Hydraulic Conductivity Values Research Articles

Groundwater dynamics simulation in Hodna (Algeria): aquifer modeling approach

Groundwater modeling using MODFLOW and GIS tools is crucial for understanding the complexities of groundwater dynamics in Algeria's semi-arid and arid climates. This study focuses on the quantitative assessment of the phreatic aquifer within the Hodna aquifer system over the period of 1973-2005. The study employs MODFLOW and GIS tools to model groundwater flow. Calibration and validation processes, using a trial and error technique, refine the models to understand water table behaviors and drawdown within the Hodna basin. Calibration efforts yield insights into groundwater dynamics, particularly significant drawdowns observed in cities like M’sila and Boussaada. Parameters such as hydraulic heads, piezometric levels, drainage, and hydraulic conductivity values are extracted from MODFLOW simulations. Analysis reveals a decline in groundwater volume and consistent drops in borehole water levels over the past 32 years, highlighting the challenges of comprehending recharge resources and the impact of groundwater depletion in the region. The study underscores the importance of calibrated groundwater models in managing and mitigating groundwater depletion in Algeria's Hodna basin. It elucidates predominant groundwater flow patterns towards Chott and emphasizes the need for comprehensive understanding and management strategies to sustainably manage groundwater resources in semi-arid and arid regions.

Determination of the Hydraulic Conductivity Behavior of Seaweed Added Zeolite-Bentonite Mixtures in the Presence of Temperature with Empirical Relationships

The temperature factor is of great importance in areas that directly affect the environment and engineering parameters of liners, such as solid waste storage areas. It is known that the temperature value increases as a result of the degradation of waste in these areas, and temperature changes affect the engineering properties of the soils. Properties vary depending on the soil type, and additives that can be used to improve the engineering properties of soils come to the fore. One of the most important criteria is that the additive to be used is sustainable and environmentally friendly. Zostera marina, with its terminological name, or dried seaweed an aquatic plant and is a sustainable, low-cost material used in thermal insulation. In this study, dried seaweed additive was added to zeolite-bentonite mixtures and compression parameters were determined under room temperature and 40°C. Hydraulic conductivity values of seaweed-added mixtures were determined with the help of volumetric compression coefficient (mv) and consolidation coefficient (cv) parameters and empirical relationships obtained as a result of consolidation tests. Its potential to be used as a buffer material in the presence of temperature in solid waste storage areas evaluated. The tests results showed that the seaweed additive decreased the hydraulic conductivity values of zeolite-bentonite mixtures at room temperature and under 40°C.

Contaminant mass discharge estimation of a sulfonamide plume by use of hydraulic profiling tool (HPT) and fluorescence techniques

The contaminant mass discharge is a relevant metric to evaluate the risk that a groundwater plume poses to water resources. However, this assessment is often vitiated by a high uncertainty inherent to the assessment method and often limited number of measurement points to carry out the assessment. Direct-Push techniques in combination with profiling tools and dedicated sampling can be an interesting alternative to increase the measurement point density and hence reduce the mass discharge uncertainty. The main objective of our study was to assess if DP logging and sampling could be employed to get a reasonable estimate of contaminant mass discharge in a large sulfonamide contaminant plume (> 1500 m wide), compared to a more traditional approach based on monitoring wells. To do so, an Hydraulic Profiling Tool (HPT) logging with a dedicated site calibration was used to estimate the hydraulic conductivity field. The sulfonamide concentrations were inferred from the compound fluorescence properties measured by laboratory spectrofluorometry (λEx / λEm = 255/340 nm) and a dedicated log-log linear regression model. Our results show that HPT-derived hydraulic conductivity values are in good agreement with the monitoring well results, and within the order of magnitude reported in similar studies or indirect geophysical techniques. Fluorescence appears as a powerful proxy for the sulfonamide concentration levels. Ultimately, the contaminant mass discharge estimate from HPT and fluorescence techniques lies within a factor 2 from the estimate by monitoring wells, with 549 [274–668] and 776 [695–879] kg/yr respectively. Overall, this study highlights that DP logging tools combined with indirect methods (correlation with fluorescence) could provide a relevant contaminant mass discharge estimate for some optically active substances, given that a proper calibration phase is carried out.

