Howardite-eucrite-diogenite Meteorites Research Articles

A slowly cooled deep crust on asteroid 4 Vesta and the recent impact history of rubble pile vestoids recorded by diogenites

In this study, we investigate the 40Ar/39Ar systematics of nineteen diogenites thought to come from deep crustal levels of asteroid 4 Vesta. We applied both Electron Backscattered Diffraction (EBSD) and 40Ar/39Ar and methods to the unbrecciated diogenite LAP 031381. We obtained three plateau ages resulting in a combined weighted mean age of 4441 ± 15 Ma (P = 0.16). The EBSD analyses suggest that LAP 031381 displays minimal evidence of shock and, when combined with petrography observations, diffusion modelling and 40Ar/39Ar data, these results suggest that the crustal volume that initially contained this diogenite, reached a temperature of ca. 630 °C at ∼ 4.44 Ga. This corresponds to a linear cooling rate of ∼ 5 °C / Ma for a crystallization age of 4550 Ma. Independent thermal models suggest that these conditions were present at a depth of 60 to 65 km at 4.44 Ga.The other eighteen diogenites yielded 40Ar/39Ar results that indicate that they have been variously shocked by impact events and seven of them yielded plateau ages ranging from 2413 ± 189 Ma to 84 ± 162 Ma. We combined these results with 40Ar/39Ar ages from eucrites and howardites and propose that the HED (Howardite, Eucrite, Diogenite) meteorites recorded impact events at the surface of Vesta until ∼ 3.4 Ga when they were then ejected during a large collision. The eucrites, diogenites and howardites were then recombined into small rubble pile asteroids which probably make up a large part of the Vestoid family. After ejection, the K/Ar system in plagioclase crystals ceased in most cases to be fully reset by impact events as the temperature spikes reached during small impacts lack enough energy to trigger significant 40Ar* diffusion. On the other hand, ultra-transient and high-temperature – sensitive pyroxene crystals kept a more systematic record of small impacts until recent time. 38Arc cosmochron cosmogenic exposure ages on diogenites mostly range from 51 ± 7 Ma to 0 ± 1 Ma and when combined with other HED cosmochron ages, suggest that almost all the HED meteorites were continuously ejected from secondary rubble pile asteroids mostly between 50 Ma and present.

Gravitational study of escape routes and residence regions of Ceres and Vesta fragments

Aims. Ceres and Vesta are the two largest bodies in the main asteroid belt (MB) and have been extensively studied, particularly since the DAWN mission. Vesta is known to have an associated asteroid family, while the existence of a Ceres family is uncertain. This study investigates the fate of multi-kilometre fragments ejected from Ceres and Vesta due to impacts over a timescale of several hundred million years. Methods. We performed purely gravitational N-body simulations to investigate the dynamical evolution of multi-kilometre-sized fragments ejected from Ceres and Vesta. We tracked the trajectories of these fragments and identified their residence regions within the MB. We analysed the escape routes and end states of the fragments that manage to leave the MB, including the delivery to the near-Earth asteroids (NEAs). We also estimated the number of collisions with Earth that could be attributed to large fragments ejected from Ceres and Vesta. Results. Our simulations show that the Ceres fragments are dispersed over a larger region in the MB compared to Vesta fragments due to their higher ejection velocities. We identified the escape routes of the fragments that leave the MB, which for the Ceres fragments are the 5:2 and 8:3 mean-motion resonances (MMR), and for the Vesta fragments are the 3:1 MMR and ν6 secular resonance, where they can be delivered to the NEA region. We also find that the Pristine region, located between the 5:2 and 7:3 MMR, is the most likely place to find any surviving member of a Ceres family. There were no collisions of large Ceres or Vesta fragments with Earth over the age of the Solar System, suggesting that, under the model considered here, the howardite–eucrite–diogenite meteorites originate from smaller NEAs from Vesta.

Pyroxene and Hydroxyl Signatures in Vesta Newly Calibrated Data from Dawn Mission

Thanks to the VIR spectrometer onboard NASA’s Dawn spacecraft, which orbited Vesta in 2011–2012, thousands of hyperspectral images of its surface have been collected. The mission confirmed the HED (Howardite–Eucrite–Diogenite) meteorite composition of Vesta. Moreover, the VIR spectrometer detected the 2.8 µm absorption band, due to the presence of the OH molecule. In this work, we took advantage of the newly calibrated data of the VIR spectrometer by characterizing new spectral features thanks to the improved signal-to-noise (S/N) ratio for these spectra. The main goals of this work are as follows: (1) to characterize Vesta’s surface in the visible range and (2) to confirm, reinforce and characterize the OH distribution on Vesta by studying the 2.8 µm band and looking for OH combination bands around 2.2–2.4 µm. A possible relation between the 1.9 µm absorption band due to the presence of pyroxenes and the one at 0.5 µm was analyzed. Finally, the analysis of hydroxyl absorption bands evidenced an anti-correlation between the abundance of hydroxyl-bearing molecules and the surface reflectance. This confirms that the hydroxyl presence is linked to the dark units on Vesta.

