Hydraulic Gradient Research Articles

A Hydraulic Gradient and Stress-Controlled Erosion Apparatus for Assessing Soil Internal Erosion

Abstract Among the four dominant mechanisms of internal erosion, suffusion appears as one of the most complex. It is indeed the result of the combination of three processes: dislodgement of fine particles, transport of them, and filtration of some fluidized fine particles. These processes depend on the soil’s stress state and on the hydraulic gradient path. Thus, to ensure the repeatability of the suffusion test and to study with accuracy the influence of the aforementioned parameters, a new apparatus was developed. This apparatus is designed to test specimens under a vertical downward flow in hydraulic gradient controlled condition while controlling the confining pressure and the stress deviator, which can be either positive or negative. Ten tests on one cohesionless soil were performed in triaxial conditions, with the same mean effective stress and four different values of stress deviator. To compare with conventional suffusion results, one test is also performed in rigid wall conditions. For all performed tests, the same hydraulic gradient path was applied and particular attention is paid to the repeatability, which implies control of each test step. At the end of each test, the specimen was divided into four layers to measure post-suffusion grain size distributions. The time evolutions of the hydraulic conductivity and the erosion rate permit to identify four different phases. Each phase is characterized by two methods: one based on the hydraulic gradient and the second based on the expended energy by the fluid. The results show the great influence on the suffusion kinetics of the preferential flow paths, which localize in the body of the specimen in triaxial conditions and on the circumference in rigid wall ones. Under a constant mean effective stress, the effect of the stress deviator on the suffusion kinetics appears limited, for the tested soil and shear stress ratios.

Effectiveness and impact factors of passive convergence-permeable reactive barrier (PC-PRB): Insights from tracer simulation study

Passive convergence-permeable reactive barrier (PC-PRB) represents a green and sustainable technology for in-situ remediation of contaminated groundwater. A laboratory-scale PC-PRB tracer simulation system was established to quantify its contaminant plume capture performance using image analysis method. Results indicate that PC-PRB captures the plume 65% wider than C-PRB, which means that fewer PRB sizes and materials volume would be necessary to treat an equivalent contaminated plume. This improvement is due to a significant drawdown within the PC-PRB's passive well, known as the passive hydraulic decompression-convergent flow effect. We further evaluated the effects of water pipe length, hydraulic gradient, and media particle size on PC-PRB's plume capture performance. Results indicate that an increased water pipe length enhances the PC-PRB's plume capture capacity due to greater well drawdown. PC-PRB not only captures the plume but also acts as a hydraulic barrier. The retardation effect of PC-PRB on plume migration increases with water pipe length. Conversely, both hydraulic gradient and media particle size impact the plume capture capacity of PC-PRB by modifying groundwater flow velocity and pollutant dispersion. An increase in either hydraulic gradient or media particle size decreases the plume capture performance of PC-PRB. Therefore, PC-PRB technology may be more effective in contaminated sites characterized by low hydraulic gradients and permeability. Overall, PC-PRB demonstrates significant effectiveness in enhancing plume capture performance, which can notably reduce remediation costs and environmental footprint, broadening its application scope.

Stability Assessment of Weirs Reinforced with Sheet Piles

Extreme weather events induced by climate change are increasing across the world. In particular, floods resulting from unpredictable heavy rains cause significant damage to property and human life. In Korea, river and underwater structure management is performed continuously in accordance with strict regulations. However, to prepare for unprecedented downpours, the structures of river reservoirs must be reinforced and their stability must be evaluated. This study focuses on the stability evaluation of piping, which represents the main cause of weir collapse. To this end, sheet piles are applied to weirs to evaluate the effects of changes in their length and location on their seepage discharge, seepage velocity, and maximum hydraulic gradient. Additionally, piping stability evaluation of weirs is conducted using sheet piles by evaluating the critical velocity. The results derived in this study are expected to be highly beneficial for reinforcing weirs currently in operation as well as for the design, construction, and operation of future underwater structures.