Application of surface geophysical investigations and pumping test data analysis for better characterization of aquifer hydraulic parameters, Upper Awash Sub-Basin, Central Ethiopia

Study regionUpper Awash River Sub-basin in central Ethiopia Study focusThe research aimed to estimate aquifer parameters and conduct resistivity modeling in the study area. Data were collected from 890 Schlumberger Vertical Electrical Soundings (VES) points strategically distributed across six selected zones. The VES data were analyzed using computer modeling and curve-matching techniques to interpret the resistivity responses of the geological formations. This analysis provided insights into the subsurface characteristics and identified potential aquifer zones. New insights for the regionThe interpreted curves from the VES data and Root Mean Square (RMS%) values ranging from 0.36 % to 1.67 %, indicating a good fit between observed and modeled data. Resistivity modeling and geoelectrical sections were produced along specific lines, visualizing subsurface structures and confirming the resistivity responses of the geological formations. To determine aquifer parameters, the Dar-Zarrouk parameters were calculated from the interpreted curves, yielding crucial information about hydraulic properties such as hydraulic conductivity (K) and transmissivity (T). Hydraulic conductivity values ranged from 1.1 m/day to 21.7 m/day, while transmissivity values ranged from 144.3 m²/day to 2763.3 m²/day. Validation against borehole pumping test data showed strong correlations: R² = 0.9873 for transmissivity and transverse resistance, and R² = 0.9352 for hydraulic conductivity and resistivity. These findings enhance the understanding of the complex volcanic aquifer characteristics in the Upper Awash River Sub-basin, aiding sustainable groundwater management and development in the area.

MPeat2D – a fully coupled mechanical–ecohydrological model of peatland development in two dimensions

Abstract. Higher-dimensional models of peatland development are required to analyse the influence of spatial heterogeneity and complex feedback mechanisms on peatland behaviour. However, the current models exclude the mechanical process that leads to uncertainties in simulating the spatial variability in the water table position, vegetation composition, and peat physical properties. Here, we propose MPeat2D, a peatland development model in two dimensions, which considers mechanical, ecological, and hydrological processes together with the essential feedback from spatial interactions. MPeat2D employs poroelasticity theory that couples fluid flow and solid deformation to model the influence of peat volume changes on peatland ecology and hydrology. To validate the poroelasticity formulation, the comparisons between numerical and analytical solutions of Mandel's problems for two-dimensional test cases are conducted. The application of MPeat2D is illustrated by simulating peatland growth over 5000 years above a flat and impermeable substrate with free-draining boundaries at the edges, using constant and variable climate. In both climatic scenarios, MPeat2D produces lateral variability in the water table depth, which results in the variation in the vegetation composition. Furthermore, the drop in the water table at the margin increases the compaction effect, leading to a higher value of bulk density and a lower value of active porosity and hydraulic conductivity. These spatial variations obtained from MPeat2D are consistent with the field observations, suggesting plausible outputs from the proposed model. By comparing the results of MPeat2D to a one-dimensional model and a two-dimensional model without the mechanical process, we argue that mechanical–ecohydrological feedbacks are important for analysing spatial heterogeneity, shape, carbon accumulation, and resilience of peatlands.

Geotechnical performance of black cotton clay in the presence of lead and cadmium solutions for geoenvironmental application

ABSTRACT The usage of bentonites and sand–bentonite mixtures as liners has become prevalent due to their low permeability. However, these materials are scarce and prohibitively expensive in India. Black cotton clay (BCC) was chosen as an alternative clay liner for this research due to its abundance in India and its mineralogical composition. Since heavy metals accumulation in municipal landfills is a rising issue with devastating effects on the ecosystem and human health, in this investigation, two heavy metals (lead and cadmium) were intended as permeants at three different concentrations (100, 500, and 1000 ppm) to imitate the impact of heavy metal leachate on BCC. The essential index and engineering properties of BCC were evaluated and compared under these two permeants from the liner perspective. Experimental results revealed that the free swell index, Atterberg limits, swelling and swelling pressures were reduced for a rise in concentration irrespective of metal type. However, this reduction was more with cadmium permeants compared to lead. The measured swelling data was compared with predicted swelling data using a rectangular hyperbola model, and a good correlation was achieved. The hydraulic conductivity (k) and unconfined compressive strength (UCS) values were increased for a rise in concentration with both metal permeants. At 1000 ppm concentration, the k values were raised to 3.5 and 6.7 times, and UCS values were enhanced by 8.3 and 5.5% for lead and cadmium permeants, respectively. At high concentrations, field emission scanning electron microscopy (FESEM) results showed the formation of huge voids and aggregation.

