Hollow Microspheres Research Articles

Fabrication of Hydroxyl Modified Hollow Glass Microsphere Composite Isocyanate‐Based Polyimide Foam and Optimization Strategy Based on Different Bonding Mechanisms

ABSTRACTIn this study, the hydroxyl modified hollow glass microsphere (HM‐HGM) is added to different foaming slurries of isocyanate‐based polyimide foam (IBPIF) at varying ratios, and different bonding effects are formed to optimize the dispersion behavior. Then, the novel HGM composited IBPIF (IBPIF/HGM) is prepared. Hydroxyl groups on HM‐HGM establish hydrogen bonding effect with pyromellitic acid dimethyl ester and dimethyl formamide in the white slurry and react with isocyanate groups in the black slurry. The cell structure of IBPIF is altered to improve its sound absorption performance and mechanical behaviors. Compared with IBPIF/HGM‐0, the average cell size of IBPIF/HGM‐1 and BPIF/HGM‐5 decreases significantly. The sound absorption performance and mechanical behaviors of them are improved to some extent. Compared with samples in which the HM‐HGM is added alone to a single slurry, when the dosage ratio of HM‐HGM in black and white slurries is 1:1, IBPIF/HGM‐3 has more uniform cell structure. The change of IBPIF cell structure by the introduction of HM‐HGM and the unique structure of HM‐HGM can enhance the sound absorption performance and mechanical behaviors of IBPIF. The design idea of different bonding mechanisms significantly provides technical assistance to enhance the acoustic performance of polymeric foam materials.

Preparation of Phosphorus/Hollow Silica Microsphere Modified Polyacrylonitrile-Based Carbon Fiber Composites and Their Thermal Insulation and Flame Retardant Properties

Since thermal insulation materials with a single function cannot satisfy the increasing requirements for complex usage, the combination of thermal insulation with flame retardancy is desirable in multiple applications. Herein, phosphorous-containing flame retardant modifier (5.0 wt.%, 9.0 wt.%, and 13.0 wt.%) and hollow silica microsphere (130 nm of diameter) were composited with polyacrylonitrile-based carbon nanofibers via electrospinning technique. Electrospun phosphorous/silica/carbon nanofibers (P/HSM/CF) exhibited a uniform and clear fibrous structure (508, 170, and 1550 nm of average fiber diameter) with modified uniform and complete spherical silica. Reduced thermal conductivity (39.9–41.2 mW/m/K) and enhanced limiting oxygen index (29.5–33.5%) were achieved, enabling fire protection grade of fiber membrane from UL-94 V-1 grade to UL-94 V-0 grade efficiently. Moreover, favorable tensile strength (8.64–9.27 MPa) and elongation at break (43.28–48.54%) were obtained, presenting expected applications in structural components. The findings of this work provided a valuable reference for the fabrication of carbon nanofiber-based thermal insulation materials with excellent flame retardant and mechanical properties.

Layer-by-Layer Deposition of Hollow TiO2 Spheres with Enhanced Photoelectric Conversion Efficiency for Dye-Sensitized Solar Cell Applications

Fabricating photoanodes with a strong light-scattering effect can improve the photoconversion efficiency of dye-sensitized solar cells (DSSCs). In this work, a facile microwave hydrothermal process was developed to prepare Au@TiO2 core–shell nanostructures, and then the Au core was removed by etching, resulting in hollow TiO2. Morphological characterizations such as field emission scanning and transmission electron microscopy measurements have been used for the successful formation of core–shell and hollow TiO2 nanostructures. Next, we attempted to deposit the different-sized hollow TiO2-based microspheres simultaneously on the surface of small-sized TiO2 nanoparticles-based compact film as light-scattering layers via electrophoretic deposition. The deposited hollow TiO2 microspheres constitute bi- and tri-layers that not only improve the light-harvesting properties but also speed up the photogenerated charge transfer. Compared to commercial TiO2 compact film (4.75%), the resulting bi-layer and tri-layered films-based DSSCs displayed power conversion efficiencies of 6.33% and 8.08%, respectively. It is revealed that the deposited bi- and tri-layered films can enhance the light absorption ability via multiple photon reflection. This work validates a novel and controllable strategy to develop light-scattering layers with increased light-harvesting properties for highly efficient dye-sensitized solar cells.