Calcium isotope constraints on the origin of eucrites and diogenites: The role of magma ocean and magmatism

Howardite-Eucrite-Diogenite (HED) meteorites represent a large suit of crustal and sub-crustal rocks from the Vesta. This work presents systematic examination of the Ca isotope data on multiple varieties of HED meteorites for a better understanding of the magmatic evolution of the Vesta. Falls and finds possess similar Ca isotope compositions, and no correlation is observed between δ44/40Ca and (Sr/Eu*)n, indicating that terrestrial weathering effect on Ca isotopes is insubstantial. According to the data in literature, the inner solar system may have a homogeneous δ44/40Ca and the average of inner solar system bodies (0.97±0.03‰) can approximate the composition of bulk silicate Vesta (BSV). Basaltic eucrites define a cluster in δ44/40Ca (0.95±0.07‰, 2SD, N=15) that is higher than the terrestrial mid-ocean ridge basalts (∼0.85‰). Combined with partial melting and magma ocean differentiation modeling, the Ca isotope signatures suggest that eucrites represent the residual melts evolved from a magma ocean formed by primordial Vesta's moderate-to-high degree melting (20-100%). Diogenites have distinguishingly higher δ44/40Ca (1.18±0.15‰, 2SD, N=7) than the basaltic eucrites, which displays a negative correlation with the 1000×Lu/Ti ratio and a positive correlation with 1/Ca. However, magma ocean crystallization can only explain diogenites with δ44/40Ca higher than 1.17‰, suggesting that diogenites have complicated petrogenesis and are not necessarily cogenetic with eucrites. Diogenites with δ44/40Ca<1.17‰ may result from magma-ocean-cumulate partial melts intruding the eucritic crust. Mixing models suggest that the eucritic component in these diogenites may be less than 10%. Two howardites have lower δ44/40Ca of 0.80±0.04‰ and 0.86±0.05‰ than eucrites and diogenites. This signature may reflect the addition of carbonaceous chondritic materials due to impact brecciation.

Characterization of achondritic cosmic spherules from the Widerøefjellet micrometeorite collection (Sør Rondane Mountains, East Antarctica)

Achondritic micrometeorites represent one of the rarest (ca. 0.5–2.1%) particle types among Antarctic micrometeorite collections. Here, we present major, trace element and oxygen isotope compositions on five vitreous, achondritic cosmic spherules (341–526 µm in size) recovered from the Widerøefjellet sedimentary trap in the Sør Rondane Mountains (SRMs) of East Antarctica. We also present the first iron isotope data for four of these achondritic cosmic spherules. The particles were initially identified based on the atomic concentrations of Fe-Mg-Mn and their distribution in Fe/Mg versus Fe/Mn space, spanning a relatively wide range in Fe/Mg ratios (ca. 0.48–1.72). The Fe/Mn ratios cover a more restricted range (22.4–31.7), comparable to or slightly below the values measured for howardite-eucrite-diogenite (HED) and martian meteorites. One particle (WF1801-AC3) displays an elevated Fe/Mn ratio of ∼78, comparable to the values determined for lunar rocks. The negative correlation observed between the CaO + Al2O3 contents and the Fe/Si ratios of achondritic spherules reflects both the mineralogy of the precursor materials, as well as the extent of volatilization experienced during atmospheric entry heating. This trend suggests that the primary mineralogy of precursor materials may have been compositionally similar to basaltic achondrites. Based on their distribution in Ca/Si versus Al/Si space, we argue that the majority of achondritic cosmic spherules predominantly sample pyroxene- and/or plagioclase-rich (i.e., basaltic) precursor bodies. Such precursor mineralogy is also inferred from their rare earth element (REE) patterns, which show resemblances to fine-grained basaltic eucrites or Type 1 achondritic spherules (n = 3 – av. REEN = 11.2–15.5, (La/Yb)N = 0.93–1.21), pigeonite-rich equilibrated eucrite precursors or Type 2 achondritic spherules (n = 1 – av. REEN = 27.9, (La/Yb)N = 0.10), and possibly Ca-phosphates from (primitive) achondritic bodies (n = 1 – av. REEN = 58.8, (La/Yb)N = 1.59). This is clearly demonstrated for particle WF1801AC-1, which was likely inherited from a fine-grained eucritic precursor body. The pre-atmospheric oxygen isotope composition was reconstructed through compensation of mass-dependent fractionation processes as well as mixing with atmospheric oxygen, using iron isotope data. Two particles (WF1801AC-2, WF1801-AC4) display corrected oxygen isotope compositions (δ18O = 3.7–4.4‰) largely consistent with HED meteorites and may thus originate from HED-like parent bodies. The corrected oxygen isotope compositions (δ18O = 12.6–12.8‰) of the remaining particles (WF1801-AC3, WF1801-AC5) do not correspond to known meteorite fields and may represent two distinct types of unknown achondritic parent bodies or residual atmospheric entry effects. Finally, the abundance (ca. 0.5%) of achondritic cosmic spherules within the Widerøefjellet sedimentary trap is comparable to that observed in the South Pole Water Well (SPWW – ca. 0.5%), Novaya Zemlya glacier (ca. 0.45%) and Transantarctic Mountain (TAM) (ca. 2.1%) collections, confirming their overall rarity in micrometeorite collections. Unambiguous evidence for micrometeorites from the Moon or Mars remains absent from collections to date.

