters of 50 bar H2 pressure and 175oC with reactant to solvent ratio of 1:9 for reaction time of 5 h are observed. The effect of IPA solvent showed that hydrogen uptake of 6.91 wt% with complete hydrogenation of quinoline and DHQ yield of more than 99% is observed. The reaction kinetic model is developed for a simplified reaction mechanism and is simulated using the Markov Chain Monte Carlo (MCMC) simulation tool to predict the rate constants and the experimental observations are validated with the model predictions. The activation energy for quinoline hydrogenation to py-THQ formation is estimated to be 136.57 kJ/mol. It is envisaged that quinoline hydrogenation to pz-THQ is the rate-limiting step in the DHQ formation.

Preparation and excellent mechanical properties of nanocrystalline GW103K Mg alloy by HDDR technology

Grain size of GW103K Mg alloy powder were markedly refined to about 45 nm from 20 μm by an optimized hydrogenation-disproportionation-desorption-recombination (HDDR) process. By changing temperature, hydrogen pressure and time, the optimum hydrogenation conditions are explored by orthogonal design. Then the complete dehydrogenation process was determined by using single factor control variables. Furtherly, the HDDRed powder was spark plasma sintering (SPS) sintered and hot extruded to prepare GW103K alloy bulk. XRD, OM, scanning electron microscopy (SEM), and transmission electron microscope (TEM) were used to analyze the phase transformation and microstructure evolution, based on which the grain refining mechanism during the HDDR were discussed. The optimum HDDR parameters for preparing nanocrystalline Mg alloy powders are hydriding at 550 °C under 5 MPa hydrogen pressure for 24 h and dehydriding at 550 °C for 8 h in vacuum. The nanocrystalline GW103 alloy presents a notable dimensional stability and the grain size of the alloy bulk is 43 nm after SPS and hot extrusion. As a result, the nanocrystalline GW103K specimens exhibit excellent mechanical properties compared to the coarse-grained counterparts. Especially, the nanocrystalline GW103K alloy has a tensile elongation of 21.1% which is much more than those of the as-cast and as-extrusion alloys.

Gradual spin crossover behavior encompasing room temperature in an iron(II) complex based on a heteroscorpionate ligand.

In this paper, we report the synthesis of six novel triazole-based heteroscorpionate ligands based on heterocycle metathesis reactions and their iron(II) complexes. Single crystal structure analyses were performed, the spectroscopic and magnetic properties of the obtained complexes were studied and their spin crossover-structural relationships were compared to those obtained for their pyrazole-based analogues reported in the literature. In particular, the amino derivative complex bis[hydrobis(pyrazol-1-yl)(3-amino-1,2,4-triazol-1-yl)]iron(II) obtained by post-synthetic catalytic nitro-group reduction under pressure of hydrogen in an autoclave presents a scarce gradual spin crossover behavior at room temperature. The profile of the SCO curve can be explained by the presence of only relatively weak H bonds, spreading only in one dimension. Among the interesting spin transition behaviors observed for the different complexes, such stable, complete and gradual spin crossover at room temperature makes this neutral complex a good candidate for sublimation and future investigation as an active element notably for thermoreflectance-based surface microthermometry applications.

The impact of fuel cell vehicle exhaust grille shape under natural ventilation on hydrogen leakage and diffusion

The rapid progression of hydrogen fuel cell vehicles has brought forth various challenges, primarily the frequent occurrence of hazardous incidents stemming from hydrogen leakage and diffusion. Consequently, there is a growing emphasis on hydrogen safety, leading to the development of stricter standards and regulations to mitigate the associated safety risks. Research on the design of exhaust port structures to facilitate the safe diffusion of hydrogen after leakage in diverse scenarios has become increasingly significant. This study examines the impact of exhaust grille shapes on hydrogen leakage and diffusion phenomena within the hydrogen storage compartment of fuel cell vehicles under natural ventilation conditions. Five distinct porous grille shapes were examined: rectangular, circular, square, rhombic, and hexagonal grilles. Numerical simulations of hydrogen leakage and diffusion within the compartment were conducted using Cradle scFLOW software. The effectiveness of the different grille shapes was assessed using several criteria, including average hydrogen molar fraction, pressure drop (indicative of negative pressure regions), density, and Richardson number. Overall, the rectangular grille exhibited superior performance in facilitating hydrogen venting.

