Hydrochemical Analysis Research Articles

Investigation of the Origin of Elevated Amounts of Iron and Manganese in a Dam Reservoir

On the outskirts of the Pinios dam reservoir (Ilia Regional Unit, Greece), a water treatment plant serves the water supply needs of the surrounding municipalities, in which high concentrations of Fe and Mn, before treatment, have been observed. The main purpose of this research was to investigate the mechanism of increased iron (Fe) and manganese (Mn) levels in the reservoir of the Pinios dam, which impacts its water treatment plant operation. A wide range of hydrochemical and sedimentological analyses were conducted over a hydrological year, focusing on the spatial and temporal distribution of Fe and Mn in both water and sediment samples across the established research monitoring stations. Sediment samples from the reservoir’s bottom revealed predominantly fine-grained material, rich in total organic carbon, with elevated Mn and Fe oxide levels. Significant seasonal variations in Fe and Mn levels were also discovered, with higher Mn levels observed in the anoxic bottom waters of the reservoir during the dry season, attributed to the reduced conditions favoring Mn oxide dissolution over Fe. Conversely, during the wet season, a homogenization of metal concentrations throughout the water column was observed due to increased oxygenation and freshwater inflow. These outcomes were confirmed by the hydrochemical analysis, indicating that the redox conditions, pH, and temperature, as well as the presence of organic matter, significantly influence the mobility and bioavailability of these metals in the reservoir. The findings of this study clarify that the high concentration of Fe and Mn can be linked to the mineral composition of the upstream Neogene and flysch formations in the study area. As these formations are affected by geological weathering, they tend to enrich the streams, through soil erosion and runoff processes, with metals like Fe and Mn, which are eventually transported into the dam reservoir. This study highlights the critical influence of lithological, sedimentological, and hydrological factors on the redox conditions and seasonal stratification that govern the behavior of Fe and Mn concentrations and mobility in dam reservoirs. These findings are critical for informing water resource management practices and dam infrastructure operators and developing effective environmental conservation strategies in similar cases.

Karst groundwater conservation based on hydrochemistry and isotope stable analysis in Obi Island, South Halmahera

Abstract This paper presents an analysis of the hydrogeological characteristics of the Kelo karst area in Obi Island, South Halmahera, focusing on hydrochemistry and isotopic methods to delineate the groundwater recharge zones and propose conservation measures. Despite its natural state, the Kelo karst area has not been previously studied for hydrogeology nor exploited for resources. Unregulated exploitation of karst areas poses significant environmental risks, leading to the degradation of their strategic and hydrological functions. This study investigates spring characteristics through hydrochemistry analysis, stable isotopes (δ18O and δ2H), and groundwater mixing processes. Hydrochemistry and isotopic analyses elucidate the hydrogeological features, including groundwater origin and recharge mechanisms. The predominant groundwater facies in the study area exhibit a Ca-Mg-HCO3 − composition, reflecting the dissolution processes of both limestone and igneous rock formations. Isotopic analysis and local meteoric water line examination indicate a recharge zone elevation ranging from 612 to 945 meters. Geological features such as fracture zones, lineaments, faults, and sinkholes significantly influence the determination of recharge areas. Protection of these recharge zones is imperative for groundwater conservation, ensuring the sustained availability and quality of groundwater amidst the development pressures on karst landscapes.

Hydrochemical characteristics of groundwater and their controlling mechanisms in irrigation and non-irrigation areas - a comparative study in the Guanzhong Plain of China

