Howardite-eucrite-diogenite Research Articles

HED zircons as a window into the solar system’s first crust: Decoupling primordial differentiation, metamorphism and impact events through textural and chemical studies

The study of Howardite-Eucrite-Diogenite (HED) meteorites provides unique insights into early planet formation and the impact events that shaped the early Solar System. However, unraveling the complex history of the HED parent body (hypothesized to be the asteroid 4 Vesta) from whole-rock samples is challenging since most HEDs are impact-related breccias comprising mixed lithic and mineral fragments that experienced variable deformation and alteration. Combining U-Pb geochronology, trace element geochemistry, and microstructural analysis of zircon can unravel magmatic, metamorphic and impact processes through time to decipher the HED parent body evolution. Here we present textural (EBSD), geochronological (207Pb/206Pb SIMS dating) and geochemical data (Th/U, REE, Ti-in-zircon thermometry) on 61 zircon grains from melt breccia eucrites, unbrecciated/monomict/polymict eucrites, howardites and diogenites. Diverse textures indicate variable histories of impact deformation and high-temperature recrystallization. Undeformed, fractured zircons preserve primary zoning (CL, Th/U, REE) indicating magmatic and metamorphic origins. At least three magmatic zircon grains (Th/U > 0.3) give 207Pb/206Pb ages of 4558–4565 Ma, suggesting primary differentiation in the parent body first million years. Twenty metamorphic zircon grains (Th/U < 0.3) date to 4420–4568 Ma, indicating prolonged thermal metamorphism from impact heating and/or crustal cooling. Impact-recrystallized granular zircon grains reveal major impacts during and just after the parent body differentiation (4500–4560 Ma), plus later events potentially linked to synchronous impacts in the Solar System (e.g. the Moon). Similarity of metamorphic and shocked zircon ages (circa 4550–4450 Ma) suggests impacts occurred for ≥100 million years after the parent body formed.

A slowly cooled deep crust on asteroid 4 Vesta and the recent impact history of rubble pile vestoids recorded by diogenites

In this study, we investigate the 40Ar/39Ar systematics of nineteen diogenites thought to come from deep crustal levels of asteroid 4 Vesta. We applied both Electron Backscattered Diffraction (EBSD) and 40Ar/39Ar and methods to the unbrecciated diogenite LAP 031381. We obtained three plateau ages resulting in a combined weighted mean age of 4441 ± 15 Ma (P = 0.16). The EBSD analyses suggest that LAP 031381 displays minimal evidence of shock and, when combined with petrography observations, diffusion modelling and 40Ar/39Ar data, these results suggest that the crustal volume that initially contained this diogenite, reached a temperature of ca. 630 °C at ∼ 4.44 Ga. This corresponds to a linear cooling rate of ∼ 5 °C / Ma for a crystallization age of 4550 Ma. Independent thermal models suggest that these conditions were present at a depth of 60 to 65 km at 4.44 Ga.The other eighteen diogenites yielded 40Ar/39Ar results that indicate that they have been variously shocked by impact events and seven of them yielded plateau ages ranging from 2413 ± 189 Ma to 84 ± 162 Ma. We combined these results with 40Ar/39Ar ages from eucrites and howardites and propose that the HED (Howardite, Eucrite, Diogenite) meteorites recorded impact events at the surface of Vesta until ∼ 3.4 Ga when they were then ejected during a large collision. The eucrites, diogenites and howardites were then recombined into small rubble pile asteroids which probably make up a large part of the Vestoid family. After ejection, the K/Ar system in plagioclase crystals ceased in most cases to be fully reset by impact events as the temperature spikes reached during small impacts lack enough energy to trigger significant 40Ar* diffusion. On the other hand, ultra-transient and high-temperature – sensitive pyroxene crystals kept a more systematic record of small impacts until recent time. 38Arc cosmochron cosmogenic exposure ages on diogenites mostly range from 51 ± 7 Ma to 0 ± 1 Ma and when combined with other HED cosmochron ages, suggest that almost all the HED meteorites were continuously ejected from secondary rubble pile asteroids mostly between 50 Ma and present.