Innovative development of high-performance aerogel-phosphogypsum thermal insulation mortars: Optimization of composition and enhanced mechanical properties

This study investigates the effects of various components on the performance of aerogel-phosphogypsum (APG) thermal insulation mortar. This study investigates the effects of various components on the performance of aerogel-phosphogypsum (APG) thermal insulation mortar, with a special focus on optimizing the composition to enhance mechanical properties. The parametric range explored included phosphogypsum content from 10 to 30 wt%, hollow glass microspheres (HGS) from 5 to 15 wt%, and aerogel slurry from 40 to 80 wt%. Our findings reveal that the optimal composition, which provided the best balance between thermal insulation and mechanical strength, consisted of 20 wt% phosphogypsum, 10 wt% HGS, and 60 wt% aerogel slurry. Notably, the introduction of 0.14 % hydroxypropyl methylcellulose (HPMC) and 1.89 % re-dispersible polymer powder (RPP) significantly enhanced the compressive strength of the mortars. Specifically, compressive strength increased from an initial 0.05 MPa–0.27 MPa post-enhancement with HPMC and RPP. This research provides a detailed understanding of how individual components influence the formulation of APG and offers insights for optimizing the overall performance of aerogel-phosphogypsum composites, contributing to advancements in sustainable building materials.

Enhancing fire resistance of lightweight high-performance cementitious composites using hollow microspheres

Fire is detrimental to skyscrapers. Lightweight high-performance concrete (L-HPC) developed by combining lightweight microspheres and ultra-high-performance concrete binder is promising for future mega infrastructure projects. This study investigates the fire resistance of lightweight high-performance cementitious composites developed using hollow ceramic microspheres (HCMs) and hollow glass microspheres (HGMs) at different temperatures. Experimental results show that incorporating lightweight microspheres significantly increases the residual compressive strength of L-HPC by maintaining those of HGMs and HCMs groups at 92% and 78%, respectively, at 900 °C. Furthermore, these lightweight microspheres effectively mitigate thermal spalling and crack propagation in L-HPC. Microstructural analysis indicates that the lightweight microspheres facilitate steam-pressure release. The melting of HGMs realizes interconnections in the pore channel, which are subsequently strengthened by HGM and matrix-binder reactions. The HCMs feature perforated shells that provide inert and high-temperature-resistant steam channels. This study confirms that L-HPC developed using the abovementioned strategy exhibits excellent fire resistance.

Ultra-lightweight asymmetric hierarchical porous structure for high-efficiency absorption-dominated electromagnetic interference shielding

In this work, ultra-lightweight composite aerogels with a hierarchical pore structure consisting of hollow Fe3O4 microspheres (∼250 nm), hollow MXene microspheres (∼580 nm) and pores (10∼40 μm) in polyimide (PI) aerogel are developed through directional freezing, followed by freeze drying and thermal annealing. The composite aerogels exhibit a distinct asymmetric structure, with a top Fe3O4/PI aerogel layer designed for impedance matching and a bottom MXene/PI aerogel layer aimed at enhancing attenuation. This deliberate structure design not only reduces the density of the composite aerogels but also greatly enhances their absorption of electromagnetic waves. The composite aerogel demonstrates an impressive X-band EMI SE of 69.7 dB, a remarkable absorption coefficient (A) of 0.73, and an excellent surface-specific SE (SE divided by material density and thickness) of 13352 dB cm2 g-1, achieved at a density of just 0.034 g/cm³. Moreover, the composite aerogel exhibits outstanding stability in compression and shielding performance. Following 100 cycles of compression, the compressive strength remains at 94.9% of the initial compressive strength (98 kPa), and its EMI SE maintains 68.5 dB with a retention rate of 98.2%. Additionally, the composite aerogel presents outstanding thermal insulation (0.046 W m-1 K-1) and thermal resistance (initial decomposition temperature > 500 °C). This work provides novel insights into the design and fabrication of ultra-lightweight and absorption-dominated EMI shielding materials.

Fabrication of hollow Fe3O4 microspheres encapsulated by single-walled carbon nanohorns for high-performance microwave absorption

Due to the increasingly serious electromagnetic radiation and pollution problems, it is urgent to develop high-performance electromagnetic wave absorbing materials. Herein, the hollow Fe3O4 microspheres encapsulated by single-walled carbon nanohorns (H-Fe3O4@SWCNHs) have been synthesized via facile solvothermal approach. The obtained H-Fe3O4@SWCNHs composite exhibits a unique hollow core-shell structure and superior microwave absorption performance. When the matching thickness is 2.0 mm, the composite shows a minimum reflection loss value of −42.2 dB at 13.6 GHz and a maximum effective absorption broadband value of 6.2 GHz covering from 11.8 to 18 GHz. The excellent microwave absorption performance of the H-Fe3O4@SWCNHs composite is mainly attributed to the unique hollow core-shell structure, optimal impedance matching, and synergistic effects of dielectric loss and magnetic loss. Therefore, the present work provides a new kind of ideal microwave absorbing material with light weight, thin thickness, wide bandwidth and strong absorption capability for high-performance microwave absorption.

