Holocene Sediment Cores Research Articles

Geochemical Characterization of the Sources and Distribution of Fatty Acids in Recent Sediment Cores from Cross River System, South-South, Nigeria

Geochemical Characterization of the Sources and Distribution of Fatty Acids in Recent Sediment Cores from Cross River System, South-South, Nigeria

BrGDGT-based quantitative reconstructions of paleotemperature in lakes: Regional vs. site-specific calibrations

Branched glycerol dialkyl glycerol tetraethers (brGDGTs) are bacterial membrane lipids that have been widely used as tools for the quantitative reconstruction of past terrestrial temperatures in lakes. Two approaches, i.e., regional/global and site-specific calibrations, have been previously employed in the reconstruction. However, their strengths and weaknesses have not been properly evaluated yet, making it challenging to choose a suitable approach to paleoreconstruction. Here, we investigated the distribution of brGDGTs in surface sediments of 65 lakes along a mean annual lake water temperature (MLWT) transect in West China and developed a regional MBT'5ME (methylation degree of 5-methylated brGDGTs) calibration for MLWT reconstruction. Meanwhile, a site-specific brGDGT calibration for Lake Yangzonghai (YZH), located within the West China transect, was generated based on the relationship between the instrumental temperature record over the past 100 years and individual brGDGT abundances in a short sediment core taken from the lake. These two calibrations were applied to global lake surface sediments, as well as a long sediment core spanning the Holocene from Lake YZH. The linear correlations between MBT'5ME and temperature are highly consistent among lakes from different regions, indicating the near-universal response of brGDGTs in global lakes to temperature. However, MLWT inferred from the site-specific calibration shows a weak relationship with actual MLWT in global lakes, indicating that the site-specific calibration might be only a result of overfitting rather than reflecting the response of brGDGT distribution to ambient temperature. Applications to a Holocene sediment core in Lake YZH suggest that the regional MBT'5ME calibration is more suitable for reconstructing paleotemperature than the site-specific calibration. The regional MBT'5ME calibration derived temperature record shows a cold Younger Dryas (YD), followed by a rapid warming of ∼3 °C during the last deglaciation, and a long-term cooling of ∼1 °C from 9.9 to ∼0.2 cal ka BP. The principal component analysis shows that temperature is the dominant factor affecting brGDGT distributions in the long sediment core whereas the site-specific calibration is strongly affected by human activities rather than reflecting the ambient temperature. We highlight the importance of using appropriate approaches to developing calibrations for paleotemperature reconstruction and assessing the reliability of the temperature records.

Middle to late Holocene environmental evolution and sea level change on the west coast of Bohai Bay

Bohai Bay is a typical area of global change research in East Asia, due to its unique geographical location and shallow water environment. In this paper, we present the results of a study of grain-size, geochemistry, pollen and algae of a middle to late Holocene sediment core from Haixing wetland, which located on the west coast of Bohai Bay. The results show that: 1) Prior to 6700 cal a B.P., the content of Cl, Sr/Ca ratio were the highest, end-member analysis of grain size suggested EM2 were dominant, which is characteristic of marine sediment and the concentrations of Pediastrum and Typha (indicating a freshwater environment) pollen were lowest, overall indicating the maximum of relative sea level; 2) During 6700–5000 cal a B.P., and the Ti and K contents, EM1 (lacustrine sedimentary component) increased substantially, EM2 decreased, and EM3 (fluvial sedimentary component) began to appear. The concentrations of Pediastrum, Dinophyceae and Typha pollen began to increase. All these indicating that the relative sea level began to fall and the study area became a lagoon environment; 3) During 5000–3500 cal a B.P. the Ti and K content increased further; EM1 was dominant, EM2 was rare, indicating that the relative sea level decreased further and the lagoon gradually became enclosed; 4) After 3500 cal a B.P., the Ti content reached its maximum and the Cl content and Sr/Ca ratio decreased to their lowest levels. EM1 was dominant and EM2 was virtually absent; dinoflagellate cysts almost disappeared and there was large increase of Typha pollen, indicating the complete exclusion of a marine influence during most of this period. However, during 2500–2000 cal a B.P. the Cl and the Sr/Ca ratio increased slightly once again, indicating a transient transgression.