The vesiculated layer in the anomalous diogenite Northwest Africa 12973

AbstractDiogenites, which are part of the howardite–eucrite–diogenite (HED) group, are considered to represent rocks from the lower crust and mantle of a differentiated planetary body, likely the asteroid 4 Vesta. The Northwest Africa 12973 (NWA 12973) meteorite was classified as an anomalous diogenite due to the occurrence of a vesiculated layer. This work reports on the petrographic and geochemical study of two fragments of this meteorite, aiming to better constrain the origin of the vesiculated layer. Whereas the interior of NWA 12973 (here called host) presents the typical characteristics of an olivine diogenite, that is, coarse‐grained pyroxene, olivine ribbons, chromite, and accessory phases, the vesiculated layer presents a fine‐grained pyroxene groundmass with local rounded relics of olivine and interstitial chromite and metal, and is characterized by abundant large vesicles. The contact between the vesiculated layer and the host is sharply defined. The composition of individual minerals does not show any significant differences between the host and the vesiculated layer, suggesting in situ melting. Geothermobarometry indicates a slightly higher crystallization temperature at lower pressure for the vesiculated layer, consistent with melting and crystallization under lower crustal conditions upon exhumation. The trigger for the local melting was likely a large impact event, which was responsible for adiabatic decompression in the central area or deep faulting and frictional melting.

Gravitational study of escape routes and residence regions of Ceres and Vesta fragments

Aims. Ceres and Vesta are the two largest bodies in the main asteroid belt (MB) and have been extensively studied, particularly since the DAWN mission. Vesta is known to have an associated asteroid family, while the existence of a Ceres family is uncertain. This study investigates the fate of multi-kilometre fragments ejected from Ceres and Vesta due to impacts over a timescale of several hundred million years. Methods. We performed purely gravitational N-body simulations to investigate the dynamical evolution of multi-kilometre-sized fragments ejected from Ceres and Vesta. We tracked the trajectories of these fragments and identified their residence regions within the MB. We analysed the escape routes and end states of the fragments that manage to leave the MB, including the delivery to the near-Earth asteroids (NEAs). We also estimated the number of collisions with Earth that could be attributed to large fragments ejected from Ceres and Vesta. Results. Our simulations show that the Ceres fragments are dispersed over a larger region in the MB compared to Vesta fragments due to their higher ejection velocities. We identified the escape routes of the fragments that leave the MB, which for the Ceres fragments are the 5:2 and 8:3 mean-motion resonances (MMR), and for the Vesta fragments are the 3:1 MMR and ν6 secular resonance, where they can be delivered to the NEA region. We also find that the Pristine region, located between the 5:2 and 7:3 MMR, is the most likely place to find any surviving member of a Ceres family. There were no collisions of large Ceres or Vesta fragments with Earth over the age of the Solar System, suggesting that, under the model considered here, the howardite–eucrite–diogenite meteorites originate from smaller NEAs from Vesta.

Linking meteorites to their asteroid parent bodies: The capabilities of dust analyzer instruments during asteroid flybys

AbstractLinking meteorites to their asteroid parent bodies remains an outstanding issue. Space‐based dust characterization using impact ionization mass spectrometry is a proven technique for the compositional analysis of individual cosmic dust grains. Here we investigate the feasibility of determining asteroid compositions via cation mass spectrometric analyses of their dust ejecta clouds during low (7–9 km s−1) velocity spacecraft flybys. At these speeds, the dust grain mass spectra are dominated by easily ionized elements and molecular species. Using known bulk mineral volume abundances, we show that it is feasible to discriminate the common meteorite classes of carbonaceous chondrites, ordinary chondrites, and howardite–eucrite–diogenite achondrites, as well as their subtypes, relying solely on the detection of elements with ionization efficiencies of ≤700 or ≤800 kJ mol−1, applicable to low (~7 km s−1) and intermediate (~9 km s−1) flyby speed scenarios, respectively. Including the detection of water ion groups enables greater discrimination between certain meteorite types, and flyby speeds ≥10 km s−1 enhance the diagnostic capabilities of this technique still further. Although additional terrestrial calibration is required, this technique may allow more unequivocal asteroid‐meteorite connections to be determined by spacecraft flybys, emphasizing the utility of dust instruments on future asteroid missions.

