Hydrate-bearing Sediments Research Articles

Application of a Thermodynamic Framework–Based Constitutive Model for Hydrate-Bearing Sediment Considering Grain Breakage and Stress History

Application of a Thermodynamic Framework–Based Constitutive Model for Hydrate-Bearing Sediment Considering Grain Breakage and Stress History

Mechanical behavior of clayey methane hydrate-bearing sediment: Effects of pore size and physicochemical characteristics using a novel DEM contact model

The mechanical behavior of Methane Hydrate-Bearing Sediment (MHBS) is essential for the safe exploitation of Methane Hydrate (MH). In particular, the pore size and physicochemical characteristics of MHBS significantly influence its mechanical behavior, especially in clayey grain-cementing type MHBS. This study employs the Distinct Element Method (DEM) to investigate both the macroscopic and microscopic mechanical behavior of clayey grain-cementing type MHBS, focusing on variations in pore size and physicochemical characteristics. To accomplish this, we propose a Thermo-Hydro-Mechanical-Chemical-Soil Characteristics (THMCS) DEM contact model that incorporates the effects of pore size and physicochemical characteristics on the strength and modulus of MH. This THMCS model is validated using experimental data available in the literature. Using the proposed contact model, we conducted a series of investigations to explore the mechanical behavior of MHBS under conventional loading paths, including isotropic and drained triaxial tests using the DEM. The numerical results indicate that smaller pore sizes and lower water content—key physicochemical characteristics resulting from variations in electrochemical properties and the intensity of the electric field—can lead to reduced shear strength and stiffness due to the increased breakage of aggregates and weakened cementation. Additionally, heating was found to further accelerate the process of structural damage in MHBS.

Research on resistivity characteristics of grain-coating and pore-filling hydrates in different sediment packings based on voxelated 3D models

Natural gas hydrate is a clean energy resource with abundant reserves. Before conducting large-scale exploitation, understanding its physical properties, such as electrical properties, is crucial for gas reserve evaluation and production process monitoring. Due to the complexity of the pore space geometry and different hydrate growth morphology, electrical resistivity may vary for different samples at the same hydrate saturation. This study considered three packings of unconsolidated marine sediment grains (simple cubic, body-centered cubic, and face-centered cubic) and two end distribution patterns of hydrates in pores (grain-coating and pore-filling). The original 3D geometries of hydrate-bearing models were replaced with voxelated meshes to achieve better stability and versatility. The resistivities of models were calculated using the finite element method and compared with the results from Archie's law. The simulation results show that the resistivity curve's shape is jointly affected by the hydrate distribution pattern and the initial pore space geometry. A rational function can be used to fit the saturation exponent curves to give critical brine saturations. The grain-coating hydrate prefers blocking the throats and has a critical brine saturation above 0. In contrast, the pore-filling hydrate has resistivities lower than the Maxwell-Garnett equation's lower boundary due to a bypassing effect, which partially compensates for the conductivity loss of the pore fluid and is more remarkable for models distributed by bigger hydrate particles, and has a critical brine saturation equal to 0. The findings are helpful in understanding the non-Archie phenomenon of hydrate-bearing sediments.

Experimental Study on Mechanical Properties of Artificial Cores Saturated With Ice: An Analogical Simulation to Natural Gas Hydrate Bearing Sediments

ABSTRACTThis work takes the natural gas hydrate (NGH) reservoir in the Shenhu area at the South China Sea as the target. Using the quartz sand, calcite grains, and illite powder as the main mineral composites, and Portland cement as the bonding material, the host skeleton with similar porosity and mechanical properties to the target reservoir were prepared. Ice was used to simulate natural gas hydrates for their high similarity in mechanical properties and distributions within porous host. The ice saturation in the host skeleton is quantitatively controlled by the quality method. As an analogical simulation, artificial samples with different ice saturations were tested by uniaxial compression measurements and the Brazilian tensile tests, aiming to reveal the mechanical behavior of NGH sediments. The results indicated that the plasticity of the artificial sample increases and its damage form transitions from brittleness to ductility as the ice saturation increases. The effects of free water and ice on the strength of saturated samples are quite different. The free water tends to reduce the strength of the sample due to illite hydration and change of internal friction. The bonding effect of ice tends to increase the strength of the sample, while the ice could also reduce the internal friction. When the ice saturation is larger than 30%, the compressive and tensile strengths of the sample increase with ice saturation, which could be regressed as yc = 2.2628S + 0.8322, and yt = 0.411S + 0.0273, respectively. The constitutive model was developed based on the equivalent medium theory and the D‐P criterion, which could describe the experiment data well with deviations less than 10%.