Selective hydrogenation of 5‐hydroxymethylfurfural to 5‐hydroxymethyltetrahydrofurfural over heterogeneous Pd catalyst under mild conditions

5‐Hydroxymethylfurfural (5‐HMF) derived from lignocellulose represents an important platform molecule that could be employed in the selective hydrogenation of the furan ring to prepare 5‑hydroxymethyltetrahydrofurfural (HMTHF). However, the reported catalytic systems for the synthesis of HMTHF using 5‐HMF still require additional hydrogen pressure. In this study, the Pd/ZrO2 catalyst with uniformly dispersed Pd nanoparticles was prepared via a simple impregnation reduction process. This catalyst exhibited excellent catalytic activity and selectivity for the hydrogenation of 5‐HMF to HMTHF. High HMTHF yield up to 92.3% was produced under mild reaction conditions of ambient hydrogen pressure and room temperature in methanol solvent. This result was superior to the most catalytic systems that had been reported so far. The mechanism study revealed that the active hydrogen species on the surface of the Pd nanoparticles and the reaction solvent in this study were the pivotal factors influencing the hydrogenation of furan rings in 5‐HMF.

Optimizing the Pore Structure of Lotus-Type Porous Copper Fabricated by Continuous Casting.

Lotus-type porous copper was fabricated using a continuous casting method in pressurized hydrogen and nitrogen gas atmospheres. This study evaluates the effects of process parameters, such as the hydrogen ratio, total pressure, and transference velocity, on the resulting pore structure. A continuous casting process was developed to facilitate the mass production of lotus-type porous copper. To achieve the desired porosity and pore diameter for large-scale manufacturing, a systematic evaluation of the influence of each process parameter was conducted. Lotus-type porous copper was produced within a hydrogen ratio range of 25-50%, a transference velocity range of 30-90 mm∙min-1, and a total pressure range of 0.2-0.4 MPa. As a result, the porosity ranged from 36% to 55% and the pore size varied from 300 to 1500 µm, demonstrating a wide range of porosities and pore sizes. Through process optimization, it is possible to control the porosity and pore size. The hydrogen ratio and total pressure were found to primarily affect porosity, whereas the hydrogen ratio, transference velocity, and total pressure significantly influenced pore diameter. When considering these parameters together, porosity was most influenced by the hydrogen ratio, whereas the total pressure and transference velocity had a greater influence on pore diameter. Reducing the hydrogen ratio and increasing the transference velocity and total pressure reduced the pore diameter and porosity. This optimization of the continuous casting process enables the control of porosity and pore diameter, facilitating the production of lotus-type porous copper with the desired pore structures.

Umpolung Approach to Aldol Products via Isoxazoline N-Oxides as Intermediates.

A two-step umpolung approach to the diastereoselective synthesis of aldols was developed, in which a conjugated nitroalkene is used as the synthetic equivalent of the enolonium cation, while a sulfur ylide acts as the equivalent of the α-carbinol anion. The resulting isoxazoline N-oxides undergo catalytic reductive cleavage to aldols under mild conditions at room temperature and under 1 atm hydrogen pressure. The efficiency of the method was demonstrated by the synthesis of a series of polysubstituted β-hydroxyketones that are difficult to synthesize using the classical aldol reaction. The developed approach allows for the regiodivergent assembly of aldols by selecting a nitroalkene isomer with the appropriate position of the C,C double bond.