Storm surge, seawater flooding, and sea-level rise paradoxically drive fresh surface water expansion

Abstract Coastal storms and sea-level rise are expected to increase seawater flooding in low-elevation coastal zones. High sea levels and seawater flooding can drive groundwater table rise via ocean-aquifer connections. These dynamics are often overlooked but can cause groundwater flooding and salinization hazards, increasing freshwater security challenges for coastal communities and driving ecosystem transgressions. Field data and numerical modeling were used to evaluate how heavy rainfall, storm surge, and seawater flooding and infiltration during Hurricane Fiona (September 2022) and projected sea-level rise impact groundwater levels, inland surface waters, and saltwater intrusion on Sable Island National Park Reserve, Canada. During the passage of Hurricane Fiona, precipitation increased groundwater and pond levels before seawater flooded the beach. Seawater flooding and infiltration caused a sharp rise in beach groundwater levels, which in turn caused inland pond levels to rise without coincident direct inputs from precipitation or seawater. Model simulations reveal that seawater infiltration on beaches flooded the subsurface and drove the observed inland groundwater rise and freshwater pond expansion. Simulations of projected sea-level rise show that seawater flooding will only inundate a small area of land along the coast; however, inland groundwater rise and flooding, which is less well-studied, may inundate up to 30 times more land area. Further, groundwater flooding driven by rising sea levels decreases hydraulic gradients and increases saltwater intrusion via freshwater lens contraction. Findings demonstrate that seawater flooding from coastal storms and sea-level rise paradoxically cause concurrent fresh surface water expansion but freshwater lens contraction. This study provides new insights into the spatiotemporal dynamics of island freshwater resources and highlights that unseen and often overlooked groundwater-surface water exchanges are critical to consider when evaluating coastal flooding and groundwater salinization hazards and management strategies for low-elevation coastlines.

Controls on regional sulphate distribution in shallow groundwater in the western Canadian Interior Plains

Sulphate (SO4), predominantly derived from sulphur (S)-bearing glacial sediments distributed widely across the Canadian Interior Plains, contributes to high groundwater salinity and can be detrimental to riparian and dry-land ecosystems, agricultural production, and water use. While previous researchers investigated SO4 distribution and dynamics in shallow groundwater at local scales (<1500 km2), we examine SO4 occurrence in groundwater at larger scales, and to depths of ~150 m, considering variations in geology, glacial history, climate, and geochemical and hydrogeological settings in the Canadian province of Alberta. Sulphate concentrations in groundwater vary considerably, with 15 % of 139,130 samples above the 500 mg/L Canadian drinking water aesthetic objective. Analysis of δ34SSO4 and δ18OSO4 from 179 wells throughout Alberta shows SO4 is dominantly derived from oxidation of S-bearing material. At this large scale, marine shale bedrock subcrops, glacial ice flow directions, and climate control SO4 distribution. Groundwater contains less SO4 (<200 mg/L) in western Alberta compared to the east due to a lack of S-bearing bedrock, higher groundwater recharge rates, thinner glacial sediments, and increased groundwater circulation. Focusing on a region in south-central Alberta (Red Deer area), hydrogeological characteristics relating to SO4 formation, recharge, permeability, hydraulic gradient, and travel time are included in a principal component analysis to identify six groundwater groups at varying stages of evolution and SO4 concentrations depending on their hydrogeological setting. Low SO4 concentrations are associated with areas of high recharge, where SO4 has been leached from the sediments, or with more evolved bedrock groundwater where SO4 has been reduced or was recharged in pre-glacial times. High SO4 concentrations are found in areas of lower recharge and permeability, where flushing occurs more slowly. Combining the Red Deer area and province-wide analyses, we identify seven regions across Alberta with characteristic distribution and controls on SO4 occurrence in shallow groundwater.

On the Scaling of Transport Phenomena at a Monotonously Changing Hydraulic Conductivity Field

Monotonously stratified porous medium, where the layered medium changes its hydraulic conductivity with depth, is present in various systems like tilled soil and peat formation. In this study, the flow pattern within a monotonously stratified porous medium is explored by deriving a non-dimensional number, Fhp, from the macroscopic Darcian-based flow equation. The derived Fhp theoretically classifies the flow equation to be hyperbolic or parabolic, according to the hydraulic head gradient length scale, and the hydraulic conductivity slope and mean. This flow classification is explored numerically, while its effect on the transport is explored by Lagrangian particle tracking (LPT). The numerical simulations show the transition from hyperbolic to parabolic flow, which manifests in the LPT transition from advective to dispersive transport. This classification is also applied to an interpolation of tilled soil from the literature, showing that, indeed, there is a transition in the transport. These results indicate that in a monotonously stratified porous medium, very low conducting (impervious) formations may still allow unexpected contamination leakage, specifically for the parabolic case. This classification of the Fhp to the flow and transport pattern provides additional insight without solving the flow or transport equation only by knowing the hydraulic conductivity distribution.

