Human-friendly Electronics Research Articles

Structural and Material-Based Approaches for the Fabrication of Stretchable Light-Emitting Diodes.

Stretchable displays, capable of freely transforming their shapes, have received significant attention as alternatives to conventional rigid displays, and they are anticipated to provide new opportunities in various human-friendly electronics applications. As a core component of stretchable displays, high-performance stretchable light-emitting diodes (LEDs) have recently emerged. The approaches to fabricate stretchable LEDs are broadly categorized into two groups, namely "structural" and "material-based" approaches, based on the mechanisms to tolerate strain. While structural approaches rely on specially designed geometries to dissipate applied strain, material-based approaches mainly focus on replacing conventional rigid components of LEDs to soft and stretchable materials. Here, we review the latest studies on the fabrication of stretchable LEDs, which is accomplished through these distinctive strategies. First, we introduce representative device designs for efficient strain distribution, encompassing island-bridge structures, wavy buckling, and kirigami-/origami-based structures. For the material-based approaches, we discuss the latest studies for intrinsically stretchable (is-) electronic/optoelectronic materials, including the formation of conductive nanocomposite and polymeric blending with various additives. The review also provides examples of is-LEDs, focusing on their luminous performance and stretchability. We conclude this review with a brief outlook on future technologies.

High-Performance Electrochemical Actuator under an Ultralow Driving Voltage with a Mixed Electronic-Ionic Conductive Metal-Organic Framework.

Although versatile deformation, high flexibility, and environmental friendliness of electrochemical actuators (EAs) have made them promising in bioinspired soft robots and biomedical devices, the relatively high driving voltages unfortunately impose great restrictions on their applications in low-energy and human-friendly electronics. Here, we find that the uses of a mixed electronic-ionic conductive metal-organic framework (c-MOF), i.e., Ni3(hexaiminotriphenylene)2 (Ni3(HITP)2), largely lower the driving voltage of EAs. The as-fabricated EA can work under a driving voltage as low as 0.1 V, representing the lowest value among those for the c-MOF-based EAs reported so far. The Ni3(HITP)2-based EA shows an excellent actuation performance such as a high bending strain difference of 0.48% (±0.5 V, 0.1 Hz) and long-term durability of >99% after 15,000 cycles due to the improved conductivity up to 1000 S·cm-1 and double-layer capacitance as high as 176.3 F·g-1 stemming from the mixed electronic-ionic conduction of Ni3(HITP)2.

Aqueous electrolyte-gated solution-processed metal oxide transistors for direct cellular interfaces.

Biocompatible field-effect-transistor-based biosensors have drawn attention for the development of next-generation human-friendly electronics. High-performance electronic devices must achieve low-voltage operation, long-term operational stability, and biocompatibility. Herein, we propose an electrolyte-gated thin-film transistor made of large-area solution-processed indium-gallium-zinc oxide (IGZO) semiconductors capable of directly interacting with live cells at physiological conditions. The fabricated transistors exhibit good electrical performance operating under sub-0.5 V conditions with high on-/off-current ratios (>107) and transconductance (>1.0 mS) over an extended operational lifetime. Furthermore, we verified the biocompatibility of the IGZO surface to various types of mammalian cells in terms of cell viability, proliferation, morphology, and drug responsiveness. Finally, the prolonged stable operation of electrolyte-gated transistor devices directly integrated with live cells provides the proof-of-concept for solution-processed metal oxide material-based direct cellular interfaces.

Bioinspired self-healing and robust elastomer via tailored slipping semi-crystalline arrays for multifunctional electronics

Self-healing and human-friendly electronics, with plenty of dynamic structural motifs, are desired to be ultrastretchable, highly sensitive, self-powered and responsive with external stimulus as the medium of artificial intelligence. Herein, meticulously engineered dynamic structural motifs, slipping semi-crystalline dynamic hydrogen bonding arrays (SSHAs) were firstly proposed and utilized to achieve ultrastretchable (2880 %), tough (115.7 MJ∙m−3) elastomers (PAT) with excellent actuation performance (actuation strain ≈ 37 %) and human-friendly healing temperature. For the multifunctionality, the elaborate assembly of SSHAs was also adopted to obtain three-dimensional (3D) physical networks (PAT-M) by integrating with Ti3C2Tx and silver nanowire. As expected, high sensitivity (gauge factor, GF ≈ 60.6) and ultrahigh energy harvesting property (2.6 W∙m−2) were simultaneously achieved attributing to the 3D physical networks. This study not only provides a brand-new and promising strategy to develop human-friendly self-healing elastomers, but also promotes the advances of multifunctional electronics.

