Hot Core Research Articles

Evolution of Chemistry in the envelope of HOt CorinoS (ECHOS). II. The puzzling chemistry of isomers as revealed by the HNCS/HSCN ratio

The observational detection of some metastable isomers in the interstellar medium with abundances comparable to those of the most stable isomer, or even when the stable isomer is not detected, highlights the importance of non-equilibrium chemistry. This challenges our understanding of the interstellar chemistry and shows the need to study isomeric forms of molecular species to constrain chemical processes occurring in the interstellar medium. Our goal is to study the chemistry of isomers through the sulphur isomer pair HNCS and HSCN, since HSCN has been observed in regions where its stable isomer has not been detected, and the observed HNCS/HSCN ratio seems to significantly vary from cold to warm regions. We used the Nautilus time-dependent gas-grain chemical code to model the formation and destruction paths of HNCS and HSCN in different astrochemical scenarios, as well as the time evolution of the HNCS/HSCN ratio. We also analysed the influence of the environmental conditions on their chemical abundances. We present an observational detection of the metastable isomer HSCN in the Class I object B1-a ($N$=(1.1pm 0.6)times 1012 cm$^ $), but not of the stable isomer HNCS, despite HNCS lying 3200 K lower in energy than HSCN. Our theoretical results show an HNCS/HSCN ratio sensitive to the gas temperature and the evolutionary time, with the highest values obtained at early stages ($t$lesssim 10$^4$ yr) and low ($T_ g $lesssim 20 K) temperatures. A more detailed analysis also shows that the main mechanism forming HNCS in young ($t$$<$10$^5$ yr) and cold ($T_ g $$=$10 K) objects at moderate-low densities ($n$$_ H $leq 10$^5$ cm$^ $) is a grain surface reaction (the chemical desorption reaction N$_ solid $+HCS$_ solid $rightarrow HNCS), unlike previous predictions that suggest only gas-phase chemistry for its formation. However, for the formation of its metastable isomer HSCN, over the same time range and physical conditions, we find that both surface and gas-phase reactions (through the ion H$_2$NCS$^+$) play important roles. In warmer ($T_ g $geq 50 K) regions, the formation of this isomer pair is only dominated by gas-phase chemistry through the ions H$_2$NCS$^+$ (mainly at low densities) and HNCSH$^+$ (mainly at high densities). The results suggest a different efficiency of the isomerisation processes depending on the source temperature. The progressive decrease of HNCS/HSCN with gas temperature at early evolutionary times derived from our theoretical results indicates that this ratio may be used as a tracer of cold young objects. This work also demonstrates the key role of grain surface chemistry in the formation of the isomer pair HNCS and HSCN in cold regions, as well as the importance of the ions H$_2$NCS$^+$ and HNCSH$^+$ in warm/hot regions. Since most of the interstellar regions where HSCN is detected are cold regions (starless cores, Class 0/I objects), a larger sample including sources characterised by high temperatures (e.g. hot cores) are needed to corroborate the theoretical results.

Observational studies of S-bearing molecules in massive star-forming regions

S-bearing molecules are powerful tools for determining the physical conditions inside a massive star-forming region. The abundances of S-bearing molecules, including H$_ $S, H$_ $CS, and HCS$^ $, are highly dependent on physical and chemical changes, which means that they are good tracers of the evolutionary stage of massive star formation. We present observational results of H$_ $S 1$_ $, H$_ $34S 1$_ $, H$_ $CS 5$_ $, HCS$^ $ 4-3, SiO 4-3, HC$_ $N 19-18, and C18O 1-0 toward a sample of 51 late-stage massive star-forming regions, and study the relationships between H$_ $S, H$_ $CS, HCS$^ $, and SiO in hot cores. We discuss the chemical connections of these S-bearing molecules based on the relations between the relative abundances in our sources. H$_ $34S 1$_ $, as the isotopic line of H$_ $S 1$_ $, was used to correct the optical depths of H$_ $S 1$_ $. Beam-averaged column densities of all molecules were calculated, as were the abundances of H$_ $S, H$_ $CS, and HCS$^ $ relative to H$_ $, which were derived from C18O. Results from a chemical model that included gas, dust grain surface, and icy mantle phases, were compared with the observed abundances of H$_2$S, H$_2$CS, and HCS$^+$ molecules. H$_ $S 1$_ $, H$_ $34S 1$_ $, H$_ $CS 5$_ $, HCS$^ $ 4-3, and HC$_ $N 19-18 were detected in 50 of the 51 sources, SiO 4-3 was detected in 46 sources, and C18O 1-0 was detected in all sources. The Pearson correlation coefficients between H$_ $CS and HCS$^+$ normalized by H$_ $ and H$_ $S are 0.94 and 0.87, respectively, and a tight linear relationship with a slope of 1.00 and 1.09 is found; this relationship is 0.77 and 0.98 between H$_ $S and H$_ $CS and 0.76 and 0.97 between H$_ $S and HCS$^ $. The full widths at half maxima of H$_ $34S 1$_ $, H$_ $CS 5$_ $, HCS$^ $ 4-3, and HC$_ $N 19-18 in each source are similar to each other, which indicates that they may trace similar regions. By comparing the observed abundance with model results, we see that there is one possible time (2-3times 105 yr) a which each source in the model matches the measured abundances of H$_ $S, H$_ $CS, and HCS$^ $. The abundances of HCS$^ $, H$_ $CS, and H$_ $S increase with the SiO abundance in these sources, which implies that shock chemistry may be playing a large role. The close abundance relation of H$_2$S, H$_2$CS, and HCS$^+$ and the similar line widths in observational results indicate that these three molecules could be chemically linked, with HCS$^+$ and H$_2$CS the most correlated. The comparison of the observational results with chemical models shows that the abundances can be reproduced for almost all the sources at a specific time. The observational results, including the abundances in these sources need to be considered in further modeling of H$_ $S, H$_ $CS, and HCS$^ $ in hot cores with shock chemistry.