Gaining insight into groundwater chemistry and its evolution in irrigation areas is essential for optimizing irrigation strategies. This study explores the origins and influencing variables of groundwater chemistry across both irrigated and non-irrigated areas of the Guanzhong Plain, aiming to elucidate how irrigation practices impact hydrochemical changes. Hydrochemical data, isotopic data, multivariate statistical techniques and hydrochemical methods were used in this study. The findings underscored that groundwater in non-irrigation areas had low total dissolved solids, with 90% of the groundwater samples exhibiting the HCO3-Ca•Mg type. In comparison, groundwater from irrigation areas showed elevated total dissolved solids levels and diverse hydrochemical types, including HCO3-Ca•Mg, HCO3-Na, and SO4•Cl-Ca•Mg types. These categories collectively represented 88% of the water samples from irrigation areas. Isotopic and hydrochemical analyses revealed that groundwater in irrigation areas experienced more intense evaporation and cation exchange. Furthermore, anthropogenic activities like sewage and manure had a more pronounced effect on groundwater chemistry in irrigation areas. Groundwater suitability for irrigation deteriorated from the western irrigation area to the eastern irrigation area. This research offers a robust scientific foundation for the careful management and conservation of groundwater resources in the region.

Assessing inter-basin groundwater input to the Verlorenvlei estuarine lake using stable isotopes and hydrochemistry

Study region: Verlorenvlei Catchment (∼1 890 km2) is an agriculture-dominated area (∼43 % per km2) on South Africa’s west coast. This semi-arid region has variable rainfall and high evaporation rates, affecting the three major aquifers and Verlorenvlei – a RAMSAR-listed estuarine lake. Study focus: Natural processes (i.e., extended dry periods and evaporation) and anthropogenic activities (i.e., agricultural expansion and groundwater abstraction) have threatened Verlorenvlei’s ecological functions. Seasonal and spatial changes between the water sources (i.e., direct rainfall, surface water, and groundwater) supporting Verlorenvlei were determined using δ18O and δ2H isotopes and hydrochemical analyses. Inter-basin aquifer contribution was investigated to assist in explaining Verlorenvlei's slow recovery since the recent 2015 – 2018 Western Cape drought. New insights: A proportion of groundwater from outside the topographic and surface-water delineated catchment supports Verlorenvlei during the dry month of April (i.e., G30F Langvlei sub-catchment). Furthermore, Verlorenvlei experiences high evaporation (evaporation best fit line: δ2H = 12.49 x δ18O - 47.68, average δ2H value of 47.1 ‰ and average δ18O value of 7.64 ‰) compared to its feeding rivers. Two sandstone and shale-dominated sub-catchments exhibit overlapping groundwater δ18O and δ2H values and water types to the sub-catchment in the nearest vicinity of Verlorenvlei, suggesting a disproportionately high groundwater contribution from these sub-catchments to Verlorenvlei. Evaluation of Verlorenvlei’s water balance should consider both surface water and groundwater sources, particularly from inter-basin aquifer sources during prolonged droughts.

Hydrochemical analysis and groundwater quality assessment for irrigation in the Remila Plain, Khenchela, Northeast Algeria

Water resources are facing significant challenges in result of rapidly growing demand, deteriorating quality, and the effects of climate change. Today, water quantity and quality issues have become prevalent in various regions across the globe, affecting both northern and southern territories. Among the sectors reliant on this resource, irrigation stands out as the largest consumer of water. When surface water becomes inaccessible due to insufficient precipitation or other factors, the use of groundwater becomes the only viable alternative for irrigation. The Remila Plain (Khenchela) is located in an endorean watershed in northeastern Algeria and extends over 250 km2 in a synclinal basin filled with water from the Mio-Plio Quaternary - the main aquifer of the region, widely used for irrigation. The aim of this work is to study the hydrochemistry of these waters, as well as the evolution of mineralisation, the identification of the origin of the chemistry, and the suitability of these waters for irrigation. Initial results indicate an evolution of mineralisation in the direction of groundwater flow, with electrical conductivity values varying between 1000μS/cm in the recharge zones, and 2700μS/cm at the outlet. This mineralisation is mainly due to the dissolution of evaporitic minerals and the alteration of silicates. In addition, the various water quality indices used indicate that the water can be used for irrigation without major risk to plants and soils.

