With the increasing demand for intelligence and automation, and the continuous strengthening of safety and efficiency requirements, the disadvantages of traditional “blind use” of nickel–cadmium batteries have become increasingly prominent, and the lack of state-of-charge (SOC) estimation needs to be changed urgently. For this purpose, a dynamic model of nickel–cadmium battery is established, and an SOC estimation method of nickel–cadmium battery based on adaptive untraced Kalman filter is proposed. Firstly, the experimental platform was built, and the open-circuit voltage and polarization characteristics of nickel–cadmium batteries were analyzed. On this basis, an equivalent circuit model is constructed to reflect the characteristics of nickel–cadmium batteries, and the model parameters were identified by the hybrid pulse power characteristic test; Then, based on the dynamic model, the SOC of the nickel–cadmium battery was estimated by combining with the Sage–Husa adaptive untrace Kalman filtering algorithm. Finally, the SOC estimation effect was verified under two operating conditions: Hybrid pulse power characteristic (HPPC) and constant cyclic charging and discharging power. The experimental results show that the proposed estimation method is insensitive to the initial value of SOC, and can still converge to the real value even if there is 30% error in the initial value. The mean absolute error and root mean square deviation of the final SOC estimation results are both less than 1%. The dynamic model and the proposed SOC estimation method provide valuable reference for the operation control, maintenance, and replacement of nickel–cadmium batteries in the use process.
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