Assessment of Soil Structural Quality Under Area Closure and Open Grazing Land in Hidabu Abote District, North Shewa Zone, Oromia Regional State, Ethiopia

The experiment was conducted at Sire Morise kebele, Hidabu Abote district, to assess soil structural quality of different land management system (area closure and open grazing land). In this study, area closure land management practice was compared with open grazing land management practice in similar slope positions for soil structural quality build up. Soil samples were collected from both land management system at three slope position with three times replication. Totally 36 undisturbed soil blocks were collected from both land management system at 10 and 20 cm sampling depths. The finding of the study showed that the average value of volumetric moisture content and saturated hydraulic conductivity of soil were greater at area closure than open grazing land management system and also higher at bottom slope position than middle and upper slope position. The mean value of air-filled porosity and bulk density were lower at both area closure management practices and bottom slope position. Bulk density, volumetric soil moisture content and saturated hydraulic conductivity at 20 cm sampling depth were shows significantly different with respect to management practices. According to visual assessment in the field, soil physical quality was unfavourable in open grazing land management system and upper part of landscape position soils and the visual assessment scores showed that the soils under area closure had a good soil structural quality. There were strong relations among the three visual field assessment methods and also between visual assessment methods and laboratory determined soil properties of both land management system. In general, the result of the study showed that physical and structural quality of soil in area closure was improved due to good land management system. Based on the result of study it can be conclude that area closure improves soil physical and soil structural qualities and from the technical point of view, open grazing lands in hilly area should be changed to area closure before soil properties and soil nutrient contents are exhausted more.

A Statistical Approach for the Assessment of Saturated Hydraulic Conductivity Values of Unsaturated Urban Soils Obtained by Field Infiltration Tests

An evaluation and interpretation of the obtained results focusing the hydraulic conductivity of anthropogenic saturated soil, k, has been performed on an urban area vadose zone. Four methods have been used to quantify the hydraulic conductivity: the tube infiltrometer (TI), the double ring infiltrometer (DRI), the minidisk infiltrometer (MDI) and the inversed auger (IA). This study comprises (a) a comparative analysis of the results obtained by each method between several trials performed at the same location and at distinct locations within the plot, (b) a comparative analysis of the results of all methods, and (c) a statistical analysis regarding the correlation between k as a dependent variable and the infiltration area A as the main independent variable. To select the k values close or corresponding to the saturation state for TI and IA methods, a domain of validity was defined. A new parameter, k* = k/A, was introduced which represents the hydraulic conductivity corresponding to an infiltration surface unit (1 cm2). An increase in this ratio with the increase in the infiltration area, within the same method or between different methods, indicates the heterogeneity of the terrain but especially the fact that the infiltration area no longer represents the main independent variable on which the hydraulic conductivity depends for the saturated state.

Optimal landfill site selection through the application of GIS analysis & geotechnical investigation

ABSTRACT Disposal of municipal solid waste is a significant environmental issue that has detrimental effects on both the environment and human life. The selection of landfill sites is critical and essential to implementing a comprehensive waste management strategy. This study optimizes the selection of landfill sites in Kuwait through the use of overlay analysis and Geographic Information System in conjunction with multi-criteria decision analysis. The study analysis takes into account human, physical economical, environmental, and governmental factors. Seven optimal locations are depicted on the resulting suitability map, each occupying 10 square kilometres or more and have the capacity to handle solid waste for at least one decade per site, considering the current reported waste generation rate. Furthermore, results of a preliminary geotechnical investigation encompassing field and laboratory tests conducted on soil samples collected at one of the proposed sites are presented. The characterization of the retrieved samples included major geotechnical parameters that are of concern in landfill design and siting studies. The results indicate that the soil at the proposed site exhibited low values of hydraulic conductivity, ranging between 3.50 X 10−07 and 8.96 X 10−08 cm/sec, confirming its suitability for siting landfills. There is an urgent need to develop and implement an integrated waste management system in Kuwait. By leveraging the findings of this study, policymakers and governmental authorities can optimize their decision-making procedures to ensure more effective site selection. This approach will significantly reduce contamination risks and enhance sustainability, leading to a more environmentally responsible waste management system in the country.