Assessment of Groundwater Quality and Vulnerability in the Nakivale Sub-Catchment of the Transboundary Lake Victoria Basin, Uganda

This study evaluates the quality and vulnerability of groundwater within the Nakivale Sub-catchment of the transboundary Lake Victoria Basin in Southwestern Uganda. Groundwater quality assessment focuses on its suitability for both drinking and agricultural uses. Hydrochemical analysis of 19 groundwater samples revealed that 90% comply with World Health Organization drinking water standards, although localized contamination was noted, particularly in terms of total iron, nitrate, potassium, magnesium, and sulfates. The drinking groundwater quality index shows that over 90% of the samples fall within the good-to-excellent quality categories. Elevated nitrate levels and chloride–bromide ratios indicate human impacts, likely due to agricultural runoff and wastewater disposal. For irrigation, Sodium Adsorption Ratio analysis revealed medium-to-high salinity hazards in the region, while Sodium Percentage and other parameters indicated low-to-moderate risks of soil degradation. DRASTIC vulnerability assessments identified low contamination risks due to impermeable geological layers, steep terrain, slow groundwater recharge, deep aquifer depth, and clayey soil cover. These findings emphasize the need for conjunctive water resource management, including improved groundwater quality monitoring, public education on sustainable practices, and protective measures for recharge zones and areas highly susceptible to contamination. By addressing these issues, this study aims to preserve groundwater resources for domestic and agricultural use, ensuring long-term sustainability in the region.

Formation Mechanism of Muji Travertine in the Pamirs Plateau, China

The Muji spring travertines, located in the Muji Basin in the eastern Pamirs Plateau, represent a typical spring deposit found on plateaus that is characterized by arid and semi-arid climatic conditions. However, its formation mechanisms remain poorly understood. This study aims to explore the recharge processes of the spring, the sedimentary environment, and the genetics of Muji spring travertines through a comparative analysis of conventional hydrochemistry, H-O stable isotope analysis of both spring and river water, and petrographic observation, as well as in situ analysis of major and trace elements present in calcite within travertines. The basin is surrounded by mountains with a topography that facilitates groundwater convergence within it. Carbonate-bearing strata are extensively developed around the basin, which serves as a crucial material foundation for travertine development. It infiltrates underground through fractures and faults, interacting with carbonate rocks to produce significant amounts of HCO3−, Ca2+, and Mg2+. The observed range of isotopic compositions (δ2H, −102.27‰ to −96.43‰; δ18O, −14.90‰ to −14.36‰) in water samples suggests that their primary origin was from glacial and snowmelt sources. The concentration of HCO3− in spring water samples exhibits significant variability, with the highest value being 1646 mg·L−1, which deviates significantly from the typical composition of karst groundwater. During its migration, groundwater undergoes the dissolution of gaseous CO2 derived from deep metamorphic processes, leading to variable degrees of mixing with geothermal groundwater containing elevated concentrations of dissolved components that enhance the dissolution potential of carbonate rocks. Eventually, upwelling occurs along the Southwestern Boundary Fault of Muji, resulting in the formation of linear springs characterized by CO2 escape. The Muji laminated travertines exhibit distinct white and dark laminae, and radial coated grains consisting of micritic and sparry layers. Chemical composition analyses reveal significant differences in the trace and rare-earth element composition, as well as the Mg/Ca ratio, of the two types of travertines. Specifically, the micritic laminae of the pisoid (Mg/Ca = 0.019; Sr = 530 × 10−6; Ba = 64.6 × 10−6) and the dark laminae of the laminated travertine (Mg/Ca = 0.014; Sr = 523 × 10−6; Ba = 48.1 × 10−6) exhibit generally higher Mg/Ca ratios and Sr, Ba contents than the neighboring sparry laminae (Mg/Ca = 0.012; Sr = 517 × 10−6; Ba = 36.6 × 10−6) and white laminae (Mg/Ca = 0.006; Sr = 450 × 10−6; Ba = 35.6 × 10−6). The development of laminated travertines and radial coated grains here is attributed to periodic changes in groundwater recharge induced by seasonal temperature fluctuations, as evidenced by the structural characteristics of the two types of travertines and the trace element analysis of different layers. Algae play a role in forming the dark laminae of laminated travertines and the micritic laminae of pisoids.

