The limited use of non-renewable energy sources facilitates a reduction in the negative environmental impact of electricity production. The policies of European countries aim to change the structure of electricity sources, focusing particularly on non-renewable sources. The aim of this study was to assess changes in the structure of electricity generation depending on the energy sources used in 34 European countries in the years 1990–2020 in terms of their environmental impact. This study was conducted using cluster analysis: a method applied in multivariate comparative analyses. Such an approach provided a new, broader outlook on changes in the structure of electric energy production in Europe. A total of nine homogeneous groups of countries were distinguished in terms of energy transformation. The ecological scarcity method 2013 was applied to assess the environmental impact of electricity production in the analyzed countries. In the investigated period, the negative environmental impact of electricity production in European countries decreased. The median of the volume of this impact, determined based on the structure of production in 1990, for the analyzed countries was 464 UBP/1 kWh. In the following years, the value of the median dropped to 413 UBP/1 kWh (2000), 322 UBP/1 kWh (2010), and 204 UBP/1 kWh (2020), respectively. The diversification of the countries in this respect also decreased, which resulted in a reduction in the number of clusters from eight in 1990 to two in 2020.
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