Hollow size optimization of α-MoC modified nitrogen-doped carbon spheres for efficient microwave absorption

Recently, electromagnetic pollution has become a serious concern. Existing microwave absorbers cannot achieve the goals of being lightweight, broadband, and strongly absorbing simultaneously. The design of hollow structures has attracted a great deal of attention because they can optimize impedance matching and enhance microwave attenuation while reducing mass. However, the effect of the hollow size on microwave absorption is not yet clear. In this study, we synthesized nitrogen-doped hollow carbon microspheres embedded with α-MoC nanoparticles (α-MoC/C, MNC) using template pyrolysis. The hollow size of MNC nanospheres was successfully controlled by adjusting the size of carboxylated PS nanospheres. The hollow structure improves microwave absorption in MNC nanospheres by facilitating the construction of the 3D conductive network. This prevents carbon aggregation, improves impedance matching, increases conductive loss, and promotes multiple reflections and scattering. Additionally, the α-MoC nanoparticles embedded in the carbon shells generate abundant nano-interfaces, which promote interfacial polarization and further attenuate the electromagnetic waves. The MNC-3 sample with the carbon sphere size of around 300 nm achieved the best reflection loss of −58.9 dB (3.16 mm thickness) and an effective absorption bandwidth of 4.80 GHz (2.07 mm thickness). This work demonstrates that the microwave absorption capacity of nanoscale carbonaceous spheres is effectively enhanced by adjusting the hollow size, providing the basis for designing and optimizing wave-absorbing materials by hollow structure.

Rheology, shrinkage, mechanical properties and microstructure of ultra-light-weight concrete with fly ash cenospheres

Cenospheres are low-density and hollow microspheres derived from coal-fired power plant fly ash waste. This study aims to prepare ultra-light-weight (<1000 kg/m3 wet density) concrete using fly ash cenospheres (FAC). To begin with, FAC’s shell thickness and the water absorption and desorption were characterized. A mixing procedure was designed to avoid the segregation between the FAC and cement slurry. FAC can affect the rheological properties of fresh mixture over time through absorption and desorption of free water. The presented ultra-light-weight concrete has several advantages compared to the ones prepared using foaming methods. First, shrinkage is significantly reduced due to FAC’s internal restraint and curing effects. Secondly, it has good mechanical performance, especially in bending and is more environmentally friendly due to use of less cement. X-ray computed tomography illustrates that FAC ultra-light-weight concrete has smaller pores of more uniform size compared with those prepared using foaming methods. X-Ray diffraction, thermal gravimetry-derivative thermal gravimetry, fourier-transform infrared spectroscopy and scanning electron microscopy are employed for the hydration products and microstructure characterization. Outcomes prove that FAC can combine well with the cement matrix, and react with calcium hydroxide to produce C-A-S-H through pozzolanic reaction.

Advances in Structural Design and Performance Regulation of Hollow Microspheres

Advances in Structural Design and Performance Regulation of Hollow Microspheres

Hollow glass microsphere/polybutadiene composites with low dielectric constant and ultralow dielectric loss in high‐frequency

AbstractHigh‐frequency dielectric materials have been widely and rapidly applied in areas such as automotive radar, Internet of Things, artificial intelligence, and quantum computing. Currently, the challenge in high‐frequency dielectric materials lies in reducing the dielectric constant (Dk) and dielectric loss (Df) without sacrificing its mechanical properties. This study addresses this challenge by introducing air, as the most common “low dielectric factor,” into the polymer matrix in the form of hollow glass microspheres. Meanwhile, the reactive vinyl groups were also introduced onto the surface of the hollow glass microspheres, enabling an interfacial chemical reaction between the side vinyl groups of polybutadiene and its surface so that the organic–inorganic interface compatibility and interface peel strength are simultaneously improved. Consequently, the minimum Dk of 1.29 and Df of 0.0012 in 3–18 GHz are achieved, and the interface peel strength also reaches 0.65 N/mm. Molecular dynamics simulations, analysis of dielectric properties, and interface peel strength reveal the influence of hollow glass microspheres' morphology and chemical structure on their high‐frequency dielectric performance and adhesive strength. This paper provides effective strategies for the structural design and preparation of high‐frequency, low‐dielectric composites, contributing to the further development of next‐generation microwave communication devices towards higher frequencies and faster information transmission.