Hydrochemical Dynamics and Water Quality Assessment of the Ramsar-Listed Ghodaghodi Lake Complex: Unveiling the Water-Environment Nexus

Human activities and climate change increasingly threaten wetlands worldwide, yet their hydrochemical properties and water quality are often inadequately studied. This research focused on the Ghodaghodi Lake Complex (GLC) and associated lakes in Nepal, a Ramsar-listed site known for its biodiversity and ecological significance. The study was conducted to assess seasonal water quality, investigate the factors influencing hydrochemistry, and assess the lakes’ suitability for irrigation. Forty-nine water samples were collected from the GLC in pre-monsoon and post-monsoon periods. Nineteen physicochemical parameters, such as dissolved oxygen (DO), total dissolved solids (TDS), and major ions (calcium ‘Ca2+’, magnesium ‘Mg2+’, and bicarbonate ‘HCO3−’), were analyzed using standard on-site and laboratory methods. Statistical methods, including analysis of variance (ANOVA), T-tests, and hydrochemical diagrams, e.g., Piper, were adopted to explore spatial and seasonal variations in water quality, revealing significant fluctuations in key hydrochemical indicators. Results showed marked seasonal differences, with pre-monsoon TDS levels averaging 143.1 mg/L compared to 78.9 mg/L post-monsoon, underscoring evaporation and dilution effects. The hydrochemical analysis identified Ca2+-HCO3− as the dominant water type, highlighting the influence of carbonate weathering on GLC’s water composition. Gibbs, mixing, and Piper diagram analysis supported these findings, confirming the predominance of HCO3−, with Ca2+ and Mg2+ as the main cations. Additionally, sodium adsorption ratio (SAR) values were consistently below 1, confirming excellent irrigation quality. These findings provided critical data for policymakers and stakeholders, supporting sustainable wetland management and aligning with the United Nations’ Sustainable Development Goals relevant to environmental conservation, i.e., clean water and life on land.

Monitoring soil salinization and waterlogging in the northeastern Nile Delta linked to shallow saline groundwater and irrigation water quality

Soil salinization and waterlogging are critical environmental issues affecting agricultural productivity and cultural heritage preservation, particularly in arid regions. This study investigated soil degradation processes in the archaeologically and agriculturally significant northeastern Nile Delta of Egypt. The objective was to assess the severity of soil degradation and identify key drivers related to water resources and soil characteristics to aid in the development of management strategies. The research employed a multi-faceted approach, including hydrochemical analyses (of groundwater, irrigation water, and soil), water quality indices calculations, statistical analyses, and satellite data. The results revealed high levels of soil salinization in the northern and central areas, with 64% of soil samples classified as strongly and very strongly saline. Soil chemistry indicated salinization sources linked to sodium chloride dominance. Satellite data from Sentinel-2 images and SRTM digital elevation data showed widespread severe waterlogging in the northern lowlands. The Irrigation Water Quality Index (IWQI) values indicated that 87.5% of irrigation water samples posed severe restrictions due to high salinity and sodium hazards, which were mismatched with the low soil permeability observed in 81% of the collected samples exhibiting clay texture and covering most of the study area. Furthermore, shallow groundwater at depths of 0.5–3 m with high salinity was detected, where total dissolved solids exceeded 20,000 mg/L, and Na-Cl water types prevailed, indicating saltwater intrusion. A strong positive correlation (r > 0.83) was found between shallow saline groundwater and soil salinity. The combination of poor irrigation water quality, shallow saline groundwater tables, and low-permeability soils created a synergistic effect that severely compromised soil health and agricultural productivity. It also posed severe risks to the structural integrity of archaeological sites and buried artifacts through accelerated physical and chemical weathering processes. This necessitates an urgent mitigation strategy to combat soil degradation in this critical area.