Tintigny meteorite: the first Belgian achondrite

A late afternoon in February 1971, a meteorite impacted the rooftop of a house in Tintigny village in southern Belgium. Confirmed as a possible meteorite by the schoolteacher, the meteorite and its fall story did not leave the village. Finally, 46 years after the fall event, we got the opportunity to study and characterize this meteorite. In this work, we give a detailed report on its textural, mineralogical, whole-rock elemental and oxygen isotopic composition. Officially named as Tintigny, we classified it as an achondrite from howardite-eucrite-diogenite (HED) clan and more precisely a polymict eucrite. A brecciated basaltic rock believed to be originated from the surface of V-type asteroids namely the asteroid 4 Vesta. Tintigny has recorded the evidence of the impact metamorphism and metasomatism processes active on its parent body. Tintigny is one of the 39 eucrite falls known to date, and one of the 11 eucrites occurred in Europe. It is the fifth officially recognized meteorite and the first achondrite from Belgium. This report shows the importance of studying and accessing such a meteorite for further cosmochemical and planetary investigations and enriching our knowledge on the formation of HED meteorites and their parent bodi(es). In addition, it brings the attention to its importance as a scientific heritage that has to be properly understood and safeguarded for the generations of scientists, scholar, and amateurs to come.

Evidence for the Disproportionation of Iron in a Eucrite Meteorite: Implications for Impact Processes on Vesta

AbstractPure metallic iron is a common component in extraterrestrial samples (e.g., ordinary chondrite, returned lunar samples), and is thought to be an indicator of extremely reducing conditions. However, tiny pure metallic iron (&lt;1 mm) particles are rarely found in Howardite–Eucrite–Diogenite meteorites, and their formation mechanism on Vesta is poorly understood. Sub‐micron sized pure metallic iron particles were identified by transmission electron microscope studies of a melt pocket in the basaltic eucrite meteorite Northwest Africa 11592. Our results demonstrate that the pure metallic iron likely formed through a dissociation reaction of ferrous iron (i.e., 3Fe2+ = Fe0 + 2Fe3+) in pyroxene. Another disproportionation reaction product, ferric iron, was confirmed to be incorporated into Al‐rich clinopyroxene in the melt pocket by electron energy loss spectra analyses. The temperature conditions required for the formation of the melt pocket are estimated to be above 1,310°C, as indicated by the crystallization of nano‐sized hercynite within acicular plagioclase. Such high temperatures on Vesta could only have been reached if an impact occurred during peak thermal metamorphism, early in the asteroid's evolution. This formation mechanism of these pure metallic iron particles could play a role in redox environment of the Vesta.

A Petrologic and Noble Gas Isotopic Study of New Basaltic Eucrite Grove Mountains 13001 from Antarctica

Howardite-Eucrite-Diogenite (HED) meteorite clan is a potential group of planetary materials which provides significant clues to understand the formation and evolution of the solar system. Grove Mountains (GRV) 13001 is a new member of HED meteorite, recovered from the Grove Mountains of Antarctica by the Chinese National Antarctic Research Expedition. This research work presents a comprehensive study of the petrology and mineralogy, chemical composition, noble gas isotopes, cosmic-ray exposure (CRE) age and nominal gas retention age for the meteorite GRV 13001. The output data indicate that GRV 13001 is a monomict basaltic eucrite with typical ophitic/subophitic texture, and it consists mainly of low-Ca pyroxene and plagioclase with normal eucritic chemical compositions. The noble gas based CRE age of the GRV 13001 is approximately 29.9 ± 3.0 Ma, which deviates from the major impact events or periods on the HED parent body. Additionally, the U,Th-4He and 40K-40Ar gas retention ages of this meteorite are ~2.5 to 4.0 Ga and ~3.6 to 4.1 Ga, respectively. Based on the noble gases isotopes and the corresponding ages, GRV 13001 may have experienced intense impact processes during brecciation, and weak thermal event after the ejection event at approximately 30 Ma.