V-type Asteroids as the Origin of Mesosiderites

We present the results of a campaign of hypervelocity impact experiments on natural mesosiderite targets, using representative main asteroid belt impact speeds. The objective is to document further the surface evolution of iron-rich asteroids. In contrast with iron meteorites, we demonstrate the fragile behavior of mesosiderite at impact since experiments result in both cratering and catastrophic disruption. The behavior of metal-rich asteroids at impact is thus highly influenced by the original ratio of metal/silicate. A visible to near-infrared spectral analysis shows that the pyroxene silicate signature of impacted mesosiderites, or their ejecta, is fully preserved. Our results thus rule out a mesosiderite hypothesis for the very nature of M/X-type asteroids including (16) Psyche, despite a small fraction of its surface possibly being covered by mesosiderite-like materials. Finally, we address the question of whether mesosiderites and howardite–eucrite–diogenite (HED) meteorites are genetically linked to (4) Vesta or other differentiated asteroids in the main belt based on their spectral similarity.

Pyroxene and Hydroxyl Signatures in Vesta Newly Calibrated Data from Dawn Mission

Thanks to the VIR spectrometer onboard NASA’s Dawn spacecraft, which orbited Vesta in 2011–2012, thousands of hyperspectral images of its surface have been collected. The mission confirmed the HED (Howardite–Eucrite–Diogenite) meteorite composition of Vesta. Moreover, the VIR spectrometer detected the 2.8 µm absorption band, due to the presence of the OH molecule. In this work, we took advantage of the newly calibrated data of the VIR spectrometer by characterizing new spectral features thanks to the improved signal-to-noise (S/N) ratio for these spectra. The main goals of this work are as follows: (1) to characterize Vesta’s surface in the visible range and (2) to confirm, reinforce and characterize the OH distribution on Vesta by studying the 2.8 µm band and looking for OH combination bands around 2.2–2.4 µm. A possible relation between the 1.9 µm absorption band due to the presence of pyroxenes and the one at 0.5 µm was analyzed. Finally, the analysis of hydroxyl absorption bands evidenced an anti-correlation between the abundance of hydroxyl-bearing molecules and the surface reflectance. This confirms that the hydroxyl presence is linked to the dark units on Vesta.

Calcium isotope constraints on the origin of eucrites and diogenites: The role of magma ocean and magmatism

Howardite-Eucrite-Diogenite (HED) meteorites represent a large suit of crustal and sub-crustal rocks from the Vesta. This work presents systematic examination of the Ca isotope data on multiple varieties of HED meteorites for a better understanding of the magmatic evolution of the Vesta. Falls and finds possess similar Ca isotope compositions, and no correlation is observed between δ44/40Ca and (Sr/Eu*)n, indicating that terrestrial weathering effect on Ca isotopes is insubstantial. According to the data in literature, the inner solar system may have a homogeneous δ44/40Ca and the average of inner solar system bodies (0.97±0.03‰) can approximate the composition of bulk silicate Vesta (BSV). Basaltic eucrites define a cluster in δ44/40Ca (0.95±0.07‰, 2SD, N=15) that is higher than the terrestrial mid-ocean ridge basalts (∼0.85‰). Combined with partial melting and magma ocean differentiation modeling, the Ca isotope signatures suggest that eucrites represent the residual melts evolved from a magma ocean formed by primordial Vesta's moderate-to-high degree melting (20-100%). Diogenites have distinguishingly higher δ44/40Ca (1.18±0.15‰, 2SD, N=7) than the basaltic eucrites, which displays a negative correlation with the 1000×Lu/Ti ratio and a positive correlation with 1/Ca. However, magma ocean crystallization can only explain diogenites with δ44/40Ca higher than 1.17‰, suggesting that diogenites have complicated petrogenesis and are not necessarily cogenetic with eucrites. Diogenites with δ44/40Ca<1.17‰ may result from magma-ocean-cumulate partial melts intruding the eucritic crust. Mixing models suggest that the eucritic component in these diogenites may be less than 10%. Two howardites have lower δ44/40Ca of 0.80±0.04‰ and 0.86±0.05‰ than eucrites and diogenites. This signature may reflect the addition of carbonaceous chondritic materials due to impact brecciation.