Novel ionic bioartificial muscles based on ionically crosslinked multi-walled carbon nanotubes-mediated bacterial cellulose membranes and PEDOT:PSS electrodes

High-performance bioartificial muscles with low-cost, large bending deformation, low actuation voltage, and fast response time have drawn extensive attention as the development of human-friendly electronics in recent years. Here, we report a high-performance ionic bioartificial muscle based on the bacterial cellulose (BC)/ionic liquid (IL)/multi-walled carbon nanotubes (MWCNT) nanocomposite membrane and PEDOT:PSS electrode. The developed ionic actuator exhibits excellent electro-chemo-mechanical properties, which are ascribed to its high ionic conductivity, large specific capacitance, and ionically crosslinked structure resulting from the strong ionic interaction and physical crosslinking among BC, IL, and MWCNT. In particular, the proposed BC-IL-MWCNT (0.10 wt%) nanocomposite exhibited significant increments of Young’s modulus up to 75% and specific capacitance up to 77%, leading to 2.5 times larger bending deformation than that of the BC-IL actuator. More interestingly, bioinspired applications containing artificial soft robotic finger and grapple robot were successfully demonstrated based on high-performance BC-IL-MWCNT actuator with excellent sensitivity and controllability. Thus, the newly proposed BC-IL-MWCNT bioartificial muscle will offer a viable pathway for developing next-generation artificial muscles, soft robotics, wearable electronic products, flexible tactile devices, and biomedical instruments.

High-performance microfibrillated cellulose-based low voltage electroactive ionic artificial muscles in bioinspired applications

The development of electroactive high-performance biofriendly artificial muscles with large mechanical bending deformation, fast response time, low actuation voltage, and excellent durability is highly desirable for human friendly electronics such as soft robots, active biomedical devices, wearable devices, and flexible haptic displays. Herein, we report a novel ultralow voltage high-performance ionic artificial muscle based on microfibrillated cellulose (MFC), ionic liquid (IL) as a plasticizer, and conducting polymer poly(3,4-ethylene dioxythiophene)-polystyrene sulfonate (PEDOT: PSS) as electrodes. The proposed MFC-IL biocomposite membrane was fabricated through doping of MFC with IL. The PEDOT:PSS layers were uniformly deposited on surfaces of the MFC-IL membrane by using the dip-coating method. The designed MFC-IL actuator demonstrated a large bending strain (0.31% under a sinusoidal input voltage of ±1.5 V at 0.1 Hz), low actuation voltage (<2 V), fast response time (<2.5 s), and excellent actuation durability (98% retention for 2 h), all of which were mainly due to its relatively large specific capacitance (115.2 mF cm−2) and tuned mechanical properties, resulting from the strong ionic interactions and crosslinking of MFC fibers with IL. More importantly, bioinspired applications including the grapple robot, bionic medical stent, and artificial soft robotic finger have been successfully realized. Therefore, the newly designed MFC-IL ionic soft actuator and its bioinspired robotic designs will provide a viable way for developing next-generation artificial muscles, soft robotics, active medical devices, and flexible displays.

Highly Stretchable Polymer Composite with Strain-Enhanced Electromagnetic Interference Shielding Effectiveness.

Polymer composites with electrically conductive fillers have been developed as mechanically flexible, easily processable electromagnetic interference (EMI) shielding materials. Although there are a few elastomeric composites with nanostructured silvers and carbon nanotubes showing moderate stretchability, their EMI shielding effectiveness (SE) deteriorates consistently with stretching. Here, a highly stretchable polymer composite embedded with a three-dimensional (3D) liquid-metal (LM) network exhibiting substantial increases of EMI SE when stretched is reported, which matches the EMI SE of metallic plates over an exceptionally broad frequency range of 2.65-40 GHz. The electrical conductivities achieved in the 3D LM composite are among the state-of-the-art in stretchable conductors under large mechanical deformations. With skin-like elastic compliance and toughness, the material provides a route to meet the demands for emerging soft and human-friendly electronics.