Geochemistry and Sm‐Nd chronology of a Stannern‐group eucrite, Northwest Africa 7188

AbstractWe report the results of a detailed study of the basaltic eucrite Northwest Africa (NWA) 7188, including its mineralogical and bulk geochemical characteristics, oxygen isotopic composition, and147,146Sm‐143,142Nd mineral isochron ages. The texture and chemical composition of pyroxene and plagioclase demonstrate thatNWA7188 is a monomict eucrite with a metamorphic grade of type 4. The oxygen isotopic composition and the Fe/Mn ratios of pyroxene confirmed thatNWA7188 belongs to the howardite–eucrite–diogenite meteorite suite, generally considered to originate from asteroid 4 Vesta. Whole‐rock TiO2, La, and Hf concentrations and aCIchondrite‐normalized rare earth element pattern are in good agreement with those of representative Stannern‐group eucrites. The147,146Sm‐143,142Nd isochrons forNWA7188 yielded ages of 4582 ± 190 and 4554 +17/−19 Ma, respectively. The closure temperature of the Sm‐Nd system for different fractions ofNWA7188 was estimated to be &gt;865 °C, suggesting that the Sm‐Nd decay system has either been resistant to reheating at ~800 °C during the global metamorphism or only partially reset. Therefore, the146Sm‐142Nd age ofNWA7188 corresponds to the period of initial crystallization of basaltic magmas and/or global metamorphism on the parent body, and is unlikely to reflect Sm‐Nd disturbance by late reheating and impact events. In either case,NWA7188 is a rare Stannern‐group eucrite that preserves the chronological information regarding the initial crustal evolution of Vesta.

Significant depletion of volatile elements in the mantle of asteroid Vesta due to core formation

Vesta, the second-largest body in the asteroid belt, is believed to be a prime example of a rocky protoplanet. Studies of the HED (Howardite–Eucrite–Diogenite) meteorite suite, considered to be sourced from the mantle of Vesta, provide insight into protoplanet differentiation processes. Eucrites and diogenites are depleted in many volatile elements, but the depletions of many volatile siderophile elements are not well constrained. Although previous work indicated that the Vestan core equilibrated with its mantle in a global melting event, the possible contribution of core formation to the volatile budget of HED meteorites has not been assessed to date. This prohibits an assessment of the overall volatile depletion systematics of Vesta.Here, we use a compilation of published volatile siderophile element (VSE; C, S, Zn, As, Se, Cd, In, Sb, Te, Tl, Pb, Bi) abundances in diogenites and eucrites to constrain their depletions in the Vestan mantle. We assess to what extent these depletions may be volatility-related, caused by partitioning into sulfides in the mantle, and/or a result of their preferential partitioning into the Vestan core during core-mantle equilibration. Our new estimates for VSE depletions in the Vestan mantle show no correlation with condensation temperature, suggesting the depletions are difficult to reconcile with partial condensation or degassing during accretionary processes only. Sulfide saturation of the diogenite and eucrite source region is also unlikely because of low indigenous S abundances in these samples compared to calculated S contents at sulfide saturation. Consideration of the metal-silicate partitioning behaviour of the VSE shows that most of these elements are sufficiently siderophile to explain a significant part of their observed depletions in the Vestan mantle by their preferential partitioning into a S-rich core.Moderately volatile elements As and Sb both appear more abundant in the Vestan mantle than expected from their highly siderophile behaviour in systems with basaltic melts. These apparent overabundances may be related to strong silicate melt compositional effects on their metal-silicate partitioning behaviour. On the other hand, Zn, and to a lesser extent Te and Tl are significantly more depleted than expected from metal-silicate partitioning alone. This could be evidence for volatile loss of these elements from Vesta through kinetic loss in a hard vacuum. Alternatively, the perceived loss of Zn may be the result of a Zn-poor Vestan bulk composition and/or partly by preferential partitioning of Zn into spinel. The additional depletion of Tl and by extension other highly chalcophile elements such as Se and Te may be explained by segregation of sulfides in the eucritic melt source region(s), if significant amounts of S degassed from eucritic melts after sulfide segregation.Our results underline the feasibility of planetary cores being a major reservoir for many volatile elements that are depleted in planetary mantles, and that are currently assumed to have suffered incomplete condensation during accretion or (partial) degassing after accretion.

Non-Vestoid candidate asteroids in the inner main belt

Most Howardite-Eucrite-Diogenite (HED) meteorites (analogs to V-type asteroids) are thought to originate from asteroid (4) Vesta. However, some HEDs show distinct oxygen isotope ratios and therefore are thought to originate from other asteroids. In this study, we try to identify asteroids that may represent parent bodies of those mismatching HEDs. In particular, the origin of the anomalous Bunburra Rockhole meteorite was traced back to the inner main asteroid belt, showing that there might be asteroids that are not genetically linked to the asteroid (4) Vesta (the main source of V-type asteroids and HED meteorites) in the inner main belt. In this work we identify V-type asteroids outside the dynamical Vesta family whose rotational properties (retrograde vs prograde rotation) suggest the direction of Yarkovsky drift that sets them apart from typical Vestoids and Vesta fugitives. Specifically Nesvorny et al. 2008 simulated escapes paths from the Vesta family and showed that typical Vesta fugitives in the inner main asteroid belt at semi-major axis a < 2.3 AU have to have retrograde rotations and physical and thermal parameters that maximize the Yarkovsky force in order to evolve to scattered orbits within 1-2 Gyrs (age of the Vesta collisional family). Therefore large asteroids outside the Vesta family and with a < 2.3 AU and having thermal and rotational properties minimizing the Yarkovsky drift or showing Yarkovsky drift direction towards (4) Vesta are the best candidates for non-Vestoids V-type asteroids and therefore parent bodies of anomalous HED. In this study, we have performed accurate photometric observations and determined sense of rotation for several asteroids testing their links to Vesta and anomalous HED. We have found several potential non-Vestoid candidates. Those objects have to be studied in more detail to fully confirm their link to anomalous HEDs.