Application of geochemical modelling and multiple regression analysis to reassess groundwater evolution in Kaduna Basin, NW Nigeria

Geochemical modelling (GM) and multiple regression analysis (MRA) are applied to reassess the evolution of groundwater to understand and estimate groundwater's quality and chemical changes. These methods provide a comprehensive procedure for evaluating and managing groundwater sources, especially in identifying the pollution sources, predicting upcoming changes and designing strategies for remediation. This review reassesses groundwater's hydrochemical evolution in the Kaduna Basin using GM and MRA. Hydrochemical data were obtained from the literature using a systematic approach and were subjected to GM and MRA. The geochemical modelling results showed that aquifers are saturated with Anhydrite, Chlorite, Chrysotile, Dolomite, Gypsum, Halite, K-Mica, Pyrite, Quartz, Dolomite, and Goethite. The Na2O-Al2O3-SiO2-H2O system indicated that the studied locations fell in Na-montmorillonite and Kalinite fields. However, the K2OAl2O3-SiO2-H2O system showed that groundwater is stable with Montmorillonite, Kaolinite, and K-Feldspar. MRA and Na+/Cl− molar ratio revealed that rock weathering significantly controls groundwater. The Na+/Cl− values are above 1 in 83.33%, 54.84%, and 26.27% sampling locations in the Kudenda-Nassarawa area, Kaduna South, and Kakuri and its Environs, respectively. The overall p-value was less than 0.01 and R-Sq = 63%, suggesting that all elements significantly influence aquifers' hydrochemistry. Results of geochemical modelling, Na+/Cl− molar ratio, and MRA are concurrent as they both show silicate weathering as the factor controlling groundwater hydrochemistry. Thus, geochemical and multiple regression analysis offers a reliable and user-friendly tool for assessing aquifers' hydrochemistry. We hope this review's findings will stimulate other researchers to an analogous procedure in a forthcoming study on hydrochemical analysis, especially those from semi-arid environments.

Assessment of groundwater quality variation characteristics and influencing factors in an intensified agricultural area: An integrated hydrochemical and machine learning approach

The decline in groundwater quality in intensive agricultural areas in recent years, driven by environmental change and intensified human activity, poses a significant threat to agricultural production and public health, requiring attention and effective management. However, distinguishing the specific impacts of various factors on groundwater quality remains challenging, which hinders the effective management and prevention of groundwater pollution. This research integrates a hydrochemical analysis with the Entropy-weighted Water Quality Index, Self-Organizing Map (SOM) approach, and Boruta algorithm to investigate groundwater chemical variations and their influencing factors in the Sanjiang Plain, an important grain-producing region in China. The findings reveal that, compared to 2012, the deep groundwater quality has improved, while the shallow groundwater quality has markedly deteriorated. This decline in shallow groundwater quality is primarily attributable to human activities and is characterized by elevated levels of chloride, sulfate, and nitrate and a shift in the groundwater hydrochemical facies from an HCO3−Ca·Mg type to a mixed HCO3−Ca·Mg and SO4·Cl−Ca·Mg type. The SOM results suggested that land use type significantly affects shallow groundwater quality. Further analysis with the Boruta algorithm identified increased sewage and manure emissions from expanding livestock operations as well as enhanced pollutant leakage from the expansion of paddy fields as the primary contributors to the decline in shallow groundwater quality. These findings offer new insights into the mechanisms of groundwater quality changes in agriculturally intensive regions and provide a foundation for improved groundwater pollution management in the Sanjiang Plain and similar areas.

Ecological Assessment of Phytoplankton Diversity and Water Quality to Ensure the Sustainability of the Ecosystem in Lake Maybalyk, Astana, Kazakhstan