A new analytic approach to infer the cosmic-ray ionization rate in hot molecular cores from HCO+, N2H+, and CO observations

Context. The cosmic-ray ionization rate (ζ2) is one of the key parameters in star formation, since it regulates the chemical and dynamical evolution of molecular clouds by ionizing molecules and determining the coupling between the magnetic field and gas. Aims. However, measurements of ζ2 in dense clouds (e.g., nH ≥ 104 cm−3) are difficult and sensitive to the model assumptions. The aim is to find a convenient analytic approach that can be used in high-mass star-forming regions (HMSFRs), especially for warm gas environments such as hot molecular cores (HMCs). Methods. We propose a new analytic approach to calculate ζ2 through HCO+, N2H+, and CO measurements. By comparing our method with various astrochemical models and with observations found in the literature, we identify the parameter space for which the analytic approach is applicable. Results. Our method gives a good approximation, to within 50%, of ζ2 in dense and warm gas (e.g., nH ≥ 104 cm−3, T = 50, 100 K) for AV ≥ 4 mag and t ≥ 2 × 104 yr at Solar metallicity. The analytic approach gives better results for higher densities. However, it starts to underestimate ζ2 at low metallicity (Z = 0.1 Z⊙) when the value is too high (ζ2 ≥ 3 × 10−15 s−1). By applying our method to the OMC-2 FIR4 envelope and the L1157-B1 shock region, we find ζ2 values of (1.0 ± 0.3) × 10−14 s−1 and (2.2 ± 0.4) × 10−16 s−1, consistent with those previously reported. Conclusions. We calculate ζ2 toward a total of 82 samples in HMSFRs, finding that the average value of ζ2 toward all HMC samples (ζ2 = (7.4±5.0)×10−16 s−1) is more than an order of magnitude higher than the theoretical prediction of cosmic-ray attenuation models, favoring the scenario that locally accelerated cosmic rays in embedded protostars should be responsible for the observed high ζ2.

Digging into the Interior of Hot Cores with ALMA (DIHCA). IV. Fragmentation in High-mass Star-forming Clumps

Fragmentation contributes to the formation and evolution of stars. Observationally, high-mass stars are known to form multiple-star systems, preferentially in cluster environments. Theoretically, Jeans instability has been suggested to determine characteristic fragmentation scales, and thermal or turbulent motion in the parental gas clump mainly contributes to the instability. To search for such a characteristic fragmentation scale, we have analyzed Atacama Large Millimeter/submillimeter Array (ALMA) 1.33 mm continuum observations toward 30 high-mass star-forming clumps taken by the Digging into the Interior of Hot Cores with ALMA survey. We have identified 573 cores using the dendrogram algorithm and measured the separation of cores by using the Minimum Spanning Tree technique. The core separation corrected by projection effects has a distribution peaked around 5800 au. In order to remove biases produced by different distances and sensitivities, we further smooth the images to a common physical scale and perform completeness tests. Our careful analysis finds a characteristic fragmentation scale of ∼7000 au, comparable to the thermal Jeans length of the clumps. We conclude that thermal Jeans fragmentation plays a dominant role in determining the clump fragmentation in high-mass star-forming regions, without the need to invoke turbulent Jeans fragmentation.

