Hot Electron Population Research Articles

Ultrafast Surface Plasmon Probing of Interband and Intraband Hot Electron Excitations.

Upon the interaction of light with metals, nonthermal electrons are generated with intriguing transient behavior. Here, we present femtosecond hot electron probing in a noveloptical pump/plasmon probe scheme. With this, we probed ultrafast interband and intraband dynamics with 15 nm interface selectivity, observing a two-component-decay of hot electron populations. Results are in good agreement with a three-temperature model of the metal; thus, we could attribute the fast (∼100 fs) decay to the thermalization of hot electrons and the slow (picosecond) decay to electron-lattice thermalization. Moreover, we could modulate the transmission of our plasmonic channel with ∼40% depth, hinting at the possibility of ultrafast information processing applications with plasmonic signals.

Femtosecond pulse train-facilitated periodic nanostructuring on TiN films via laser-oxidation

Laser-induced periodic surface structure is a universal phenomenon observed when solid materials are irradiated with pulsed lasers. Typically, these structures are generated using Gaussian pulses. Here, we investigate the formation of periodic nanostructures on titanium nitride thin films using two different laser sources: Gaussian pulses and femtosecond pulse trains generated through a Fabry-Perot cavity. Our findings indicate that the formation of self-organized nanostructures on the thin films can occur through either laser-induced oxidation or laser ablation processes, depending on laser fluence, scanning speed, and pulse duration. Interestingly, when utilizing femtosecond pulse trains, we observe that the range of laser fluence thresholds for oxidative nanostructure formation is significantly wider compared to Gaussian pulses. To comprehend the underlying mechanisms driving these observations, we employ a two-temperature model to calculate the ultrafast dynamics of hot electrons when exposed to laser irradiation. Our results reveal that the initial sub-pulse generates a substantial population of hot electrons, exciting surface plasmons and resulting in the creation of a periodic energy distribution. Before these hot electrons can dissipate, subsequent sub-pulses reach the thin film, re-exciting a large number of hot electrons. Consequently, the periodic energy distribution persists for an extended duration, creating more favorable conditions for the formation of periodic oxidative nanostructures when using pulse trains. These findings contribute to a comprehensive understanding of the mechanisms involved in the formation of periodic nanostructures under femtosecond laser irradiation.

Disentangling Photoelectrons and Penetrating Solar Wind Electrons in the Dayside Martian Upper Atmosphere

AbstractIn situ produced photoelectrons and precipitating solar wind electrons are two distinct hot electron populations in the dayside Martian upper atmosphere. While each population has been known for decades, its relative contribution to the measured hot electron flux has not been adequately characterized up to now. In this study, we implement a two‐stream kinetic model to compute the hot electron flux for a open magnetic field configuration. By comparing model results to realistic data acquired by the Mars Atmosphere and Volatile Evolution mission, we show that the electron fluxes predicted by the pure photoelectron model are enormously underestimated, especially in the direction toward Mars, but the measurements can be adequately reproduced once solar wind electron precipitation is taken into account. Such a precipitation plays a crucial role above 180 km, not only for hot electrons at all energies that move toward Mars but also for electrons above 1,000 eV that move away from Mars due to the backscattering of precipitating electrons. In contrast, the hot electron population is predicted to be mostly composed of photoelectrons below 180 km. The significance of precipitating solar wind electrons is also evaluated, revealing an appreciable impact on the structure of the dayside Martian upper atmosphere at high altitudes, where electron impact ionization is enhanced by a factor of 7 and cold electron heating enhanced by a factor of 4.

Characterization of hot electrons generated by laser–plasma interaction at shock ignition intensities

In an experiment carried out at the Prague Asterix Laser System at laser intensities relevant to shock ignition conditions (I > 1016 W/cm2), the heating and transport of hot electrons were studied by using several complementary diagnostics, i.e., Kα time-resolved imaging, hard x-ray filtering (a bremsstrahlung cannon), and electron spectroscopy. Ablators with differing composition from low Z (parylene N) to high Z (nickel) were used in multilayer planar targets to produce plasmas with different coronal temperature and collisionality and modify the conditions of hot-electron generation. The variety of available diagnostics allowed full characterization of the population of hot electrons, retrieving their conversion efficiency, time generation and duration, temperature, and angular divergence. The obtained results are shown to be consistent with those from detailed simulations and similar inertial confinement fusion experiments. Based on the measured data, the advantages, reliability, and complementarity of the experimental diagnostics are discussed.