ВІДНОВЛЕННЯ ПАЛАДІЄВИХ МЕМБРАН ПІСЛЯ КОНТАКТУ З ВОД-НЕМ ДЛЯ ВОДНЕВО-КИСНЕВИХ ПАЛИВНИХ ЕЛЕМЕНТІВ

Annotation. Studying the deformations of palladium membranes under the influence of hydrogen, which is a relevant issue for hydrogen energy and the nuclear industry. The mechanisms of palladium membrane shape change due to hydrogen penetration and the formation of temporary gradient alloys such as α-PdHn are consid-ered. Experiments were conducted using a hydrogen-vacuum installation, where the processes of membrane satu-ration and degassing were studied at temperatures from 100°C to 360°C and hydrogen pressures from 0.01 MPa to 2.5 MPa. It was established that the change in the shape of the membrane occurs in two stages: first, a rapid bending of the membrane is observed, and then a gradual return to the initial state. It was established that the maximum change in the shape of the membrane, which occurs at a constant temperature, depends on the diffu-sion coefficient and the equilibrium solubility of hydrogen in palladium. However, when the temperature chang-es, the diffusion coefficient of hydrogen in palladium and the equilibrium concentration of hydrogen in palladi-um also change, which affects the temperature dependence of the final shape change of the membrane. This fact makes it possible to effectively determine the time of hydrogen penetration into the membrane, control the change in shape and adjust the operating modes of the fuel cell. Special attention is paid to the use of palladium alloys with copper and silver to increase the resistance of membranes to the influence of hydrogen. It is shown that such alloys have better mechanical characteristics and a longer service life at high temperatures. The effect of degassing on the restoration of membranes after contact with hydrogen was studied, the main factors affecting the efficiency of this process were determined. The results of the work confirm the need for further research on increasing the resistance of palladium membranes to deformations, as well as the development of new materials and technologies to improve their operational characteristics

Hydrogenation process intensification of 2-nitro-4-acetylamino anisole by HiGee technology

The catalytic hydrogenation of 2-nitro-4-acetylamino anisole (NMA) is the main path to synthesize 2-amino-4-acetylamino anisole (AMA), belonging to a typical gas-liquid-solid system. However, the small mass transfer rate of traditional hydrogenation reactor can't match its intrinsic fast reaction rate, resulting in the low hydrogenation efficiency. In this work, a rotating packed bed (RPB) reactor with excellent mass transfer performance was applied for the hydrogenation process intensification of NMA. The characterization analysis of the commercial Raney-Ni catalyst shows that the liquid-solid mass transfer resistance during the reaction process can be ignored, and improving the gas-liquid mass transfer rate is the key to improve the macroscopic reaction rate. The effects of operating conditions (solvent, rotational speed, hydrogen pressure, temperature, and catalyst dosage) on NMA conversion and AMA selectivity were investigated. A macro-kinetic equation of NMA catalytic hydrogenation in the RPB reactor was proposed. Under optimized conditions, the NMA was completely converted in the RPB reactor within 30 min, while it took 4 h in the stirred tank reactor. The overall reaction efficiency of RPB reactor was increased by 87.5 % in comparison with STR. This study provides practical guidance for the industrial application of RPB reactor for gas-liquid-solid hydrogenation.

A 500 kW hydrogen fuel cell-powered vessel: From concept to sailing

This paper presents the “Three Gorges Hydrogen Boat No. 1”, a novel green hydrogen-powered vessel that has been successfully delivered and is currently sailing. This vessel, integrated with a hydrogen production and bunkering station at its dedicated dock, achieves zero-carbon emissions. It stores 240 kg of 35 MPa gaseous hydrogen and has a fuel cell system rated at 500 kW. We analysed the engineering details of the marine hydrogen system, including hydrogen bunkering, storage, supply, fuel cell, and the hybrid power system with lithium-ion batteries. In the first bunkering trial, the vessel was safely refuelled with 200 kg of gaseous hydrogen in 156 min via a bunkering station 13 m above the water surface. The maximum hydrogen pressure and temperature recorded during bunkering were 35.05 MPa and 39.04 °C, respectively, demonstrating safe and reliable shore-to-ship bunkering. For the sea trial, the marine hydrogen system operated successfully during a 3-h voyage, achieving a maximum speed of 28.15 km/h (15.2 knots) at rated propulsion power. The vessel exhibited minimal noise and vibration, and its dynamic response met load change requirements. To prevent rapid load changes to the fuel cells, 68 s were used to reach 483 kW from startup, and 62 s from 480 kW to zero. The successful bunkering and operation of this hydrogen-powered vessel demonstrates the feasibility of zero-carbon emission maritime transport. However, four lessons were identified concerning bunkering speed, hydrogen cylinder leakage, hydrogen pressure regulator malfunctions, and fuel cell room space. The novelty of this work lies in the practical demonstration of a fully operational, hydrogen-powered maritime vessel achieving zero emissions, encompassing its design, building, operation, and lessons learned. These parameters and findings can be used as a baseline for further engineering research.