Concomitant changes of lipid biomarker and water column mixing since mid-Holocene

An increasing observation of in-situ production of branched glycerol dialkyl glycerol tetraethers (brGDGTs) in marine environments has aroused concerns about the utility of BIT (the ratio of brGDGTs over isoGDGTs) index to indicate soil contribution in marine environment. In this study, GDGT biomarkers and foraminiferal carbon isotope (δ13C) are analyzed in a mid-to-late Holocene sediment core from the northern South China Sea (SCS). The BIT values exhibited an overall similar pattern as compared to Δδ13C(P-G) (the δ13C difference between subsurface and surface planktonic foraminifera) index that indicates water column productivity, implying that the variations in BIT are likely related to marine productivity status. A positive relation between BIT and Δδ13C(P-G) was observed and explained by the downward transport of organic matter due to change of upper water mixing, with higher BIT Δδ13C(P-G) values during strengthened upper water mixing. Despite these findings, further investigations on the mechanistic processes that regulate the productions and dynamics of brGDGTs and isoGDGTs in marine sediments are warranted.

New recorded diatoms in Holocene sediment cores from the Gonggeom-ji Wetland in Korea

The Gonggeom-ji reservoir is an agricultural one built for rice farming during the Proto-Three Kingdoms period and was designated as Gyeongsangbuk-do monument No. 121 because of its high historical value. The Nakdonggang National Institute of Biological Resources has been conducting paleontological and paleoenvironmental studies on major wetlands from Korea since 2016, as well as diatom, geological, and depth distribution analyses on the sedimentary soil of Gonggeom-ji. This study summarized the description and ecological characteristics of six newly recorded diatoms (Gomphonema lacusrankala, Pinnularia diandae, P. gibba var. hyaline, P. lacunarum, Sellaphora labda var. nipponica, Stauroneis angustilancea) found in samples collected through drilling in Gonggeom-ji in 2019.

Planktonic foraminifera organic carbon isotopes as archives of upper ocean carbon cycling

The carbon cycle is a key regulator of Earth’s climate. On geological time-scales, our understanding of particulate organic matter (POM), an important upper ocean carbon pool that fuels ecosystems and an integrated part of the carbon cycle, is limited. Here we investigate the relationship of planktonic foraminifera-bound organic carbon isotopes (δ13Corg-pforam) with δ13Corg of POM (δ13Corg-POM). We compare δ13Corg-pforam of several planktonic foraminifera species from plankton nets and recent sediment cores with δ13Corg-POM on a N-S Atlantic Ocean transect. Our results indicate that δ13Corg-pforam of planktonic foraminifera are remarkably similar to δ13Corg-POM. Application of our method on a glacial sample furthermore provided a δ13Corg-pforam value similar to glacial δ13Corg-POM predictions. We thus show that δ13Corg-pforam is a promising proxy to reconstruct environmental conditions in the upper ocean, providing a route to isolate past variations in δ13Corg-POM and better understanding of the evolution of the carbon cycle over geological time-scales.

Deciphering hydroclimate fluctuations of Nile watershed from Holocene sediment of Manzala lagoon: Bio-geochemical implications