Optimizing Hot Electron Harvesting at Planar Metal-Semiconductor Interfaces with Titanium Oxynitride Thin Films.

Understanding metal-semiconductor interfaces is critical to the advancement of photocatalysis and sub-bandgap solar energy harvesting where electrons in the metal can be excited by sub-bandgap photons and extracted into the semiconductor. In this work, we compare the electron extraction efficiency across Au/TiO2 and titanium oxynitride (TiON)/TiO2-x interfaces, where in the latter case the spontaneously forming oxide layer (TiO2-x) creates a metal-semiconductor contact. Time-resolved pump-probe spectroscopy is used to study the electron recombination rates in both cases. Unlike the nanosecond recombination lifetimes in Au/TiO2, we find a bottleneck in the electron relaxation in the TiON system, which we explain using a trap-mediated recombination model. Using this model, we investigate the tunability of the relaxation dynamics with oxygen content in the parent film. The optimized film (TiO0.5N0.5) exhibits the highest carrier extraction efficiency (NFC ≈ 2.8 × 1019 m-3), slowest trapping, and an appreciable hot electron population reaching the surface oxide (NHE ≈ 1.6 × 1018 m-3). Our results demonstrate the productive role oxygen can play in enhancing electron harvesting and prolonging electron lifetimes, providing an optimized metal-semiconductor interface using only the native oxide of titanium oxynitride.

Efficient Generation of Axial Magnetic Field by Multiple Laser Beams with Twisted Pointing Directions.

Strong laser-driven magnetic fields are crucial for high-energy-density physics and laboratory astrophysics research, but generation of axial multikilotesla fields remains a challenge. The difficulty comes from the inability of a conventional linearly polarized laser beam to induce the required azimuthal current or, equivalently, angular momentum (AM). We show that several laser beams can overcome this difficulty. Our three-dimensional kinetic simulations demonstrate that a twist in their pointing directions enables them to carry orbital AM and transfer it to the plasma, thus generating a hot electron population carrying AM needed to sustain the magnetic field. The resulting multikilotesla field occupies a volume that is tens of thousands of cubic microns and it persists on a picosecond timescale. The mechanism can be realized for a wide range of laser intensities and pulse durations. Our scheme is well suited for implementation using multikilojoule petawatt-class lasers, because, by design, they have multiple beamlets and because the scheme requires only linear polarization.

Langmuir probe measurements of the secondary electron population across the cathodic pre-sheath of a DC argon discharge

Cylindrical Langmuir probe measurements in a low-pressure DC argon discharge are used to obtain the spatial evolution of ion, cold and hot electron parameters across the cathodic pre-sheath. The cathodic pre-sheath is formed by a stainless steel plate allowed to float negatively with respect to the plasma. The velocity distribution function of the hot electron population in the pre-sheath is shown to be matched by a drifting Maxwellian that thermalizes across it. The source of the hot electron population is hypothesized to arise from secondary electron emission from the plate. A Bayesian estimation routine is proposed to compare and validate different Langmuir probe models as well as calculating the relative uncertainty between models. The results are analyzed using existing pre-sheath theory for which experimental evidence of the spatial influence of energetic electrons is lacking. The data are shown to follow Riemann's pre-sheath model that the ion-neutral mean free path λ i is proportional to the pre-sheath characteristic length l, and that the potential drop ϕ ( x ) with distance x from the sheath/pre-sheath boundary x0 follows ϕ ( x ) ∝ ( x 0 − x ) / l.

Nonlinear models for coupling the effects of stimulated Raman scattering to inertial confinement fusion codes

Laser plasma instabilities (LPI) reduce driver-target coupling, alter implosion symmetry, and therefore can fundamentally limit fusion performance in inertial confinement fusion (ICF). Developing a predictive modeling capability for LPI effects can critically advance the success of the field. We perform vector particle-in-cell simulations of multi-speckled laser beams undergoing stimulated Raman scattering (SRS) at various densities and intensities relevant to mainly indirectly driven and a subset of parameter space for directly driven ICF systems, focusing on the regimes with intensities above the onset of electron trapping. Based on the wavenumber of the SRS daughter electron plasma wave, we identify several regions with underpinning SRS saturation physics: the electron-trapping dominated region with intermediate kλD values, the strong Landau damping region at larger kλD values, and the region where the Langmuir decay instability arises at lower kλD values. We develop a nonlinear SRS reflectivity model that features the base trapping-dominated scaling of (kλD)−4 and its modifications. Electron trapping deforms the initialized electron distribution functions, and we have developed a new δf-Gaussian-mixture algorithm for an accurate characterization of the trapped hot electron population. With this SRS hot electron description, we construct a nonlinear energy deposition model and a hot electron source model—based on a modified Manley–Rowe relation—suitable for including SRS effects as a sub-grid module in a high-fidelity ICF design code.