Evaluation of the hydrogeological response to neotectonics of the Quequén Grande River Watershed using geoelectrical methods

The Quequén Grande River Watershed (Southeast of Buenos Aires Province, Argentina) is a strong asymmetrical watershed in the Pampean Plain. It is marked by the stream capture of the Quequén Grande River eastward. The topographic slopes and hydraulic gradients are typically low in this area, with streams and rivers primarily effluent along their courses. This behavior is attributable to the influence of the unconfined and shallow Pampean aquifer, which serves as the region's main source of water supply. In the southwestern limit of this drainage basin, several shallow lakes, disconnected from the surface drainage network and related to an old deflation/accumulation relief, occur over hillock formations. In this area, Paleozoic rocks crop out and constitute the hydrological basement of the aquifer. The bedrock architecture of this formation could explain the stream piracy of the Quequén Grande River eastward and the local geomorphology, where structural lineaments related to neotectonic movements have been reported. However, there is a lack of information related to the hydrological basement in depth, which is needed to understand the surface water dynamics of this drainage basin, linked to the topographic control of the landscape. To fill this gap, a geoelectric model of the hydrological basement is proposed from 37 Vertical Electrical Soundings and 6 Electric Resistivity Tomographies, aiming to contribute to understanding this portion of the Earth's crust. Geoelectrical surveys were performed over 3000 km2 of the southwestern limit of the Quequén Grande River Watershed. Results obtained and field observations suggest the deviation of the Quequén Grande River catchment eastward is caused by the hydrogeological basement structure in depth, in response to neotectonic movements inferred by structural lineaments.

Temporal and spatial evolution of residual saltwater contamination in coastal subterranean reservoirs

This study numerically investigated the dynamic process of residual saltwater contamination in subterranean reservoirs (aquifer upstream of subsurface physical barrier) for the first time. The results indicated that the groundwater level elevation resulting from subsurface physical barriers induced a small hydraulic gradient in the subterranean reservoir, with residual saltwater convection driven by the density contrast between saltwater and freshwater. This led to persistent inland intrusion of residual saltwater, causing a gradual expansion of the contamination area (i.e., concentration higher than 0.25 g/L) and a decreased area of high-salinity zone. The area of low concentration residual saltwater (0.25 g/L) initially increased and then decreased over time. For large-scale aquifers, the proportion of the maximum contaminated area to the total aquifer area increased from 0.05 to 0.17. Subsequently, the low-concentration saltwater was considered as a relative high-concentration for ambient freshwater, which released salts into the surroundings and the contamination area reduced to 0.0003 at 160000 d. In small-scale aquifers, residual saltwater transport was affected by inland boundary, and the low-concentration saltwater reached inland boundary at approximately 2000 d, which limited its horizontal expansion and resulted in the polluted area reaching an inflection point early relative to large-scale aquifers. The salt transfer from high-concentration residual saltwater to low-concentration saltwater was closely related to aquifer parameters of hydraulic conductivity, dispersivity, and molecular diffusion coefficient. These findings suggest that residual saltwater contamination should not be overlooked when assessing the efficiency of subterranean reservoirs.

Physical modeling of organics-contaminated groundwater remediation by ozone micro-nano-bubbles enhanced oxidation