Igneous lithologies on asteroid (4) Vesta mapped using gamma-ray and neutron data

We use data collected by the Dawn Gamma-Ray and Neutron Detector (GRaND) at Vesta to map compositions corresponding to nearly pure igneous lithologies in the howardite, eucrite, diogenite (HED) meteorite clan (samples likely from Vesta). At the ∼300-km spatial scale of GRaND measurements, basaltic eucrite occurs on only 3% of the surface, whereas cumulate eucrite and orthopyroxenitic diogenite are not detected. The basaltic eucrite region is generally coincident with an area of the surface with thick regolith, elevated H, and moderate crater density, and may represent the best compositional sample of primordial vestan crust. We observe an absence of pure orthopyroxenitic diogenite terrains in the Rheasilvia basin and its ejecta, an observation corroborated by VIR (0.1%), which suggests the south-polar crust was a polymict mixture of igneous lithologies (howardite) at the time of the Rheasilvia impact, or was a thick basaltic eucrite crust with heterogeneously distributed orthopyroxenitic diogenite plutons. The most dominant igneous composition detected (11% of the surface) corresponds to one of the least-abundant igneous lithologies in the HED meteorite collection, the Yamato Type B diogenites (plagioclase-bearing pyroxenites). The distribution of Type B diogenite is spatially correlated with post-Rheasilvia craters in the north-polar region that are in close proximity to the Rheasilvia basin antipode. This suggests that north-polar Type B plutonism may have been associated with the Rheasilvia impact event. We propose that this was either through 1) uplift of pre-existing plutons at the antipode through focusing of Rheasilvia impact stress, or 2) Rheasilvia impact antipodal crustal melting, creating magmas that underwent fractionation to produce Type B plutons.

High-pressure minerals in eucrite suggest a small source crater on Vesta.

High-pressure minerals in meteorites are important records of shock events that have affected the surfaces of planets and asteroids. A widespread distribution of impact craters has been observed on the Vestan surface. However, very few high-pressure minerals have been discovered in Howardite-Eucrite-Diogenite (HED) meteorites. Here we present the first evidence of tissintite, vacancy-rich clinopyroxene, and super-silicic garnet in the eucrite Northwest Africa (NWA) 8003. Combined with coesite and stishovite, the presence of these high-pressure minerals and their chemical compositions reveal that solidification of melt veins in NWA 8003 began at a pressure of >~10 GPa and ceased when the pressure dropped to <~8.5 GPa. The shock temperature in the melt veins exceeded 1900 °C. Simulation results show that shock events that create impact craters of ~3 km in diameter (subject to a factor of 2 uncertainty) are associated with sufficiently high pressures to account for the occurrence of the high-pressure minerals observed in NWA 8003. This indicates that HED meteorites containing similar high-pressure minerals should be observed more frequently than previously thought.

Near-infrared spectroscopy of 3:1 Kirkwood Gap asteroids III

The research is an integrated effort beginning with telescopic observations and extending through detailed mineralogical characterizations to provide constraints on the composition and meteorite affinities of a subset of fourteen asteroids in/near the 3:1 Kirkwood Gap. Eight asteroids were identified as having either one or two absorption features, while six were deemed featureless. The compositional analysis of Asteroids (355) Gabriella and (1447) Utra reveal Fs and Fa values which are consistent with values for the L-type ordinary chondrites (Fs19–22 and Fa22–26). The location of these two bodies with respect to each other and to the previously identified L-chondrite parent body Asteroid (1722) Goffin, suggests a small L-chondrite genetic family. These results support the model that the L-chondrites come from an asteroid family rather than from a single object. Asteroids (1368) Numidia, (1587) Kahrstadt, (1854) Skvortsov, (2497) Kulikovskij, and (5676) Voltaire were analyzed and determined to have “basaltic” silicate mineralogies similar to those of the HED (howardite–eucrite–diogenite) meteorite group. In particular, we found that the compositions of (1368), (1587) and (1854) are consistent with olivine-orthopyroxenitic diogenites, while (2497) and (5676)’s compositions are consistent with harzburgitic diogenites. The Band I and Band II absorption feature depths are much shallower than seen in diogenite spectra, typically ∼70% depth (Burbine, T.H. et al. [2000]. Forging asteroid–meteorite relationships through reflectance spectroscopy. Lunar Planet. Sci. XXXI. Abstract 1844). The nature of the weak features seen in the asteroid spectra when compared to measured band depths of in situ diogenite samples indicate an additional mechanism(s) acting to weaken the features, most likely space weathering. The aforementioned five asteroids are plausible sources for the olivine-orthopyroxenitic diogenites and harzburgitic diogenites, and very well may be fragments of Vesta. Asteroid (46) Hestia is an interesting object whose surface minerals may be consistent with a CR2 chondrite; however, the unique spectrum deserves further study in the future. Featureless Asteroids (248) Lameia, (1960) Guisan, (3345) Tarkovskij and (6212) 1993 MS1 surface materials are likely organic assemblages consistent with the Type 1 or 2 carbonaceous chondrite meteorite class; however specific terrestrial meteorite analog could not be identified. The spectra of Asteroids (3228) Pire and (3999) Aristarchus are consistent with each other and have been assigned to the Eulalia by Walsh et al. (Walsh, K.J. et al. [2013]. Icarus 225, 283–297). Spectrally they are similar to (495) in terms of blue-slope and albedo (Fieber-Beyer, S.K., et al. [2012]. Icarus 221, 593–602), thus increasing our confidence the three bodies are truly related dynamically and genetically. By extrapolation and due to their location adjacent to the 3:1 Kirkwood Gap, (3228) and (3999) are plausible sources of the CV3OXB carbonaceous chondrites.