Mass-dependent nickel isotopic variations in achondrites and lunar rocks

We present high-precision mass-dependent nickel isotopic data for a comprehensive suite of achondrites and lunar rocks, providing key insights into the early planetary differentiation and Earth-Moon system formation. The primitive achondrites display high Ni contents and invariant Ni isotopic compositions. Incomplete core-mantle differentiation in primitive achondrite parent bodies resulted in the retention of metal in the mantle, which dominated the Ni budget and accounted for the bulk chondritic Ni isotopic values. The highly reduced differentiated achondrites, aubrites and an ungrouped achondrite (NWA 8409), have variable, and extremely light Ni isotopic compositions. Acid leaching experiments demonstrate that the sulfides are a significant host of light Ni isotopes in aubrites. The most extreme Ni isotope values of aubrites may be due to large Ni isotope fractionation accompanied by silicate-sulfide-metal separation during differentiation of the parent bodies, and subsequent global disruptive collision and reassembly with variably high proportions of sulfides enriched in the mantle. The howardite-eucrite-diogenite (HED) meteorites show Ni isotopic variations that are positively correlated with Ni/Co ratios, a feature that cannot be produced by igneous differentiation. Late accretion of high-Ni and high-Ni/Co chondritic materials after core formation of their likely parent body, Vesta, could have accounted for this correlation. Thus, the primitive silicate mantle of Vesta may have sub-chondritic Ni isotopic compositions, implying possible Ni isotope fractionation during core-mantle differentiation of small planetary bodies. The lunar breccia meteorites have homogenously chondritic Ni isotope values, together with their high Ni/Co of bulk rock and metals therein, suggesting impact contamination. Lunar basalt meteorites have low Ni/Co ratios and are systematically isotopically lighter than the breccias, displaying a positive correlation between Ni isotope value and Ni/Co ratio, as that seen in the HEDs. Therefore, the Ni isotopic systematics in lunar rocks also indicates the effect of late accretion, with the primitive lunar mantle having sub-chondritic Ni isotope values. This implies that the Moon-forming impactor, Theia, was likely an aubrite-like differentiated planetary body whose mantle was enriched in light Ni isotopes. We suggest that there was significant Ni isotope fractionation between core and mantle during differentiation of early formed small planetary bodies, but this signature can be obscured by late accretion in the bulk achondrite records.

A new prospect to analyse the spectral properties of v-type asteroids

Among main belt asteroids, some have a spectrum similar to Vesta so they are taxonomically classified as V-type asteroids. Probably they were removed from Vesta and migrated to their current positions via some still unknown dynamical mechanisms. Several issues on the relationship between V-type asteroids, Howardite-Eucrite-Diogenite (HED) meteorites and Vesta are still unresolved. Although some of them can be directly linked to (4) Vesta, forming its dynamical family, others do not appear to have a clear dynamical link, thus suggesting the existence of other basaltic parent bodies. In this work we present a new approach of analysis to investigate 76 VNIR V-type asteroids spectra downloaded from PDS. The composition of the regolith and particle size of V-type asteroid have been investigated with a combination of spectroscopic analysis and Hapke radiative transfer model. Retrieved particle sizes are very small, with a mean value of 20 μm.Therefore, we look for statistically significant differences among the modal mineralogy of V-type asteroids belonging to different dynamical subclasses. It seems there is a possible chronologic link between impact events on Vesta and the V-type families. The most ancient V-type family, e.g. Low-I asteroids, seems to have a eucritic composition compatible with an ejection of the outermost layer of Vesta. The Fugitive V-type were probably ejected in an older cratering event that produced the Veneneia basin while the Vestoids family, whose dynamical parameters are still more similar to Vesta and which seems to be the youngest family among them, could be associated to Rheasilvia basin. The last two families seem to have a diogenitic composition compatible with that of the south of Vesta, where the two huge craters are located.Spartacus asteroid is also analysed and it was found to have a modal mineralogy consistent with the presence of olivine as noted before (Moskovitz et al.,2010; Burbine et al., 2001).