Ozone micro-nano-bubbles (MNBs) enhanced oxidation is a promising in-situ remediation technology for organics-contaminated groundwater. The transport behavior of MNBs and contaminant removal effect in actual groundwater scene is not yet comprehensively understood, although one-dimensional column experiments and batch tests were conducted to investigate the migration of MNBs and contaminant degradation in previous studies. Here, a novel two-dimensional (2D) physical modeling facility was developed, which can characterize the tempo-spatial distribution of MNBs and contaminant in groundwater. The facility was used to explore the migration of MNBs under different hydraulic gradients and the removal of methyl orange, a representative organic pollutant, using ozone MNBs. The experimental results show that groundwater flow velocity has a significant influence on the migration behavior of MNBs. A model including groundwater flow, MNBs transport, and dissolved gas transport can well capture the migration and distribution of MNBs under different hydraulic gradients. The longitudinal and transverse dispersivities of the MNBs were calculated to be 1.14 cm and 0.18 cm, respectively. MNBs are able to migrate with groundwater flow to long distances and exhibit strong dispersion in the lateral and longitudinal directions. The increase in hydraulic gradient greatly enhances the transport of MNBs in groundwater and relieves the deposited MNBs on the surface of porous media. At a hydraulic gradient increasing from 0.033 to 0.1, the range of influence of MNBs increased from about 80 cm × 40 cm to 140 cm × 39 cm after 36 h of injection of oxygen MNBs water. The methyl orange in groundwater is effectively removed by ozone MNBs enhanced oxidation, showing the remarkable remediation ability of ozone MNBs. The area of influence and pollutant removal of the ozone MNBs expanded with injection, and the area of influence was approximately 48 cm × 30 cm after 48 h of treatment. We also discuss the effect of groundwater matrix on ozone MNB migration and degradation of contaminants. The 2D model tests illustrate the mechanism of MNB migration and indicate that ozone MNBs enhanced oxidation technology has great potential in the remediation of organics-contaminated groundwater.

A Comparative Study for Evaluating the Groundwater Inflow and Drainage Effect of Jinzhai Pumped Storage Power Station, China

Various hydrogeological problems like groundwater inflow, water table drawdown, and water pressure redistribution may be encountered in the construction of hydraulic projects. How to accurately predict the occurrence of groundwater inflow and assess the drainage effect during construction are still challenging problems for engineering designers. Taking the Jinzhai pumped storage power station (JPSPS) of China as an example, this paper aims to use different methods to calculate the water inflow rates of an underground powerhouse and evaluate the drainage effect caused by tunnel inflow during construction. The methods consist of the analytical formulas, the site groundwater rating (SGR) method, and the Signorini type variational inequality formulation. The results show that the analytical methods considering stable water table may overestimate the water inflow rates of caverns in drained conditions, whereas the SGR method with available hydro-geological parameters obtains a qualitative hazard assessment in the preliminary phase. The numerical solutions provide more precise and reliable values of groundwater inflow considering complex geological structures and seepage control measures. Moreover, the drainage effects, including a seepage-free surface, pore water pressure redistribution, and hydraulic gradient, have been accurately evaluated using various numerical synthetic cases. Specifically, the faults intersecting on underground caverns and drainage structures significantly change the groundwater flow regime around caverns. This comparative study can not only exactly identify the capabilities of the methods for cavern inflow in drained conditions, but also can comprehensively evaluate the drainage effect during cavern construction.

Analytical Solutions for Consolidation of Soft Ground With Impervious Columns Considering Non‐Darcian Flow

ABSTRACTCohesive material columns have been extensively used in foundation improvement projects to enhance the bearing capacity of composite foundations and mitigate post‐construction settlement. However, the low permeability of cohesive material columns restricts the dissipation of pore water primarily through the top surface of the foundation, potentially resulting in longer drainage paths compared to foundations treated with granular material columns or vertical drains. Moreover, the impact of non‐Darcian flow within soils on consolidation behavior becomes increasingly pronounced as the drainage path increases. Consequently, a novel analytical model for the consolidation of impervious column‐assisted foundations is established, which can incorporate the seepage model accounting for the initial hydraulic gradient. The accuracy and reasonableness of the obtained solution are then validated by conducting a comparative analysis with existing models and through a detailed case study. Furthermore, a parametric analysis is conducted to delve into the influence of several crucial factors on the consolidation performance. The findings demonstrate that non‐Darcian flow has a greater influence on composite foundations compared to natural foundations. Additionally, the threshold value of the well‐diameter ratio decreases with the increase in the initial hydraulic gradient. Finally, the final seepage front remains at a shallower position when the column–soil modulus ratio becomes larger, and the influence of non‐Darcian flow on the consolidation rate becomes more pronounced.