Pore-Scale Analysis of the Permeability and Effective Thermal Conductivity of Hydrate-Bearing Sediments Based on a High-Pressure Microfluidics Approach

Pore-Scale Analysis of the Permeability and Effective Thermal Conductivity of Hydrate-Bearing Sediments Based on a High-Pressure Microfluidics Approach

3D CFD-DEM modeling of sand production and reservoir compaction in gas hydrate-bearing sediments with gravel packing well completion

Sand production is one of the bottlenecks restricting the safe, efficient, and controllable production of hydrates. Enhancing the understanding of mesoscopic sand production responses is essential for sand production risk management. Yet, existing mesoscopic sand production models inadequately capture the effects of hydrate cementation, resulting in an incomplete assessment of the mechanical impacts of hydrates on sand production. Herein, we developed a new three-dimensional model for sand production in gas hydrate-bearing sediments (GHBSs) with gravel packing well completion, utilizing the coupled computational fluid dynamics and discrete element method (CFD-DEM). The model considers the coupled interactions of mechanical weakening and permeability variation in GHBSs caused by hydrate cementation reduction. Simulations are analyzed to clarify the responses of sand production and reservoir compaction under the coupled mechanical, hydraulic, and sand control completion in GHBSs during depressurization. The high fluid flow rate induced by a high production pressure differential can promote sand production and reservoir compaction. Additionally, the high effective stress and high hydrate dissociation rate induced by a high production pressure differential are beneficial for initial sand production, but they can also prematurely lead to gravel packing layer obstruction, inhibiting the final sand production. This also results in a dual impact on compaction deformation, enhancing it through compaction while decelerating it by inhibiting sand production. This work provides a viable simulation idea and preliminary insights into the mechanism of sand production from GHBSs.

Mechanical Properties and Strength Criteria of Hydrate-Bearing Sediments Considering Clay Minerals.

Understanding the effect of clay on the mechanical properties and strength criteria of hydrate-bearing sediments (HBS) is essential for evaluating the safety of clay-rich reservoirs. In this study, a series of triaxial shear tests were conducted to investigate the impacts of clay type and content on the mechanical behavior of I-HBS (hydrate-bearing sediments containing illite) and M-HBS (hydrate-bearing sediments containing montmorillonite). The findings reveal that M-HBS exhibit greater susceptibility to strain hardening compared to I-HBS, accompanied by more extensive volume deformation, and both strain hardening and shear shrinkage intensify with increasing clay content. Moreover, the results demonstrate higher failure strength and Young's modulus in I-HBS than M-HBS. The failure strength of sediments is affected by both the clay content and effective confining pressure, with an established relationship between the failure strength and these two factors. Additionally, the cohesion and internal friction angle of sediments exhibit distinct linear correlations with clay content due to variations in the clay type. The Mohr-Coulomb strength criterion incorporating the clay content is established, enabling the prediction of shear strength in clay-rich hydrate reservoirs. The clay type and content are the cause for different strengths and shear mechanisms of sediments. This research holds significant implications for the safe mining of natural gas clay-rich hydrate reservoirs.

Review of Research Progress on Acoustic Test Equipment for Hydrate-Bearing Sediments

When acoustic waves propagate through hydrate samples, they carry extensive information related to their physical and mechanical properties. These details are comprehensively reflected in acoustic parameters such as velocity, attenuation coefficient, waveform, frequency, spectrum, and amplitude variations. Based on these parameters, it is possible to invert the physical and mechanical indicators and microstructural characteristics of hydrate samples, thereby addressing a series of issues in hydrate development engineering. This study first provides an overview of the current applications and prospects of acoustic testing in hydrate development. Subsequently, it systematically elaborates on the progress in research on acoustic testing systems for hydrate samples, including the principles of acoustic testing, ship-borne hydrate core acoustic detection systems, laboratory hydrate sample acoustic testing systems, and resonance column experimental systems. Based on this foundation, this study further discusses the development trends and challenges of acoustic testing equipment for hydrate-bearing sediments.