Pressure dependence of CO2 effect on hydrogen-assisted fatigue crack growth in two pipeline steels

This study investigated the pressure-dependent CO2 effect on the hydrogen embrittlement of X80 and GB20# pipeline steels by combining experiments and first-principles calculations. Results revealed that the CO2 effect enhanced the fatigue crack growth for GB20# steel in 10 MPa CO₂-enriched hydrogen mixtures. However, the improved degree by the CO₂ effect at 10 MPa was less pronounced than at 0.4 MPa, which was found for the first time. This was attributed to the decreased adsorption rate of CO₂ on iron as hydrogen pressure increased. Therefore, in high-pressure CO₂-enriched hydrogen mixtures, CO2 could not significantly accelerate the inherent rapid hydrogen uptake at high pressure.

Research progress of hydrogen blocking coatings

In the context of carbon peak and carbon neutrality, the use of clean energy has become the focus of attention. Hydrogen energy as the most potential secondary energy has a very important position in various fields, so the storage and transport of hydrogen energy is one of our most important concerns. Long distance pipeline is regarded as an effective means to transport hydrogen, but the high pressure hydrogen environment is easy to cause hydrogen embrittleness and other problems in the pipeline, which seriously threatens the safety of pipeline transportation. Hydrogen blocking coatings are one of the most effective ways to solve such problems. In this paper, the research results in recent years are reviewed and summarized. The article points out the hydrogen barrier mechanism, advantages and disadvantages of various types of hydrogen barrier coatings, the current status of research, as well as future research focus and development trend.

An MPPT Controller with a Modified Four-Leg Interleaved DC/DC Boost Converter for Fuel Cell Applications

A fuel cell system can produce electricity and water more efficiently while emitting near-zero emissions. Internal constraints and operating parameters such as hydrogen, temperature, humidity levels, and oxygen gas partial pressures trigger a nonlinear power characteristic in a typical fuel cell stack, resulting in reduced overall system efficiency. Consequently, it's critical to get the most power out of the fuel cell stack while minimizing fuel use. This study examines and proposes a radial basis function network (RBFN) based maximum power point tracking technique (MPPT) for a 6-kW proton exchange membrane fuel cell (PEMFC) system. The proposed MPPT algorithm modulates the duty cycle of the modified four-leg interleaved DC/DC boost converter (MFLIBC) to extricate the maximum power from the fuel cell system. To validate the execution of the proposed controller, the outcome is related to the various MPPT control strategies such as PID & Mamdani fuzzy inference systems. Finally, it was observed that the proposed RBFN controller has achieved an enhanced efficiency of 83.2 % relative to the PID and fuzzy logic controllers of 75.5 % and 77.4 % respectively. The efficiency of the proposed configuration is analysed using the MATLAB/Simulink platform.

Green Diesel Production Through Deoxygenation Reaction with Natural Zeolite-supported Nickel and Copper Catalyst

The depletion of fossil fuels and their environmental impact necessitate sustainable alternatives. Green diesel, a biofuel with a chemical structure similar to conventional diesel, has gained traction as a viable alternative. This study explores the development of a cost-effective catalyst for green diesel production using deoxygenation. Deoxygenation refers to a broad class of chemical reactions where oxygen atoms are stripped from a molecule. This research employed abundant Indonesian natural zeolite (NZ) as a catalyst support, impregnated with non-noble metals, nickel (Ni), and copper (Cu). The investigation revealed that the NiCu/NZ catalyst achieved the highest oleic acid conversion (90.40%) and green diesel yield. The product distribution, ranging from C15 to C18 hydrocarbons, reflects the moderate acidity of the catalyst, promoting diverse cracking patterns compared to highly acidic catalysts. Additionally, the high specific surface area of NZ facilitates the conversion and good product distribution. Furthermore, the optimization process demonstrated that increasing hydrogen pressure during deoxygenation enhances both conversion rate and green diesel production.