Thermo-neutronic integrated coupling effects on nuclear reactor core calculations

Small Modular Reactors (SMRs) have gained significant attention as the next generation of nuclear reactors due to their unique features, such as improved economic viability and safety. This study focuses on the SMART reactor, the first certified design of an SMR, and investigates various Thermo-Neutronics aspects using an integrated coupling scheme of nuclear codes. The Neutronics cell and core calculations are performed using the DRAGON/DONJON codes, while the COBRA code is employed for thermal-hydraulic calculations. The analysis considers parameters including axial and radial power peaking factors (PPFs), critical heat flux (CHF), minimum departure from nucleate boiling ratio (MDNBR), axial average coolant temperature in hot channel and core, and maximum fuel temperature. These parameters are evaluated using the developed coupling system. Code-to-code verification is conducted to ensure the accuracy of the results, demonstrating good agreement. The coupling approach reveals significant effects compared to stand-alone code modeling, emphasizing the importance of considering the coupling between Neutronics and thermal-hydraulics, especially during the cycle length. This study contributes to the understanding of SMRs, particularly the SMART reactor, by providing insights into key parameters and their interdependencies. The integrated coupling scheme enhances the accuracy of the analysis and highlights the significance of considering coupling effects in the modeling process during the steady state and the cycle length.

S vacancies and heterojunction modulated MoS2/C@Fe3O4 towards improved full-spectrum photo-Fenton catalysis: Enhanced interfacial charge transfer and NIR absorption

Fe3O4-based core–shell/heterojunction composites exhibit favorable photothermal catalytic performance in environmental remediation, but limited by the weak interface electron transport efficiency and poor near infrared (NIR) absorption capacity. Herein, Sv-MoS2/C@Fe3O4 core–shell composites were prepared for the first time by coating S vacancies-bearing MoS2 (Sv-MoS2) on the surface of carbon-decorated Fe3O4 microspheres (C@Fe3O4) derived from copper slag-based polymer microspheres and was used as photothermal catalyst to activate H2O2 towards chlortethromycin hydrochloride (CTC) elimination from wastewater. By virtue of the synergistic effect of the petal-like Sv-MoS2, carbon-decorated layer and multi light reflection in porous microspheres, Sv-MoS2/C@Fe3O4 exhibited excellent full spectrum absorption and carrier migration efficiency, with catalytic activity of 0.149 min−1 and H2O2 utilization rate of 93.6 %. The degradation rate is 3.9 and 3.1 times of C@Fe3O4 and MoS2/C@Fe3O4 under full light irradiation which can heat the solution from room temperature to 72.4 °C. This excellent catalytic performance is mainly originated from that the S-type heterostructure promotes the charge separation, transfer and redox ability, and enhances catalytic oxidation by regulating electron density of the interfacial carbon and reducing the energy barrier of H2O2 activation through S vacancies. Moreover, the decorated carbon layer can serve as a hot core to provide heat to Sv-MoS2 and enhance the collision chance of photogenerated carriers, thus improving the catalytic performance of Sv-MoS2/C@Fe3O4. This work provides new strategies for constructing heterojunction materials with fast electron transport efficiency and using solar energy for environmental remediation.

SO2 and OCS toward high-mass protostars

Context. OCS and SO2 are both major carriers of gaseous sulfur and are the only sulfurated molecules detected in interstellar ices to date. They are thus the ideal candidates for exploring the evolution of the volatile sulfur content throughout the different stages of star formation. Aims. We aim to investigate the chemical history of interstellar OCS and SO2 by deriving a statistically significant sample of gas-phase column densities toward massive protostars and comparing them to observations of gas and ices toward other sources, from dark clouds to comets. Methods. We analyzed a subset of 26 line-rich massive protostars observed by ALMA in Band 6 as part of the High Mass Protocluster Formation in the Galaxy (ALMAGAL) survey. Column densities were derived for OCS and SO2 from their rare isotopologs O13CS and 34SO2 toward the compact gas around the hot cores. We compared the abundance ratios of gaseous OCS, SO2, and CH3OH with ice detections toward both high- and low-mass sources as well as dark clouds and comets. Results. We find that gas-phase column density ratios of OCS and SO2 with respect to methanol remain fairly constant as a function of luminosity between low- and high-mass sources, despite their very different physical conditions. In our dataset, OCS and SO2 are weakly correlated. The derived gaseous OCS and SO2 abundances relative to CH3OH are overall similar to protostellar ice values, with a significantly larger scatter for SO2 than for OCS. Cometary and dark-cloud ice values agree well with protostellar gas-phase ratios for OCS, whereas higher abundances of SO2 are generally seen in comets compared to the other sources. Gaseous SO2/OCS ratios are consistent with ices toward dark clouds, protostars, and comets, albeit with some scatter. Conclusions. The constant gas-phase column density ratios throughout low- and high-mass sources indicate an early-stage formation before intense environmental differentiation begins. Icy protostellar values are similar to the gas-phase medians and are compatible with an icy origin for these species followed by thermal sublimation. The larger spread in SO2 compared to OCS ratios with respect to CH3OH is likely due to a more water-rich chemical environment associated with the former, as opposed to a CO-rich origin for the latter. Post-sublimation gas-phase processing of SO2 can also contribute to the large spread. Comparisons to ices in dark clouds and comets point to a significant inheritance of OCS from earlier to later evolutionary stages.