Features and Constitutive Model of Hydrate-Bearing Sandy Sediment’s Triaxial Creep Failure

In the longstanding development of hydrate-bearing sediment (HBS) reservoirs, slow and permanent deformation of the formation will occur under the influence of stress, which endangers the safety of hydrate development projects. This paper takes hydrate-bearing sandy sediment (HBSS) as the research object and conducts triaxial compression creep tests at different saturation degrees (20%, 30%, and 40%). The results show that the hydrate-containing sandy sediments have strong creep characteristics, and accelerated creep phenomenon will occur under the long-term action of high stress. The longstanding destructive power of the specimen progressively raises with the increase in hydrate saturation, but the difference in the triaxial strength of the specimen progressively increases. This indicates that the damage to the hydrate structure during long-term loading is the main factor causing the strength decrease. Further, a new nonlinear creep constitutive model was developed by using the nonlinear Burgers model in series with the fractional-order viscoplastic body model, which can well describe the creep properties of HBSS at different saturation levels.

Low-field MRI study of the 1H distribution and migration in porous sediments during natural gas conversion from methane hydrate

Gas hydrates, crystalline compounds formed from water and guest molecules like methane, are gaining attention as a promising clean energy source. While research has extensively focused on the extraction and transport of natural gas hydrates from offshore marine sediments, the dynamic processes in the porous sediments remain under explored. This study employs low-field Magnetic Resonance Imaging (MRI) to investigate the in-situ formation and dissociation of methane hydrate within a partially saturated stack of glass beads. By integrating advanced MRI techniques, including 1D dhk SPRITE, bulk T1 distribution, and 2D spatial T2 imaging, this research provides a comprehensive analysis of fluid distribution and migration during phase transitions in the porous sediments. Three key findings emerged from the study. First, SE-SPI measurements successfully quantified hydrate and residual water saturation, aligning with previous X-ray CT and high-field MRI studies and validating low-field MRI for hydrate research. Secondly, this study introduced a volumetric approach to T1 and T2 measurements, distinguishing between free and bound water, with characteristic relaxation times for each, confirming the technique's capability to differentiate types of residual water. Finally, spatially resolved T2 relaxation time distributions revealed vertical fluid migration within the pore spaces, identifying an equilibrium zone where inflow and outflow rates were balanced. Overall, this study underscores the effectiveness of low-field MRI as a noninvasive tool for analyzing hydrate-bearing sediments. The findings lay the groundwork for further exploration of hydrate in porous sediments, enhancing our understanding of gas production dynamics in hydrate-rich environments.

The role of phase saturation in depressurization and CO2 storage in natural gas hydrate reservoirs: Insights from a pilot-scale study

The natural gas recovery and CO2 storage in natural gas hydrate (NGH) reservoirs is a promising integrated strategy for implementing clean energy production and CCUS. However, the fundamental characteristics (phase saturation) of NGH reservoirs on the feasibility and efficiency of the above-integrated processes remain unclear. In this study, we synthesized methane hydrate-bearing sediments (MHBS) with varying hydrate saturation (SH = 18–66 %) and aqueous saturation (SA = 7–92 %) at marine NGH conditions (T = 283.8 K, P = 11.0 MPa). The effect of phase saturation on depressurization-induced hydrate dissociation, and subsequent CO2 storage and hydrate restoration by CO2/N2 injection was investigated. The water-saturated MHBS with high SA can promote faster MH dissociation during the depressurization stage and prevent secondary hydrate formation, but a slower MH dissociation during the later stage due to slow heat transfer. A relatively high SH (> 63 %) results in sustained low temperatures due to insufficient heat supply slowing down MH dissociation. The CH4/CO2/N2 mixed hydrates (Mix-H) formation and CO2 storage in depleted MHBS after CO2/N2 injection initially increase and then decrease with post-mining SA (peak at SA = 54.5 %). The rate of Mix-H formation decreases as the post-mining SA increases. Higher pre-mining SH and CO2/N2 injection rate facilitates rapid gas phase mixing within the sediments, thereby improving the kinetics and homogeneity of Mix-H formation and hydrate-based CO2 storage efficiency. MHBS with relatively low SH and SA exhibit enhanced safety for the integrated process, offering reduced depressurization-induced sediment subsidence and increased hydrate restoration ratios (∼85 %) by Mix-H formation.