A 19.5-m long Holocene sediment core (MZ-1) was retrieved from Manzala lagoon coast, the depocenter of the Nile Delta. AMS-dating shows the complete Holocene strata of MZ-1, mostly consisting of lagoon muds. The high-resolution dated geochemical elements (major and trace) and bio-markers (n-alkanes) of MZ-1 serve as effective hydroclimate proxies that oscillated during the Africa Humid Period (AHP). Our measurements show the highest value of diagnostic geochemical elements of provenance implications (e.g. Ti/Al, Zr/Al, Cr/Al) prior to 7.5 ka - Period I, indicating the peak period of the AHP, when the African monsoon was intense over the Nile watershed, mainly the East African Plateau (EAP). This is immediately followed by Period II ca. 7.5–4.5 ka, characterized by the highly variable hydroclimatic conditions when the Intertropical Convergence Zone (ITCZ) withdrew southwards. It is denoted by a sharp drop of many diagnostic elements, then succeeded by a gentle, but highly-fluctuated rise, especially the metallic elements Fe, Ti and Cr of basaltic origins of the Ethiopian Highlands. It ascribes to an instability of the hydroclimate in the Blue Nile watershed due to eastward shift of the Congo Air Boundary (CAB) during the AHP receding. In response, the biomarker (n-alkanes) showed remarkably high terrestrial derived primary productivity in Manzala lagoon during 7.5–4.5 ka, evidently reversal to the Early-Holocene marine-enhanced ecological setting. The high Nile floods triggered by unstable hydroclimate of the Nile watershed, particularly in the Ethiopian Highlands of Period II delivered much terrestrial organic matter to coast, making lagoon water less saline. Minor geo-elemental and biomarker fluctuations occurred after ca. 4.5 ka in response to the post-AHP termination in the upper Nile Basin.

Luminescence dating of Holocene sediment cores from a wave-dominated and mountainous river delta in central Vietnam

Sediments of river deltas provide valuable records of past coastal environments. Optically-stimulated luminescence (OSL) dating has become an alternative to radiocarbon dating for constraining the sediment chronology in large deltas that allow for sufficient sunlight bleaching of sediments during the fluvial transport. However, its applicability to smaller deltas with mountainous riverine systems has not been confirmed yet. To check this, we examine multiple signals from two Holocene sediment cores in the wave-dominated Thu Bon River delta in central Vietnam. Two cores were collected, respectively, 3.9 km and 1.2 km inland from the present shoreline and both show a >-25-m thick succession of coarsening-upward mud to sand deposits. Coarse grains (180–250 μm in diameter) of quartz and K-feldspar, and fine grains (4–11 μm in diameter) of quartz and polymineral were extracted from the upper and lower parts of the cores for multi-grain measurements of quartz OSL, and of feldspar infrared-stimulated luminescence (IRSL) at 50 °C (IR50) and post-IR IRSL at 175 °C (pIRIR175) to determine burial ages. In addition, facies analysis and radiocarbon dating were conducted. The landward core consists of transgressive to early regressive estuarine and prodelta facies, which is overlain by a sandy beach-shoreface facies. The seaward core consists of a relatively simple shallowing-upward succession from muddy prodelta facies to sandy beach-shoreface facies. All luminescence ages except for pIRIR175 of fine grains are mostly consistent with the radiocarbon ages. Instead, pIRIR175 ages of fine grains are significantly overestimated with variable offsets. OSL and IR50 of fine grains provide reasonable age estimates, as these grains were likely well bleached during the transport even along a short and steep mountainous river. Consistent age estimates of all signals from sand indicate that sand was well-bleached in the beach and shoreface owing to the frequent sediment reworking by waves and currents. These results support the hypothesis that luminescence dating is applicable to Holocene wave-dominated deltas and reiterate that comparing different luminescence signals is an effective way to check reliability of the age estimates in environments where the sunlight bleaching is not ensured.

REE Geochemistry of Neogene–Holocene Sediments of La Fontanilla Cove (Tinto Estuary, SW Spain)

The Tinto and Odiel rivers (SW Spain) drain from a vast sulfide mining district and join at a 20-km-long estuary that enters the Atlantic Ocean. In this work, the contents of rare earth elements (REE) and fractionation in Neogene–Holocene sediment cores from La Fontanilla cove (Tinto estuary) were studied. The sediments were collected from a depth of 18 m at different distances from the recent river flow and were analyzed for new information on the temporal development of the REE load in the sediment column. Results show that the ∑ REE is higher in the finer sediments and during periods of mining activity from prehistoric to recent times. Marine influence appears to increase the light REE (LREE) relative to the heavy REE (HREE). The REE patterns of these estuarine sediments show convex curvatures in the MREE relative to the LREE and HREE, indicating the presence of acid-mixing processes between the fluvial waters affected by acid mine drainage (AMD) and seawater, as well as the precipitation of poorly crystalline mineral phases. Significant positive Eu anomalies were found in ebb-tide channels and marsh deposits, which can reflect the mineralogical composition and/or a strong localized salinity gradient combined with organic matter degradation. Sedimentological characteristics of the deposits appear to play the main role in accumulation and fractionation of the REE.