Overview of ASDEX upgrade results in view of ITER and DEMO

Experiments on ASDEX Upgrade (AUG) in 2021 and 2022 have addressed a number of critical issues for ITER and EU DEMO. A major objective of the AUG programme is to shed light on the underlying physics of confinement, stability, and plasma exhaust in order to allow reliable extrapolation of results obtained on present day machines to these reactor-grade devices. Concerning pedestal physics, the mitigation of edge localised modes (ELMs) using resonant magnetic perturbations (RMPs) was found to be consistent with a reduction of the linear peeling-ballooning stability threshold due to the helical deformation of the plasma. Conversely, ELM suppression by RMPs is ascribed to an increased pedestal transport that keeps the plasma away from this boundary. Candidates for this increased transport are locally enhanced turbulence and a locked magnetic island in the pedestal. The enhanced D-alpha (EDA) and quasi-continuous exhaust (QCE) regimes have been established as promising ELM-free scenarios. Here, the pressure gradient at the foot of the H-mode pedestal is reduced by a quasi-coherent mode, consistent with violation of the high-n ballooning mode stability limit there. This is suggestive that the EDA and QCE regimes have a common underlying physics origin. In the area of transport physics, full radius models for both L- and H-modes have been developed. These models predict energy confinement in AUG better than the commonly used global scaling laws, representing a large step towards the goal of predictive capability. A new momentum transport analysis framework has been developed that provides access to the intrinsic torque in the plasma core. In the field of exhaust, the X-Point Radiator (XPR), a cold and dense plasma region on closed flux surfaces close to the X-point, was described by an analytical model that provides an understanding of its formation as well as its stability, i.e., the conditions under which it transitions into a deleterious MARFE with the potential to result in a disruptive termination. With the XPR close to the divertor target, a new detached divertor concept, the compact radiative divertor, was developed. Here, the exhaust power is radiated before reaching the target, allowing close proximity of the X-point to the target. No limitations by the shallow field line angle due to the large flux expansion were observed, and sufficient compression of neutral density was demonstrated. With respect to the pumping of non-recycling impurities, the divertor enrichment was found to mainly depend on the ionisation energy of the impurity under consideration. In the area of MHD physics, analysis of the hot plasma core motion in sawtooth crashes showed good agreement with nonlinear 2-fluid simulations. This indicates that the fast reconnection observed in these events is adequately described including the pressure gradient and the electron inertia in the parallel Ohm’s law. Concerning disruption physics, a shattered pellet injection system was installed in collaboration with the ITER International Organisation. Thanks to the ability to vary the shard size distribution independently of the injection velocity, as well as its impurity admixture, it was possible to tailor the current quench rate, which is an important requirement for future large devices such as ITER. Progress was also made modelling the force reduction of VDEs induced by massive gas injection on AUG. The H-mode density limit was characterised in terms of safe operational space with a newly developed active feedback control method that allowed the stability boundary to be probed several times within a single discharge without inducing a disruptive termination. Regarding integrated operation scenarios, the role of density peaking in the confinement of the ITER baseline scenario (high plasma current) was clarified. The usual energy confinement scaling ITER98(p,y) does not capture this effect, but the more recent H20 scaling does, highlighting again the importance of developing adequate physics based models. Advanced tokamak scenarios, aiming at large non-inductive current fraction due to non-standard profiles of the safety factor in combination with high normalised plasma pressure were studied with a focus on their access conditions. A method to guide the approach of the targeted safety factor profiles was developed, and the conditions for achieving good confinement were clarified. Based on this, two types of advanced scenarios (‘hybrid’ and ‘elevated’ q-profile) were established on AUG and characterised concerning their plasma performance.

Analysis of a plasma reactor performance for direct nitrogen fixation by use of three-dimensional simulations and experiments