Microalgae in planktonic communities are the main producers of biomass in lake ecosystems; however, their stability is influenced by many environmental factors. This study aims to assess the ecological state of Lake Maybalyk, located in Astana (Kazakhstan), based on the study of the taxonomic diversity and structure of phytoplankton, zooplankton, and the physico-chemical properties of the water. From 2019 to 2021, samples were taken for phytoplankton analysis, hydrochemical analysis of the water, zooplankton, and saprobiological analysis of the algocenosis. The study also investigated the main morphometric parameters of the lake, as well as the composition of hydrobionts, such as zooplankton, zoobenthos, and ichthyofauna. The analysis of phytoplankton revealed the presence of 97 species and intraspecific taxa of microalgae, with 71 types of microalgal indicators indicating water saprobity. The planktonic algoflora in Lake Maybalyk is predominantly composed of diatoms (Bacillariophyta) and green algae (Chlorophyta), which play a vital role in oxygen production and the food chain within the reservoir. Based on the Pantle–Buck saprobity index (2.15–2.5), the water quality in Lake Maybalyk is classified as moderately polluted. The assessment of the water quality, considering the number and composition of indicator phytoplankton species, places Lake Maybalyk in class III (β-mesosaprobic). The hydrochemical indicators align with the hydrobiological indicators, confirming the water quality as class III. The trophic status of the reservoir, during the study period, can be described as average. The obtained data on both the hydrobiological and hydrochemical indicators correlate, suggesting satisfactory water quality and the ability of the reservoir to purify itself. This study contributes to the sustainable management of water resources, by providing essential data on the ecological state of Lake Maybalyk. The results underscore the importance of continuous biomonitoring, with microalgae as indicators of water quality, which is crucial for developing effective ecosystem conservation strategies.

Interaction regimes of surface water and groundwater in a hyper-arid endorheic watershed on Tibetan Plateau: Insights from multi-proxy data

The interaction between surface water and groundwater is crucial for the management of water resources and the preservation of ecosystems within arid basins, but knowledge on their interaction regimes at the watershed scale remains relatively limited. The present research synthesizes a range of multi-proxy data, including satellite thermal infrared remote sensing, water piezometric level, hydrochemical analyses, and isotopic signatures (2H, 18O and 222Rn), to elucidate the interaction dynamics and patterns between surface water and groundwater within a representative hyper-arid closed basin on Tibetan Plateau. The findings indicate that the water in the basin originates primarily from the glacier/snow melt water and precipitation in the mountainous regions, and would experience multiple but spatially heterogeneous interactions between river and aquifers from the mountain pass to the tail salt lakes after entering the basin. Water interaction in the piedmont alluvial plain is dominated by the pattern of river seepage into aquifers with a water flux of 25.82 m3/s, which drives the development of hierarchical groundwater flow systems in the basin. The interaction pattern converts to groundwater discharge of the local groundwater flow system at the front of alluvial fan plain, which forms the principal spring-fed rivers and the predominant overflow zone in the basin with the groundwater discharge flux of 3.22 m3/s. Most of these discharged groundwaters would infiltrate back into the aquifers in the middle-upper part of the loess plain with the river water leakage flux of 2.89 m3/s. River water and phreatic groundwater present a gradual enrichment of hydrochemcial components and water stable isotopes (2H and 18O) along the flow path due to the intense evaporation in the loess plain. The multiple water interactions between surface water and groundwater lead to the anomalous distribution of fresh water in the middle-lower stream area, which is related to the intermediate groundwater flow system and the local variable groundwater flow system. Water interaction in the lowest salt-marsh plain is in the pattern of regional groundwater flow system discharge into the tail salt lakes under natural condition, but evolves to only discharge into the artificial brine extraction canals rather than the tail salt lakes after decades of brine exploitation. Our findings provide a conceptual and preliminarily quantificational understanding of the interaction regimes between surface water and groundwater in large arid closed basins at the watershed scale.

Controversial insights into irrigation water quality in arid and semi-arid regions using AI driven predictions: Case of southern Gabès

Effective groundwater management is critical in arid and semi-arid regions, where water resources are essential for agriculture. This study assesses the Irrigation Water Quality Index (IWQI) of the Southern Gabès aquifer in Tunisia using a combination of traditional hydrochemical analysis and machine learning models—specifically, Classification and Regression Tree (CART) and Support Vector Machine (SVM). A total of 83 groundwater samples were analyzed based on five key parameters: Electrical Conductivity (EC), Sodium Adsorption Ratio (SAR), Chloride (Cl-), Sodium (Na+), and Bicarbonate (HCO3-). The results show that the CART model demonstrated superior performance with an R2 value of 0.99 and a Root Mean Square Error (RMSE) of 0.43, while the SVM model achieved an R2 of 0.87. These findings underscore CART's robustness in predicting IWQI, offering high precision even with limited datasets.The groundwater quality was categorized, revealing that 62% of samples were classified as "satisfactory" for irrigation, while 31% were deemed "unsuitable" without treatment, highlighting areas of concern for agricultural use. The study also emphasizes the importance of continuous monitoring and adaptive management strategies to ensure sustainable water use in the region.Overall, this research demonstrates the effectiveness of machine learning models, particularly CART, in accurately assessing groundwater quality. These insights provide valuable tools for resource managers to make informed decisions, ensuring the sustainable exploitation of groundwater in arid and semi-arid regions. The findings pave the way for future research and policy development in water resource management.