Ultrasensitive probing of plasmonic hot electron occupancies

Non-thermal and thermal carrier populations in plasmonic systems raised significant interest in contemporary fundamental and applied physics. Although the theoretical description predicts not only the energies but also the location of the generated carriers, the experimental justification of these theories is still lacking. Here, we demonstrate experimentally that upon the optical excitation of surface plasmon polaritons, a non-thermal electron population appears in the topmost domain of the plasmonic film directly coupled to the local fields. The applied all-optical method is based on spectroscopic ellipsometric determination of the dielectric function, allowing us to obtain in-depth information on surface plasmon induced changes of the directly related electron occupancies. The ultrahigh sensitivity of our method allows us to capture the signatures of changes induced by electron-electron scattering processes with ultrafast decay times. These experiments shed light on the build-up of plasmonic hot electron population in nanoscale media.

Kinetic modeling and experiments of a pulsed-bias plasma in a multipole plasma chamber

A pulse of electron timescale applied to a planar electrode immersed in a homogeneous plasma in a multipole plasma chamber (MPC) is modeled using a fully kinetic particle-in-cell (PIC) approach. In the time-explicit PIC simulations, we observed that the ion-sheath expansion is accompanied by electron timescale harmonic plasma oscillations at the sheath edge that decay after applying the pulse. First, we validate our PIC approach by comparing it with previous analytical and semi-empirical sheath expansion studies. Then, we compare our PIC results with experiments conducted in the MPC where similar electron frequency oscillations were excited when an electron timescale pulse was applied to a flat-conductor plate. In both PIC simulations and experiments, we find that the shape of the applied pulse dictates the amplitude of the sheath edge oscillations. In the PIC simulations, we observe that Landau damping has no discernible effect on these oscillations. However, in the experiments, the presence of a hot electron population results in a higher damping of electron oscillations. In both PIC simulations and experiments, the amplitude of the electron frequency oscillations decreases with the applied pulse width and these oscillations disappear for a linear pulse of a longer timescale of tpulse=1 μs (ωpetpulse=178), in the PIC simulations.

Electron Energization Signatures in Traveling Kinetic Alfvén Waves at Storm Time Injection Fronts

AbstractThe properties of traveling kinetic Alfvén waves (KAWs) and their role in energizing electrons in the inner magnetosphere during a geomagnetic storm are examined using measurements from the Van Allen Probes and Gyrofluid‐Kinetic Electron (GKE) model simulations. Traveling KAWs occur in the vicinity of energetic plasma injection fronts in association with magnetic field dipolarizations. The KAWs coincide with energized field‐aligned electrons at energies ≲1 keV. By using observational constraints and incorporating hot and cold electron populations, the GKE simulations are able to reproduce the observed energized electron distribution signatures. The modeling results demonstrate the crucial importance of cold electrons for best observational agreement. The results show that the electron response to KAWs can be substantially different for opposing current regions and are a sensitive function of the cold electron relative density.

Role of hot electrons in shock ignition constrained by experiment at the National Ignition Facility

Shock ignition is a scheme for direct drive inertial confinement fusion that offers the potential for high gain with the current generation of laser facility; however, the benefits are thought to be dependent on the use of low adiabat implosions without laser–plasma instabilities reducing drive and generating hot electrons. A National Ignition Facility direct drive solid target experiment was used to calibrate a 3D Monte Carlo hot-electron model for 2D radiation-hydrodynamic simulations of a shock ignition implosion. The α=2.5 adiabat implosion was calculated to suffer a 35% peak areal density decrease when the hot electron population with temperature Th=55 keV and energy Eh=13 kJ was added to the simulation. Optimizing the pulse shape can recover ∼1/3 of the peak areal density lost due to a change in shock timing. Despite the harmful impact of laser–plasma instabilities, the simulations indicate shock ignition as a viable method to improve performance and broaden the design space of near ignition high adiabat implosions.