Distinct sources of bacterial branched GMGTs in the Godavari River basin (India) and Bay of Bengal sediments

Branched glycerol monoalkyl glycerol tetraethers (brGMGTs) are a group of membrane-spanning lipids produced by (yet) unidentified bacteria. They are characterized by a C-C bond connecting the two alkyl chains, which is thought to enhance membrane stability at higher temperatures. So far, they have been found in peats, lakes, and marine sediments, where their abundance relative to that of branched glycerol dialkyl glycerol tetraethers (brGDGTs) increases with temperature. However, the preferred niche(s) for production and the origin of brGMGTs in the terrestrial and marine realm remain unknown. Here we explore the occurrence of brGMGTs in soils, suspended particulate matter (SPM) and riverbed sediments in the Godavari River basin, and compare these with brGMGTs in a Holocene sediment core from the Bay of Bengal close to the Godavari River mouth. BrGMGTs are mostly detected in agricultural and/or regularly inundated soils, and in the river at sites with standing water and/or agricultural/wastewater effluents, as well as in the delta, where low oxygen conditions and/or high nutrient levels prevail. In contrast, brGMGTs are continuously present in the marine sediment core, but with a different isomeric composition than in the terrestrial realm, indicating a primarily marine source. The stable brGMGT distribution downcore and brGMGT-inferred temperature estimates which resemble the bottom water temperature, may suggest marine brGMGT production in the deep water column and/or sediments. However, to establish the proxy potential of brGMGTs for paleoreconstructions in the terrestrial and marine realm, brGMGT sources and environmental controls require further study.

BUILDING A MASTER CHRONOLOGY FOR THE WESTERN LAKE BONNEVILLE BASIN WITH STRATIGRAPHIC AND ELEMENTAL DATA FROM MULTIPLE SITES, USA

ABSTRACTWe present a novel approach to developing a unified radiocarbon-based chronology for multiple sediment cores from a location where radiocarbon dating is challenging. We used 36 radiocarbon ages from eight terminal Pleistocene and Holocene sediment cores with correlated stratigraphies. Stratigraphic correlation was accomplished using a combination of high-resolution photography, high-resolution X-ray fluorescence-based elemental composition data, and volcanic tephra identification. Results show that despite problems associated with potential contamination or radiocarbon reservoir effect, a useful age-depth model has been created for the correlated lacustrine sections of these eight sediment cores, providing chronological controls for future paleoenvironmental analyses of the cores.

Temporal trend of polychlorinated biphenyls contamination in the northwestern Arabian Gulf – Evidence from sediment records

This study provides an insight into the polychlorinated biphenyls (PCBs) inventories in the sediments of the northwestern Arabian/Persian Gulf. PCBs can be used as chemical markers that correlate with historical events in the region, to estimate the sedimentation rates in the northern Gulf, and to determine the sources of pollutants in the study area. The concentrations of PCBs were generally patchy in sediments. At Station 1 the ΣPCB concentrations generally fluctuated between 0.100 and 0.400 ng g−1 dw throughout the depositional history measured in a sediment core. There were four peaks in the ΣPCB profile corresponding to 1969, 1979, 1983 and 1991. Station 2 showed a prominent peak at depth of 25 cm. The concentrations of the ΣPCBs and ΣICE congeners at this depth were 28 and 12 ng g−1 dw respectively. Concentrations then dropped dramatically thereafter by a factor of 4. The ΣPCB concentrations at Station 3 were very low compared to the concentrations measured at Stations 1 and 2. The PCB concentration in Core 4 which was taken from open waters was 2–3 orders of magnitude lower than those in the other coastal cores. However, a 1990–91 peak was omnipresent in these cores. There is no record of PCB production within the Gulf region, and PCB releases into the Kuwait marine environment are likely to originate from their use in products. These maxima in early-1990s can be correlated to inputs from war-related activities, including the reported destruction of PCB-containing transformers and military equipment during the occupation of Kuwait. None of the recent sediment core sections at the four stations had a ΣPCB concentration near the effects range-median (ERM) concentration of 180 ng g−1, or permissible exposure limits (PEL) of 189 ng g−1, or were above the effect range-low (ERL) values of 22.7 ng g−1.