Asteroids accretion, differentiation, and break-up in the Vesta source region: Evidence from cosmochemistry of mesosiderites

The cosmochemistry of meteorites provides unique clues on asteroids accretion, differentiation, collisional break-up and reassembly - processes of critical importance for understanding planet formation in the early solar system. Mesosiderites are a complex group of achondrites whose nearly 50:50 metal-silicate composition is interpreted in the literature as resulting from the mixing of core and crustal materials derived from differentiated asteroids. Because of their complex nature and contrasting geochemical, isotopic, and spectroscopic data, the formation mechanism of mesosiderites is still poorly understood and is open to a large variety of planetary differentiation scenarios and collisional histories. In this study, based on new petrographic and geochemical data of 16 mesosiderites, we investigate in detail the proposal that mesosiderites are related to the howardite-eucrite-diogenite (HED) meteorite group, whose parent body is widely considered to be asteroid 4 Vesta (∼500 km diameter), the target of the recent NASA’s Dawn mission. We present the first high precision oxygen isotope analyses on the matrix of a set of mesosiderite samples, coupled with new chemical and petrographic analyses of mesosiderites Um Hadid, Estherville, and Mount Padbury. Concordant Δ17O values between mesosiderites (–0.241 ± 0.015 (2σ)) and howardite-eucrite-diogenites (−0.241 ± 0.017‰ (2σ)) indicate that they derived from the same oxygen isotope reservoir, but petrological evidence, in particular the distinctly lower Fe/Mn ratios and the larger lithological diversity in mesosiderites, indicates that they formed within different parent bodies. This suggests that mesosiderites and howardite-eucrite-diogenites originated in distinct parent bodies that accreted in the 4 Vesta source region but experienced different geologic evolution in terms of crustal differentiation and impact history, which were more complex and catastrophic in the mesosiderite parent body.

Characterization of achondritic cosmic spherules from the Widerøefjellet micrometeorite collection (Sør Rondane Mountains, East Antarctica)

Achondritic micrometeorites represent one of the rarest (ca. 0.5–2.1%) particle types among Antarctic micrometeorite collections. Here, we present major, trace element and oxygen isotope compositions on five vitreous, achondritic cosmic spherules (341–526 µm in size) recovered from the Widerøefjellet sedimentary trap in the Sør Rondane Mountains (SRMs) of East Antarctica. We also present the first iron isotope data for four of these achondritic cosmic spherules. The particles were initially identified based on the atomic concentrations of Fe-Mg-Mn and their distribution in Fe/Mg versus Fe/Mn space, spanning a relatively wide range in Fe/Mg ratios (ca. 0.48–1.72). The Fe/Mn ratios cover a more restricted range (22.4–31.7), comparable to or slightly below the values measured for howardite-eucrite-diogenite (HED) and martian meteorites. One particle (WF1801-AC3) displays an elevated Fe/Mn ratio of ∼78, comparable to the values determined for lunar rocks. The negative correlation observed between the CaO + Al2O3 contents and the Fe/Si ratios of achondritic spherules reflects both the mineralogy of the precursor materials, as well as the extent of volatilization experienced during atmospheric entry heating. This trend suggests that the primary mineralogy of precursor materials may have been compositionally similar to basaltic achondrites. Based on their distribution in Ca/Si versus Al/Si space, we argue that the majority of achondritic cosmic spherules predominantly sample pyroxene- and/or plagioclase-rich (i.e., basaltic) precursor bodies. Such precursor mineralogy is also inferred from their rare earth element (REE) patterns, which show resemblances to fine-grained basaltic eucrites or Type 1 achondritic spherules (n = 3 – av. REEN = 11.2–15.5, (La/Yb)N = 0.93–1.21), pigeonite-rich equilibrated eucrite precursors or Type 2 achondritic spherules (n = 1 – av. REEN = 27.9, (La/Yb)N = 0.10), and possibly Ca-phosphates from (primitive) achondritic bodies (n = 1 – av. REEN = 58.8, (La/Yb)N = 1.59). This is clearly demonstrated for particle WF1801AC-1, which was likely inherited from a fine-grained eucritic precursor body. The pre-atmospheric oxygen isotope composition was reconstructed through compensation of mass-dependent fractionation processes as well as mixing with atmospheric oxygen, using iron isotope data. Two particles (WF1801AC-2, WF1801-AC4) display corrected oxygen isotope compositions (δ18O = 3.7–4.4‰) largely consistent with HED meteorites and may thus originate from HED-like parent bodies. The corrected oxygen isotope compositions (δ18O = 12.6–12.8‰) of the remaining particles (WF1801-AC3, WF1801-AC5) do not correspond to known meteorite fields and may represent two distinct types of unknown achondritic parent bodies or residual atmospheric entry effects. Finally, the abundance (ca. 0.5%) of achondritic cosmic spherules within the Widerøefjellet sedimentary trap is comparable to that observed in the South Pole Water Well (SPWW – ca. 0.5%), Novaya Zemlya glacier (ca. 0.45%) and Transantarctic Mountain (TAM) (ca. 2.1%) collections, confirming their overall rarity in micrometeorite collections. Unambiguous evidence for micrometeorites from the Moon or Mars remains absent from collections to date.