More chips off of Asteroid (4) Vesta: Characterization of eight Vestoids and their HED meteorite analogs

Vestoids are generally considered to be fragments from Asteroid (4) Vesta that were ejected by past collisions that document Vesta’s collisional history. Dynamical Vestoids are defined by their spatial proximity with Vesta (Zappala, V., Bendjoya, Ph., Cellino, A., Farinella, P., Froeschle’, C. [1995]. Icarus 116, 291–314; Nesvorny, D. [2012]. Nesvorny HCM Asteroid Families V2.0. EAR-A-VARGBDET-5-NESVORNYFAM-V2.0. NASA Planetary Data System.). Taxonomic Vestoids are defined as V-type asteroids that have a photometric, visible-wavelength spectral, or other observational relationship with Vesta (Tholen, D.J., 1984. Asteroid Taxonomy from Cluster Analysis of Photometry. Ph.D. Thesis, University of Arizona, Tucson; Bus, S.J., Binzel, R.P. [2002]. Icarus 158, 106–145; Carvano, J., Hasselmann, P.H., Lazzaro, D., Mothe’-Diniz, T. [2010]. Astron. Astrophys. 510, A43). We define ‘genetic Vestoids’ as V-type asteroids that are probable fragments ejected from (4) Vesta based on the supporting combination of dynamical, near-infrared (NIR) spectral, and taxonomic evidence. NIR reflectance spectroscopy is one of the primary ground-based techniques to constrain an asteroid’s major surface mineralogy (Burns, R.G. [1993a]. Mineralogical Applications of Crystal Field Theory. Cambridge University Press, Cambridge, UK, 551 p). Despite the reasonable likelihood that many dynamical and taxonomic Vestoids likely originate from Vesta, ambiguity exists concerning the fraction of these populations that are from Vesta as compared to the fraction of asteroids that might not be related to Vesta.Currently, one of the most robust techniques to identify the genetic Vestoid population is through NIR reflectance spectroscopy from ∼0.7 to 2.5μm. The derivation of spectral band parameters, and the comparison of those band parameters with those from representative samples from the Howardite–Eucrite–Diogenite (HED) meteorite types, allows a direct comparison of their primary mineralogies. Establishing tighter constraints on the genetic Vestoid population will better inform mass estimates for the current population of probable Vestoids, will provide more accurate orbital information of Vestoid migration through time that will assist dynamical models, and will constrain the overall current abundance of basaltic material in the main asteroid belt (Moskovitz, N.A., Jedicke, R., Gaidos, E., Willman, M., Nesvorny, D., Fevig, R. [2008]. Icarus 198, 77–90).This work reports high-quality NIR spectra, and their respective interpretations, for eight Vp-type asteroids, as defined by Carvano et al. (Carvano, J., Hasselmann, P.H., Lazzaro, D., Mothe’-Diniz, T. [2010]. Astron. Astrophys. 510, A43), that were observed at the NASA Infrared Telescope Facility on January 14, 2013 UT. They include: (3867) Shiretoko, (5235) Jean-Loup, (5560) Amytis, (6331) 1992 FZ1, (6976) Kanatsu, (17469) 1991 BT, (29796) 1999 CW77, and (30872) 1992 EM17. All eight asteroids exhibit the broad ∼0.9- and ∼1.9-μm mineral absorption features indicative of pyroxene on each asteroid’s surface. Data reduction and analysis via multiple techniques produced consistent results for the derived spectral absorption band centers and average pyroxene surface chemistries for all eight asteroids (Reddy, V., Sanchez, J.A., Nathues, A., Moskovitz, N.A., Li, J.-Y, Cloutis, E.A., Archer, K., Tucker, R.A., Gaffey, M.J., Mann, P.J., Sierks, H., Schade, U. [2012c]. Icarus 217, 153–168; Lindsay, S.S., Emery, J.P., Marchis, F., Enriquez, J., Assafin, M. [2013]. A spectroscopic and mineralogic study of multiple asteroid systems. American Astronomical Society, DPS Meeting #45, #112.04; Lindsay, S.S., Marchis, F., Emery, J.P., Enriquez, J.E., Assafin, M. [2014]. Icarus, submitted for publication; Gaffey, M.J., Cloutis, E.A., Kelley, M.K., Reed, K.L. [2002]. Mineralogy of asteroids. In: Bottke Jr., W.F., Cellino, A., Paolicchi, P., Binzel, R.P. (Eds.), Asteroids III. The University of Arizona Press, Tucson, pp. 183–204; Burbine, T.H., Buchanan, P.C., Dolkar, T., Binzel, R.P. [2009]. Met. Planet. Sci. 44, 1331–1341.). (3867) Shiretoko is most consistent with the eucrite meteorites while the remaining seven asteroids are most consistent with the howardite meteorites. The existing evidence suggests that all eight of these Vp-type asteroids are genetic Vestoids that probably originated from Vesta’s surface.

