The concentrations of the solute (pyridine) were measured by means of modified liquid scintillation techniques to within 0.66,μm of the interface as well as in the bulk of the organic (toluene) phase during the solute transfer from the toluene to the water phase at different temperatures, flow rates and solute concentrations. These measurements allow the comparison of the mass transfer resistance of the diffusive transfers with the interfacial resistance. In extremely pure systems the interfacial resistance is negligible in comparison with the resistances of the diffusive transfers. In the presence of surface active agents the interfacial resistance strongly increases and exceeds those of the diffusive transfers. The solute transfer from the water to the toluene phase because of the Marangoni instabilities could only be considered qualitatively. The concentrations of the solute (pyridine) to within 0.66 μm of the interface and in the bulk of the organic phase (toluene) during the solute transfer from the organic to water phase in a horizontal cylindrical flow channel with concurrent flow of the phases at different temperatures, flow rates and solute concentrations were measured by means of a modified liquid scintillation technique. These measurements allow the comparison of the mass transfer resistances of the diffusive transfers to and from the interface with the interfacial resistance. In extremely pure systems, the solute concentration at the interface quickly drops to very low values with increasing distance from the channel entrance, which indicates that the mass transfer resistance of the interface is negligible in comparison with the resistances of the diffusive transfers in the laminar flow region. In the presence of surface active agents (LPC) the solute concentration to within 0.66 μm of the interface dramatically increases and exceeds the solute concentration in the bulk of the toluene phase. This indicates a strong increase of the mass transfer interfacial resistance. The high solute concentration at the interface, exceeding its bulk concentration, is caused by the enrichment of the solute in the interface, which was measured by the interfacial tension depression in the presence of the solute. Because the solute transfer from the water to the toluene phase causes interfacial (Marangoni) instabilities, which increase the geometrical interfacial area due to uncontrolled eruptions and formations of microemulsions, the solute concentration could not be measured to within 0.66 μm of the interface in the toluene phase during the water to toluene solute transfer. Only qualitative statements could be made with regard to the area of the interface. Further measurements are necessary in order to determine quantitative relationships with regard to the mass transfer interfacial resistance as a function of different process parameters
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