Geoelectric Investigation for Groundwater in Imo State University Campus and Environs using Direct Current Electrical Resistivity Method

Eighteen, vertical electrical soundings (VES), were carried out in Imo State University and Environs to delineate the potential site for groundwater. Data were acquired using ABEM SAS 300 resistivity meter. Schlumberger array and maximum electrode spread of 700m were adopted. Data were interpreted with IP2WIN software. Contour maps were done using Sulfer 20 software. Geoelectric cross-sections constructed along three profile lines delineated subsurface stratification. Sediments consist of sequence of sandstone/gravel, silty sand/sand and clay with geology representing the Benin Formation. Groundwater was delineated within the zone interpreted to be sand with quartz making up more than 95% of all grains. Resistivity of aquifer varies across study area and ranges from 159Ωm, observed around Library and Information Department (VES 11) to 100000Ωm recorded at IMSU Plaza (VES 10). Depth to water table also varied across study area with higher values of 150m and 130m observed at College of Health Science (VES 3) and Behind Old ETF (VES 4). A relatively shallow aquifer is delineated behind Senate Building and Okwu-Uratta with water table at depths of 23.5m and 26.5m. The transmissivity values are moderately high except at some locations. The variation in longitudinal conductance and transverse resistance values show that part of the study area such as Aso Rock, Female Hostel, Law Faculty and IMSU Plaza are underlain by relatively resistive (low longitudinal conductance) aquifer material. Distribution of hydraulic conductivity and electrical conductivity values indicates that in some of the VES points, the values are fairly constant. This could be seen as areas with similar geologic settings and water quality. Storativity of study area ranges from 0.00003 at VES 1 and 12 to 0.00028 at VES 4. Study area shows a good prospect for groundwater development, except at Library and Information Department, where the zone delineated is an aquitard.

Hydrogeochemical Investigation and Estimation of Aquifer Properties at Dhaka University Campus

The University of Dhaka has its own water supply system and entirely relies on groundwater. Ten groundwater samples were collected from 10 production wells of 120-320 m depth across the University campus from upper and lower Dupi Tila aquifers. The pH values revealed that water is mildly acidic to neutral and electrical conductivity (EC) values ranging from 325 to 654 μS/cm, indicating fresh groundwater. The total hardness (TH) of the samples ranges from 76-203 mg/L, suggesting moderately hard to very hard water. Of the ten groundwater samples, nine are of Ca-Mg-HCO3 type, whereas one shows Ca-Na-HCO3 type of groundwater. The saturation indices show that the groundwater samples are near-saturated for calcite, dolomite, gypsum, siderite, and rhodochrosite, indicating the low potential for dissolution-precipitation of these mineral. Notably, the results of WQI indicate that all the wells are safe for drinking. As of July 2023, the groundwater level was 72 m below ground level with a declination rate of 2.8 m/year. The estimated hydraulic conductivity values of 20 to 90 m/day and transmissivity values of 637 to 2740 m²/day suggest better permeability and water transmission potential within the lower aquifer. These results provide essential information for the university authority to implement appropriate strategies for efficient groundwater management. The Dhaka University Journal of Earth and Environmental Sciences, Vol. 12(2), 2023, P 55-67

Porosity and hydraulic conductivity of gap graded natural sand considering shape parameters