Ultrawhite and ultrablack asymmetric coatings for radiative cooling and solar heating

Passive daytime radiative cooling, a zero-energy and zero‑carbon cooling technology, has significant potential to substantially reduce reliance on compression-based cooling systems, combat the urban heat island effect, and mitigate global warming. However, current radiative cooling materials either exhibit low efficiency or are susceptible to overcooling, resulting in cooling penalties on winter days. In this work, we designed and fabricated the ultrawhite and ultrablack asymmetric coatings. The top-layer, designed for efficient radiative cooling, consists of a porous polymethyl methacrylate and hollow silica microspheres composite. The underlayer, tailored for solar heating, is composed of a carbon nanotubes and carbon black composite. The cooling side with an exceptional solar reflectivity of 0.98 and a mid-infrared emissivity of 0.97 achieves a comparable daytime subambient cooling of 7.6 °C, with a theoretical net cooling power of 98.8 W/m2. Conversely, the heating side with a solar absorptivity of 0.96, a ultra-high visible light absorptivity of 0.985, and a mid-infrared emissivity of 0.97, results in a daytime above-ambient heating of 12.8 °C, corresponding to a theoretical net heating power of 745 W/m2. Promisingly, our ultrawhite and ultrablack asymmetric coatings hold the promise of addressing the long-standing challenge of all-season temperature regulation, offering significant potential for electricity savings and CO2 emission reduction.

Emerging SiO2@ATO hierarchical submicron hollow microspheres with efficient photo-thermal shielding properties

Silicon dioxide/antimony doped tin oxide (SiO2@ATO) submicron hollow microspheres were prepared by hydrothermal method. The morphology and microstructure of the microspheres were characterized by XRD, SEM, EDS and HRTEM. The composite coatings were prepared by adding SiO2@ATO powders to acrylic matrix, and their photothermal shielding properties were investigated. In addition, the electronic structure and optical properties of SiO2@ATO heterojunction were calculated and analyzed using first principle. The results show that the interface binding energy of SiO2@ATO is ∼2.496 J/m2, which indicates that the interface can exist stably. The light transmittance of the acrylic matrix coating with 1.0 wt% submicron hollow SiO2@ATO microspheres can reach about 83 %. Moreover, it was found that the hollow double-shell SiO2@ATO/acrylic matrix coating lowered the indoor temperature of the homemade incubator by 11.5℃. In summary, the SiO2@ATO structure shows potential in the application of transparent thermal insulation coatings.

Sulfonate-Bonded Conjugated Microporous Polymer Hollowed-Out Spheres to Capture Fluoroquinolone Antibiotics and Cationic Dyes from Wastewater.

Developing adsorbent materials for the efficient removal of multiple organic pollutants in water is of importance technological significance. In the present work, a kind of conjugated microporous polymer (CMP) with a hollow sphere structure was constructed by applying SiO2 nanoparticles as a template and 1,3,5-triethynylbenzene (TEB) and 2,7-dibromocarbazole (27-DBCZ) as building blocks via the Sonogashira-Hagihara cross-coupling reaction. In order to further improve the dispersibility of the as-resulting CMPs in water, hydrophilic CMPs (H-S-CMPs) were obtained by a sulfonation modification. The adsorption performance of H-S-CMPs on dyes and antibiotics was investigated, which was based on different experimental parameters such as the initial concentration, contact time, temperature, pH, and adsorbent dose. The adsorption isotherm, kinetics, and thermodynamics were also studied, and the possible adsorption mechanism of H-S-CMPs was discussed. The experimental results illustrated that the adsorption process of H-S-CMPs on dyes and antibiotics is more consistent with the Langmuir isotherm model and the pseudo-second-order kinetic model. The maximum adsorption capacities of H-S-CMPs for rhodamine B (RhB), methylene blue (MB), ciprofloxacin, and norfloxacin were 206.2, 324.7, 222.2, and 216.9 mg/g, respectively, which were determined according to the Langmuir isothern model. In addition, the adsorption mechanism of H-S-CMPs may be attributed to the synergistic effects of hydrogen bonding, electrostatic attraction, π-π stacking, and pore filling. After 5 cycles, H-S-CMPs still maintained good stability, and their removal rate of dyes could reach more than 70%. Notably, this polymeric hollow microsphere has been less extensively investigated as an adsorbent for the removal of dyes and antibiotics. As a result, based on the designable flexibility of CMPs and the unique structure of hollow microspheres, the material holds great promise for wastewater treatment in the presence of multiple pollutants.