Large-amplitude electrostatic fluctuations at the Earth’s magnetopause with a vortex-like distribution of hot electrons

Large-amplitude electrostatic solitary waves (ESWs) associated with asymmetric magnetic reconnection at the Earth’s magnetopause are studied in a four-component plasma composed of a mixture of the magnetosheath and magnetosphere plasma of a cold, warm and hot electron populations, and background ions. The species are modeled as adiabatic fluids except for the hot electrons which have a kinetic vortex-like velocity distribution. The hybrid model uses the Sagdeev pseudopotential technique to study the arbitrary amplitude ion- and electron-acoustic solitons and double layers. The numerical computations reveal that for the parameters corresponding to magnetosphere side of the ion diffusion region, only slow electron-acoustic solitons and double layer can exist. On the magnetosheath side of the ion diffusion region, only the electron-acoustic/beam solitons can exist. The electric field amplitude of the electrostatic solitary waves (ESWs) predicted by our model are consistent with the Magnetospheric Multiscale (MMS) observations.

X-ray diagnostics of ECR ion sources-Techniques, results, and challenges.

The high magnetic confinement provided by the minimum-B structure of electron cyclotron resonance ion sources (ECRIS) hosts a non-equilibrium plasma, composed of cold multi-charged ions and hot electrons whose energy can expand up to ≈1MeV. With a very limited accessibility, the ECR plasma is difficult to study. The x-ray photons generated by the interaction of the warm and hot electron populations within the plasma, as well as the photons generated by electrons lost to the chamber wall, are a signal of great interest as it gives an insight to the properties of the ECR plasma. After an introduction presenting the mechanism generating the x rays in ECRIS, this Review presents the methodology to measure x rays both for volumetric measurements and plasma imaging. The main insights of those measurements are presented. Prospects of x-ray measurements to better understand the plasma dynamics are finally highlighted.

Characterization of a new variable magnetic field linear plasma device

A radio frequency plasma device is presented in which the regions of plasma creation and maximum plasma magnetization can be separated along a 1.5-m tube. Measurements of the plasma density, plasma potential, and electron temperature in the device successfully reproduce previously reported plasma features. These validate the ability of the experiment to continue the investigation of a regime of operation in which the axial plasma density follows the profile of the applied magnetic field, as long as the ions are magnetized under the antenna. The density is shown to increase on axis owing to the decreasing cross section of the converging magnetic funnel connecting the antenna region to the solenoids. When the funnel pinching is increased, stronger magnetic fields are required to inhibit cross-field diffusion and to bring the density on axis in the expected 1012 cm−3 range. Collisionless transport of hot electron populations is observed along the field lines which intersect the area under the antenna and coincides with the presence of high-density conics more than 0.5 m away from the antenna for magnetic fields ≥600 G.

Hot electron retention in laser plasma created under terawatt subnanosecond irradiation of Cu targets

Laser plasma created by intense light interaction with matter plays an important role in high-energy density fundamental studies and many prospective applications. Terawatt laser-produced plasma related to the low collisional and relativistic domain may form supersonic flows and is prone to the generation of strong spontaneous magnetic fields. The comprehensive experimental study presented in this work provides a reference point for the theoretical description of laser-plasma interaction, focusing on the hot electron generation. It experimentally quantifies the phenomenon of hot electron retention, which serves as a boundary condition for most plasma expansion models. Hot electrons, being responsible for nonlocal thermal and electric conductivities, are important for a large variety of processes in such plasmas. The multiple-frame complex-interferometric data providing information on time resolved spontaneous magnetic fields and electron density distribution, complemented by particle spectra and x-ray measurements, were obtained under irradiation of the planar massive Cu and plastic-coated targets by the iodine laser pulse with an intensity of above 1016 W cm−2. The data shows that the hot electron emission from the interaction region outside the target is strongly suppressed, while the electron flow inside the target, i.e. in the direction of the incident laser beam, is a dominant process and contains almost the whole hot electron population. The obtained quantitative characterization of this phenomenon is of primary importance for plasma applications spanning from ICF to laser-driven discharge magnetic field generators.