A young age of formation of Rheasilvia basin on Vesta from floor deformation patterns and crater counts

AbstractDelivery of significant volumes of howardite–eucrite–diogenite (HED) meteorites from Vesta to Earth is linked to the largest impact events on that protoplanet, especially the giant Rheasilvia basin. Dawn mapping of Rheasilvia reveals a well‐preserved impact structure with extensive deformation patterns and moderate superposed cratering. Spiral and radial deformation features across the floor of Rheasilvia are also common to complex craters on Ceres and icy satellites, as well as larger bodies like the Moon, Mars, and Mercury, when floor units are not buried by impact melt and debris. These deformation features predate the solidification of such melt/debris mixtures and are important structural elements in complex craters related to failure in converging floor material during late stages of crater formation. The similarity and commonality of such features and lack of preserved ancient units within Rheasilvia indicate that these patterns formed during the latter stages of the impact event and that the original basin floor and subsequent cratering record are preserved. Updated counts and interpretation of this observed superposed cratering indicate an ~0.8–0.9 Ga age of basin formation, supporting a young impact and ejection age. This young age is consistent with recent Ar‐Ar ages of feldspar grains in HED (Lindsay et al., 2015), and it may also be consistent with ancient bulk Ar‐Ar ages (&gt;~3.2 Ga) for some HEDs because resetting such ages requires prolonged heating from the residual impact heating of rocks left on Vesta during earlier impacts. The complex morphology and recent formation of Rheasilvia basin are also consistent with dynamical estimates for delivery of these meteorites to the Earth–Moon system.

Tintigny meteorite: the first Belgian achondrite

A late afternoon in February 1971, a meteorite impacted the rooftop of a house in Tintigny village in southern Belgium. Confirmed as a possible meteorite by the schoolteacher, the meteorite and its fall story did not leave the village. Finally, 46 years after the fall event, we got the opportunity to study and characterize this meteorite. In this work, we give a detailed report on its textural, mineralogical, whole-rock elemental and oxygen isotopic composition. Officially named as Tintigny, we classified it as an achondrite from howardite-eucrite-diogenite (HED) clan and more precisely a polymict eucrite. A brecciated basaltic rock believed to be originated from the surface of V-type asteroids namely the asteroid 4 Vesta. Tintigny has recorded the evidence of the impact metamorphism and metasomatism processes active on its parent body. Tintigny is one of the 39 eucrite falls known to date, and one of the 11 eucrites occurred in Europe. It is the fifth officially recognized meteorite and the first achondrite from Belgium. This report shows the importance of studying and accessing such a meteorite for further cosmochemical and planetary investigations and enriching our knowledge on the formation of HED meteorites and their parent bodi(es). In addition, it brings the attention to its importance as a scientific heritage that has to be properly understood and safeguarded for the generations of scientists, scholar, and amateurs to come.