The contamination of the surface of Vesta by impacts and the delivery of the dark material

The Dawn spacecraft recently observed the presence of dark material, which in turn proved to be associated with the presence of OH and H-rich material, on the surface of Vesta. The source of this dark material has been almost unanimously identified with the low albedo asteroids, likely analogous to the carbonaceous chondrites found on Earth, that impacted on Vesta over its lifetime. However, it is still a matter of debate whether the delivery of the dark material is associated with a few large impact events, to micrometeorites or to the continuous, secular flux of impactors on Vesta. The “continuous flux” scenario, in particular, predicts that a significant fraction of the exogenous material accreted by Vesta should be due to non-dark impactors likely analogous to ordinary chondrites, which instead represent only a minor contaminant in the Howardite–Eucrite–Diogenite meteorites. In this work, we explored the “continuous flux” scenario and its implications for the composition of the vestan regolith, taking advantage of the data from the Dawn mission and the Howardite–Eucrite–Diogenite meteorites to constrain the contamination history of Vesta. We developed a model for the delivery of the exogenous material to Vesta and verified how the results it supplies are sensitive to the different parameters we consider. We calibrated the flux of impactors predicted by our model with the number of dark craters observed inside the Rheasilvia basin and we tested the assumptions on the impact conditions by studying the formation of Cornelia crater and of its dark deposits with a hydrocode simulation. We used our calibrated model to show that the “stochastic events” scenario and the “micrometeoritic flux” scenario are just natural consequences of the “continuous flux” scenario. We then used the model to estimate the amounts of dark and hydroxylate materials that were delivered on Vesta since the Late Heavy Bombardment and we showed how our results match well with the values estimated by the Dawn mission. We finally used our model to assess the amount of Fe and siderophile elements that the continuous flux of impactors would mix in the vestan regolith: concerning the siderophile elements, we focused our attention on the role of Ni. The results we obtained are in agreement with the data available on the Fe and Ni content of the Howardite–Eucrite–Diogenite meteorites and can be used as a reference frame in future studies of the data from the Dawn mission and of the Howardite–Eucrite–Diogenite meteorites. Our model cannot yet provide an answer to the conundrum of the fate of the missing non-carbonaceous contaminants, but we discuss some possible reasons for this discrepancy with the otherwise coherent picture described by our results.

Gravity field expansion in ellipsoidal harmonic and polyhedral internal representations applied to Vesta

A 20th degree ellipsoidal harmonic gravity field of Vesta is determined by processing radiometric Doppler and range data from the Dawn mission. The gravity field shows sensitivity up to degree 18 and the coefficients are globally determined on average to degree 15. Gravity anomalies are mapped to the Brillouin ellipsoid (304×289×247-km), which is a substantially closer fit to the surface than the reference ellipsoid (290×290×265-km) used to map the conventional spherical harmonic series, especially near the poles. Two models of internal structure are subsequently explored, in which density variations are permitted in the uppermost layer (i.e., crust) in order to explain Vesta’s local gravitational signature. These models include the case of a two-layer model with an average crustal thickness of 55.5km and a three-layer model with an average crustal thickness of 22.4km. For both two-layer and three-layer scenarios, the Bouguer gravity anomaly is minimized for a crustal density of 2970kg/m3. The remaining Bouguer anomalies can be explained by lateral crustal density variation of 2310–3440kg/m3 and 2660–3240kg/m3 for the 22.4km and 55.5km crustal thickness models, respectively. The general trend of the estimated lateral crustal densities for the two cases is very similar, with a wider range for the 22.4km case due to a thinner crust. This indicates that a thick crust (e.g., 55.5km) would be more favorable for minimizing the range of lateral crustal density variations. Consideration of independent geochemical and petrological constraints suggests that a three-layer model is a more appropriate representation of Vesta’s internal structure, despite the fact that two-layer models provide a satisfactory fit to gravity data alone. In detail, it is found that densities derived from gravity data assuming three-layer models and those derived from the howardite–eucrite–diogenite meteorites and estimates of plausible bulk-Vesta composition show an excellent level of mutual consistency.