Synthesis of chiral hollow polymer microspheres and their applications in the spectroscopic chiral discrimination of tryptophan isomers

Hollow polymer microspheres (HPMs) were synthesized, which were then hydrolyzed in aqueous ammonia to produce carboxyl (–COOH) groups on their surface. L-phenylalanine (L-Phe) was grafted to the hydrolyzed HPMs (H-HPMs) through amidation reactions, endowing the H-HPMs with chirality. The resultant chiral HPMs (C-HPMs) were used for the chiral discrimination of tryptophan (Trp) isomers. Due to the same rotatorydirection of L-Phe and L-Trp, the C-HPMs showed greatly higher selectivity toward L-Trp than its isomer. After being adsorbed by the C-HPMs, the absorbance of the residual L-Trp is significantly lower than that of the residual D-Trp, and thus spectroscopic chiral discrimination of the Trp isomers was successfully achieved. The Trp isomers were also discriminated by the chiral solid polymer microspheres (C-SPMs), while the difference in the absorbance of the residual L-Trp and D-Trp is remarkably smaller than that obtained by the C-HPMs. The outstanding discrimination capability of the C-HPMs might be ascribed to their high surface permeability resulted from their unique hollow structure.

Regulating the Electronic Structure of Cu Single-Atom Catalysts toward Enhanced Electro-Fenton Degradation of Organic Contaminants via 1O2 and •OH.

Heterogeneous electro-Fenton degradation with 1O2 and •OH generated from O2 reduction is cost-effective for the removal of refractory organic pollutants from wastewater. As 1O2 is more tolerant to background constituents such as salt ions and a high pH value than •OH, tuning the production of 1O2 and •OH is important for efficient electro-Fenton degradation. However, it remains a great challenge to selectively produce 1O2 and improve the species yield. Herein, the electronic structure of atomically dispersed Cu-N4 sites was regulated by doping electron-deficient B into porous hollow carbon microspheres (CuBN-HCMs), which improved *O2 adsorption and significantly enhanced 1O2 selectivity in electro-Fenton degradation. Its 1O2 yield was 2.3 times higher than that of a Cu single-atom catalyst without B doping. Meanwhile, •OH was simultaneously generated as a minor species. The CuBN-HCMs were efficient for the electro-Fenton degradation of phenol, sulfamethoxazole, and bisphenol A with a high mineralization efficiency. Its kinetic constants showed insignificant changes under various anions and a wide pH range of 1-9. More importantly, it was energy-efficient for treating actual coking wastewater with a low energy consumption of 19.0 kWh kgCOD-1. The superior performance of the CuBN-HCMs was contributed from 1O2 and •OH and its high 1O2 selectivity.

Waterborne novolac epoxy‐based thermal resistant and fire‐retardant thermal insulation coatings

AbstractWaterborne novolac epoxy based thermal resistant and fire‐retardant thermal insulation coatings were developed in this work. Novolac (phenolic) epoxy emulsion (PEE) was prepared by the phase inversion method based on formulation optimization by orthogonal array testing. The prepared emulsions have similar particle size, viscosity, and stability to commercial bisphenol a glycidyl ether epoxy emulsion (PZ). DSC results showed that the varnish film based on PEE had a higher glass transition temperature and initial thermal decomposition temperature compared with PZ cured by the same curing agent. Waterborne thermal insulation coating with PEE and PZ as binders and hollow glass microspheres (HGMs) as thermal insulation fillers were studied. The results indicated that the thermal conductivity of the coating decreased with an increase in HGMs content. Specifically, the thermal conductivity of the PEE coating containing 20 wt% HGMs is as low as 0.093 W/(m·K). It reduces the exterior temperature of the hot tank from approximately 200 °C to approximately 106 °C. Furthermore, the HGMs/PEE waterborne thermal insulation coating exhibits good thermal stability and flame retardance.