Filtration compatibility of clay-nonwoven geotextiles under normal stress

Nonwoven geotextiles are commonly utilized as filter materials in drainage and filtration engineering. This study focuses on the clogging phenomenon of the nonwoven geotextile filter wrapping the blind drain in the active anti-floating technology of underground structures. In this paper, the filtration compatibility of clay-nonwoven geotextiles was evaluated using a newly developed gradient ratio test device that can apply normal stress. Two fabrication technics and four specifications of nonwoven geotextiles were used to filter clay, and the geotextiles’ clogging degree was assessed after the test. The influences of normal stresses, hydraulic gradients, and fabrication technics on nonwoven geotextile filtration performance were discussed based on results from a series of gradient ratio tests. Relevant assessment parameters (clogging coefficient, soil retention, and equivalent porosity) were also presented to quantify the clogging degree of nonwoven geotextiles after the test. Furthermore, the clogging process of nonwoven geotextiles filtering clay was initially explored, and the filtration effect of the needle-punched and heat-bonded nonwoven geotextiles was evaluated. The results showed that normal stress had a significant effect on nonwoven geotextile filtration, with needle-punched nonwoven geotextiles having better soil filtration and water permeability. Discussions on nonwoven geotextile applications in specific environments or conditions are also presented.

Comprehensive, Multi‐Scale Evaluation of Field Methods for Assessing Stream–Aquifer Interactions Along Channelised Lowland Streams

ABSTRACTStream–aquifer interactions (SAIs) play a critical role in effective groundwater management, yet their complex dynamics remain poorly understood in channelized lowland perennial streams. This study presents a multi‐scale, multi‐technique investigation of SAIs along two long‐stream reaches in Tennessee, United States. The goal is to define a suitable methodology for characterising SAIs in this specific hydrological setting, serving as a starting point for developing a more standardised and replicable approach. The methodology includes an initial evaluation of various field techniques, followed by extensive surveys using potentiomanometers, electromagnetic induction (EMI), vertical temperature profilers (VTPs) and complementary methods such as seepage meters, bank tests and well‐data analyses. Results reveal distinct hydrogeomorphic behaviours across and along the streams, challenging the SAI‐homogeneity notions typically assumed in groundwater models. Nonconnah Creek exhibited streambed colmation and negligible hydraulic gradients, resulting in disconnection from the aquifer during low flows, except for a 300‐m losing reach with high downward gradients. In contrast, the Loosahatchie River displayed relatively homogeneous streambed properties and small, upward hydraulic gradients, suggesting uniform SAIs along the surveyed reaches. EMI proved highly effective for mapping streambed sediments quickly, while potentiomanometers accurately measured small head differences critical for understanding SAI dynamics. VTPs were less practical due to the extended data‐collection times required and their vulnerability to flooding. This study emphasises the importance of multi‐scale investigations using diverse techniques to accurately characterise SAIs in lowland streams, highlighting the confounding influences of geological formations, anthropogenic alterations and depositional processes on groundwater–surface water interactions. The findings contribute to refining local water balances, informing groundwater management strategies and underscoring the need for incorporating local‐scale field data into regional groundwater models. The proposed methodology serves as a foundation for developing a standardised approach for characterising SAIs in lowland channelized perennial streams, adaptable for similar stream systems worldwide.

Examining the Mid to Long‐Term Variability in Saturated Hydraulic Conductivity of Sandy Soils and Its Influencing Factors Under Constant Head Test in the Laboratory

AbstractSaturated hydraulic conductivity (Ks) is a crucial parameter that influences water flow in saturated soils, with applications in various fields such as surface water runoff, soil erosion, drainage, and solute transport. However, accurate determination of Ks is challenging due to temporal and spatial uncertainties. This study addresses the knowledge gap regarding the long‐term behavior of Ks in sandy soils with less than 10% fine particles. The research investigates the changes in Ks over a long period of constant head tests and examines the factors influencing its variation. Two sandy samples were tested using a hydraulic conductivity cell, and the hydraulic head and discharge were recorded for over 50 days. The results show a general decline in Ks throughout the test, except for brief periods of increase. At the end of both tests, there are noticeable reductions in the saturated hydraulic conductivities of the samples, with one sample being 96% and the other sample 91% less than the maximum recorded saturated hydraulic conductivity during the tests. Furthermore, the relationship between flow rate and hydraulic head gradient does not follow the expected linear correlation from Darcy's law, highlighting the complex nature of sandy soil saturated hydraulic conductivity. The investigation of soil properties in three different sections of the samples before and after the tests revealed a decrease in the percentage of fine particles and a shift in specific gravity from the bottom to the top of the sample, suggesting particle migration along the flow direction. Factors such as clogging by fine particles and pore pressure variation contribute to the changes in Ks. The findings of this research show the importance of considering changes of saturated hydraulic conductivity during constant‐head laboratory tests. Therefore, this study provides evidence for the requirement to further assess the laboratory methods for measurement of the saturated hydraulic conductivity in sandy soil mixtures.