This study utilizes state-of-the-art in-situ measurements and advanced three-dimensional simulations to investigate the operation of a microwave plasma reactor for nitrogen fixation at a high subatmospheric pressure under various power inputs. It is shown that the system should be treated as a warm plasma due to negligible differences in vibrational and rotational temperatures and that it is required to account for chemical non-equilibrium. Complex flow field and significant temperature and concentration gradients are observed, emphasizing the need for three-dimensional simulations to accurately describe the interactions between mass, heat, and momentum transport and chemical reactions in non-equilibrium conditions. The innermost plasma regions reach temperatures close to 6000 K, while wall temperatures remain low due to presence of a low-temperature swirling flow field around the hot core. Analysis reveals that the swirling flow field around the hot core provides intrinsic partial quenching in regions with large temperature gradients which counteract the return to chemical equilibrium and enrich the flow surrounding the hot core. The inner flow exhibits a recirculation zone, stagnation point, and a transition into an increasingly parabolic flow profile closer to the reactor outlet. The agreement between the numerical modeling and the measurements is strong. In-situ Raman spectroscopy measurements confirm the calculated temperature field inside the reactor. Thermocouple measurements on the reactor wall are also in good agreement with the simulation. Additionally, Fourier-transform infrared spectroscopy measurements agree very well with the simulated amount of nitrogen oxide exiting the reactor at different microwave power inputs. The understanding and modeling capabilities are expected to support the development of future reactor designs that can facilitate higher yields.

Thick Columnar-Structured Thermal Barrier Coatings Using the Suspension Plasma Spray Process

Higher operating temperatures for gas turbine engines require highly durable thermal barrier coatings (TBCs) with improved insulation properties. A suspension plasma spray process (SPS) had been developed for the deposition of columnar-structured TBCs. SPS columnar TBCs are normally achieved at a short standoff distance (50.0 mm–75.0 mm), which is not practical when coating complex-shaped engine hardware since the plasma torch may collide with the components being sprayed. Therefore, it is critical to develop SPS columnar TBCs at longer standoff distances. In this work, a commercially available pressure-based suspension delivery system was used to deliver the suspension to the plasma jet, and a high-enthalpy TriplexPro-210 plasma torch was used for the SPS coating deposition. Suspension injection pressure was optimized to maximize the number of droplets injected into the hot plasma core and achieving the best particle-melting states and deposition efficiency. The highest deposition efficiency of 51% was achieved at 0.34 MPa injection pressure with a suspension flow rate of 31.0 g/min. With the optimized process parameters, 1000 μm thick columnar-structured SPS 8 wt% Y2O3-stabilized ZrO2 (8YSZ) TBCs were successfully developed at a standoff distance of 100.0 mm. The SPS TBCs have a columnar width between 100 μm and 300 μm with a porosity of ~22%. Furnace cycling tests at 1125 °C showed the SPS columnar TBCs had an average life of 1012 cycles, which is ~2.5 times that of reference air-plasma-sprayed dense vertically cracked TBCs with the same coating thickness. The superior durability of the SPS columnar TBCs can be attributed to the high-strain-tolerant microstructure. SEM cross-section characterization indicated the failure of the SPS TBCs occurred at the ceramic top coat and thermally grown oxide (TGO) interface.

Detection of antifreeze molecule ethylene glycol in the hot molecular core G358.93–0.03 MM1

ABSTRACT The identification of complex pre-biotic molecules using millimetre and submillimetre telescopes allows us to understand how the basic building blocks of life are formed in the universe. In the interstellar medium, ethylene glycol ($({\rm CH}_2{\rm OH})_{2}$) is the simplest sugar alcohol molecule, and it is the reduced alcohol of the simplest sugar-like molecule, glycolaldehyde (${\rm CH}_{2}{\rm OHCHO}$). We present the detection of the rotational emission lines of $aGg^{\prime }$ conformer of ethylene glycol ($({\rm CH}_2{\rm OH})_{2}$) towards the hot molecular core G358.93–0.03 MM1 using the Atacama Large Millimeter/Submillimeter Array. The estimated column density of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ towards the G358.93–0.03 MM1 is (4.5$\pm 0.1)\times 10^{16}$ cm$^{-2}$ with an excitation temperature of 155$\pm$35 K. The abundance of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ with respect to ${\rm H}_{2}$ is (1.4$\pm 0.5)\times 10^{-8}$. Similarly, the abundances of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ with respect to ${\rm CH}_{2}{\rm OHCHO}$ and ${\rm CH}_{3}{\rm OH}$ are 3.1$\pm$0.5 and (6.1$\pm 0.3)\times 10^{-3}$. We compare the estimated abundance of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ with the existing three-phase warm-up chemical model abundance of $({\rm CH}_2{\rm OH})_{2}$, and we notice the observed abundance and modelled abundance are nearly similar. We discuss the possible formation pathways of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ towards the hot molecular cores, and we find that $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ is probably created via the recombination of two ${\rm CH}_{2}{\rm OH}$ radicals on the grain surface of G358.93–0.03 MM1.