Cross Comparison of GALDIT Method Application in Three Costal Aquifers in Greece

Seawater intrusion into Greece’s coastal aquifers is a prevalent issue. The Greek coastline extends for 15,147 km. Once groundwater sources become contaminated, remediation methods are often challenging, costly, and protracted. This study focuses on three coastal aquifer systems in the Peloponnese region. Initially, the main ions and cations were determined for these aquifers. Hydrochemical analyses revealed elevated concentrations of Na+, Mg2+, Ca2+, SO42−, and Cl−, indicating a significant impact from seawater intrusion. The study evaluates the vulnerability of groundwater to this intrusion. Utilizing Geographical Information Systems (GIS) software (ArcGISPro), maps were created to illustrate each parameter of the GALDIT method. The acronym GALDIT encapsulates the main elements influencing seawater intrusion. Each parameter is analyzed as follows: Groundwater occurrence (including the following aquifer types: unconfined, confined, and leaky confined), Aquifer hydraulic conductivity, depth to groundwater Level above the sea, Distance from the shore (inland distance perpendicular from shoreline), Impact of existing status of sea water intrusion in the area, and Thickness of the aquifer. The final map that emerged from this study shows their vulnerability to seawater intrusion in Peloponnese. Notably, Larissos exhibits lower vulnerability in contrast to the seawater incursion in the other two groundwater systems.

Hydrochemical Analysis of Salt Lakes in the Caspian Lowland of the Mangistau Region of the Republic of Kazakhstan

Hydrochemical Analysis of Salt Lakes in the Caspian Lowland of the Mangistau Region of the Republic of Kazakhstan

Hydrochemical Assessment of Groundwater in Ludhiana and Amritsar Districts of Punjab and Identification of Fluoride Hotspots using GIS

High fluoride concentrations in soil, water, or air can pose serious environmental and health risks to plants, and animals. Along with other hydrochemical parameters, this study investigates fluoride concentrations in the groundwater in the Ludhiana and Amritsar districts of Punjab, India. A total of 222 water samples were uniformly collected at approximately five-kilometer intervals for hydrochemical analyses. Statistical methods such as inverse distance weighting (IDW) and correlation matrices were used to assess the fluoride distribution and its relationships with other parameters. According to WHO guidelines, most fluoride concentrations were below 0.6 ppm in Ludhiana (84.30%) and Amritsar (77.23%). Fluoride levels that were within the permissible range (0.6–1.5 ppm) were found in 15.70% of Ludhiana’s samples and 21.78% of Amritsar’s samples; only 1% of Amritsar’s samples exceeded the permissible limit (>1.5 ppm). The water quality index (WQI) analysis indicated that0.83% of the groundwater samples from the Ludhiana district and 4.95% from the Amritsar district were unfit for consumption. This study demonstrates the importance of standardized sample collection and the use of GIS technology for comprehensive hydrochemical assessments, raising awareness and reducing health risks.

Integrated study of hydrochemistry, quality and risk to human health of groundwater in the upper reaches of the Wulong River Basin.