Late Holocene environmental evolution of Qilihai Lagoon, North China, based on a high-resolution multi-proxy sedimentary record

Lagoons are sensitive to the interaction between marine and terrestrial environments, and their evolution is also closely related to climate and sea level changes. Bohai Bay is a representative area of global change research in East Asia, due to its unique geographical location and shallow water environment. Here, we present the results of a study of pollen, algae, and grain-size of a late Holocene sediment core from Qilihai Lagoon in Bohai Bay, which is the largest lagoon in North China. The results show that the Qilihai Lagoon area experienced three stages of environmental change in 3,100–1,000 cal yr BP: during 3,100–1,800 cal yr BP the regional vegetation was broadleaved forest dominated by Quercus with a small amount of Pinus, indicating that the regional climate was warm and wet. The level of the Bohai Sea was high, and the sampling site was a shallow bay environment. During 1,800–1,400 cal yr BP, corresponding to the Dark Ages Cold Period (DACP), coniferous trees and grassland expanded. The sedimentary environment of the sampling area was greatly influenced by terrestrial sediment sources as the sea level fell and sandbars were exposed. We speculate that the modern Qilihai Lagoon formed at ∼ 1,800 cal yr BP. The lagoon shrank during the coldest interval of the DACP, and an extensive area of coastal wetland developed around the lagoon. During 1,400–1,000 cal yr BP the regional climate warmed, however, there was little change in the terrestrial vegetation. The lagoon became closed and the sedimentary environment was unstable due to the encroachment of coastal dunes driven. The coastal wetland began to decrease due to the expansion of the lagoon. Our study provides an important supplement for the environmental response research in the East Asian coastal areas, as well as other regions of the world.

Paleoecological analysis of Holocene sediment cores from the southern basin of Lake Tanganyika: implications for the future of the fishery in one of Africa’s largest lakes

Paleoecological analysis of Holocene sediment cores from the southern basin of Lake Tanganyika: implications for the future of the fishery in one of Africa’s largest lakes

Magnetic Properties of a Holocene Sediment Core from the Yeongsan Estuary, Southwest Korea: Implications for Diagenetic Effects and Availability as Paleoenvironmental Proxies

The sensitivity of magnetic properties, which characterize the mineralogy, concentration, and grain size distribution of magnetic minerals, to environmental processes may provide useful information on paleoenvironmental changes in estuarine environments. Magnetic property studies of estuaries are less common than other environments and, due to the west coast of South Korea having an abundance of estuaries, it provides a good place to study these processes. In this study, we analyzed a variety of magnetic properties based on magnetic susceptibility, hysteresis parameters, progressive acquisition of isothermal remanent magnetization and first-order reversal curve data from a Holocene muddy sediment core recovered from the Yeongsan Estuary on the west coast of South Korea. We examined diagenetic effects on magnetic properties and tested their availability as proxies of paleoenvironmental change. The presence of generally low magnetic susceptibility, ubiquitous greigite-like authigenic magnetic component, and very fine magnetic particle occurrence suggested that the analyzed sediments had undergone considerable early diagenetic alteration. Electron microscopic observations of magnetic minerals support this suggestion. Our results confirm that the use of initial bulk susceptibility as a stand-alone environmental change proxy is not recommended unless it is supported by additional magnetic analyses. We recognized the existence of ferromagnetic-based variabilities related to something besides the adverse diagenetic effects, and have examined possible relationships with sea-level and major climate changes during the Holocene. The most remarkable finding of this study is the two distinct intervals with high values in magnetic coercivity (Bc), coercivity of remanence (Bcr), and ratio of remanent saturation moment to saturation moment (Mrs/Ms) that were well coincident with the respective abrupt decelerations in the rate of sea-level rise occurred at around 8.2 and 7 thousand years ago. It is then inferred that such condition with abrupt drop in sea-level rise rate would be favorable for the abrupt modification of grain size distribution toward more single-domain-like content. We modestly propose consideration of the Bc, Bcr, and Mrs/Ms variability as a potential indicator for the initiation/occurrence of sea-level stillstand/slowstand or highstand during the Holocence, at least at estuarine environments in and around the studied area.