Widely distributed exogenic materials of varying compositions and morphologies on asteroid (101955) Bennu

ABSTRACTUsing the multiband imager MapCam on board the OSIRIS-REx (Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer) spacecraft, we identified 77 instances of proposed exogenic materials distributed globally on the surface of the B-type asteroid (101955) Bennu. We identified materials as exogenic on the basis of an absorption near 1 $\mu$m that is indicative of anhydrous silicates. The exogenic materials are spatially resolved by the telescopic camera PolyCam. All such materials are brighter than their surroundings, and they are expressed in a variety of morphologies: homogeneous, breccia-like, inclusion-like, and others. Inclusion-like features are the most common. Visible spectrophotometry was obtained for 46 of the 77 locations from MapCam images. Principal component analysis indicates at least two trends: (i) mixing of Bennu's average spectrum with a strong 1-$\mu$m band absorption, possibly from pyroxene-rich material, and (ii) mixing with a weak 1-$\mu$m band absorption. The end member with a strong 1-$\mu$m feature is consistent with Howardite-Eucrite-Diogenite (HED) meteorites, whereas the one showing a weak 1-$\mu$m feature may be consistent with HEDs, ordinary chondrites, or carbonaceous chondrites. The variation in the few available near-infrared reflectance spectra strongly suggests varying compositions among the exogenic materials. Thus, Bennu might record the remnants of multiple impacts with different compositions to its parent body, which could have happened in the very early history of the Solar system. Moreover, at least one of the exogenic objects is compositionally different from the exogenic materials found on the similar asteroid (162173) Ryugu, and they suggest different impact tracks.

Evidence for the Disproportionation of Iron in a Eucrite Meteorite: Implications for Impact Processes on Vesta

AbstractPure metallic iron is a common component in extraterrestrial samples (e.g., ordinary chondrite, returned lunar samples), and is thought to be an indicator of extremely reducing conditions. However, tiny pure metallic iron (&lt;1 mm) particles are rarely found in Howardite–Eucrite–Diogenite meteorites, and their formation mechanism on Vesta is poorly understood. Sub‐micron sized pure metallic iron particles were identified by transmission electron microscope studies of a melt pocket in the basaltic eucrite meteorite Northwest Africa 11592. Our results demonstrate that the pure metallic iron likely formed through a dissociation reaction of ferrous iron (i.e., 3Fe2+ = Fe0 + 2Fe3+) in pyroxene. Another disproportionation reaction product, ferric iron, was confirmed to be incorporated into Al‐rich clinopyroxene in the melt pocket by electron energy loss spectra analyses. The temperature conditions required for the formation of the melt pocket are estimated to be above 1,310°C, as indicated by the crystallization of nano‐sized hercynite within acicular plagioclase. Such high temperatures on Vesta could only have been reached if an impact occurred during peak thermal metamorphism, early in the asteroid's evolution. This formation mechanism of these pure metallic iron particles could play a role in redox environment of the Vesta.

Mineralogical characterization of an eucrite Serra Pelada by Raman and XRD

Serra Pelada is a newly discovered eucrite from an observed fall. Eucrites belong to the meteorite group HED. The HED represent the largest clan among the achondrites, which are extraterrestrial rocks that have gone through the process of planetary differentiation. Although few specific asteroids have been identified as meteorite sources, there is an association between asteroid (4) Vesta and the Howardite, Eucrite, Diogenite (HED) clan of achondrites. The main objective of this work is to characterize the mineralogical composition of the Serra Pelada eucrite and verify if it is petrologically consistent with eucrite meteorites. Raman and X-ray diffraction were used to search for mineralogical information. The main reason for using both techniques is the rapid acquisition of data and because they are considered non-destructive techniques. The results obtained through the techniques of Raman and XRD generated information on the chemical and mineralogical compositions consistent with those of an eucrite meteorite. Furthermore, the information generated by both techniques, as well as with existing data on the asteroid (4) Vesta, contributed greatly to better understand the Serra Pelada eucrite and its relation with its parental body. Currently, there is no article published in an international journal that has characterized the Serra Pelada meteorite, providing mineralogical information on the material. The characterization of the mineralogical composition of the Serra Pelada eucrite is important to understand the process of origin, formation and evolution of differentiated planetaries bodies such as (4) Vesta, which can even generate relevant information for terrestrial planets like Earth.