High-mass star formation across the Large Magellanic Cloud

Context. The formation of massive stars passes through a so-called hot molecular core phase, where the temperature of molecular gas and dust rises to above 100 K within a size scale of approximately 0.1 pc. The hot molecular cores are rich in chemical compounds found in the gas phase, which are a great probe of ongoing star formation. Aims. To study the impact of the initial effects of metallicity (i.e., the abundance of elements heavier than helium) on star formation and the formation of different molecular species, we searched for hot molecular cores in the sub-solar metallicity environment of the Large Magellanic Cloud (LMC). Methods. We conducted Atacama Large Millimeter/submillimeter Array (ALMA) Band 6 observations of 20 fields centered on young stellar objects (YSOs) distributed over the LMC in order to search for hot molecular cores in this galaxy. Results. We detected a total of 65 compact 1.2 mm continuum cores in the 20 ALMA fields and analyzed their spectra with XCLASS software. The main temperature tracers are CH3OH and SO2, with more than two transitions detected in the observed frequency ranges. Other molecular lines with high detection rates in our sample are CS, SO, H13CO+, H13CN, HC15N, and SiO. More complex molecules, such as HNCO, HDCO, HC3N, CH3CN, and NH2CHO, and multiple transitions of SO and SO2 isotopologues showed tentative or definite detection toward a small subset of the cores. According to the chemical richness of the cores and high temperatures from the XCLASS fitting, we report the detection of four hot cores and one hot core candidate. With one new hot core detection in this study, the number of detected hot cores in the LMC increases to seven. Conclusions. Six out of seven hot cores detected in the LMC to date are located in the stellar bar region of this galaxy. These six hot cores show emission from complex organic molecules (COMs), such as CH3OH, CH3CN, CH3OCHO, and CH3OCH3. The only known hot core in the LMC with no detection of COMs is located outside the bar region. The metallicity in the LMC presents a shallow gradient increasing from outer regions toward the bar. Various studies emphasize the interaction between the LMC and the Small Magellanic Cloud, which resulted in the mixing and inhomogeneity of the interstellar medium of the two galaxies. These interactions triggered a new generation of star formation in the LMC. We suggest that the formation of hot molecular cores containing COMs ensues from the new generation of stars forming in the more metal-rich environment of the LMC bar.

Probing the sterile neutrino dipole portal with SN1987A and low-energy supernovae

Beyond the Standard Model electromagnetic properties of neutrinos may lead to copious production of sterile neutrinos in the hot and dense core of a core-collapse supernova. In this work, we focus on the active-sterile transition magnetic moment portal for heavy sterile neutrinos. Firstly, we revisit the SN1987A cooling bounds for dipole portal using the integrated luminosity method, which yields more reliable results (especially in the trapping regime) compared to the previously explored via emissivity loss, also known as the Raffelt criterion. Secondly, we obtain strong bounds on the dipole coupling strength reaching as low as 10−11 GeV−1 from energy deposition, i.e., constrained from the observation of explosion energies of underluminous Type IIP supernovae. In addition, we find that sterile neutrino production from Primakoff upscattering off of a proton dominates over scattering off of an electron for low sterile neutrino masses. Published by the American Physical Society 2024

Following fuel conversion during biomass gasification using tunable diode laser absorption spectroscopy diagnostics

The efficiency of the gasification process and product quality largely depend on the degree of fuel conversion. We present the real-time in-situ tunable diode laser measurements of main carbon and oxygen-containing species in the hot reactor core of a pilot-scale entrained flow biomass gasifier (EFG). The concentrations of CO, CO2, CH4, C2H2, H2O, soot, and gas temperature were measured during the air and oxygen-enriched gasification of stem wood at varying equivalence ratios. The experiments were made at the upper and lower optical ports inside a 4 m long, ceramic-lined, atmospheric EFG, allowing to access the degree of the fuel conversion inside the reactor. The exhaust composition was measured by micro-GC, FTIR, and low-pressure impactor. There was a good agreement between the data measured inside the reactor and at the exhaust for oxygen-enriched gasification implying that the chemical reactions are practically frozen downstream the optical ports. For air, the data indicated that the gasification reactions are still active at the measurement locations. Significant concentrations of C2H2, up to 5000 ppm, were found inside the reactor.

The Cygnus Allscale Survey of Chemistry and Dynamical Environments: CASCADE. III. The large scale distribution of DCO+, DNC, and DCN in the DR21 filament