Planktonic foraminifera assemblages from the Brazil–Malvinas Confluence: palaeoceanographic implications of sub-surface temperature reconstructions in the western South Atlantic

Planktonic foraminifera census data have been widely used to reconstruct changes in ocean ecosystems as well as ocean chemistry and circulation through calibration functions. Here we analyse new core-top census data from 22 sites in the western South Atlantic, improving the geographical coverage and spatial resolution of the environmental gradients from the region covered by the Brazil–Malvinas Confluence (˜38°S–53°W). We combine them with previous data to provide an up-to-date compilation of the western South Atlantic planktonic foraminifera–calibration data set. We study the relationship between the assemblages present in the core-top samples and the most dynamic environmental variables from the region to establish the environmental variable(s) more resolved by the assemblages. Therefore, we develop and assess a new calibration function using the data set and testing several statistical models at different water depths. Our results reveal that the distribution and abundance of the species in the Brazil–Malvinas Confluence region mainly reflect the influence of two environmental variables: the mixed layer temperature and mixed layer depth (57% of total variance). The most precise reconstructions were obtained when using sub-surface temperatures between 40 and 50 m water depth. The application of the calibration function to a Holocene sediment core at ˜37°S–53°W revealed mean annual sub-surface temperature reconstructions between 8°C and 11°C, confirming the northward displacement of the Brazil–Malvinas Confluence during the onset of the Holocene and suggesting a major influence of the Malvinas Current during the entire Holocene at the studied site.

Evaluation of anhydrosugars as a molecular proxy for paleofire activity: A case study on a Holocene sediment core from Agios Floros, Peloponnese, Greece

The anhydrosugars, levoglucosan, mannosan and galactosan, are regarded as suitable molecular indicators of natural biomass combustion. Here, we evaluate summed anhydrosugars (SAS) as a paleofire indicator in a 6000 year-long fossil core from Agios Floros fen, Peloponnese, Greece, by analyzing charcoal fragments in parallel, throughout the sediment sequence. Modern surface soil samples from the same region were analysed for the presence of SAS, confirming the biomarker as an indicator of recent fire activity. The highest SAS concentrations in the fossil core were found in sections representing periods of wet conditions, both on local and regional scales and regionally widespread arboreal vegetation. Low amounts, or the absence, of SAS in the fossil core were associated with periods of dryness, regional dominance of non-arboreal vegetation and the presence of a fen rather than a lake ecosystem at the site. Micro-charcoal fragments were generally more abundant under these conditions. This suggests that SAS yield and deposition may vary with fuel availability and fire behavior, which in turn is affected by climate, local moisture and vegetation type. Forest fires result in more SAS compared to grass fires. SAS yield is also favored by low-temperature fires sustained under wet climate conditions. Preservation of SAS is likely to be compromised in the only seasonally wet fen ecosystem under the dry and warm Mediterranean climate conditions. The moist and shallow conditions in the wetland during hot summer months probably promote oxidation and biodegradation of the labile SAS molecules, compared to the more robust charcoal fragments. Thus, a multiproxy approach - using several proxies, both for fire, hydroclimate and vegetation change - is preferred when aiming to reconstruct past biomass burning from wetland ecosystems in a Mediterranean environment. The micro-charcoal record from Agios Floros reveals significant fire activity between 4400 and 2800 cal yr BP. This partly overlaps the Bronze Age period, associated with intense human environmental interaction and climate change in this area of Peloponnese, Greece.