Gap graded natural sand is widely used in hydraulic structures, foundation treatment and recharge well fillers, and it’s also common in geological structures such as landslide deposits. In order to study the influence of grain shape on its pore and permeability characteristics, river sand in Yichang (YS), standard sand in Henan (HS) and standard smooth glass beads (BZ) are selected as test materials, and the grain shape parameters of three materials are analyzed on multiple scales. Then tests on porosity and hydraulic conductivity of gap graded natural sand were conducted. On this basis, a numerical model considering grain size distribution, coarse grain content and grain shape was established. The results showed that the average values of the shape parameters increased or decreased with the increase of grain size, and the coefficients of variation for the parameters were between 0.026 and 0.208. The shape parameters showed a negative skewness distribution, but the absolute value of the skewness coefficient was small (0.254–0.616). Grain size distribution and grain shape are the main factors controlling the porosity and hydraulic conductivity of gap graded natural sand. The minimum values of porosity and hydraulic conductivity appear at about 70 % and 30 % of large grains, respectively. The closer the grains are to the sphere, the closer the material is stacked, and the smaller the porosity value is. The grain size ratio has a significant effect on the minimum porosity of the mixture and the minimum porosity increases with the increase of the grain size ratio. The porosity of gap graded natural sand obtained by numerical method is accurate, and the error is within 10 %. The hydraulic conductivity is obtained by deriving fluid grid information and the results show that the simulated value of hydraulic conductivity is highly matched with the experimental value, and the error range is roughly between 10 % and 30 %.

Combined effects of geological heterogeneity and discharge events on groundwater and surface water mixing

Stream water (SW) infiltration to the subsurface and subsequent mixing with groundwater (GW) is crucial for controlling water quality in river-corridors. Mixing of solutes from SW and GW triggers biogeochemical reactions, which can attenuate contaminant influx from upstream SW or from GW that eventually enters the river in downstream regions. It is known that geological heterogeneity affects SW-GW exchange fluxes (EF), however, the combined effects of both hydrological and geological aspects (e.g., sand fraction present in the aquifer material) on EF and on SW-GW mixing in strong contrasting bimodal aquifer units remain unclear. Here, we examined this gap by combining geostatistical realizations, fully-integrated numerical flow simulations, and a mixing-cell routine to assess the major controls on EF and to evaluate how mixing develops and is affected by stream discharge events with different magnitudes and durations. Results show that subsurface heterogeneity at the river-reach scale mainly affects EF magnitudes rather than EF patterns. Yet, both EF magnitudes and SW-GW mixing increased with the introduction of subsurface heterogeneity and with the increase of average hydraulic conductivity (K) values and sand fraction in the models. The simulations further indicated a larger potential for mixing under more frequent, short events regardless of the aquifer material, however, mixing values were generally higher for sandier and heterogeneous models. Lastly, for a high K contrast between subsurface units, these effects were more pronounced. This characterization is critical for river restoration strategies and for downstream management of dam-regulated rivers. Our study elucidates the interplay between hydrological and geological controls on the development of SW-GW mixing at intermediate scales and highlights the importance of considering aquifer characteristics in future studies.

Development of a multi-layer green-ampt infiltration based modeling framework for hydrologic process simulation and design of various low impact development measures for mitigating urban flooding

ABSTRACT Low Impact Development (LID) measures have proven to be effective in reducing the runoff volume and the peak of runoff at small spatial scales. Assessment of the hydrological impacts of LID measures at river basin scales is currently limited by the absence of adequate physically-based process models that can simulate LID processes at such scales. In this study, an attempt has been made to develop LID modules to simulate the water balance and hydrological processes based on the Multi-Layer Green-Ampt (MLGA) infiltration method, which is an advancement to the existing LID modeling techniques. The performance of the MLGA-based LID modules was benchmarked with the process-intensive numerical tool HYDRUS 1D for about 5000 soil samples across the soil textural classes. The results indicated that the MLGA-based model simulates the hydrological processes in close agreement with HYDRUS for soils with moderate-to-high hydraulic conductivity values, which are amenable for LID implementation.

Sand-bentonite backfill amended with composite polymer exposed to organic acid: Hydraulic performance and microstructural properties

Soil-bentonite (SB) backfills in vertical cutoff walls are used extensively to contain contaminated groundwater. Previous studies show that the hydraulic conductivity of backfill can exceed the typically recommended maximum value (k = 1 × 10−9 m/s) if exposed to groundwater impacted by organic acids commonly released from uncontrolled landfills and municipal solid waste dumps. Polymer amended backfills exhibit excellent chemical compatibility to metal-laden groundwater. However, few studies to date have explored the effect of organic acid contaminated groundwater on hydraulic performance of polymer amended backfills. This study presents an experimental investigation on the hydraulic performance and microstructural properties of a composite polymer amended backfill used to contain flow of acetic acid-laden groundwater. A series of laboratory experiments were performed to evaluate free-swell indices of the composite polymer amended bentonites, liquid limits of the composite polymer amended and unamended bentonites, and slump heights and hydraulic conductivity (k) values of the amended backfills to acetic acid solutions with varying concentrations. The results were compared with those of the unamended bentonites and unamended backfills reported in a previous study. The results showed that the free-swell index and liquid limit of the amended bentonites were higher than those of the unamended bentonites. Permeation with acetic acid solutions with concentrations ranging from 40 mmol/L to 320 mmol/L conducted on the amended backfill only resulted in an increase in k of less than a factor of about 10 related to that based on permeation with tap water (1.68 × 10−10 -4.41 × 10−11 m/s to acetic acid solution versus 1.65 × 10−11 m/s to tap water). Mechanisms contributing to enhanced chemical compatibility of amended backfill were ascertained based on scanning electron microscopy, mercury intrusion porosimetry, and zeta potential analyses.