Effects of magnetic configuration on hot electrons in a minimum-B ECR plasma

To investigate the hot electron population and the appearance of kinetic instabilities in highly charged electron cyclotron resonance ion source (ECRIS), the axially emitted bremsstrahlung spectra and microwave bursts emitted from ECRIS plasma were synchronously measured on SECRAL-II (Superconducting ECR ion source with Advanced design in Lanzhou No. II) ion source with various magnetic field configurations. The experimental results show that when the ratio of the minimum field to the resonance field (i.e. Bmin/Becr) is less than ∼0.8, the bremsstrahlung spectral temperature Ts increases linearly with the Bmin/Becr–ratio when the injection, extraction and radial mirror fields are kept constant. Above this threshold Ts saturates and the electron cyclotron instability appears simultaneously. This study has also demonstrated that Ts decreases linearly with the increase of the average gradient over the ECR surface when the on-axis gradient and hexapole field strengths are constant. In addition, it is found that Ts decreases with the increase of the gradient at the resonance zone (∇Becr on axis and <∇Becr>) at relatively low mirror ratio and is insensitive to the gradient at high mirror ratio when Bmin is constant. Compared to a recent study taken on a fully superconducting ECRIS (Benitez et al 2017 IEEE Trans. Plasma Sci. 45 1746–54), in which it was concluded that Ts is only sensitive with Bmin, this article shows different results discussing the mechanisms behind the correlation of magnetic field parameters to Ts.

Tunable Onset of Hydrogen Evolution in Graphene with Hot Electrons.

Here, we show that the turn-on voltage for the hydrogen evolution reaction on a graphene surface can be tuned in a semiconductor-insulator-graphene (SIG) device immersed in a solution. Specifically, it is shown that the hydrogen evolution reaction (HER) onset for the graphene can shift by >0.8 V by application of a voltage across a graphene-Al2O3-silicon junction. We show that this shift occurs due to the creation of a hot electron population in graphene due to tunneling from the Si to graphene. Through control experiments, we show that the presence of the graphene is necessary for this behavior. By analyzing the silicon, graphene, and solution current components individually, we find an increase in the silicon current despite a fixed graphene-silicon voltage, corresponding to an increase in the HER current. This additional silicon current appears to directly drive the electrochemical reaction, without modifying the graphene current. We term this current "direct injection current" and hypothesize that this current occurs due to electrons injected from the silicon into graphene that drives the HER before any electron-electron scattering occurs in the graphene. To further determine whether hot electrons injected at different energies could explain the observed total solution current, the nonequilibrium electron dynamics was studied using a 2D ensemble Monte Carlo Boltzmann transport equation (MCBTE) solver. By rigorously considering the key scattering mechanisms, we show that the injected hot electrons can significantly increase the available electron flux at high energies. These results show that semiconductor-insulator-graphene devices are a platform which can tune the electrochemical reaction rate via multiple mechanisms.

Dual plasmonic nanostructures for switching polarity of hot electron-induced photocurrent.

We report on the experimental investigation of polarity-switchable hot electron-induced photocurrents in dual-plasmonic nanostructures, consisting of two layers of gold nanoparticles (AuNPs) separated by a TiO2 film. Hot electrons generated through the non-radiative decay of the localized surface plasmon resonances supported by the top and bottom layers of AuNPs can be simultaneously injected into the TiO2 film in opposite directions and counteract each other. As a result, the polarity and magnitude of the net photocurrents can be tailored by controlling the population of hot electrons either generated from or collected by the two layers of AuNPs. We believe the wavelength-dependent photocurrent polarity switching could be useful for biosensors with a direct electrical readout and photoconversion applications.

Obliquely propagating electron-acoustic solitary waves in magnetized plasmas: the role of trapped superthermal electrons

The properties of obliquely propagating electron-acoustic solitary waves (OPEASWs) have been investigated in a magnetized superthermal plasma (containing inertial cold electron species, inertialess electrons following Vasyliunas-Schamel distribution function, and static ions) via the fluid dynamical approach. The reductive perturbation technique is employed to derive the Schamel equation and the solitary wave solution of the Schamel equation is used to examine the basic features of small but finite amplitude OPEASWs in such a magnetized plasma in the presence of trapped k-superthermal hot electron population. The basic features (width, amplitude, speed, etc.) of OPEASWs are found to be significantly modified by the different plasma configuration parameters, such as plasma superthermality, obliqueness, the particle trapping effect, and external magnetic field effect. The nature of electrostatic disturbances, that may propagate in different realistic space and laboratory plasma systems (e.g., in Saturn ring), is briefly discussed.