A Novel Theoretical Method for Upscaling Permeability in Hydrate‐Bearing Sediments

AbstractThe accurate prediction of Darcy‐scale permeability (absolute permeability and gas‐water relative permeability) of hydrate‐bearing sediments (HBS) plays a crucial role in assessing reservoir potential and optimizing recovery strategies. However, the challenges of field coring, the rigorous conditions encountered in laboratory permeability tests, and the multi‐scale pore structure characteristics of HBS complicate the understanding of the relationship between pore structures and Darcy‐scale permeability of HBS. In this study, we propose an innovative upscaling method that integrates flow properties of typical regions, such as coarse, medium, and fine regions, to predict the Darcy‐scale permeability of HBS from the pore‐scale. This method considers two hydrate habits (pore‐filling and grain‐coating hydrates), heterogeneity and anisotropy of HBS, and multi‐scale pore structures. Taking the absolute permeability of hydrate‐free sediments in the y direction for example, the permeability values for the fine region, the medium region, the coarse region, and the equivalent HBS are 9.43 D, 13.59 D, 18.87 D, and 14.06 D, respectively. Thus, the predicted permeability (14.06 D) is much closer to the experimental data (15.44 D), which validates the efficacy of our upscaling method in estimating Darcy‐scale permeability. Moreover, the characteristics of our predicted Darcy‐scale permeability align with those reported in previous literature. This approach introduces a groundbreaking perspective for predicting permeability in HBS from pore‐scale to Darcy‐scale. It offers essential insights into predicting permeability in HBS while effectively preserving the impact of pore‐scale structural variations caused by local heterogeneity and facilitating numerical simulations of gas production from hydrate reservoirs.

Effect of Hydrate Saturation on Triaxial Shear Mechanical Properties of Methane Hydrate-Bearing Sediment

Abstract As a clean energy source, natural gas hydrate resources are essential to the development of energy in the twenty-first century. However, the degree of consolidation of the hydrate reservoir is low, and complex accidents such as wellbore instability, reservoir collapse, and gas production leakage will be caused if improperly exploited. The laboratory employs a self-developed triaxial shear test equipment that operates under high pressure and low temperature conditions. This equipment is specifically designed to determine the mechanical parameters and strength characteristics of methane hydrate bearing sediment (MHBS) samples. It is used to create water-saturated hydrate deposits with varying levels of saturation. The synthesis of MHBS samples with varying saturations is achieved by precisely regulating the amount of water. The saturation of MHBS is then determined and confirmed by the utilization of the “water content method” and the “gas collection method.” Triaxial shear tests are conducted on MHBS to examine the impact of hydrate saturation on the mechanical parameters and strength behaviours of MHBS. The experimental findings demonstrate that the presence of hydrate crystals enhances the robustness of the depositing medium. The stress-strain curves of MHBS have a hyperbolic shape, indicating strain hardening features. The stress-strain curves may be categorized into three distinct stages: the initial elastic deformation, followed by a slow shift to the initial yield deformation, and ultimately leading to strain hardening. As axial strain rises, the behaviour of the MHBS transitions progressively from elastic deformation to plastic deformation. The shear strength and initial yield strength of MHBS enhance with higher hydrate saturation. The reason for this is that as the hydrate saturation rises, the influence of hydrate crystals on the enhancement of sediment strength becomes more pronounced. However, the initial yield strain of each MHBS sample is between 0.5% and 1.5%, and the difference is not significant. When the hydrate saturation rises gradually, the cohesion of MHBS enhances. Nevertheless, the hydrate saturation has a very minor impact on the internal friction angle.