A multifunctional platform based on ZIF-67 templated NiCo-LDH and Fe3O4 hollow spheres for photocatalytic CO2 conversion and supercapacitors

This work presented a series of hybrid materials F@P-LDHs exhibiting the core-shell structure with PPy as the interface modifier, explored as dual-functional materials for studying photocatalytic reduction of CO2 and electrochemical behaviors. F@P-LDHs served as photocatalysts, effectively convert CO2 into CO without using any sacrificial agents and photosensitizers via the gas-solid mode under the visible light irradiation. The generation rate of CO was as high as 10.32 μmol g−1h−1, which was 5.4 and 6.4 times higher than the original Fe3O4@PPy and NiCo-LDH. The well performance might be ascribed to the generation of type Z heterojunction with the interface modifier PPy, jointly accelerating the separation and migration of photo-generated charge carriers between Fe3O4@PPy and NiCo-LDH. Besides, F@P-LDHs were also developed as supercapacitors, and their electrochemical behaviors were investigated. Their good electrochemical performances were attributed to the synergistic effect among hollow Fe3O4 microspheres, polypyrrole and NiCo-LDH. Therefore, as dual-functional materials, the hybrid materials have great potential in the field of CO2 conversion and supercapacitors.

Template-synthesized CdWO4/Cd0.5Zn0.5S hollow microsphere photocatalyst for high-efficient hydrogen evolution under visible light

Photocatalytic water splitting for hydrogen production is a promising strategy for renewable energy. While Cd1-XZnXS catalysts display high photocatalytic hydrogen evolution efficiency in pure water, they are limited by severe photocorrosion and rapid recombination of electron–hole pairs. In this study, HGM (hollow glass microspheres) was used as the support template, Cd0.5Zn0.5S and CdWO4 were successively coated on the template by hydrothermal method. The tightly packed heterojunction interface between the coatings ensures efficient electron transport and suppresses the recombination of electron-hole pairs. Under visible light irradiation, when the theoretical mass ratio of Cd0.5Zn0.5S to CdWO4 is 4:1, the Cd0.5Zn0.5S/CdWO4-25% hollow microsphere photocatalyst exhibits the highest hydrogen evolution rate, reaching 41.40 mmol g−1 h−1, which is approximately 3.4 times higher than the hydrogen evolution rate of pure Cd0.5Zn0.5S (12.31 mmol g−1 h−1). This research provides a novel approach for the design and synthesis of efficient and stable photocatalysts.

Experimental study on the improvement of bamboo properties using amide polymer repair material based on the principle of self-energy dissipation

Traditional bamboo and wood components have different holes due to their own and external factors, and the appropriate hole repair technology is the key to improve the component's energy dissipation capacity. In this paper, based on the principle of in-situ free radical polymerization and hollow glass microsphere (HGM) reinforced polymer, PAM hydrogel (PAMHG) with better deformation recovery ability and PAM/HGM amide polymer (AP) with better mechanical properties were prepared. Based on the principle of self-energy dissipation of components, AP is used to improve the deformation capacity of hollow bamboo. The ratio of PAMHG and AP was optimized by single factor test and orthogonal test. The performance of AP was verified by bending test, SEM, energy consumption analysis，durability test and statistical analysis of small diameter round bamboo. The size of the bamboo sample is 250 mm (L)×15 mm (D)×2.5 mm (t), in accordance with LY/T 3347–2023 " Testing methods for physical and mechanical properties of small diameter round bamboo " (China). The results showed that an appropriate amount of glycerol could effectively improve the volume stability of the hydrogel. HGM effectively improved the strength of the polymer, and when the mass ratio of HGM/PAM was 0.48, the maximum compressive strength was 0.8 MPa, which was 2.4 times higher than that of the undoped HGM, and at this time, the optimal polymer ratios were 25 g of AM, 1 g of MBA, 0.01 g of APS, 2 g of TEA, 2 g of Carbomer SF-1, a volume ratio of 1:1 of glycerol/deionized water that the dispersion medium was 70 ml, and HGM was 12 g. The average energy dissipation of grouted bamboo at ultimate load was 2.02 times that of the control group, and the highest bending strength and elastic modulus were 128.01 MPa and 11.24 GPa, which were 41.39 % and 39.75 % higher than that of the control group, respectively. The SEM results revealed that the AP partially prepolymerized solution could infiltrate into the cells and pores of the bamboo material to achieve filling, bonding, as well as reinforcing the bamboo tissue. In addition, the durability test shows that AP has good resistance to environmental pressure. The results of this paper can provide a reference for the restoration materials of bamboo and wood components.