Morphology of Brine‐Seawater Interface and Spatial Distribution of Submarine Groundwater Discharge Windows in the Muddy Coast

AbstractThe brine‐seawater interface (BSI) is a unique type of groundwater‐seawater interface (GSI) characterized by the higher density of underground brine compared to seawater. This study focuses on characterizing the bay‐scale BSI morphology and identifying submarine‐groundwater discharge windows using a comprehensive in‐situ geophysical detection on the south bank of Laizhou Bay. Our findings reveal that the BSI forms an extensive mixing zone (15–20 km) without distinct contours between waters of varying salinities. The discharge windows for underground brine are located in nearshore areas with fine sand distribution and offshore pockmark areas. Hydraulic and salinity gradients drive the underground brine discharge through these windows. The aquitard window is the primary area for shallow and deep brine exchange, likely evolved from paleochannels, ancient tidal creeks, or ancient underwater barriers. These findings provide crucial modeling support for analyzing environmental evolution mechanisms and theoretical basis for planning the underground brine mining in similar coastal regions.

Evidence of Subsurface Control on the Coevolution of Hillslope Morphology and Runoff Generation

AbstractTopography is a key control on runoff generation, as topographic slope affects hydraulic gradients and curvature affects water flow paths. Simultaneously, runoff generation shapes topography through erosion, affecting landscape morphology over long timescales. Previous modeling efforts suggest that subsurface hydrological properties, relative to climate, are key mediators of this relationship. Specifically, when subsurface transmissivity and water storage capacity are low, (a) saturated areas and storm runoff should be larger and more variable, and (b) hillslopes shorter and lower relief, assuming other geomorphic factors are held constant. However, it remains uncertain whether subsurface properties can exert such strong controls on emergent properties in real landscapes. We compared emergent hydrological function and topography in two watersheds with very similar climatic and tectonic history, but very different subsurface properties due to contrasting bedrock lithology. We found that hillslopes were systematically shorter and saturated areas more dynamic at the lower transmissivity site. To test whether these features could be the result of coevolution between topography, hydrological function, and subsurface properties, we estimated all parameters of a coupled groundwater‐landscape evolution model for each site. Limitations were revealed in the model's ability to reproduce aspects of morphology and hydrologic behavior, however, model results suggested differences in hillslope length and variably saturated area between the sites could be explained by differences in subsurface properties, and not by differences in geomorphic process rates alone. This work demonstrates one way subsurface hydrology can profoundly affect landscape evolution.

Assessment of the impact of greenhouse rainwater harvesting managed aquifer recharge on the groundwater system in the southern Jeju Island, South Korea: Implication from a numerical modeling approach

Managed aquifer recharge (MAR) is increasingly being adopted worldwide to mitigate groundwater depletion and ensure the sustainability of water resources. Rainwater harvesting (RWH)-MAR can augment aquifer storage and reduce flood damage in rural areas with dense greenhouse facilities. This study has assessed the feasibility of greenhouse RWH-MAR in Namwon agricultural areas in the southern part of Jeju Island, South Korea, by considering the injection rate and location of MAR using a numerical model. The model results showed that groundwater level increases were directly related to the infiltration rate, although spatial differences in head rise were observed owing to the spatial variability of hydraulic conductivity. In addition, installing the RWH-MAR in highland areas (>100 masl) enhanced the water level rise when compared to the expected values, indicating that a higher hydraulic gradient and thick unsaturated zone facilitated more effective MAR outcomes than in lowland areas. To optimize the contribution of source water to the agricultural water demand, placing the RWH-MAR near the pumping well improved the availability of injected rainwater to agricultural wells. This study highlights the importance of designing RWH-MAR schemes considering MAR objectives and the topographic and hydrogeological characteristics of the site.