Deuterated molecules and their molecular D/H-ratios ($R_D$(D)) are important diagnostic tools with which to study the physical conditions of star-forming regions. The degree of deuteration, $R_D$(D), can be significantly enhanced over the elemental D/H-ratio depending on physical parameters such as temperature, density, and the ionization fraction. Within the Cygnus Allscale Survey of Chemistry and Dynamical Environments (CASCADE), we aim to explore the large-scale distribution of deuterated molecules in the nearby ($d 1.5$ kpc) Cygnus-X region, a giant molecular cloud complex that hosts multiple sites of high-mass star formation. We focus on the analysis of large-scale structures of deuterated molecules in the filamentary region hosting the prominent region DR21 and DR21(OH), a molecular hot core that is in an earlier evolutionary state. The DR21 filament has been imaged using the IRAM 30-m telescope in a variety of deuterated molecules and transitions. Here we discuss the HCO+ HNC, and HCN molecules and their deuterated isotopologs DCO+ DNC, and DCN, and their observed line emissions at 3.6, 2, and 1.3 mm. The spatial distributions of integrated line emissions from DCO+ DNC, and DCN reveal morphological differences. Notably DCO+ displays the most extended emission, characterized by several prominent peaks. Likewise, DNC exhibits multiple peaks, although its emission appears less extended compared to DCO+ . In contrast to the extended emission of DCO+ and DNC, DCN appears the least extended, with distinct peaks. Focusing only on the regions where all three molecules are observed, the mean deuteration ratios for each species, $R_D$, are 0.01 for both DNC and DCN, and $=0.005$ for DCO+ respectively. Anticorrelations are found with deuterated molecules and dust temperature or $N$( H2 The strongest anticorrelation is found with $R_D$( DCO+ ) and $N$( H2 ), with a Pearson correlation coefficient of $ -0.74$. We analyzed the SiO emission as a tracer for shocks and the $N$(HCO)/$N$( H^13CO+ ) as a tracer for increased photodissociation by ultraviolet radiation. It is suggested that the anticorrelation of $R_D$( DCO+ ) and $N$( H2 ) is a result of a combination of an increased photodissociation degree and shocks. A strong positive correlation between the ratio of integrated intensities of DCN and DNC with their 13C-isotopologs is found in high-column-density regions. The positive relationship between the ratios implies that the D-isotopolog of the isomers could potentially serve as a tracer for the kinetic gas temperature.

ALMA-IMF

Context. The star formation process leads to an increased chemical complexity in the interstellar medium. Sites associated with high-mass star and cluster formation exhibit a so-called hot core phase, characterized by high temperatures and column densities of complex organic molecules. Aims. We aim to systematically search for and identify a sample of hot cores toward the 15 Galactic protoclusters of the ALMA-IMF Large Program and investigate their statistical properties. Methods. We built a comprehensive census of hot core candidates toward the ALMA-IMF protoclusters based on the detection of two CH3OCHO emission lines at 216.1 GHz. We used the source extraction algorithm GExt2D to identify peaks of methyl formate (CH3OCHO) emission, a complex species commonly observed toward sites of star formation. We performed a cross-matching with the catalog of thermal dust continuum sources from the ALMA-IMF 1.3 mm continuum data to infer their physical properties. Results. We built a catalog of 76 hot core candidates with masses ranging from ~0.2 M⊙ to ~80 M⊙, of which 56 are new detections. A large majority of these objects, identified from methyl formate emission, are compact and rather circular, with deconvolved full width at half maximum (FWHM) sizes of ~2300 au on average. The central sources of two target fields show more extended, but still rather circular, methyl formate emission with deconvolved FWHM sizes of ~6700 au and 13 400 au. About 30% of our sample of methyl formate sources have core masses above 8 M⊙ and range in size from ~1000 au to 13 400 au, which is in line with measurements of archetypical hot cores. The origin of the CH3OCHO emission toward the lower-mass cores may be explained as a mixture of contributions from shocks or may correspond to objects in a more evolved state (i.e., beyond the hot core stage). We find that the fraction of hot core candidates increases with the core mass, suggesting that the brightest dust cores are all in the hot core phase. Conclusions. Our results suggest that most of these compact methyl formate sources are readily explained by simple symmetric models, while collective effects from radiative heating and shocks from compact protoclusters are needed to explain the observed extended CH3OCHO emission. The large fraction of hot core candidates toward the most massive cores suggests that they rapidly enter the hot core phase and that feedback effects from the forming protostar(s) impact their environment on short timescales.

Observation of Complex Organic Molecules Containing Peptide-like Bonds Toward Hot Core G358.93–0.03 MM1

In star formation regions, the complex organic molecules (COMs) that contain peptide bonds (–NH–C(=O)–) play a major role in the metabolic process because –NH–C(=O)– is connected to amino acids (R-CHNH2–COOH). Over the past few decades, many COMs containing peptide-like bonds have been detected in hot molecular cores (HMCs), hot corinos, and cold molecular clouds, however, their prebiotic chemistry is poorly understood. We present the first detection of the rotational emission lines of formamide (NH2CHO) and isocyanic acid (HNCO), which contain peptide-like bonds toward the chemically rich HMC G358.93–0.03 MM1, using high-resolution and high-sensitivity Atacama Large Millimeter/submillimeter Array bands 6 and 7. We estimate that the column densities of NH2CHO and HNCO toward G358.93–0.03 MM1 are (2.80 ± 0.29) × 1015 cm−2 and (1.80 ± 0.42) × 1016 cm−2 with excitation temperatures of 165 ± 21 K and 170 ± 32 K, respectively. The fractional abundances of NH2CHO and HNCO toward G358.93–0.03 MM1 are (9.03 ± 1.44) × 10−10 and (5.80 ± 2.09) × 10−9. We compare the estimated abundances of NH2CHO and HNCO with the existing three-phase warm-up chemical model abundance values and notice that the observed and modeled abundances are very close. We conclude that NH2CHO is produced by the reaction of NH2 and H2CO in the gas phase toward G358.93–0.03 MM1. Likewise, HNCO is produced on the surface of grains by the reaction of NH and CO toward G358.93–0.03 MM1. We also find that NH2CHO and HNCO are chemically linked toward G358.93–0.03 MM1.