Spectroscopy and surface properties of (809) Lundia

Telescopic observation of binary system of (809) Lundia in the in the 0.8–2.5µm spectral range is presented in order to determine its physical and mineralogical parameters. Observations covering several oppositions were performed using NASA telescope Infrared Telescope Facility and SpeX spectrograph. One of these spectra was observed during a mutual event (an occultation between components). A detailed analysis of spectra was performed using M4AST tools. (809) Lundia complex is a V-type object having similar mineralogy on both components of the system. By applying different mineralogical models a composition similar to the one of howardite–diogenite meteorites was found. The comparison of composite visible and near-infrared spectra with meteorites from Relab data base confirms this solution. From this comparison a surface covered by fine dusty regolith with grain size less than 100µm was found. Orthopyroxene is the most abundant pyroxene of the regolith. Howarditic and diogenitic minerals seem to be the most abundant on the surface of (809) Lundia. The discrepancy between howardite–eucrite–diogenite meteorite bulk density and the one computed for the binary system suggests a rubble pile structure of both components.

Lithium systematics in howardite–eucrite–diogenite meteorites: Implications for crust–mantle evolution of planetary embryos

We present lithium (Li) abundances and isotope compositions in a suite of howardites, eucrites and diogenites (HEDs). These meteorites most likely originated from asteroid Vesta and were delivered to Earth by a series of independent impact events. The Li concentrations show striking differences between Li-poor diogenites plus cumulate eucrites and Li-enriched eucrites whilst howardites have Li abundances intermediate between eucrites and diogenites. Contrary to Li elemental inter-group differences, Li isotope compositions are irresolvable among these individual groups of HED meteorites despite their wildly distinct petrography, attesting to insignificant Li isotope fractionation during formation of a thick basaltic crust by melting of the Vestan mantle. The mean Li isotope composition of Bulk Silicate Vesta is estimated at 3.7±0.6‰ (1σ), intermediate to that of the Earth versus Mars and Moon but identical with these terrestrial bodies within uncertainty. This further validates largely homogeneous inner Solar System solids from the Li isotope perspective and supports the lack of loss of moderately volatile elements from planetary embryos during their magmatic histories because Li does not follow depletion trends inferred from more volatile elements. Pasamonte eucrite has the same Li isotope composition as other eucrites although it may not be directly linked to Vesta. These observations are also important for generating Li elemental and isotope signatures in juvenile basaltic crusts of large terrestrial planets and numerous planetary embryos in the early Solar System. A combination of CV+L chondrites may be less suitable for building Vesta from Li perspective but this may face sampling bias of available data and only further analyses may resolve this issue. Alternatively, significant shift of ∼1‰ towards heavier Li isotope compositions must have occurred during thermal processing of CV+L (2.2–2.8‰) mixture in order to account for the observed Li isotope systematics in HED meteorites. No correlation is observed between Li versus Zn, Fe or Si isotopes, respectively, implying unrelated processes of forming stable isotope variations observed in HED meteorites.

Vesta, vestoids, and the HED meteorites: Interconnections and differences based on Dawn Framing Camera observations

The Framing Camera (FC) on the Dawn spacecraft provided the first view of 4 Vesta at sufficiently high spatial resolution to enable a detailed correlation of the asteroid's spectral properties with geologic features and with the vestoid (V‐type) asteroids and the Howardite‐Eucrite‐Diogenite (HED) class of meteorites, both of which are believed to originate on Vesta. We combine a spectral analysis of the basin with visible and near‐IR spectroscopy of vestoids and with archived data over the same spectral range for HED meteorites. The vestoids are only slightly more akin to the Rheasilvia basin than to Vesta as a whole, suggesting that the crustal material ejected is a well‐mixed collection of eucritic and diogenitic materials. The basin itself is more diogenitic, implying Vesta is differentiated and the impact that created Rheasilvia uncovered a mineralogically distinct layer. The Rheasilvia basin exhibits a larger range in pyroxene band strengths than Vesta as a whole, further implying that the basin offers a view into a complex, differentiated protoplanet. The discrepancy between the spectral properties of the HED meteorites and Vesta, in particular the meteorites' deeper pyroxene absorption band and the redder color of the vestoids, can be explained by the abundance of smaller particles on Vesta and by the addition of low‐albedo exogenous particles to its surface, which in turn are due to its larger gravity and longer exposure time to impact processing. Solar phase effects are slight and do not explain the spectral discrepancies between the HEDs, Vesta, and the vestoids.