Hydraulic conductivity of cement and fly ash stabilised clay mixes – Application to soil mixing techniques for seepage barrier construction

In-situ ground improvement techniques, namely, deep soil mixing, jet grouting, cutter soil mixing, and mass stabilisation are often utilized to improve the strength of soft grounds, and construct seepage barriers. Due to economic and environmental concerns, there is a global shift towards using industrial wastes such as fly ash (FA) from conventional binders such as ordinary Portland cement and lime. There is a plethora of literature on unconfined compressive strength (UCS) of cement-treated clays, and clays treated with fly ash-cement mixes with alkali activator (FCAA) binders. However, much remains unclear about the hydraulic conductivity of the FCAA-treated clays as low permeable hydraulic barrier systems. In this paper, the hydraulic conductivities of cement-treated and FCAA-treated clays are studied both quantitatively and qualitatively for different binder-content, FA:cement ratios, curing periods, and effective confining stress. The hydraulic conductivity of treated clay is measured by performing a series of accelerated permeability tests using a custom-fabricated triaxial system. The trends obtained from the measured hydraulic conductivity values are explained from the observations of X-ray diffraction analysis and scanning electron microscopy analysis. Results showed that the values of hydraulic conductivity for cement-treated clay were mostly higher than those of untreated clay. On the contrary, the hydraulic conductivities for the FCAA clay mixes were comparable to, or even lower than those for the untreated clay. The hydraulic conductivity reduced with the increase in effective confining stress; the influence of effective confining stress, however, became less substantial for 28 days curing period and higher cement-content (40 and 50 %). The relationships between the hydraulic conductivity, UCS, and water-binder (w/b) ratios were also determined for both cement-treated and FCAA-treated clays. The exponential function was found suitable to express the relationship between hydraulic conductivity and UCS of treated clays. In contrast, a strong logarithmic relationship was obtained for measured values of hydraulic conductivity and adopted w/b ratios. The results shall serve as a guide to adopting suitable binder-content or target UCS for achieving design hydraulic conductivity in ground improvement projects that involve cement and/or FCAA-treatment of clays.

Hydrogeological characterization of low permeability medium for conceptualization of a mine site in Eastern Turkey

The mining site in Eastern Anatolia of Turkey were encounter a significant risk of slope instability within the operational area. One of the processes that govern slope stability is the pore water pressure distribution. The conceptualization and characterization of porous media serve as fundamental prerequisites for the implementation of numerical methods aimed at predicting pore water distribution. This study aims to characterize the hydrogeological properties of water bearing rocks in the active mining site in Eastern Anatolia of Turkey. A total of 21 wells and drill holes were drilled in the study area to conduct in-situ tests, monitoring, and sampling. The large diameter wells drilled in surrounding the carbonate rocks were to determine the groundwater flow and boundary conditions and also wells tapped metasediments and diorite unit for hydraulic testing. The lugeon tests and installation of vibrating wire piezometers were carried out at small diameter drill holes to obtain localized hydraulic conductivity of metasediments and diorite at different depths and monitoring pore water pressure distribution along some critical cross-sections. The results obtained from these tests are used for developing hydrogeological conceptual model for groundwater flow. The results of in-situ tests show that the metasediment and diorite units act as a single hydrostratigraphic unit. The metasediments and diorite have high total porosity and low specific yield indicating that the pore water is retained by electrostatic forces in the medium and it resists flow due to low hydraulic conductivity. The vertical variation in hydraulic conductivity values indicates that the medium is highly heterogeneous.