Core to ultracompact HII region evolution in the W49A massive protocluster

Aims. We aim to identify and characterize cores in the high-mass protocluster W49A, determine their evolutionary stages, and measure the associated lifetimes. Methods. We built a catalog of 129 cores extracted from an ALMA 1.3 mm continuum image at 0.26″ (2900 au) angular resolution. The association between cores and hypercompact or ultracompact HII (H/UC HII) regions was established from the analysis of VLA 3.3 cm continuum and H30α line observations. We also looked for emission of hot molecular cores (HMCs) using the methyl formate doublet at 218.29 GHz. Results. We identified 40 cores associated with an H/UC HII region and 19 HMCs over the ALMA mosaic. The 52 cores with an H/UC HII region and/or an HMC are assumed to be high-mass protostellar cores, while the rest of the core population likely consists of prestellar cores and low-mass protostellar cores. We found a good agreement between the two tracers of ionized gas, with 23 common detections and only four cores detected at 3.3 cm and not in H30α. The spectral indexes from 3.3 cm to 1.3 mm range from 1, for the youngest cores with partially optically thick free-free emission, to about −0.1, which is for the optically thin free-free emission obtained for cores that are likely more evolved. Conclusions. Using the H/UC HII regions as a reference, we found the statistical lifetimes of the HMC and massive protostellar phases in W49N to be about 6 × 104 yr and 1.4 × 105 yr, respectively. We also showed that HMCs can coexist with H/UC HII regions during a short fraction of the core lifetime, about 2 × 104 yr. This indicates a rapid dispersal of the inner molecule envelope once the HC HII is formed.

First observations from the Kr multi-monochromatic x-ray imager for time and spatially resolved diagnosis of hot implosion cores

This paper presents initial findings from the recently deployed Kr multi-monochromatic x-ray imager (Kr MMI) at the Omega laser facility. The experiment focuses on exploring implosion dynamics in exploding pusher capsules at three distinct initial gas fill densities. Utilizing time-gated and spatially integrated measurements, core size, electron temperature (Te), and electron densities (ne) are extracted through the analysis of the spectral region encompassing the Kr He α and its satellite lines. A comprehensive spectral database, incorporating atomic kinetics, spectroscopic-quality radiation transport, and Stark broadened line shapes, has been developed for rigorous data analysis. These measurements underscore the utility of the new Kr MMI instrument, which, combined with sophisticated analysis techniques, enables the diagnosis of plasma conditions at Te>2000 eV, thereby extending the capabilities beyond the prior Ar MMI design. This is an important stepping stone for achieving time-gated and space-resolved diagnostics of electron temperature, electron density, and heat transport in high temperature implosion cores.

A Hot Core in the Group-dominant Elliptical Galaxy NGC 777

NGC 777 provides an example of a phenomenon observed in some group-central ellipticals, in which the temperature profile shows a central peak, despite the short central cooling time of the intragroup medium. We use deep Chandra X-ray observations of the galaxy, supported by uGMRT 400 MHz radio imaging, to investigate the origin of this hot core. We confirm the centrally peaked temperature profile and find that the entropy and cooling time both monotonically decline to low values (2.62 −0.18+0.19 keV cm2 and 71.3−13.1+12.8 Myr, respectively) in the central ∼700 pc. Faint diffuse radio emission surrounds the nuclear point source, with no clear jets or lobes but extending to ∼10 kpc on the northwest–southeast axis. This alignment and extent agree well with a previously identified filamentary Hα + [N ii] nebula. While cavities are not firmly detected, we see X-ray surface brightness decrements on the same axis at 10–20 kpc radii, which are consistent with the intragroup medium having been pushed aside by expanding radio lobes. Any such outburst must have occurred long enough ago for lobe emission to have faded below detectability. Cavities on this scale would be capable of balancing radiative cooling for at least ∼240 Myr. We consider possible causes of the centrally peaked temperature profile, including gravitational heating of gas as the halo relaxes after a period of active galactic nucleus jet activity, and heating by particles leaking from the remnant relativistic plasma of the old radio jets.