Mineral effects on methane hydrate formation and distribution in sand sediments

Methane hydrate is a promising energy resource widely occurring in the world, but the formation and distribution of methane hydrate in marine sediments with complex minerals remains unclear. Due to the small pore space and fine-grained size of clay minerals, the contact relationship between methane hydrate and clay mineral surface under excess water has not been characterized fully, which is required to investigate the mineral effect on methane hydrate formation. In this study, cryo-SEM was applied to observe the distribution of methane hydrate synthesized in pure quartz sands and the quartz sands mixed with montmorillonite or illite separately. According to the results of the research, methane hydrate dispersedly forms in the pore space away from and on the surface of quartz under a local excess water condition. In addition, methane hydrate occurs away from montmorillonite in pores with excess water and contacts the edge of montmorillonite under a local excess-gas condition. Moreover, methane hydrate was only observed to form away from illite aggregates in the pore with residual water. Montmorillonite and illite influence the preferable distribution of methane hydrate to occur away from mineral surface in excess water condition. In the sediments composed of different minerals, methane hydrate forms stochastically in the pore space and grows up individually. As a result, the findings of this study significantly expand the understanding of the formation and distribution of methane hydrate in marine sediments and the prediction of physical properties of hydrate-bearing sediments, and provide insights into natural gas hydrate exploration and production.

Borehole Stability of Natural Gas Hydrate Reservoirs

Abstract The decomposition of natural gas hydrate (NGH) due to long-term drilling may decrease the strength of reservoirs and increase the borehole failure risk. Meanwhile, the creep properties of NGH reservoirs also may give rise to engineering problems including borehole shrinkage and jamming of drilling tools in the late stage of drilling, which seriously impairs the drilling safety. A thermal-fluid-solid multi-field coupling model considering the decomposition kinetics of NGH and creep properties of reservoirs was established to explore the influence mechanism of NGH decomposition and creep properties of hydrate-bearing sediments on mechanical behaviors of boreholes. In addition, influences of drilling parameters and geomechanical properties of reservoirs on borehole stability in the drilling process of NGH reservoirs were analyzed. Research results show that creep properties of NGH deposits causes homogenization of stress distribution in different directions of NGH reservoirs around boreholes, transition of plastic zones around boreholes to a round shape, and possibly overall borehole collapse. As the horizontal geostress becomes more inhomogeneous, the borehole instability risk increases; the higher the initial pore pressure of formation is, the lower the effective geostress and the lower the borehole instability risk. The research results can provide theoretical support for safe drilling of NGH reservoirs in South China Sea and promote the early commercial exploitation of NGH resources in China.

Experimental studies and pore-scale modeling of hydrate dissociation kinetics at different depressurization rates in a cubic hydrate simulator

Natural gas hydrate (NGH) is a promising energy resource that has triggered a race for scientific innovation in energy and environmental research. However, there still faces the challenges of low-efficiency hydrate dissociation and unstable gas production during the hydrate production. Clarifying the kinetic mechanism of hydrate dissociation is the key to improving the efficiency of “phase-transition to gas-supply” in hydrate-bearing sediment. This study successfully conducts hydrate dissociation experiments with different depressurization rates in the Cubic Hydrate Simulator (CHS). A novel dissociation kinetic model integrating the hydrate pore-scale morphology and its evolutions are established, and the sensitivities of the kinetic and thermal parameters are discussed in detail. The mathematical relationship between the hydrate saturation and reaction area is quantitatively analyzed for the hydrate formation and dissociation kinetics. The history matching simulation with the newly developed model achieves an excellent agreement with the experimental results. The full-lifecycle kinetic behaviors of the hydrate dissociation in the depressurization experiments are finely characterized. It is found that the evolutions of the hydrate saturation (SH) and temperature (T) spatial distributions exhibit strong heterogeneous characteristics in the vessel due to the phase transition and heat transfer effects. In addition, this reveals that the relatively high depressurization rate can lead to a more significant dissociation rate in the depressurization stage. This provides a new reliable and adaptable method for describing the hydrate dissociation kinetics in the porous media.