Novel MoS2-based heterojunction as an efficient and magnetically retrievable piezo-photocatalyst for diclofenac sodium degradation

It is a challenging and meaningful task to design a piezo-photocatalyst with excellent performance under mild mechanical stirring conditions rather than ultrasonic irradiation. Herein, a hydraulic-driven piezo-photocatalytic process was proposed, using MoS2-based heterojunction as catalysts for diclofenac sodium (DCF) degradation. A magnetically retrievable MoS2/TiO2/Fe3O4 composite was designed and successfully prepared by a facile one-step solvothermal process. Among various heterojunction composites and pure MoS2, the ternary composite MoS2/TiO2/Fe3O4 exhibited the strongest piezo-photocatalysis capability, with a DCF degradation efficiency of 99.6% and a pseudo-first-order rate constant of 0.733 min−1. Additionally, the degradation efficiency of DCF was still up to 85.2% in 6 min after 5 cycles by MoS2/TiO2/Fe3O4. The ternary composite can be easily collected and separated using a magnet. There was an optimum hydraulic gradient value (0.45 s–1) for DCF degradation. •OH played a major role in DCF degradation during the hydraulic-driven piezo-photocatalytic process. A satisfactory DCF degradation was found in the actual water media. The results verify the existence of a synergetic effect between piezo and photocatalytic processes. Thereupon, the hydraulic-driven piezo-photocatalysis can be an efficient, sustainable, and energy-saving process for water treatment.

MoS2@Hydrochar nanocomposites with cost-effective fluid turbulent eddies induced piezoelectric catalytic peroxymonosulfate utilization efficiency for water polluted dye degradation

Piezoelectric materials can induce strain due to the fluid turbulent force produced during fluid shaking, which may be used to activate peroxymonosulfate (PMS). In this study, the effective interfacial interaction of few-odd-numbered layered MoS2 nanosheets and hydrochar (HC) nanocomposites as the piezoelectric material was used in a hydrodynamics energy-driven piezoelectric catalytic PMS activation process (piezo-PMS activation process) for Eriochrome Black T dye degradation. The results showed that Black T dye was efficiently degraded with an efficiency of 99.23 % within 15 min and a pseudo-first-order rate constant of 3.10 min−1 in the MoS2@HC-(6.5:3.5)/PMS/Shaking system. To clearly see the influence of hydraulic gradient (G) value, the hydrodynamics energy-driven piezo-PMS activation process for Black T dye degradation was performed at different shaking frequencies. The results indicated an optimal G value of (14.106 s−1) for Black T dye degradation. Notably, the MoS2@HC-(6.5:3.5)/ PMS/Shaking system produced the lowest EE/O value (34.05 kWhm−3 order−1), resulting in energy savings over 127 times of HC and 9 times of MoS2. Furthermore, piezoelectrochemical measurements of MoS2@HC-(6.5:3.5) indicated that these superior performances primarily resulted from the synergistic effects of MoS2 and HC. This led to a stronger piezoelectric response with effective piezo-generated charge separation, which in turn improved the efficiency of producing reactive species. Combining the scavenger test, FT-IR, and zeta potential analysis, we determined that •OH and SO4•− played a major role, while O2•− and 1O2 played a secondary role in Black T dye degradation. The steady-state concentrations of [•OH]ss, and [SO4•−]ss were 14.52 × 10−14 M and 20.00 × 10−14 M, respectively in the fluid turbulent force driven piezo-PMS activation process. Furthermore, a plausible degradation pathway of Black T dye was proposed based on the assessment of carbon number reduction, the mean oxidation number of organic carbon (MOC) and the predicted TOC/color index.

Multiple holdup equilibria and hydraulic gradients in stratified gas–liquid flows

Experimental ramp-up tests for a two-phase flow with very low liquid loading have been conducted for 2°, 3° and 2° + 3° straight pipe configurations. The liquid draining process resulting from the ramp-up operation is explained by multiple holdup equilibria. For the conditions of the experiments, the multiple holdup equilibria region extends down to a gas oil volume flow rate ratio of about 1000. The flow of a pipe segment operating in the multiple holdup equilibria region will obtain the low holdup equilibrium if the holdup at the end of the pipe is sufficiently low. Otherwise, the flow of the pipe segment will obtain the high holdup equilibrium. Liquid accumulation can be minimized by avoiding steep inclination angles at the culmination of uphill sections in low liquid loading gas condensate systems. Ensuring low holdup equilibria throughout the pipeline, where multiple equilibria exist, minimizes liquid accumulation and reduces minimum flow rate limits during operating conditions.