Flow and contaminant transport dynamics in clay-amended barriers through flushing experiments and multi-porosity-based modeling

Clay-amended barriers are widely used to prevent hazardous leachate percolation from landfill to subsurface. The performance of these barriers is mostly evaluated through numerical simulations with limited experimental investigation through leachate flushing experiments. To bridge this gap, contaminant loading and its flushing experiments were carried out to assess the performance of clay-amended composite materials as landfill liners. River sand (Sa), loamy soil (Ns), and alternative waste materials like fly ash (Fa) and flushed silt (Si) were used to prepare the composites. Composites fulfilling the hydraulic conductivity (<10−7 cm/s) and compressive strength (200 kPa) criteria were selected for contaminant loading and its flushing experiments to understand the fate of fluoride ions. The experimentally determined hydraulic conductivity (Ks) values for all the composites were in the order of 10−8 cm/s. The experimental breakthrough curves exhibited skewed shape, long tailing, and dual peaks. Dual porosity and dual permeability with immobile water models were employed to simulate these curves, revealing that preferential flow pathways and random chemical sorption sites significantly affect solute transport in clay-amended barriers. Further, scanning electron microscopy and energy-dispersive X-ray spectroscopy were employed to trace the preferred path of fluoride ions through the barrier. The removal efficiency and temporal moments were used to determine the percentage mass retained, mean arrival time, and spreading within the barrier. The highest solute mass was retained by sand-clay barrier (SaB30) (91%), followed by loam-clay barrier (NsB30) (59%), fly ash-clay barrier (FaB30) (38%), and silt-clay barrier (SiB30) (4%) with the least mass. The lowest mean arrival time was calculated for NsB30 (269 h) and the highest for SaB30 (990 h), with FaB30 (384 h) and SiB30 (512 h) having values in between. This study concludes that validating the design hypothesis of clay-amended barriers through contaminant loading and its flushing studies leads to an effective and sustainable design.

Applicability of Single-Borehole Dilution Tests in Aquifers with Vertical Flow

A set of experimental field single-borehole dilution tests were completed in the Motril–Salobreña detrital aquifer (Spain) in a sector with coarse material in four different moments under variable hydrological conditions. The comparative study of the tracer washing, and the temperature profile patterns for the tests carried out in two wells located hundreds of m from each other, revealed the presence of ascending vertical flows in one of the wells (not detected by other means) that compromises the reliability of the tracer test. The values of both the apparent horizontal velocity and hydraulic conductivity obtained in the affected well were less than half of those estimated in the well not affected by the upward vertical flows. The repetition of the test eight times during different seasons showed that the hydraulic conductivity calculated from the apparent horizontal velocity can vary; therefore, to approximate to a representative hydraulic conductivity value, using this method is recommended to carry out tests under different hydrological conditions and average the results. The difference generated by the changes in conditions for the specific setting of the study area was 25%. Taking this into account, it was considered that an approximation to the more representative value would be an average under variable hydrological conditions, resulting in a horizontal velocity of 6.7 m/d and hydraulic conductivity of 337 m/d. This information is critical for the management of the aquifer as it has strategic resources against droughts that are becoming more frequent in the Mediterranean area.

Landfill cap models under simulated climate change precipitation: assessing long-term infiltration using the HELP model

The Hydrologic Evaluation of Landfill Performance (HELP) model (v 3.04) was used to assess the hydrological performance of two large-scale (~ 80 × 80 × 90 cm) laboratory-based landfill cap models. Desiccation cracking under simulated climate change precipitation (CCP) events was modelled to predict the performance of landfill caps over a 50-year period in Cumbria England, UK. Cumulative infiltration values under different climate conditions were highly sensitive to macro-pore development in the clay liner which is represented by the changing hydraulic conductivity in HELP simulations. Simulation results of cap design 1 (a clay barrier layer only) show that cumulative annual infiltration under normal precipitation (NP) and CCP events, with the initial hydraulic conductivity, ranged between 1 and 2% of the annual precipitation; however, cumulative annual infiltration was 10 to 68% when maximum (degraded) hydraulic conductivity values were used in simulations. A geosynthetic clay liner (GCL) included in cap design 2 significantly reduce cumulative infiltration.