Comparative Study of Temperature and Pressure Variation Patterns in Hydrogen and Natural Gas Storage in Salt Cavern

Clarifying the distribution of temperature and pressure in the wellbore and cavern during hydrogen injection and extraction is crucial for quantitatively assessing cavern stability and wellbore integrity. This paper establishes an integrated flow and heat transfer model for the cavern and wellbore during hydrogen injection and withdrawal, analyzing the variations in temperature and pressure in both the wellbore and the cavern. The temperature and pressure parameters of hydrogen and natural gas within the chamber and wellbore were compared. The specific conclusions are as follows. (1) Under identical injection and withdrawal conditions, the temperature of hydrogen in the chamber was 10 °C higher than that of natural gas, and 16 °C higher in the wellbore. The pressure of hydrogen in the chamber was 2.9 MPa greater than that of natural gas, and 2.6 MPa higher in the wellbore. (2) A comparative analysis was conducted on the impact of surrounding rock’s horizontal and numerical distance on temperature during hydrogen and natural gas injection processes. As the distance from the cavity increases, from 5 to 15 m, the temperature fluctuation in the surrounding rock diminishes progressively, with the temperature effect in the hydrogen storage chamber extending to at least 10 m. (3) The influence of rock thermal conductivity parameters on temperature during the processes of hydrogen injection and natural gas extraction is also compared. The better the thermal conductivity, the deeper the thermal effects penetrate the rock layers, with the specific heat capacity having the most significant impact.

Pressure control of tritiated hydrogen isotopologues in hermetically sealed vessels by non-evaporable getters for sub-Doppler-resolution spectroscopy

Small molecules serve as valuable benchmarks for testing quantum chemical theories. Ultra-high-resolution spectroscopy currently offers the capability of measuring molecular hydrogen energy levels with a relative accuracy on the order of 10-10. Expanding such investigations to encompass different isotopologues of molecular hydrogen has emerged as a promising avenue for examining mass-dependent contributions to the full description of molecular structure in the framework of relativistic quantum electrodynamics. However, the delicate nature of handling radioactive tritium in a high-resolution spectroscopy environment poses significant technological challenges, thereby limiting the extension of these studies to include T2, DT and HT isotopologues. In this work, we present the experimental setup of the very sensitive, Doppler-free technique of Noise-Immune Cavity-Enhanced Optical Heterodyne Molecular Spectroscopy (NICE-OHMS), used to measure rovibrational transitions in the HT molecule. The NICE-OHMS measurements were performed in a closed cavity system without connection to an actively pumped vacuum system. For this reason, a new method for tritium storage and pressure regulation within 0.05–1Pa based on a temperature-controlled mini-getter system is employed using less activity than the tritium exemption limit (1GBq). Non-Evaporable Getters of the type SAES St171 were used for this purpose exploiting their property that hydrogen is released upon heating, while other gases remain being pumped. Prior to the NICE-OHMS experiment, the reversible sorption properties of the getter for hydrogen isotopes were investigated. We show measurements of the equilibrium (hydrogen) pressure for all three pure isotopes and for a H2:HT:T2 mixture (with H:T = 1:1) as a function of temperature for a system of defined volume and amount of gas. For the read-out of the temperature, a method using the resistance of the getter in combination with a pyrometric calibration has been implemented. We discuss the experiences from practical use of the tritium getter and show results obtained with the NICE-OHMS setup leading to frequency calibration of near-infrared transitions in HT at an accuracy, surpassing previous studies by nearly three orders of magnitude.