Groundwater, a vital source of water supply, is currently experiencing a pollution crisis that poses a significant risk to human health. To understand the hydrochemical formation mechanisms, quality and risk to human health of groundwater in the upper reaches of the Wulong River basin, 63 sets of groundwater samples were collected and analyzed. A combination of mathematical statistics, correlation analysis, Gibbs diagram, ion ratio, and cation exchange were comprehensively employed for hydrochemical analysis, and further water quality index (WQI) and human health risk assessment were conducted. The results indicate that groundwater is generally neutral to weakly alkaline. The dominant cations in the groundwater are Ca2+ and Mg2+, while the main anions are HCO3- and SO42-. The hydrochemical types of groundwater mainly include HCO3·SO4-Ca, HCO3-Ca and HCO3-Na. The diverse hydrochemical types are mainly due to the fractured and discontinuous nature of the aquifers. The hydrochemical characteristics are influenced by the dissolution of silicate and carbonate minerals, cation exchange processes, and anthropogenic pollution. The presence of NO3- in groundwater is primarily attributed to agricultural activities. The groundwater is mainly categorized as "Good" (36.6%) and "Poor" (60.8%). "Very poor" and "Excellent" categories are rare, accounting for only 1.2% and 1.4%, respectively, and no samples are classified as "Non-drinkable". The Ewi for NO3- is the highest, indicating severe contamination by anthropogenic NO3- pollution. Human health risk assessment reveals that water samples posing exposure risks account for 82.54% for children and 79.37% for adults. This study highlighted that anthropogenic nitrate pollution has deteriorated groundwater quality, posing risks to human health. It also suggests an urgent need to enhance research and protective measures for groundwater in similar regions, such as the Shandong Peninsula.

Hydrographic and hydrochemical characteristics of selected groundwater outflows in desert and semi-desert areas

The presence of natural groundwater outflows depends on many factors, such as lithology, geological structure, and climate. Areas with particularly poor crenological recognition are arid and semi-arid regions, primarily due to rarity of groundwater outflows in these locations. The article presents the hydrographic and hydrochemical characteristics of selected groundwater outflows in arid and semi-arid areas. In addition to hydrographic mapping, basic physical parameters of water were measured in selected springs, such as temperature (T, °C), electrolytic conductivity (EC, μS∙cm–1), and reaction (pH, –). Laboratory analyses determined the major cations and anions in water: Ca2+, Mg2+, Na+, K+, NH4+, SO42−, Cl−, NO3−, Br−, PO43−,. The analyses were performed using an ion chromatograph Metrohm 850 Professional IC. Twenty-four natural groundwater outflows in South America, Africa, and Asia were selected for research. It was found that the vast majority of outflows are transit sources. Their supply area may be far from discharge points. The supply source is rainwater or meltwater from high mountain massifs. Other types of outflow are springs of alluvial fans and braided rivers. They are fed by waters from glacial rivers, which infiltrate alluvial deposits and flow back to the surface. Hydrochemical analysis has shown that the physicochemical properties of water in dry areas vary significantly. Still in the hydrochemical type, there is a predominance of sulphate, chloride, and sodium ions. This distinguishes the spring waters from these areas in temperate latitudes, which are dominated by bicarbonate and calcium ions.

The mechanical and hydrochemical properties of cemented calcareous soil under long-term soaking

This study investigates the impact of long-term water immersion on the mechanical and hydrochemical properties of cemented calcareous soil, emphasizing the critical role of carbonate content in mechanical performance. Utilizing hydrochemical analysis and triaxial testing, the research revealed that prolonged immersion disrupts the acid-base balance of the solution, resulting in an increased concentration of ions and chemicals. Significant dissolution of carbonates and soluble minerals occurs, which reacts with carbon dioxide to generate bicarbonate ions, thereby elevating the alkalinity of the soaking solution. Additionally, the gradual dissolution of clay minerals compromises the cementitious structure, leading to particle reorientation and interlocking. The study quantitatively assesses the changes in soil properties, demonstrating a substantial reduction in soil cohesion by up to 86.1% and an increase in the internal friction angle by 37.5%. Furthermore, the gradual dissolution of clay minerals compromises the cementitious structure, resulting in particle reorientation and interlocking that contribute to the observed mechanical changes. The findings underscore the importance of understanding the effects of extended immersion on the stability and engineering applicability of cemented calcareous soils.