Little Ice Age to modern lake-level fluctuations from Ferguson's Gulf, Lake Turkana, Kenya, based on sedimentology and ostracod assemblages

AbstractLacustrine sedimentary records and the proxies contained within them are valuable archives of past climate. However, the resolution of these records is frequently coarse or contains a high degree of uncertainty, making it difficult to resolve how climatic variability impacts the ecosystems on which humans depend. The goal of this study is to couple recent sediment cores sampled at centimeter-scale resolution with paleo- and historical information about lake levels to document how changes in the paleoenvironment impact the paleoecology of a rift basin lake. We present multiproxy data from three short cores collected from Ferguson's Gulf (FG), a shallow embayment connected to the western shore of Lake Turkana, Kenya. Five distinct biozones were interpreted on the basis of ostracods and geochemistry (δ18O, δ13C, and major elements), spanning the Little Ice Age (LIA) to the modern. Overall, ostracod total abundance and assemblage diversity decreased up-core, with the largest total abundance and genera diversity occurring during the LIA. This fits with regional datasets that indicate the Eastern Branch of the East African Rift System was wetter during the LIA than it is today. This also suggests that human impact in and around Lake Turkana has weakened the resiliency of the ecosystems in FG.

Mid-Holocene Antarctic sea-ice increase driven by marine ice sheet retreat

Abstract. Over recent decades Antarctic sea-ice extent has increased, alongside widespread ice shelf thinning and freshening of waters along the Antarctic margin. In contrast, Earth system models generally simulate a decrease in sea ice. Circulation of water masses beneath large-cavity ice shelves is not included in current Earth System models and may be a driver of this phenomena. We examine a Holocene sediment core off East Antarctica that records the Neoglacial transition, the last major baseline shift of Antarctic sea ice, and part of a late-Holocene global cooling trend. We provide a multi-proxy record of Holocene glacial meltwater input, sediment transport, and sea-ice variability. Our record, supported by high-resolution ocean modelling, shows that a rapid Antarctic sea-ice increase during the mid-Holocene (∼ 4.5 ka) occurred against a backdrop of increasing glacial meltwater input and gradual climate warming. We suggest that mid-Holocene ice shelf cavity expansion led to cooling of surface waters and sea-ice growth that slowed basal ice shelf melting. Incorporating this feedback mechanism into global climate models will be important for future projections of Antarctic changes.

Inter-comparison of optically stimulated luminescence (OSL) ages between different fractions of Holocene deposits from the Yangtze delta and its environmental implications

In fluvial and deltaic environments, different grain-size fractions experience varying degrees of bleaching of OSL signals due to variations in hydrodynamics and depositional processes. This has led to ambiguity for selection of grain-size fraction suitable for OSL dating. Comparison of OSL results from multiple grain-size fractions is one approach to ensure the reliability of OSL ages. We determined the quartz OSL ages of four grain-size fractions from fine silt to sand, together with the single grain OSL sensitivity in a Holocene sediment core from the Yangtze delta. For samples from the lower part of the sediment succession (including tidal river, tidal trough fill, estuarine front, tidal sand and delta front facies), OSL ages determined for different grain-size fractions were generally mutually consistent within the age range of ~2–9 ka, implying minor portion of incompletely bleached grains in the sediment at the time of burial. In contrast, significant partial bleaching was observed for three samples from younger delta front facies deposited during 0.4–0.6 ka. In these three samples, fine-silt quartz OSL ages were overestimated by ~0.5–2.0 ka compared with ages of coarser fractions. Based on the investigation of quartz luminescence sensitivity, we suggest that the southward shift of the Yellow River and increasing erosion in the Yangtze River catchment have led to enhanced water turbidity, resulting in partial bleaching of the sediment and substantial overestimation of the quartz OSL ages of fine silt during 0.4–0.6 ka. Alternatively, the erosion of older deposits and their redeposition elsewhere could retain large residual OSL ages. Notably, fine-silt quartz provides reliable ages for the period of 9–2 ka, suggesting that there was a lower degree of water turbidity compared with that since 2 ka. Therefore, the degree of OSL age overestimation may provide an indication of changes in water turbidity and sedimentary environment. Overall, our findings highlight the complexity of OSL dating in delta environments, and that an understanding of sediment transport and depositional processes is critical for reliable OSL dating.