Material Design and Fabrication Strategies for Stretchable Metallic Nanocomposites

Stretchable conductive nanocomposites fabricated by integrating metallic nanomaterials with elastomers have become a vital component of human-friendly electronics, such as wearable and implantable devices, due to their unconventional electrical and mechanical characteristics. Understanding the detailed material design and fabrication strategies to improve the conductivity and stretchability of the nanocomposites is therefore important. This Review discusses the recent technological advances toward high performance stretchable metallic nanocomposites. First, the effect of the filler material design on the conductivity is briefly discussed, followed by various nanocomposite fabrication techniques to achieve high conductivity. Methods for maintaining the initial conductivity over a long period of time are also summarized. Then, strategies on controlled percolation of nanomaterials are highlighted, followed by a discussion regarding the effects of the morphology of the nanocomposite and postfabricated 3D structures on achieving high stretchability. Finally, representative examples of applications of such nanocomposites in biointegrated electronics are provided. A brief outlook concludes this Review.

Ecofriendly high-performance ionic soft actuators based on graphene-mediated cellulose acetate

Ionic-type artificial muscles with eco-friendly, biodegradable, and biocompatible functionalities have attracted attention for a wide range of potential applications in wearable electronics, soft haptic-feedback systems, and active biomedical devices. Here, we report on the development of an ecofriendly high-performance ionic soft actuator based on biofriendly cellulose acetate (CA), graphene nanopowders (GN), ionic liquid (IL) as a plasticizer, and biofriendly-flexible-nonmetallic conducting polymer poly(3,4-ethylene-dioxythiopene)-polystyrenesulfonate (PEDOT: PSS) as an electrode, thereby realizing a novel ecofriendly CA-IL-GN actuator with a large bending mechanical deformation and a fast response time. The proposed CA-IL-GN (0.2 wt%) nanocomposite membrane exhibited dramatic increments in specific capacitance (2.92 times) and Young’s modulus (2.38 times), thus leading to a 2.9 times larger bending deformation and a 4.8 times faster response than those of pure CA-IL actuator. Therefore, the developed ecofriendly high-performance CA-IL-GN actuator can be considered to be a promising candidate for human-friendly electronics, including artificial muscles, flexible haptic devices, soft wearable devices, and bio-medical devices, due to its cost-effectiveness, large bending mechanical actuation, fast response, and bio-friendly functionalities.

Material-Based Approaches for the Fabrication of Stretchable Electronics.

Stretchable electronics are mechanically compatible with a variety of objects, especially with the soft curvilinear contours of the human body, enabling human-friendly electronics applications that could not be achieved with conventional rigid electronics. Therefore, extensive research effort has been devoted to the development of stretchable electronics, from research on materials and unit device, to fully integrated systems. In particular, material-processing technologies that encompass the synthesis, assembly, and patterning of intrinsically stretchable electronic materials have been actively investigated and have provided many notable breakthroughs for the advancement of stretchable electronics. Here, the latest studies of such material-based approaches are reviewed, mainly focusing on intrinsically stretchable electronic nanocomposites that generally consist of conducting/semiconducting filler materials inside or on elastomer backbone matrices. Various approaches for fabricating these intrinsically stretchable electronic materials are presented, including the blending of electronic fillers into elastomer matrices, the formation of bi-layered heterogeneous electronic-layer and elastomer support-layer structures, and modifications to polymeric molecular structures in order to impart stretchability. Detailed descriptions of the various conducting/semiconducting composites prepared by each method are provided, along with their electrical/mechanical properties and examples of device applications. To conclude, a brief future outlook is presented.

Natural cellulose ionogels for soft artificial muscles

Rapid development of soft micromanipulation techniques for human friendly electronics has raised the demand for the devices to be able to carry out mechanical work on a micro- and macroscale. The natural cellulose-based ionogels (CEL-iGEL) hold a great potential for soft artificial muscle application, due to its flexibility, low driving voltage and biocompatibility. The CEL-iGEL composites undergo reversible bending already at ±500mV step-voltage values. A fast response to the voltage applied and high ionic conductivity of membranous actuator is achieved by a complete dissolution of cellulose in 1-ethyl-3-methylimidazolium acetate [EMIm][OAc]. The CEL-iGEL supported cellulose actuator films were cast out of cellulose-[EMIm][OAc] solution via phase inversion in H2O. The facile preparation method ensured uniform morphology along the layers and stand for the high ionic-liquid loading in a porous cellulose scaffold. During the electromechanical characterization, the CEL-iGEL actuators showed exponential dependence to the voltage applied with the max strain difference values reaching up to 0.6% at 2 V. Electrochemical analysis confirmed the good stability of CEL-iGEL actuators and determined the safe working voltage value to be below 2.5V. To predict and estimate the deformation for various step input voltages, a mathematical model was proposed.