Pore Characteristics of Hydrate-Bearing Sediments from Krishna-Godavari Basin, Offshore India

Pore-filling hydrates are the main occurrence forms of marine gas hydrates. Pore characteristics are a vital factor affecting the thermodynamic properties of hydrates and their distribution in sediments. Currently, the characterization of the pore system for hydrate-bearing reservoirs are little reported. Therefore, this paper focuses on the Krishna-Godavari Basin, via various methods to characterize the hydrate-bearing sediments in the region. The results showed that X-ray diffraction (XRD) combined with scanning electron microscopy (SEM) and cast thin section (CTS) can better characterize the mineral composition in the reservoir, high-pressure mercury injection (HPMI) focused on the contribution of pore size to permeability, constant-rate mercury injection (CRMI) had the advantage of distinguishing between the pore space and pore throat, and nuclear magnetic resonance cryoporometry (NMRC) technique can not only obtain the pore size distribution of nanopores with a characterization range greater than nitrogen gas adsorption (N2GA), but also quantitatively describe the trend of fluids in the pore system with temperature. In terms of the pore system, the KG Basin hydrate reservoir develops nanopores, with a relatively dispersed mineral distribution and high content of pyrite. Rich pyrite debris and foraminifera-rich paleontological shells are observed, which leads to the development of intergranular pores and provides more nanopores. The pore throat concentration and connectivity of the reservoir are high, and the permeability of sediments in the same layer varies greatly. The reason for this phenomenon is the significant difference in average pore radius and pore size contribution to pore permeability. This article provides a reference and guidance for exploring the thermodynamic stability of hydrates in sediments and the exploration and development of hydrates by characterizing the pores of hydrate reservoirs.

Pore-scale deformation characteristics of hydrate-bearing sediments with gas replacement

Gas replacement method enables the simultaneous exploitation of natural gas and the realization of carbon capture, utilization, and storage (CCUS). Safe exploitation of hydrate-bearing sediments (HBS) has garnered significant attention, particularly concerning the engineering geological risks involved. Understanding deformation characteristics during shear after the replacement of HBS is crucial for safe and efficient exploitation. This study employs microfocus computer tomography and digital volume correlation (DVC) to investigate the deformation characteristics of HBS samples with varying replacement percentages. Key findings include: 1. An increase in failure strength of HBS is observed with higher replacement percentages due to improved hydrate cementation and consolidation under confining pressure. 2. DVC analysis shows that narrower radial displacement ranges are associated with increased pore compression, while wider ranges indicate greater particle repositioning. Frequent large axial displacements suggest significant pore compaction, whereas smaller axial displacements indicate particle movement and pore-filling phenomena. 3. The gas replacement process enhances the cementation structure of HBS without altering hydrate saturation, resulting in thinner shear bands and accelerated strain softening with higher replacement percentages. 4. The DVC approach effectively captures volumetric strain and deformation behaviors, offering valuable insights into sediment responses under shear. This study provides a theoretical reference for geological safety evaluation during gas replacement exploitation.

Effect of particle size, water saturation, inorganic salt and methane on the phase equilibrium of CO2 hydrates in sediments

Understanding the thermal stability of gas hydrate in complex marine geological environment is of importance to hydrate-based carbon sequestration. In this work, the factors affecting the equilibrium of CO2 hydrate in ocean sediments, including quartz sands, inorganic salts and gas impurities were quantitatively measured in a temperature range from 273 to 283 K and a phase equilibrium model of hydrate was established. To reveal the distribution in pore structure, the micro-morphologies of hydrate-bearing sediments were measured by cryo-SEM. Results showed that reduction of initial water saturation, addition of NaCl and CH4 were found to have inhibitory effect on CO2 hydrate equilibrium. Initial water saturation reduced the equilibrium temperature by the capillary pressure, but only 0.3–0.7 K temperature depression was observed as the water saturation reduced to 5 %. About 5.7 K in the average temperature depression was found by the addition of 10 wt% NaCl and 24 mol% CH4. NaCl and CH4 influenced the hydrate equilibrium by changing the water activity and chemical potential of hydrate water lattice. SEM images showed that the hydrate formed in pores of quartz sand had porous surface and coated the sand particles like a layer of cells which are 5–20 μm in diameter, suggesting the hydrate layer exists between the liquid and gas phase. Based on the van der Waals-Platteeuw model, a hydrate equilibrium model was developed. The model provided a good prediction of the hydrate equilibrium in the presence of quartz sand, NaCl and CH4 with an averaged deviation of ±4.2 %, which had the potential to be applicated in more complexed ocean sedimentary environment.

Numerical Investigation of the Deformation Characteristics of Hydrate-Bearing Sediments during Hydrate Extraction

Numerical Investigation of the Deformation Characteristics of Hydrate-Bearing Sediments during Hydrate Extraction