A Petrologic and Noble Gas Isotopic Study of New Basaltic Eucrite Grove Mountains 13001 from Antarctica

Howardite-Eucrite-Diogenite (HED) meteorite clan is a potential group of planetary materials which provides significant clues to understand the formation and evolution of the solar system. Grove Mountains (GRV) 13001 is a new member of HED meteorite, recovered from the Grove Mountains of Antarctica by the Chinese National Antarctic Research Expedition. This research work presents a comprehensive study of the petrology and mineralogy, chemical composition, noble gas isotopes, cosmic-ray exposure (CRE) age and nominal gas retention age for the meteorite GRV 13001. The output data indicate that GRV 13001 is a monomict basaltic eucrite with typical ophitic/subophitic texture, and it consists mainly of low-Ca pyroxene and plagioclase with normal eucritic chemical compositions. The noble gas based CRE age of the GRV 13001 is approximately 29.9 ± 3.0 Ma, which deviates from the major impact events or periods on the HED parent body. Additionally, the U,Th-4He and 40K-40Ar gas retention ages of this meteorite are ~2.5 to 4.0 Ga and ~3.6 to 4.1 Ga, respectively. Based on the noble gases isotopes and the corresponding ages, GRV 13001 may have experienced intense impact processes during brecciation, and weak thermal event after the ejection event at approximately 30 Ma.

End of magmatism in the upper crust of asteroid 4 Vesta

AbstractAsteroid 4 Vesta is the only largely preserved differentiated asteroid and thus is an excellent proxy to study early magmatism occurring on planets and moons. In this study, we focus on eucrite Pecora Escarpment (PCA) 82502, a medium‐ to fine‐grained eucrite which chemical analyses suggest belongs to the main howardite–eucrite–diogenite clan, albeit with some peculiarities. We carried out backscattered electron and electron backscattered diffraction microscopy analyses of the meteorite along with step‐heating 40Ar/39Ar dating analyses of various types of groundmass aliquots. We show that Pecora Escarpment 82502 is composed of medium‐grained igneous crystalline clasts and smaller fractured satellite clasts surrounded by approximately 50 µm wide impact melt veins of the same composition. Our results show that the large crystalline clasts and fine‐grained veins both display little evidence of shock processes. Six groundmass aliquots from large crystalline clasts returned concordant plateau (&gt;70% of 39Ar) or mini‐plateau (50–70% of 39Ar) 40Ar/39Ar ages with a weighted mean of 4531 ± 6 Ma (P = 0.67). Thermodynamic cooling and 40Ar diffusion models suggest that the K/Ar system recorded and preserved the igneous age despite subsequent infiltration of hot and quickly quenched melt veins. Our new igneous age, combined with evidence for four other young volcanic and plutonic eucrites of similar age, shows that Vesta was still magmatically active around 4531 Ma. The lack of younger ages suggests that this age might well represent the end of the magmatic activity in the upper crust of Vesta. When combined with existing paleomagnetic constraints, our data suggest that 4 Vesta had an active dynamo that was still active ~35 Ma after accretion.

Exogenic basalt on asteroid (101955) Bennu

When rubble-pile asteroid 2008 TC3 impacted Earth on 7 October 2008, the recovered rock fragments indicated that such asteroids can contain exogenic material1,2. However, spacecraft missions to date have only observed exogenous contamination on large, monolithic asteroids that are impervious to collisional disruption3,4. Here, we report the presence of metre-scale exogenic boulders on the surface of near-Earth asteroid (101955) Bennu—the 0.5-km-diameter, rubble-pile target of the OSIRIS-REx mission5 that has been spectroscopically linked to the CM carbonaceous chondrite meteorites6. Hyperspectral data indicate that the exogenic boulders have the same distinctive pyroxene composition as the howardite–eucrite–diogenite (HED) meteorites that come from (4) Vesta, a 525-km-diameter asteroid that has undergone differentiation and extensive igneous processing7–9. Delivery scenarios include the infall of Vesta fragments directly onto Bennu or indirectly onto Bennu’s parent body, where the latter’s disruption created Bennu from a mixture of endogenous and exogenic debris. Our findings demonstrate that rubble-pile asteroids can preserve evidence of inter-asteroid mixing that took place at macroscopic scales well after planetesimal formation ended. Accordingly, the presence of HED-like material on the surface of Bennu provides previously unrecognized constraints on the collisional and dynamical evolution of the inner main belt. Six bright boulders of exotic material on near-Earth asteroid (101955) Bennu stand out from the average asteroidal surface. This unexpected record of impactors offers clues to the formation history of Bennu.